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 Degree Level: Master's
 Collection: UNT Theses and Dissertations
Baeyer-Villiger Oxidation of 1,7- & 1,9-dibromopentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione

Baeyer-Villiger Oxidation of 1,7- & 1,9-dibromopentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione

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Date: May 2004
Creator: Akinola, Adeniyi O.
Description: Baeyer-Villiger oxidation of 1,9-dibromopentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione (1,9-dibromo-PCU-8,11-dione) was performed by using an excess amount of m-chloroperbenzoic acid (3 equivalents) and resulted in the formation of the corresponding monolactone. The reaction would not proceed to the dilactone stage. The structure of the reaction product was established unequivocally via single crystal X-ray diffraction. Baeyer-Villiger oxidation of 1,9-dibromo-PCU-8,11-dione using ceric ammonium nitrate (CAN) was also performed and afforded a mixture of lactones. Only one of these lactones, which also contained an alkene functionality, could be isolated and characterized. 1,7-dibromo-PCU-8,11-dione was also reacted with CAN, yielding the mono-lactone, which has also been characterized.
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True Selves: Narrative Distance in Stories of Fiction and Nonfiction

True Selves: Narrative Distance in Stories of Fiction and Nonfiction

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Date: December 2009
Creator: Al-Qasem, Ruby
Description: True Selves: Narrative Distance in Stories of Fiction and Nonfiction consists of a scholarly preface and four creative works. The preface discusses narrative distance as used in both fiction and nonfiction, and as compares to other narrative agents such as point of view, especially in contemporary creative writing. The selection of stories examines relationships, especially familial, and themes of isolation, community, and memory. Collection includes two chapters of a novel-in-progress, Fences, short fiction story "Trees and Furniture," and creative nonfiction essays, "Floating" and "On the Sparrow."
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Comparison and Evaluation of Existing Analog Circuit Simulator using Sigma-Delta Modulator

Comparison and Evaluation of Existing Analog Circuit Simulator using Sigma-Delta Modulator

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Date: December 2006
Creator: Ale, Anil Kumar
Description: In the world of VLSI (very large scale integration) technology, there are many different types of circuit simulators that are used to design and predict the circuit behavior before actual fabrication of the circuit. In this thesis, I compared and evaluated existing circuit simulators by considering standard benchmark circuits. The circuit simulators which I evaluated and explored are Ngspice, Tclspice, Winspice (open source) and Spectre® (commercial). I also tested standard benchmarks using these circuit simulators and compared their outputs. The simulators are evaluated using design metrics in order to quantify their performance and identify efficient circuit simulators. In addition, I designed a sigma-delta modulator and its individual components using the analog behavioral language Verilog-A. Initially, I performed simulations of individual components of the sigma-delta modulator and later of the whole system. Finally, CMOS (complementary metal-oxide semiconductor) transistor-level circuits were designed for the differential amplifier, operational amplifier and comparator of the modulator.
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Iconoclast in the mirror.

Iconoclast in the mirror.

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Date: August 2005
Creator: Alexander, Lydia L.
Description: This work explores identity positions of speakers in modern and contemporary poetry with respect to themes of subjectivity, self-awareness, lyricism, heteroglossia, and social contextualization, from perspectives including Bakhtinian, queer, feminist and postructuralist theories, and Peircian semiotics. Tony Hoagland, W.H. Auden, Adrienne Rich, and the poetic prose of Hélène Cixous provide textual examples of an evolving aesthetic in which the poet's self and world comprise multiple dynamic, open relationships supplanting one in which simple correspondences between signifiers and signifieds define selves isolated from the world. Hypertext and polyamory serve as useful analogies to the semantic eros characteristic of such poetry, including the collection of original poems that the critical portion of this thesis introduces.
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An Examination of Methodological Rigor and Its Effects on Organizational Development and Change Outcomes

An Examination of Methodological Rigor and Its Effects on Organizational Development and Change Outcomes

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Date: May 2005
Creator: Alexander, Sandra G.
Description: Organizational development and change (ODC) is a broad field because change occurs in all organizations, occurs at multiple organizational levels, consists of numerous interventions, and can impact multiple outcomes. Many ODC efforts attempt to examine the effectiveness of their initiatives, yet fail to account for the quality, or rigor of their methods. The purpose of this paper is to examine how methodological rigor and intervention implementation quality impact ODC outcomes. The results indicate that overall methodological rigor is not a significant predictor of organizational change outcomes; however, several individual rigor criteria exhibit predictive power. Implementation quality is a significant predictor of organizational outcomes, but in a negative direction.
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Novel Role of Trypsin in Zebrafish

