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China’s National Climate Change Programme
Government of China hereby formulates China’s National Climate Change Programme, outlining objectives, basic principles, key areas of actions, as well as policies and measures to address climate change for the period up to 2010. Guided by the Scientific Approach of Development, China will sincerely carry out all the tasks in the CNCCP, strive to build a resource conservative and environmentally friendly society, enhance national capacity to mitigate and adapt to climate change, and make further contribution to the protection of the global climate system. digital.library.unt.edu/ark:/67531/metadc501461/
Climate Change 2014 Synthesis Report
This Synthesis Report is based on the reports of the three Working Groups of the Intergovernmental Panel on Climate Change (IPCC), including relevant Special Reports. It provides an integrated view of climate change as the final part of the IPCC’s Fifth Assessment Report (AR5). This summary follows the structure of the longer report, which addresses the following topics: Observed changes and their causes; Future climate change, risks and impacts; Future pathways for adaptation, mitigation and sustainable development; Adaptation and mitigation. digital.library.unt.edu/ark:/67531/metadc501489/
China's Policies and Actions for Addressing Climate Change (2012)
The Chinese government attaches great importance to the issue of climate change.It defines the objectives, tasks and policy orientation of China’s response to climate change over the next five years and identifies key tasks, including controlling greenhouse gas emissions, adapting to climate change, and strengthening international cooperation. digital.library.unt.edu/ark:/67531/metadc501479/
The Hexagon, Volume 104, Number 4, Winter 2013
Quarterly publication of the Alpha Chi Sigma chemistry fraternity containing articles related to chemistry research and the activities of the organization, including local chapters and groups. digital.library.unt.edu/ark:/67531/metadc501459/
The Hexagon, Volume 105, Number 2, Summer 2014
Quarterly publication of the Alpha Chi Sigma chemistry fraternity containing articles related to chemistry research and the activities of the organization, including local chapters and groups. digital.library.unt.edu/ark:/67531/metadc501452/
The Evolution of Publishing Agreements at the University of Michigan
Article on the evolution of publishing agreements at the University of Michigan Library. Taking as an example an open-access journal with a single editor, this article discusses the various configurations of rights agreements used by the University of Michigan Library throughout the evolution of its publishing operation, the advantages of the various models, and the reasons for moving from one to another. digital.library.unt.edu/ark:/67531/metadc501458/
The Evolution of Publishing Agreements at the University of Michigan Library
Book chapter on the evolution of publishing agreements at the University of Michigan Library. Taking as an example an open-access journal with a single editor, this chapter discusses the various configurations of rights agreements used by the University of Michigan Library throughout the evolution of its publishing operation, the advantages of the various models, and the reasons for moving from one to another. digital.library.unt.edu/ark:/67531/metadc501437/
Enhancing Access to E-books
Article on a study of enhancing access to e-books. digital.library.unt.edu/ark:/67531/metadc501455/
Joseph Paul Vejvanovsky Sonata Tribus
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Pavel Joseph Vejvanovsky,(composer ca. 1640-1693) - Play ... Sonata Tribus for Trumpet, Trombone, Violin, and Bass Continuo ... digital.library.unt.edu/ark:/67531/metadc501429/
Joseph Paul Vejvanovsky Sonata XXIX
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Joseph Paul Vejvanovsky,(composer ca. 1640-1693) - Play ... Sonata XXIX for Trumpets, Trombone, 2 Violins, Viola, and Bass Continuo ... digital.library.unt.edu/ark:/67531/metadc501434/
Concerto a VII Clarini con Tymp.
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Johann Ernst Altenburg has been called «the last representative of the heroic guild of trumpeters and timpanists.» Born in Weissenfels on June 15, 1734, he was apprenticed to his father Johann Caspar Altenburg (1689-1761) at the tender age of two and released from his articles as a trumpeter sixteen years later. ... digital.library.unt.edu/ark:/67531/metadc501431/
Johann Heinrich Schmelzer Sonata à 3
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Philipp Jakob Rittler (composer ca. 1637-1690) - Play streams in full ... Sonata a 17, for 6 trumpets, 3 trombones, 2 violins, 3 violas, timpani and continuo ... digital.library.unt.edu/ark:/67531/metadc501432/
Joseph Paul Vejvanovsky Sonata à 4 in g Minor
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Pavel Joseph Vejvanovsky,(composer ca. 1640-1693) - Play ... Sonata à 4 in g Minor for Trumpet, Strings, and Bass Continuo ... digital.library.unt.edu/ark:/67531/metadc501430/
Philipp Jakob Rittler Sonata à 18
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Philipp Jakob Rittler (composer ca. 1637-1690) - Play streams in full ... Sonata a 18, for 6 trumpets, 3 trombones, 2 violins, 3 violas, timpani and continuo ... digital.library.unt.edu/ark:/67531/metadc501433/
Philipp Jakob Rittler Sonata à 17
Access: Use of this item is restricted to the UNT Community.
