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 Studies of Charged Particle Dynamics for Antihydrogen Synthesis
 Synthesis and capture of antihydrogen in controlled laboratory conditions will enable precise studies of neutral antimatter. The work presented deals with some of the physics pertinent to manipulating charged antiparticles in order to create neutral antimatter, and may be applicable to other scenarios of plasma confinement and charged particle interaction. The topics covered include the electrostatic confinement of a reflecting ion beam and the transverse confinement of an ion beam in a purely electrostatic configuration; the charge sign effect on the Coulomb logarithm for a two component (e.g., antihydrogen) plasma in a Penning trap as well as the collisional scattering for binary Coulomb interactions that are cut off at a distance different than the Debye length; and the formation of magnetobound positronium and protonium. digital.library.unt.edu/ark:/67531/metadc699934/
 Analysis of Biological Materials Using a Nuclear Microprobe
 The use of nuclear microprobe techniques including: Particle induced xray emission (PIXE) and Rutherford backscattering spectrometry (RBS) for elemental analysis and quantitative elemental imaging of biological samples is especially useful in biological and biomedical research because of its high sensitivity for physiologically important trace elements or toxic heavy metals. The nuclear microprobe of the Ion Beam Modification and Analysis Laboratory (IBMAL) has been used to study the enhancement in metal uptake of two different plants. The roots of corn (Zea mays) have been analyzed to study the enhancement of iron uptake by adding Fe (II) or Fe (III) of different concentrations to the germinating medium of the seeds. The Fe uptake enhancement effect produced by lacing the germinating medium with carbon nanotubes has also been investigated. The aim of this investigation is to ensure not only high crop yield but also Ferich food products especially from calcareous soil which covers 30% of world’s agricultural land. The result will help reduce iron deficiency anemia, which has been identified as the leading nutritional disorder especially in developing countries by the World Health Organization. For the second plant, Mexican marigold (Tagetes erecta), the effect of an arbuscular mycorrhizal fungi (Glomus intraradices) for the improvement of leadphytoremediation of lead contaminated soil has been investigated. Phytoremediation provides an environmentally safe technique of removing toxic heavy metals (like lead), which can find their way into human food, from lands contaminated by human activities like mining or by natural disasters like earthquakes. The roots of Mexican marigold have been analyzed to study the role of arbuscular mycorrhizal fungi in enhancement of lead uptake from the contaminated rhizosphere. digital.library.unt.edu/ark:/67531/metadc700099/
 Electrical Conduction Mechanisms in the Disordered Material System Ptype Hydrogenated Amorphous Silicon
 The electrical and optical properties of boron doped hydrogenated amorphous silicon thin films (aSi) were investigated to determine the effect of boron and hydrogen incorporation on carrier transport. The aSi thin films were grown by plasma enhanced chemical vapor deposition (PECVD) at various boron concentrations, hydrogen dilutions, and at differing growth temperatures. The temperature dependent conductivity generally follows the hopping conduction model. Above a critical temperature, the dominant conduction mechanism is Mott variable range hopping conductivity (MVRH), where p = ¼, and the carrier hopping depends on energy. However, at lower temperatures, the coulomb interaction between charge carriers becomes important and EfrosShklosvkii variable hopping (ESVRH) conduction, where p=1/2, must be included to describe the total conductivity. To correlate changes in electrical conductivity to changes in the local crystalline order, the transverse optical (TO) and transverse acoustic (TA) modes of the Raman spectra were studied to relate changes in short and midrange order to the effects of growth temperature, boron, and hydrogen incorporation. With an increase of hydrogen and/or growth temperature, both short and midrange order improve, whereas the addition of boron results in the degradation of short range order. It is seen that there is a direct correlation between the electrical conductivity and changes in the short and midrange order resulting from the passivation of defects by hydrogen and the creation of trap states by boron. This work was done under the ARO grant W911NF1010410, William W. Clark Program Manager. The samples were provided by L3 Communications. digital.library.unt.edu/ark:/67531/metadc700106/
 Sputtering of Bi and Preferential Sputtering of an Inhomogeneous Alloy