Novel Role of Trypsin in Zebrafish

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Date: May 2013
Creator: Alsrhani, Abdullah Falleh
Description: It has been shown previously in our laboratory that zebrafish produce trypsin from their gills when they are under stress, and this trypsin is involved in thrombocyte activation via PAR2 during gill bleeding. In this study, I investigated another role of the trypsin that is secreted from zebrafish. This investigation has demonstrated a novel role of trypsin in zebrafish. Not only did this investigation demonstrate the role of trypsin in zebrafish behavior, but also it showed that PAR2 might be the receptor that is involved in trypsin-mediated behavioral response. In addition, we have shown that Gq and ERK inhibitors are able to block the trypsin pathway and prevent the escaping behavior. Finally, the results of this investigation suggest that the cells that respond to trypsin are surface cells, which have an appearance similar to that of neuromast cells.
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Integrating life cycle analysis and the ecological footprint calculator to foster sustainable behaviors

Integrating life cycle analysis and the ecological footprint calculator to foster sustainable behaviors

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Date: December 2002
Creator: Anderle, Kathryn
Description: Many tools have been developed to assess global, national or regional sustainable development policies. However, as governments develop sustainable policies, individuals must also feel empowered to affect their personal impact on the planet. This thesis integrates three sustainability concepts that lend themselves to individual sustainability: The natural step, life cycle assessment, and the ecological footprint. TNS serves to provide the meaning and substance toward sustainable development. LCA helps provide the framework for assessing sustainability. The EF calculator determines the driving components and measures the qualitative decisions made through TNS and LCA. From the analysis of the household footprint calculator a simplified footprint calculator was developed to assist individuals and communities in setting benchmarks and goals as they move away from over-consumption and towards a sustainable lifestyle.
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Stretched Out On Her Grave: The Evolution of a Perversion

Stretched Out On Her Grave: The Evolution of a Perversion

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Date: August 2000
Creator: Angel-Cann, Lauryn
Description: The word "necrophilia" brings a particular definition readily to mind – that of an act of sexual intercourse with a corpse, probably a female corpse at that. But the definition of the word did not always have this connotation; quite literally the word means "love of the dead," or "a morbid attraction to death." An examination of nineteenth-century literature reveals a gradual change in relationships between the living and the dead, culminating in the sexualized representation of corpses at the close of the century. The works examined for necrophilic content are: Mary Wollstonecraft’s Mary, A Fiction, Mary Shelley’s Frankenstein, Emily Brontë’s Wuthering Heights, and Bram Stoker’s Dracula and The Jewel of Seven Stars.
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Barriers Limiting Access to Hospice Care for Elderly African Americans in Amarillo, Texas

Barriers Limiting Access to Hospice Care for Elderly African Americans in Amarillo, Texas

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Date: August 2001
Creator: Anthony, Tomagene
Description: This study examines barriers limiting access to hospice care for elderly African Americans. Ethnic background plays a critical role in the development of attitudes, beliefs and expectations related to death and issues surrounding hospice care. The purpose of this study was to identify barriers that may limit access to hospice care for African Americans. A questionnaire was administered to 56 elderly African Americans in three religious settings and an African American senior citizens center. The questionnaire was designed to obtain information concerning African Americans' attitudes toward death and dying; religious beliefs; health beliefs; familiarity with hospice and prospective use of hospice. The results of the study indicate a number of barriers in access to hospice care for African Americans including: hospice knowledge barriers; education/outreach barriers; cultural knowledge barriers related to death/dying values; family/social support barriers; hospice organizational/provider barriers; health care organizational/provider barriers; and reimbursement barriers.
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Evaluation of virulence in wild type and pyrimidine auxotrophs of  Pseudomonas aeruginosa using the eukaryotic model system  Caenorhabditis elegans.

Evaluation of virulence in wild type and pyrimidine auxotrophs of Pseudomonas aeruginosa using the eukaryotic model system Caenorhabditis elegans.