Philipp Jakob Rittler (composer ca. 1637-1690) - Play streams in full ... Sonata a 17, for 6 trumpets, 3 trombones, 2 violins, 3 violas, timpani and continuo ... digital.library.unt.edu/ark:/67531/metadc501435/
The Hexagon, Volume 105, Number 3, Fall 2014
Quarterly publication of the Alpha Chi Sigma chemistry fraternity containing articles related to chemistry research and the activities of the organization, including local chapters and groups. digital.library.unt.edu/ark:/67531/metadc501390/
Literature Review: Assessment of Cataloging Services in an Academic Library
Paper discussing a literature review on the assessment of cataloging services in an academic library. This paper is part of a Cataloging Survey Project at the University of North Texas (UNT) Libraries. digital.library.unt.edu/ark:/67531/metadc501406/
A Multimedia Atlas of Dissection for Comparative Anatomy of the Vertebrates
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This interactive multimedia content is part of the thesis that was prepared for the degree of Master of Science in Biology: http://digital.library.unt.edu/ark:/67531/metadc2224. Traditional methods of teaching the laboratory course for Comparative Anatomy of the Vertebrates could be improved by applying current computer technology to construct an interactive, multimedial atlas of dissection. Five specimens used in comparative anatomy courses at most institutions were chosen as representative members of the Phylum Chordata: amphioxus, lamprey, dogfish shark, mud puppy, and cat. Specimens were dissected according to the modified method of Wischnitzer, 1993, and each stage was photographed with a Kodak DC120 digital zoom camera. These images were processed on a Power Macintosh 7600 computer with Adobe Photoshop v. 5.0. The atlas was constructed from these images using Macromedia Authorware v. 4.0.3. Each image contains a series of interactive objects that display a highlight and descriptive text as the cursor passes over each object. digital.library.unt.edu/ark:/67531/metadc500425/
Critical Discussion of Pleroma: A Digital Drama and Its Relevance to Tragic Form in Music
Pleroma is a digital drama: a work composed of digital animation combined with electroacoustic music, presenting an original dramatic narrative. Pleroma's dramatic elements evoke both the classical form of tragedy and the concept of perceptual paradox. A structural overview of the drama and its characters and a plot synopsis are given to provide context for the critical discussion. Analytical descriptions of Beethoven's Coriolan Overture Op.62 and Mahler's Symphony No. 9 are provided to give background on tragic form and Platonic allegory in music. An investigation into the elements discussed in the analysis of the instrumental works reveals several layers of possible interpretation in Pleroma. Dramatic elements allow for tragic narratives to be constructed, but they are complemented by character associations formed by pitch relationships, stylistic juxtapositions, and instrumentation. A copy of the dramatic text is included to supplement the multimedia production: http://digital.library.unt.edu/ark:/67531/metadc33228/ digital.library.unt.edu/ark:/67531/metadc500424/
Geek As a Constructed Identity and a Crucial Component of Stem Persistence
The fields of science, technology, engineering and mathematics (STEM) have long been the bastions of the white male elite. Recently, academia has begun to recognize gender and ethnic disparities. In an effort to expand the recruitment pool for these STEM fields in college, various efforts have been employed nationally at the secondary level. In California, the latest of these efforts is referred to as Linked Learning, a pedagogy that combines college preparation with career preparation. The current study is investigating the connection between what has been referred to in current scholarship as "Geeking Out" with higher academic performance. The phenomenon of “Geeking Out” includes a variety of non-school related activities that range from participating in robotics competitions to a simple game of Dungeons & Dragons. The current project investigates the relationship between long term success in STEM fields and current informal behaviors of secondary students. This particular circumstance where Linked Learning happens to combine with "Geeking Out" is successful due to the associated inclusionary environment. Methods included a yearlong ethnographic study of the Center for Advanced Research and Technology, a Central Valley school with a diverse student body. Through participant observation and interviews, the main goal of this research is to examine the circumstances that influence the effectiveness found in the environment of the Center for Advanced Research and Technology. digital.library.unt.edu/ark:/67531/metadc500004/
Multilingual Word Sense Disambiguation Using Wikipedia
Ambiguity is inherent to human language. In particular, word sense ambiguity is prevalent in all natural languages, with a large number of the words in any given language carrying more than one meaning. Word sense disambiguation is the task of automatically assigning the most appropriate meaning to a polysemous word within a given context. Generally the problem of resolving ambiguity in literature has revolved around the famous quote “you shall know the meaning of the word by the company it keeps.” In this thesis, we investigate the role of context for resolving ambiguity through three different approaches. Instead of using a predefined monolingual sense inventory such as WordNet, we use a language-independent framework where the word senses and sense-tagged data are derived automatically from Wikipedia. Using Wikipedia as a source of sense-annotations provides the much needed solution for knowledge acquisition bottleneck. In order to evaluate the viability of Wikipedia based sense-annotations, we cast the task of disambiguating polysemous nouns as a monolingual classification task and experimented on lexical samples from four different languages (viz. English, German, Italian and Spanish). The experiments confirm that the Wikipedia based sense annotations are reliable and can be used to construct accurate monolingual sense classifiers. It is a long belief that exploiting multiple languages helps in building accurate word sense disambiguation systems. Subsequently, we developed two approaches that recast the task of disambiguating polysemous nouns as a multilingual classification task. The first approach for multilingual word sense disambiguation attempts to effectively use a machine translation system to leverage two relevant multilingual aspects of the semantics of text. First, the various senses of a target word may be translated into different words, which constitute unique, yet highly salient signal that effectively expand the target word’s feature space. Second, the translated context words themselves embed co-occurrence information that a translation engine gathers from very large parallel corpora. The second approach for multlingual word sense disambiguation attempts to reduce the reliance on the machine translation system during training by using the multilingual knowledge available in Wikipedia through its interlingual links. Finally, the experiments on a lexical sample from four different languages confirm that the multilingual systems perform better than the monolingual system and significantly improve the disambiguation accuracy. digital.library.unt.edu/ark:/67531/metadc500036/
The Impact of Professional Development on Student Achievement As Measured by Math and Science Curriculum-based Assessments