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Date: August 2004
Creator: Anvari, Sara
Description: The human opportunistic pathogen, Pseudomonas aeruginosa PAO1, has been shown to kill the nematode Caenorhabditis elegans. C. elegans has been a valuable model for the study of bacterial pathogenesis, and has reinforced the notion that common virulence and host defense mechanisms exist. Recently, the pyrimidine pathway was shown to regulate virulence levels. Therefore, mutations in the pyrimidine pathway of PAO1 showed decrease virulence in the nematode. When starving the nematode, bacterial resistance was also shown to increase. It was hypothesized that starvation induced the DAF pathway, which regulates the transcription of genes involved with the antibacterial defense mechanism. Further research will be conducted to test this theory by performing RNAi experiments for the genes functioning in the antibacterial defense mechanism.
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Inquiry-based science for high school students: a forensic unit

Inquiry-based science for high school students: a forensic unit

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Date: August 2000
Creator: Apple, Kendra Kea
Description: This project constitutes an instructional unit for honors biology that involves the use of science in the field of criminal investigation and forensics. Before beginning the unit, the learners should have mastered basic laboratory skills, including use of the microscope. They should also have an understanding of the basic structure and function of DNA and its role in heredity and protein synthesis. The standard time frame is 24 days with 70-minute periods, but can be easily adjusted to meet classroom needs. Several instructional strategies enhance student learning and make science fun. The unit is inquiry-driven and activity-based. Students are surprised by the crime, gather and analyze evidence, and work towards proposing an explanation. This real world problem involves the use of cooperative learning and a variety of assessment techniques.
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Development of a Coaxiality Indicator

Development of a Coaxiality Indicator

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Date: December 1999
Creator: Arendsee, Wayne C.
Description: The geometric dimensioning and tolerancing concept of coaxiality is often required by design engineers for balance of rotating parts and precision mating parts. In current practice, it is difficult for manufacturers to measure coaxiality quickly and inexpensively. This study examines feasibility of a manually-operated, mechanical device combined with formulae to indicate coaxiality of a test specimen. The author designs, fabricates, and tests the system for measuring coaxiality of holes machined in a steel test piece. Gage Repeatability and Reproducibility (gage R&R) and univariate analysis of variance is performed in accordance with Measurement System Analysis published by AIAG. Results indicate significant design flaws exist in the current configuration of the device; observed values vary greatly with operator technique. Suggestions for device improvements conclude the research.
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The Apologist Tradition: A Transitional Period in Southern Proslavery Thought, 1831-1845

The Apologist Tradition: A Transitional Period in Southern Proslavery Thought, 1831-1845

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Date: December 2000
Creator: Austin, Clara
Description: Early antebellum defenders of slavery acknowledged that slavery created problems for southern society. They contended, however, that slave society was better and more natural than other forms of social organization. Thomas R. Dew, William Harper, and James Henry Hammond each expressed a social philosophy in which slavery had a crucial role in preserving social order. They argued from the basis of social organicism, the idea that society should have an elite that controlled the masses. For all three men, slavery represented a system of order that helped balance the dangers of democracy. Significantly, however, all three men recognized that the slave system was not perfect, and despite their defense of slavery, argued that it was a human institution and therefore corruptible.
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A model for designing a new telecommunication system in Mongolia

A model for designing a new telecommunication system in Mongolia

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Date: May 2001
Creator: Baatarjav, Enkhbat
Description: The objective of this research is to design, and determine the feasibility of, a telecommunication system for the city of Erdenet, Mongolia. The Mongolian Telecommunication Company, Telecommunication Company of Erdenet city, and the National Statistical Office of Mongolia provided the data required for telecommunication forecasting of Erdenet. The literature review and analysis of the telecommunication forecasting indicate the need for a model of a new Telecommunication system in Erdenet, Mongolia. The model, as indicated, should become a useful example for planning and updating the telecommunication system in Mongolia. The design of a proposed telecommunication network involves the following considerations: analyzing and forecasting telephone traffic, calculating the required number of channels, determining exchange locations, traffic matrix, and establishing a basic hierarchical structure.
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Personality Correlates of Eating Disorder Symptomatology in a Nonclinical Sample of Female Undergraduates

Personality Correlates of Eating Disorder Symptomatology in a Nonclinical Sample of Female Undergraduates

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Date: May 2003
Creator: Baker, Kristine Genovese
Description: Research indicates the existence of an eating disorder continuum. The two-component model of disordered eating suggests that certain personality traits may increase an individual's vulnerability to develop more severe variants of disordered eating symptomatology. The present study investigates pre-clinical elevations on a measure of personality based on the Five-Factor Model (FFM) and pre-clinical elevations on a measure of eating disorder symptomatology in a sample of nonclinical undergraduates. The personality dimensions Neuroticism, Extraversion, and Agreeableness accounted for 7% of the variability in Body Dissatisfaction. Subcomponents comprising the personality dimensions of the FFM as determined by Saucier (1998) (see Appendix A) were analyzed. The Self-Reproach and Intellectual Interests subcomponents were the strongest predictors of Drive for Thinness and Body Dissatisfaction. The subcomponent Sociability was the strongest predictor of Bulimia. Findings present implications for prevention and treatment interventions. Longitudinal studies are needed to determine the temporal directionality of personality and disturbed eating.
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A New N-way Reconfigurable Data Cache Architecture for Embedded Systems

A New N-way Reconfigurable Data Cache Architecture for Embedded Systems

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Date: December 2009
Creator: Bani, Ruchi Rastogi
Description: Performance and power consumption are most important issues while designing embedded systems. Several studies have shown that cache memory consumes about 50% of the total power in these systems. Thus, the architecture of the cache governs both performance and power usage of embedded systems. A new N-way reconfigurable data cache is proposed especially for embedded systems. This thesis explores the issues and design considerations involved in designing a reconfigurable cache. The proposed reconfigurable data cache architecture can be configured as direct-mapped, two-way, or four-way set associative using a mode selector. The module has been designed and simulated in Xilinx ISE 9.1i and ModelSim SE 6.3e using the Verilog hardware description language.
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Application of Cyclic Polarization of Aluminum 3003 Used in All-aluminum Microchannel Heat Exchangers

Application of Cyclic Polarization of Aluminum 3003 Used in All-aluminum Microchannel Heat Exchangers

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Date: May 2015
Creator: Barnes, Javier
Description: All-aluminum microchannel heat exchangers are designed to significantly reduce refrigerant charge requirements, weight, reduced brazed joints, and decreased potential for leakage by increasing reliability. Al 3003 alloy is corrosion resistant and can be formed, welded, and brazed but the issue with all-aluminum heat exchangers is localized corrosion (pitting) in corrosive environments. Currently, there is no universally accepted corrosion test that all coil manufacturers use to characterize their products. Electrochemical testing method of cyclic polarization was employed in this investigation and relevant parameters including electrolyte corrosive agent and its concentration, electrolyte pH, and applied potential scan rate was varied to find an optimal set of parameters. Results of cyclic polarization of Al 3003 in electrolytes containing various concentrations of NaCl were compared with those of the tests in Sea Water Acidified Accelerated Test (SWAAT) electrolyte and it is shown the SWAAT electrolyte (4.2% sea salt acidified to pH of 2.9) is by far stronger (in terms of corrosivity) than typical 3.5% NaCl solution used in most corrosion testing. Corrosion rates (g/m2yr) of Al 3003 measured in this investigation were comparable to those provided by ISO 9223 standard corresponding to C1 through CX categories. Duration of cyclic polarization test is much shorter ...
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Organizational development: A comparison of individual and organizational level change.

Organizational development: A comparison of individual and organizational level change.

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Date: August 2005
Creator: Barnett, Michelle L.
Description: Organizational change and development (OCD) has been studied by researchers to identify the effectiveness of change initiatives. Because of the broad scope of interventions in OCD, these studies have covered a range of areas including multiple interventions and the methodological rigor used by researchers. However, few have looked at organizational versus individual change within an organization, to examine whether individual change is more effective than organizational change. The purpose of this study is to determine if organizational change occurs in a top down or bottom up manner. A meta-analysis was conducted using 238 field experiments. Each study was coded for intervention and organizational outcome and for individual or organizational level variables. Effect sizes were calculated for each study, each level, and each level by intervention and outcome measure. Results indicate that while OCD interventions overall had a moderate effect size, the level of intervention or outcome was not a moderating variable.
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Clutch

Clutch

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Date: August 2009
Creator: Bauge, Jessica M.
Description: Clutch is the title of the creative portion of my thesis as well as the name of my theory 'clutch' which I outline in the preface section. The purpose of the clutch theory is to recognize modes of inspiration in the body, heart and mind so that the poet can consciously move beyond passive receptivity to engage inspiration more fully. Mechanically, to "clutch" does not mean to create inspiration, but it is the opportunistic, spirited encouragement of these moments of inspiration and, more importantly, the direction of the artist's own response in moving from inspiration to creation. The clutch process unfolds through three centers: body, heart and mind, where we initially encounter inspiration. And, through a discussion of three notable poets' work, Henri Cole, Li-Young Lee and T.S. Eliot, the relationship between a completed work and clutch as a process further explains the boundaries of each mode.
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James Earl Rudder: A Lesson in Leadership