The purpose of this study was to explore the impact of teacher professional development on student achievement measured by scores on curriculum-based assessments, CBAs. The participants in the study included 260 3rd, 4th, and 5th grade math and science teachers. Teacher participation in professional development courses was collected for curriculum, instruction, differentiation, assessment, technology integration, and continuous improvement credit types. Achievement data for 8,454 students was used: 2,883 in 3rd grade, 2,752 in 4th grade, and 2,819 in 5th grade. The dependent variable of student achievement was dichotomized at the median: half of the student participants scored above the median and half of the students scored at and below the median. A series of logistic regression models were fit to the data that included examining all main effects and interaction terms among all variables to determine the best fitting model. The results of this study indicate that for 4th grade science, teacher professional development participation in curriculum, instruction, and differentiation credit strands increased the chances for students to score above the district median on CBAs. The larger number of professional development hours in a variety of credit strands had a negative impact on student achievement in 4th grade science. In 5th grade science, the students whose teacher spent more hours in professional learning for continuous improvement had an increased likelihood of scoring above the district median on CBAs. digital.library.unt.edu/ark:/67531/metadc500022/
Sustainable Energy Solutions for Water Purification Applications: Municipal and Industrial Case Studies
In several areas around the world, clean water is a precious asset that at anytime, and mainly due to circumstances of weather and climate, can become scarce. Mainly in the dry and remote places, people suffer with lack of water. A solution for this suffering can be a water desalination system, which makes water potable and usable for industry. That solution inherently, brings the problem of power requirement, which is sometimes arduous to accomplish in such remote areas of difficult access and long distances to overcome to build the infrastructure required to operate an electric power plant. Texas and the USA also face this scenario for many regions, for which the government has been creating some programs and driving forward incentives, looking for solutions to support water desalination. Water desalination has future applications for municipalities water-consuming or for arid and remote regions, as well as for industries that rely on heavy water usage, such as natural gas drilling operations, for which millions of gallons are trucked overland to the site and also hauled away afterwards, when the waste water produced must be treated. This thesis created the concept of autonomy for water desalination plants replacing the actual power supply from fossil fuel to a renewable source from wind or sun, giving capacity to them to produce its own electricity to operate as an autonomous unit, as demonstrated in the business case done for the Brownsville water desalination facility. digital.library.unt.edu/ark:/67531/metadc500086/
Preschool Teachers’ Constructions of Early Reading
Much of the current discourse surrounding the practice of early reading has emerged from policies that dictate the definition and means by which reading is taught and by which reading success is measured. Although this discourse directly influences the work of preschool teachers, little is known about what preschool teachers think about early reading and how they develop these understandings or constructions. Research concerning preschool teachers’ constructions is useful because of the potential influence on teachers' decisions and classroom behaviors. The purpose of this study is to better understand preschool teachers’ constructions concerning early reading and the process of learning to read. Six preschool teachers, with a variety of personal, educational, and professional experiences, from four diverse early childhood programs in the North Texas area were interviewed over a nine-month period during which each participant was interviewed for approximately three hours. Through systematic, inductive analysis, three themes were identified under an overarching theme of the interdependent and relational nature of early reading influences: out-of-school interactions, in-school interactions, and interactions with text. Without exception, these teachers referred to their life experiences as influencing their approach to teaching in general and to teaching reading in particular. The goals these preschool teachers had for their students and their instructional decisions were indications of their unique and evolving constructions of early reading and are absolutely grounded in their practice – in their life experiences and in their daily interactions with children. This study suggests that stakeholders should remember that these practical experiences are a primary influence on how preschool teachers think about early reading and the process of learning to read. digital.library.unt.edu/ark:/67531/metadc500020/
Academic Advising Professional Characteristics and Standards: Do Academic Advisors Follow Recognized Professional Standards in Their Work?
There were two main purposes of this quantitative study. The first purpose was to identify characteristics associated with the selected sample of academic advisors that comprise study. Secondly, the study sought to determine how well work related activities of a selected population of academic advisors correlate with professional characteristics constructs and professional standards constructs of academic advising as a profession. The study used Habley’s (1986) characteristics of a profession to derive the studies professional characteristic construct, education activities, research activities, and professional development activities as it relates to a selected group of academic advisors work related activities. The studies professional standards construct was derived from five Council for the Advancement of Standards (CAS) professional standards for academic as it relates to a selected group of academic advisors work related activities. The study of 78 out of 210 identified full-time academic advisors at two-and four-year public colleges and universities in the North Texas Region utilized a multidimensional researcher-developed Web survey instrument designed to measure professional standards and characteristic within the field of academic advising. Study results reinforced current criticism of research and education activities within the field of academic advising showing that the lack of scholarly research and education activities among academic advisors decreases significantly their efforts towards professionalization. Also, professional standards construct results suggest that the utilization of CAS standards for academic advising as an evaluation tool may enhance an academic advisor’s knowledge of professional standards within the field. digital.library.unt.edu/ark:/67531/metadc500023/
Gender, Peace and Democracy
In the last several decades there has been immense international emphasis and promotion of gender equality and female participation in the social, economic, and political spheres of society. There has also been an increase in civil conflict recurrence in countries as well as countries transitioning to democracy. This study explores the effect of female participation on peace and democracy. In the first part, I focus on the effect female participation has on decreasing the risk of peace failing in post-civil conflict countries. In many countries, women are marginalized and conflict further marginalizes them. However, I argue that the post-conflict environment allows women to escape this cycle of marginalization and their inclusion and participation is very crucial to sustaining peace. I find that female political and social female decreases the risk of peace failing in post-civil war countries. In the second part, I focus on the effect female participation has on decreasing the risk of authoritarian reversals in countries that have transitioned to and toward democracy. Previous empirical research has focused on women’s role in transitions to democracy, factors that contribute to the survival of democracy, as well as how women’s participation affects the stability country. I argue that women’s social, economic, and political participation decreases the risk of authoritarian reversals in countries that have newly transitioned to and toward democracy. I find that female social participation sustains democracy in countries that have transitioned to democracy and that female economic participation sustains democracy in countries that have transitioned toward democracy. Overall I find support that female participation matters for both peace and democracy. digital.library.unt.edu/ark:/67531/metadc500006/
Is Mindfulness Just Another Ego Depletion Exercise?
Given increasing interest in the therapeutic benefits of mindfulness, limitations of its treatment utility are frequently questioned. As such, the purpose of the study was to examine the effects of mindfulness on a subsequent self-control task in a sample of college students. A total of 67 participants were randomly assigned to one of three conditions: a control condition, an experimental mindfulness-only condition or a comparison expectancy-plus-mindfulness condition to investigate the utility of mindfulness practice when motivated by an outcome of increased self-control. Results did not indicate a difference in persistence on a difficult task between conditions, regardless of the manipulation. Conceptual and experimental limitations of current study’s findings, as well as future directions, are discussed. digital.library.unt.edu/ark:/67531/metadc499980/
Defining the Contralto Voice Through the Repertoire of Ralph Vaughan Williams
At the beginning of the twentieth century, the recognition of the contralto voice type had reached its apex in England. Throughout the remainder of the century, the number and popularity of recorded contraltos has decreased alongside the rise of the mezzo-soprano voice type. Due to the contralto’s decline and the lack of repertoire composed specifically for the voice, the definition of “contralto” remains somewhat ambiguous. The large contralto repertoire of English composer Ralph Vaughan Williams displays a unique sensitivity to the contralto, particularly with regards to vocal range, flexibility, tessitura, and sustainability. These works thus suggest a new perspective for the voice type. The scope of Vaughan Williams’s oeuvre examined includes each of his operatic roles for contralto and choral works featuring the contralto. Also examined will be the compositional techniques implemented within these pieces which demonstrate the strengths and weaknesses of the contralto voice. A workable definition of the voice type for the pedagogue and performer is included. digital.library.unt.edu/ark:/67531/metadc499999/
Recidivism Among Determinately Sentenced Youth in Texas
In Texas, determinate sentencing allows extremely serious and violent delinquents one more chance to change their ways by releasing them to the streets instead of being transferred to prison. This research study examined the recidivism outcomes of 416 serious and violent juvenile offenders previously exposed to rehabilitative treatment in the renowned Capital and Serious Violent Offender Treatment Program provided by the Texas Youth Commission. Further, this research study looked to a group of 1,261 determinately sentenced offenders who did not participate in Capital and Serious Violent Offender Treatment Program but were released from Texas Youth Commission as well. Both groups of juveniles were followed for three years following their release from institutionalization. This analysis revealed that 50% of both groups were rearrested at least once during the follow-up period for any offense. Of the Capital and Serious Violent Offender Program participants, 81% were rearrested for at least one new felony offense. Of those non-participants, 78% were rearrested for at least one new felony offense. The factors that served to distinguish both groups included African-American race and a number of delinquent history measures. This study concludes with a discussion of policy implications and suggestions for future research. digital.library.unt.edu/ark:/67531/metadc499985/
Effect of Dispersed Particles and Branching on the Performance of a Medium Temperature Thermal Energy Storage System
The main objective of my thesis is to develop a numerical model for small-scale thermal energy storage system and to see the effect of dispersing nano-particles and using fractal-like branching heat exchanger in phase change material for our proposed thermal energy storage system. The associated research problems investigated for phase change material (PCM) are the low thermal conductivity and low rate of heat transfer from heat transfer fluid to PCM in thermal energy storage system. In this study an intensive study is carried out to find the best material for thermal storage and later on as a high conductive nano-particle graphite is used to enhance the effective thermal conductivity of the mixed materials. As a thermal storage material molten solar Salt (60% NaNO3+40%KNO3) has been selected, after that detailed numerical modeling of the proposed design has been done using MATLAB algorithm and following the fixed grid enthalpy method. The model is based on the numerical computation of 1-D finite difference method using explicit scheme. The second part of the study is based on enhancing the heat transfer performance by introducing the concept of fractal network or branching heat exchanger. Results from the numerical computation have been utilized for the comparison between a conventional heating system (with a simple single tube as a heat exchanger) and a passive PCM thermal energy storage system with branching heat exchanger using NTU-effectiveness method and charging time calculation. The comparison results show a significant amount improvement using branching network and mixing nano-particle in terms of heat transfer (13.5% increase in effectiveness of branching level-02 heat exchangers from the conventional one ), thermal conductivity (increased 73.6% with 20% graphite nano-particle mix with solid PCM), charging time (57% decrease of charging time for the effect of both the dispersion of Graphite nano-particle and branching heat exchange) and pressure drop (36% decrease in level-02 branching). The results of this study prove that the proposed medium temperature TES system coupled with solar ORC can be the stepping-stone for energy efficient and sustainable future in small-scale/building level as the system proves to be better in terms of enhanced heat transfer, increased thermal conductivity and reduced pumping power and overall sustainability. digital.library.unt.edu/ark:/67531/metadc499995/
The Contribution of Mira Behn and Sarala Behn to Social and Environmental Transformation in the Indian State of Uttarakhand
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The influence of Mohandas K. Gandhi on social and environmental movements in post-colonial India has been widely acknowledged. Yet, the contributions of two European associates of Gandhi, Madeleine Slade and Catherine Mary Heilemann, better known in India as Mira Behn and Sarala Behn, have not received the due attention of the academic community. This dissertation is an examination of the philosophy and social activism of Mira Behn and Sarala Behn and their roles in the evolution of Gandhian philosophy of socioeconomic reconstruction and environmental conservation in the present Indian state of Uttarakhand. Instead of just being acolytes of Gandhi, I argue that these women developed ideas and practices that drew upon from an extensive intellectual terrain that cannot be limited to Gandhi’s work. I delineate the directions in which Gandhian thought and experiments in rural development work evolved through the lives, activism, and written contributions of these two women. Particularly, I examine their influence on social and environmental movements, such as the Chipko and the Anti-Tehri Dam movements, and their roles in promoting grassroots social development and environmental sustainability in the mountain communities of Uttarakhand. Mira Behn and Sarala Behn’s integrative philosophical worldviews present epistemological, sociopolitical, ethical, and metaphysical principles and practices that have local and global significance for understanding interfaith dialog, social justice, and environmental sustainability and thus constitute a useful contribution to the theory and practice of human emancipation in our times. digital.library.unt.edu/ark:/67531/metadc499983/