James Earl Rudder: A Lesson in Leadership

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Date: December 2003
Creator: Bean, Christopher B.
Description: This thesis is the about the life of Rudder. The emphasis of this work, however, is that Rudder was successful primarily because of his character and leadership style. Much of the study was drawn from primary sources. Secondary sources were also consulted. This thesis opens with a brief Introduction, which discusses the need for this work. Chapter 1 discusses Rudder's life prior to WW II, emphasizing particular characteristics that benefited his leadership ability. Chapter 2 examines the 2nd Ranger Battalion's transformation under Rudder's leadership and guidance. Chapter 3 chronicles the 2nd Ranger Battalion's assault on the Pointe du Hoc battery, ending in December 1944, when Col. Rudder was reassigned to the 109th Infantry Regiment. Moreover, the controversy surrounding the Ranger's mission is also examined in this chapter. Chapter 4 describes Col. Rudder's leadership with the 109th in the Battle of the Bulge. A chapter accounting Rudder's political career and leadership follows. Chapter 6 examines his term as chancellor and president of the Texas A&M University system, until his death in 1970, and the major institutional changes that he enacted during his tenure, which resulted in A&M becoming the respected research university it is today. This significance and recapitulation of Rudder's ...
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Reflections of Other/Reflections of Self

Reflections of Other/Reflections of Self

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Date: August 2002
Creator: Bebout, Lee
Description: This Thesis collection contains a critical preface and five stories. The preface, “Reflejos y Reflexiones” (translated: Images and Thoughts), addresses the issues of writing the cultural or gendered Other; these issues include methodology, literary colonialism, a dialogue between works, and creating distance through defamiliarizing the self. “Perennials” is the story of Noemi Tellez, an immigrant to the U.S. who must choose between working and taking care of her family. In “Load Bearing” Luis, the eldest child, faces his family and friends on one of his last days before moving away to college. “La Monarca” deals with Lily's, the youngest daughter, struggle to mediate a place between her friends and her family. In “Reflections in the River,” Arabela, the second youngest, faces the ghost of an unwanted pregnancy and La Llorona. “La Cocina de Su Madre” is the story of Magda, the oldest daughter, and her own teenage girl, Natalia, as they attempt to find themselves in a new town after moving a thousand miles from home.
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A morphological study of the avian (Gallus domesticus) ductus arteriosi during hatching.

A morphological study of the avian (Gallus domesticus) ductus arteriosi during hatching.

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Date: May 2006
Creator: Belanger, Candace
Description: The ductus arteriosi (DA) are two blood vessels connecting the pulmonary arteries to the descending aorta in the avian embryo. Following hatching, the DA closes, separation of the systemic and pulmonary circulation. I present the morphological changes that occur in the chicken DA during prepipping, internal pipping, external pipping, and hatching. The avian DA consists of two distinct tissue types, a proximal and a distal portion. Histological examination shows developmental differences between the proximal and distal portions of the DA with regard to lumen occlusion, endothelial cells, smooth muscle and elastin. Endothelial cell proliferation begins to occur as early as external pipping, with the lumen almost completely occluded by the 3rd day of post-hatching life. Expression of vascular endothelial growth factor (VEGF) increases in avian endothelial cells during hatching. I provide a morphological timeline of changes in the DA as the chicken develops from embryo to hatchling.
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Evidentiary Value of Condoms: Comparison of Durable Physical and Chemical Characteristics of Condoms

Evidentiary Value of Condoms: Comparison of Durable Physical and Chemical Characteristics of Condoms

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Date: May 2000
Creator: Belcher, Kelly Leigh
Description: Condom trace evidence must not be overlooked in sexual assault cases; understanding the chemical and physical characteristics of condoms is imperative if condoms are to be useful evidence. Previous research shows that condom identification is possible, but it is equally important to evaluate durability of condom residues versus time. Using FT-IR, this study examined vaginal swabs from subjects who self-sampled at intervals for up to 72 hours after having intercourse with a condom. This study investigated whether age and the stage of the menstrual cycle affected the durability of residues in the vagina over time. This study revealed that condoms containing nonoxynol-9, silicone-based lubricants, and particulates provide valuable information for identification, and that nonoxynol-9 specifically withstands the vaginal environment for up to 72 hours. Additionally, age and menstrual cycle both appeared to have an effect on the durability of residues although larger sample size is desirable.
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The “Nigger Trinity”: Engaging the Discourse in Post Civil Rights/Post 1960s America

The “Nigger Trinity”: Engaging the Discourse in Post Civil Rights/Post 1960s America

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Date: December 2011
Creator: Bell, Adrian Shane
Description: The cultural and popular media landscape of the United States of America changed after the Civil-Rights movement of the 1960s. The word “Nigger” was changed during that same period of American history. There are several authors and a comic that helped change this word during the 1960s. The post Civil-Rights American has a different experience and understanding with this word than those born before 1970. This work triangulates the current cultural location of the word “Nigger,” “nigga,” and “the n-word” using linguistics, law, and two media case studies. The “Nigger” trinity is a model that adds value to the discourse that surrounds this one word in post civil-rights/post 1960s America.
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