The Impact of Teacher Perception of Cultural Competence on the Instructional Decision Making of English As Second Language (Esl) Students
Recent research suggests that culturally responsive teaching (CRT) practices have the potential to increase student educational outcomes, as well as to reduce unnecessary or inappropriate placement referrals. Examination of the core components in CRT, teacher efficacy and cultural competence, is proposed to be a critical step to reduce unwarranted referrals of culturally and linguistically diverse students. However, there is limited empirical support for the relationship between CRT and instructional referrals, and even among existing studies there is inconsistency regarding the relation of these constructs. The purpose of this study is to examine teacher factors (i.e., teacher role, degree earned, years of teaching, ESL certification held, language proficiency and ethnicity) as a predictor of teacher competence, and the role these factors play in teachers’ referral decision making. To investigate these relationships, a national sample of elementary teachers (N = 258) completed a survey addressing their background, profession endorsements, sense of teaching efficiency, and the instructional decisions they would make in the scenarios presented. The results of this study revealed that teacher role (i.e., general, ESL or special educator) and ESL certification were important predictors of teacher competency. A statistically significant mean difference in teacher competency was found between teachers with and without ESL certification, indicating ESL certification as an important factor in deciding the level of teacher competency. Finally, teacher competency was found to improve teachers’ instructional decision making in scenarios in which the students displayed linguistic difficulties. The findings provide valuable insights to teacher training programs and other professional development entities regarding how to prepare educators to work more efficiently with ESL students. digital.library.unt.edu/ark:/67531/metadc499978/
From Development of Semi-empirical Atomistic Potentials to Applications of Correlation Consistent Basis Sets
The development of the semi-empirical atomistic potential called the embedded atom method (EAM) has allowed for the efficient modeling of solid-state environments, at a lower computational cost than afforded by density functional theory (DFT). This offers the capability of EAM to model the energetics of solid-state phases of varying coordination, including defects, such as vacancies and self-interstitials. This dissertation highlights the development and application of two EAMs: a Ti potential constructed with the multi-state modified embedded atom method (MS-MEAM), and a Ni potential constructed with the fragment Hamiltonian (FH) method. Both potentials exhibit flexibility in the description of different solid-states phases and applications. This dissertation also outlines two applications of DFT. First, a study of structure and stability for solid-state forms of NixCy (in which x and y are integers) is investigated using plane-wave DFT. A ground state phase for Ni2C is elucidated and compared to known and hypothesized forms of NixCy. Also, a set of correlation consistent basis sets, previously constructed using the B3LYP and BLYP density functionals, are studied. They are compared to the well-known to the correlation consistent basis sets that were constructed with higher-level ab initio methodologies through computations of enthalpies of formation and combustion enthalpies. The computational accuracy with regard to experiment is reported. digital.library.unt.edu/ark:/67531/metadc500219/
Development of Enabling Technologies to Visualize the Plant Lipidome
Improvements in mass spectrometry (MS)-based strategies for characterizing the plant lipidome through quantitative and qualitative approaches such as shotgun lipidomics have substantially enhanced our understanding of the structural diversity and functional complexity of plant lipids. However, most of these approaches require chemical extractions that result in the loss of the original spatial context and cellular compartmentation for these compounds. To address this current limitation, several technologies were developed to visualize lipids in situ with detailed chemical information. A subcellular visualization approach, direct organelle MS, was developed for directly sampling and analyzing the triacylglycerol contents within purified lipid droplets (LDs) at the level of a single LD. Sampling of single LDs demonstrated seed lipid droplet-to-droplet variability in triacylglycerol (TAG) composition suggesting that there may be substantial variation in the intracellular packaging process for neutral lipids in plant tissues. A cellular and tissue visualization approach, MS imaging, was implemented and enhanced for visualizing the lipid distributions in oilseeds. In mature cotton seed embryos distributions of storage lipids (TAGs) and their phosphatidylcholine (PCs) precursors were distribution heterogeneous between the cotyledons and embryonic axis raising new questions about extent and regulation of oilseed heterogeneity. Extension of this methodology provides an avenue for understanding metabolism in cellular (perhaps even subcellular) context with substantial metabolic engineering implications. To visualize metabolite distributions, a free and customizable application, Metabolite Imager, was developed providing several tools for spatially-based chemical data analysis. These tools collectively enable new forms of visualizing the plant lipidome and should prove valuable toward addressing additional unanswered biological questions. digital.library.unt.edu/ark:/67531/metadc499986/
Leadership Styles and Cultural Sensitivity of Department Chairs at Texas Public Universities
As the U.S. population diversifies, so do its higher education institutions. Leadership at these institutions should be prepared for this diversification of students, faculty, and staff. The purpose of this study was to gain greater knowledge about the leadership styles and cultural sensitivity of department chairs. Survey research was used to determine if department chairs’ leadership styles correlated with their cultural sensitivity. The target population was department chairs from public universities in the state of Texas. The survey was distributed to 406 randomly selected department chairs. The participants completed three measures: Leadership Behavior Description Questionnaire (LDBQ) for leadership style, the Intercultural Sensitivity Scale (ISS) for cultural sensitivity, and a demographic questionnaire (gender, age range, race/ethnicity, and years of service as department chair). The sample included 165 usable surveys (40% return rate). The department chairs were primarily male (72%), White (78%), and over 50 (71%) years of age. First, a statistically significant negative correlation (r = -.431, p < .0001) occurred between LBDQ overall scores and overall ISS scores: As chairs scored higher on leadership ability, they scored lower on intercultural sensitivity. Second, leadership style by demographic variable displayed mixed results. No significant difference was found for leadership style by age, gender, years of service, or region of service. For ethnicity, White participants scored significantly lower than Minority participants on the LBDQ scales of consideration (t [162] = -2.021, p = .045), structure (t [162] = -2.705, p = .008), and overall (t [162] = -2.864, p = .005). Minority participants might work more diligently to increase their leadership abilities based on their higher LDBQ scores. Third, findings on intercultural sensitivity by demographic variable were mixed. No statistical significance was observed between any of the ISS scales and age, gender, years of service, and region. For ethnicity, Minority participants’ scores showed significantly lower intercultural sensitivity than White participants scores on two of six ISS subscales: interaction enjoyment (t = -2.46, p = .015) and respect (t = 2.107, p = .037). It was concluded that the Minority and White department chairs’ leadership style and intercultural sensitivity differences could be due in part to differences in the chairs’ ethnic affiliations, associated cultural backgrounds, and views of dominant versus non-dominant cultures. Recommendations for study are included. digital.library.unt.edu/ark:/67531/metadc499977/
Development of a Cost Effective Wireless Sensor System for Indoor Air Quality Monitoring Applications
Poor air quality can greatly affect the public health. Research studies indicate that indoor air can be more polluted than the outdoor air. An indoor air quality monitoring system will help to create an awareness of the quality of air inside which will eventually help in improving it. The objective of this research is to develop a low cost wireless sensor system for indoor air quality monitoring. The major cost reduction of the system is achieved by using low priced sensors. Interface circuits had to be designed to make these sensors more accurate. The system is capable of measuring carbon dioxide, carbon monoxide, ozone, temperature, humidity and volatile organic compounds. The prototype sensor node modules were developed. The sensor nodes were the connected together by Zigbee network. The nodes were developed in such a way that it is compact in size and wireless connection of sensor nodes enable to collect air quality data from multiple locations simultaneously. The collected data was stored in a computer. We employed linear least-square approach for the calibration of each sensor to derive a conversion formula for converting the sensor readings to engineering units. The system was tested with different pollutants and data collected was compared with a professional grade monitoring system for analyzing its performance. The results indicated that the data from our system matched quite well with the professional grade monitoring system. digital.library.unt.edu/ark:/67531/metadc499988/
Synthesis Strategies and a Study of Properties of Narrow and Wide Band Gap Nanowires
Various techniques to synthesize nanowires and nanotubes as a function of growth temperature and time were investigated. These include growth of nanowires by a chemical vapor deposition (CVD) system using vapor-liquid-solid (VLS) growth mechanism and electro-chemical synthesis of nanowires and nanotubes. Narrow band gap InSb Eg = 0.17 eV at room temp) nanowires were successively synthesized. Using a phase diagram, the transition of the nanowire from metallic- semiconducting- semi-metallic phase was investigated. A thermodynamic model is developed to show that the occurrence of native defects in InSb nanowires influenced by the nanowire growth kinetics and thermodynamics of defect formation. Wide band gap ZnO (Eg = 3.34 eV) and In2O3 (3.7 eV) were also synthesized. ZnO nanowires and nanotubes were successfully doped with a transition metal Fe, making it a Dilute Magnetic Semiconductor of great technological relevance. Structural and electronic characterizations of nanowires were studied for different semiconducting, metallic and semi-metallic nanowires. Electron transport measurements were used to estimate intrinsic material parameters like carrier concentration and mobility. An efficient gas sensing device using a single In2O3 nanowire was studied and which showed sensitivity to reducing gas like NH3 and oxidizing gas like O2 gas at room temperature. The efficiency of the gas sensing device was found to be sensitive to the nature of contacts as well as the presence of surface states on the nanowire. digital.library.unt.edu/ark:/67531/metadc499984/
A Quantitative Assessment of Site Formation at the Dmanisi Archaeological Site, Republic of Georgia
The focus of this thesis was to gather and analyze micromorphological and petrographic data on soils at the archaeological site of Dmanisi in order to better understand the extent to which the deposition and alteration of the sediments has affected the preservation of artifacts and faunal remains. A major goal of this research was to test hypothesis related to why bone material is discovered in some strata and not in others. This research focuses on the application of micromorphology (supplemented with other methods) to the soils through the use of petrographic analysis of thin sections and scanning electron microscopy. These techniques complement previous field analyses by providing a quantitative assessment of individual strata through point counting and chemical mapping. The results of this research support the hypothesis that the sediments are predominantly mafic ashes, while showing that there is very little soil development in the strata. This suggests quick episodic burial in a relatively dry climate, confirming the hypothesis for a short time sequence in the strata. Additionally, differential weathering probably did not play a significant role in the differential abundance of bone remains among the strata at Dmanisi. digital.library.unt.edu/ark:/67531/metadc499979/
Autonomic Failure Identification and Diagnosis for Building Dependable Cloud Computing Systems
The increasingly popular cloud-computing paradigm provides on-demand access to computing and storage with the appearance of unlimited resources. Users are given access to a variety of data and software utilities to manage their work. Users rent virtual resources and pay for only what they use. In spite of the many benefits that cloud computing promises, the lack of dependability in shared virtualized infrastructures is a major obstacle for its wider adoption, especially for mission-critical applications. Virtualization and multi-tenancy increase system complexity and dynamicity. They introduce new sources of failure degrading the dependability of cloud computing systems. To assure cloud dependability, in my dissertation research, I develop autonomic failure identification and diagnosis techniques that are crucial for understanding emergent, cloud-wide phenomena and self-managing resource burdens for cloud availability and productivity enhancement. We study the runtime cloud performance data collected from a cloud test-bed and by using traces from production cloud systems. We define cloud signatures including those metrics that are most relevant to failure instances. We exploit profiled cloud performance data in both time and frequency domain to identify anomalous cloud behaviors and leverage cloud metric subspace analysis to automate the diagnosis of observed failures. We implement a prototype of the anomaly identification system and conduct the experiments in an on-campus cloud computing test-bed and by using the Google datacenter traces. Our experimental results show that our proposed anomaly detection mechanism can achieve 93% detection sensitivity while keeping the false positive rate as low as 6.1% and outperform other tested anomaly detection schemes. In addition, the anomaly detector adapts itself by recursively learning from these newly verified detection results to refine future detection. digital.library.unt.edu/ark:/67531/metadc499993/
Fundamental Studies of Copper Bimetallic Corrosion in Ultra Large Scale Interconnect Fabrication Process
In this work, copper bimetallic corrosion and inhibition in ultra large scale interconnect fabrication process is explored. Corrosion behavior of physical vapor deposited (PVD) copper on ruthenium on acidic and alkaline solutions was investigated with and without organic inhibitors. Bimetallic corrosion screening experiments were carried out to determine the corrosion rate. Potentiodynamic polarization experiments yielded information on the galvanic couples and also corrosion rates. XPS and FTIR surface analysis gave important information pertaining inhibition mechanism of organic inhibitors. Interestingly copper in contact with ruthenium in cleaning solution led to increased corrosion rate compared to copper in contact with tantalum. On the other hand when cobalt was in contact with copper, cobalt corroded and copper did not. We ascribe this phenomenon to the difference in the standard reduction potentials of the two metals in contact and in such a case a less noble metal will be corroded. The effects of plasma etch gases such as CF4, CF4+O2, C4F8, CH2F2 and SF6 on copper bimetallic corrosion was investigated too in alkaline solution. It was revealed that the type of etching gas plasma chemistry used in Cu interconnect manufacturing process creates copper surface modification which affects corrosion behavior in alkaline solution. The learning from copper bimetallic corrosion studies will be useful in the development of etch and clean formulations that will results in minimum defects and therefore increase the yield and reliability of copper interconnects. digital.library.unt.edu/ark:/67531/metadc499992/
Sensitivity and Uncertainty Analysis of Occupancy-related Parameters in Energy Modeling of Unt Zero Energy Lab
The study focuses on the sensitivity and uncertainty analysis of occupancy-related parameters using Energyplus modeling method. The model is based on a real building Zero Energy Lab in Discovery Park, at University of North Texas. Four categories of parameters are analyzed: heating/cooling setpoint, lighting, equipment and occupancy. Influence coefficient (IC) is applied in the sensitivity study, in order to compare the impact of individual parameter on the overall building energy consumption. The study is conducted under Texas weather file as well as North Dakota weather file in order to find weather’s influence of sensitivity. Probabilistic collocation method (PCM) is utilized for uncertainty analysis, with an aim of predicting future energy consumption based on history or reference data set. From the study, it is found that cooling setpoint has the largest influence on overall energy consumption in both Texas and North Dakota, and occupancy number has the least influence. The analysis also indicates schedule’s influence on energy consumption. PCM is able to accurately predict future energy consumption with limited calculation, and has great advantage over Monte Carlo Method. The polynomial equations are generated in both 3-order and 6-order, and the 6-order equation is proved to have a better result, which is around 0.1% compared with real value. digital.library.unt.edu/ark:/67531/metadc499991/
The Effect of Natural Gas Well Setback Distance on Drillable Land in the City of Denton, Texas
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Municipalities protect human health and environmental resources from impacts of urban natural gas drilling through setback distances; the regulation of distances between well sites and residences, freshwater wells, and other protected uses. Setback distances have increased over time, having the potential to alter the amount and geographical distribution of drillable land within a municipality, thereby having implications for future land use planning and increasing the potential for future incompatible land uses. This study geographically applies a range of setback distances to protected uses and freshwater wells in the city limits of Denton, Texas to investigate the effect on the amount of land remaining for future gas well development and production. Denton lies on the edge of a productive region of the Barnett Shale geological formation, coinciding with a large concentration of drillable land in the southwestern region of the study area. This region will have the greatest potential for impacts to future municipal development and land use planning as a result of future gas well development and higher setback standards. Given the relatively high acreage of drillable land in industrially zoned subcategory IC-G and the concern regarding gas well drilling in more populated areas, future drilling in IC-G, specifically in IC-G land cover classes mowed/grazed/agriculture and herbaceous, would have the least impact on residential uses and tree cover, as well as decreasing the potential for future incompatible land uses. digital.library.unt.edu/ark:/67531/metadc499998/
Reading Beyond the Words: How Implementing Esl Strategies During Modified Guided Reading Affects a Deaf Student’s Language Acquisition Process
While Deaf students are not typically classified as English as a second language (ESL) students, the majority of deaf students first become fluent in a signed language, making them ideal candidates for ESL research. This case study has been designed to explore the ways in which one method of ESL reading instruction, known as modified guided reading (MGR), affects the language acquisition process, and resulting reading comprehension level, of a deaf student over eleven weeks. The study documented the student’s language acquisition development both in American Sign Language (ASL) and in English, as well as tracked the student’s growth in reading comprehension, metalinguistic awareness, and visual attention skills. The Accelerated Reader (AR) program, benchmark testing, and daily observations were used to measure growth. Findings of the study suggest that the ESL methods implemented through MGR positively impacted the student’s language acquisition process, reading comprehension level, metalinguistic awareness, and visual attention skills. Results showed an increase in all three of the student’s AR scores as follows: 31% in reading level, 13.1% in number of words read, and 13.2 % in comprehension test scores. Observations and benchmark testing revealed increased metalinguistic knowledge in word, syntactic, and pragmatic awareness. Visual attention skills were found to be the key element in allowing reading comprehension to take place and strategies for improving these skills were found to be a necessary part of the MGR process. digital.library.unt.edu/ark:/67531/metadc499994/
Études: Five Compositional and Technical Studies for Solo Organ
Études was composed as a set of five interrelated movements in the followingorder: Prelude, Introduction and Fugue, Triptych, Chorale, and Response. The pieces are compositional as well as technical studies. The movements specifically explore certain styles and forms unique to organ music, and reintroduce these elements in creative ways. As in the traditional étude, each movement contains virtuosic technical studies, which are designed to enhance manual and pedal facility and prepare the performer for advanced repertoire. digital.library.unt.edu/ark:/67531/metadc499990/
Spatial Ability in Registered Nurses
Spatial ability is the skill associated with mental relations among objects, the process of maintaining the physical aspects of an object after mentally rotating it in space. Many studies report a strong association of spatial ability with success in various areas of health care, especially surgery, radiology and dentistry. To date, similar investigations in professional nursing could not be located. Registered nurses, employed in an acute care multi-hospital setting, were surveyed using the Shipley-2Block Pattern Test, the Group Embedded Figures Test, and a newly created test of general nursing knowledge. The sample size of 123 nurses was composed of 31 male nurses and 92 female nurses. Data was collected between May and August of 2013 and analyzed using R, version 2.15.2. The present study did not demonstrate a statistically significant effect for gender differences on two measures of spatial ability. However, Cohen’s d effect sizes for mean gender differences in the present study are consistent with prior studies. This may suggest the nursing profession is comparable with other professions where males perform higher than females on spatial ability. The present study should be considered an initial step toward evaluating the relevance of spatial ability in the performance of nursing care. digital.library.unt.edu/ark:/67531/metadc499989/
A Performance Analysis of Solar Chimney Passive Ventilation System in the Unt Zero Energy Lab
The purpose of this investigation is to find out suitability of the solar chimney natural ventilation system in a Zero Energy Lab located at the University of North Texas campus, to figure out performance of the solar chimney. Reduction in the heating and ventilation and air conditioning energy consumption of the house has been also analyzed. The parameters which are considered for investigation are volumetric flow rate of outlet of chimney, the absorber wall temperature and glass wall temperatures. ANSYS FLUENT 14.0 has been employed for the 3-D modeling of the solar chimney. The dimensions of the solar chimney are 14’2” X 7’4” X 6’11”. The flow inside solar chimney is found to be laminar and the simulation results show that maximum outlet volumetric flow rate of about 0.12m3/s or 432 cfm is possible from chimney. The experimental velocity of chimney was found to be 0.21 m/s. Density Boussinesq approximation is considered for the modeling. Velocity and temperature sensors have been installed at inlet and outlet of the chimney in order to validate the modeling results. It is found that based on simulated volumetric flow rate that cooling load of 9.29 kwh can be saved and fan power of 7.85 Watts can be saved. digital.library.unt.edu/ark:/67531/metadc499996/
A Pedagogical and Methodical Approach to Unaccompanied Euphonium Literature Through Performance and Analyses of Original Works by Torstein Aagaard-nilsen
Original unaccompanied literature currently stands as one of the most understudied bodies of music in the euphonium repertory. This is largely due to a lack of access to reference recordings, live performances, and study/performance guides. Many of the commissioning projects for new euphonium music in the late 20th and early 21st centuries have promoted the composition of large scale works for euphonium and large ensembles, but very few have generated new unaccompanied pieces for euphonium. Many of the most recent commissions for unaccompanied euphonium music have been for competitions such as the Lieksa Brass Festival (Finland) and Leonard Falcone International Festival (USA). These competitions are also where many students get their only exposure to the unaccompanied repertoire. Unfortunately, there is a small number of standard unaccompanied works that are continuously recycled for these competitions and the exposure to new pieces in the repertoire is further diminished for many developing euphoniumists. This study will examine the three works for unaccompanied euphonium by Torstein Aagaard-Nilsen and provide solutions for many common technical challenges and pose suggestions for approaching and preparing this genre of music. Connections are made throughout the study to specific etudes and other unaccompanied solos that can be used as complementary and precursory studies to aid in the mastery of this literature. digital.library.unt.edu/ark:/67531/metadc499997/
A Study of Silver: an Alternative Maldi Matrix for Low Weight Compounds and Mass Spectrometry Imaging
Soft-landing ion mobility has applicability in a variety of areas. The ability to produce material and collect a sufficient amount for further analysis and applications is the key goal of this technique. Soft-landing ion mobility has provided a way to deposit material in a controllable fashion, and can be tailored to specific applications. Changing the conditions at which soft-landing ion mobility occurs effects the characteristics of the resulting particles (size, distribution/coverage on the surface). Longer deposition times generated more material on the surface; however, higher pressures increased material loss due to diffusion. Larger particles were landed when using higher pressures, and increased laser energy at ablation. The utilization of this technique for the deposition of silver clusters has provided a solvent free matrix application technique for MALDI-MS. The low kinetic energy of incident ions along with the solvent free nature of soft-landing ion mobility lead to a technique capable of imaging sensitive samples and low mass analysis. The lack of significant interference as seen by traditional organic matrices is avoided with the use of metallic particles, providing a major enhancement in the ability to analyze low mass compounds by MALDI. digital.library.unt.edu/ark:/67531/metadc499981/
Remembering the Forgotten D-day: the Amphibious Landing at Collado Beach During the Mexican War
The current historiography of the Mexican War does not give due credit to the significance of the landing at Collado Beach. No one source addresses all aspects of the landing, nor have any included an analysis of the logistical side of the operation. This thesis presents a comprehensive analysis of the operation from conception to execution in an attempt to fill the gap in the historiography. Additionally, the lessons learned and lessons forgotten from this landing are addressed as to how this landing shaped American military doctrine regarding joint operations and amphibious operations. The conclusion drawn from the historical sources supports the argument that this operation had a significant impact on the American military. The influence of this operation shows itself throughout American military history, including the establishment of amphibious doctrine by the Unites States Marine Corps and during World War II. digital.library.unt.edu/ark:/67531/metadc499987/
Does Underwriter Size Matter? Only Within the Right Context
The initial matching relationships between underwriters and bonds/issuing firms and the certification quality of underwriters, as determined by changes in the issuing firm’s financial strength post issue, are the two primary research topics in this dissertation. Based on total underwriter syndicate market share, two distinct categories, low market power (LMP) syndicates and high market power (HMP) syndicates were defined. Firm financial strength is examined based on a new factor developed in this research. A comparison of the two underwriting categories, or pools, indicates that the HMP underwriters take on firms of lower initial financial strength and additionally, the issuing firms decline more in financial strength two years following bond issuance than do firms using LMP underwriters. Notwithstanding these results, the more interesting findings are the relationships within each of these pools. In the LMP pool of underwriters, financially stronger firms used the larger LMPs to underwrite their bonds, while the weaker firms used smaller LMPs. In contrast, among HMP underwriters, the largest HMPs aligned with the firms of relatively lower financial strength. The relationships in both pools reverse when changes in financial strength are examined. Larger LMPs are associated with greater issuing firm financial decline while larger HMPs correlate with lower levels of decline in firm financial strength. Divergent patterns in initial underwriter-issuer matching and underwriter certification found in this research indicate that there are true differences in the “small” underwriting syndicates as compared to the larger syndicates. These patterns should be considered by both issuing firms and investors as both constituencies contemplate the corporate bond market. digital.library.unt.edu/ark:/67531/metadc500223/