 Angular distributions and total yields of atoms sputtered from bismuth targets by normally incident 10 keV 50 keV Ne+ and Ar+ ions have been measured both experimentally and by computer simulation. Polycrystalline Bi targets were used for experimental measurements. The sputtered atoms were collected on high purity aluminum foils under ultrahigh vacuum conditions, and were subsequently analyzed using Rutherford backscattering spectroscopy. The MonteCarlo based SRIM code was employed to simulate angular distributions of sputtered Bi atoms and total sputtering yields of Bi to compare with experiment. The measured sputtering yields were found to increase with increasing projectile energy for normally incident 10 keV  50 keV Ne+ and Ar+ ions. The shapes of the angular distributions of sputtered Bi atoms demonstrated good agreement between experiment and simulation in the present study. The measured and simulated angular distributions of sputtered Bi exhibited an overcosine tendency. The measured value of the degree of this overcosine nature was observed to increase with increasing incident Ne+ ion energy, but was not strongly dependent on incident Ar+ ion energy. The differential angular sputtering yield and partial sputtering yields due to Ar ion bombardment of an inhomogeneous liquid Bi:Ga alloy have been investigated, both experimentally and by computer simulation. Normally incident 25 keV and 50 keV beams of Ar+ were used to sputter a target of 99.8 at% Ga and 0.2 at% Bi held at 40° C in ultrahigh vacuum (UHV), under which conditions the alloy is known to exhibit extreme Gibbsian surface segregation that produces essentially a monolayer of Bi atop the bulk liquid. Angular distributions of sputtered neutrals and partial sputtering yields obtained from the conversion of areal densities of Bi and Ga atoms on collector foils were determined. The MonteCarlo based SRIM code was employed to simulate the experiment and obtain the angular distribution of sputtered components. The angular distribution of sputtered Ga atoms, originating from underneath the surface monolayer, was measured to be sharply peaked in angle about the surface normal direction compared to the Bi atoms originating from surface monolayer. The simulation study produced contradicting results, where the species originating from surface monolayer was strongly peaked around the surface normal compared to the species originating from beneath the surface monolayer. digital.library.unt.edu/ark:/67531/metadc700021/
 Temporal Complexity and Stochastic Central Limit Theorem
 Complex processes whose evolution in time rests on the occurrence of a large and random number of intermittent events are the systems under study. The mean time distance between two consecutive events is infinite, thereby violating the ergodic condition and activating at the same time a stochastic central limit theorem that explains why the MittagLeffler function is a universal property of nature. The time evolution of these complex systems is properly generated by means of fractional differential equations, thus leading to the interpretation of fractional trajectories as the average over many random trajectories, each of which fits the stochastic central limit theorem and the condition for the MittagLeffler universality. Additionally, the effect of noise on the generation of the MittagLeffler function is discussed. Fluctuations of relatively weak intensity can conceal the asymptotic inverse power law behavior of the MittagLeffler function, providing a reason why stretched exponentials are frequently found in nature. These results afford a more unified picture of complexity resting on the MittagLeffler function and encompassing the standard inverse power law definition. digital.library.unt.edu/ark:/67531/metadc700093/
 Enhancement of Mechanical, Thermal Stability, and Tribological Properties by Addition of Functionalized Reduced Graphene Oxide in Epoxy
 The effects of octadecylaminefunctionalized reduced graphene oxide (FRGO) on the frictional and wear properties of diglycidylether of bisphenolA (DGEBA) epoxy are studied using a pinondisk tribometer. It was observed that the addition of FRGO significantly improves the tribological, mechanical, and thermal properties of epoxy matrix. Graphene oxide (GO) was functionalized with octadecylamine (ODA), and then reduction of oxygencontaining functional groups was carried out using hydrazine monohydrate. The Raman and xray photoelectron spectroscopy studies confirm significant reduction in oxygencontaining functional groups and formation of ODA functionalized reduced GO. The nanocomposites are prepared by adding 0.1, 0.2, 0.5 and 1.0 wt % of FRGO to the epoxy. The addition of FRGO increases by more than an order of magnitude the sliding distance during which the dynamic friction is ≤ 0.1. After this distance, the friction sharply increases to the range of 0.4  0.5. We explain the increase in sliding distance during which the friction is low by formation of a transfer film from the nanocomposite to the counterface. The wear rates in the low and high friction regimes are approximately 1.5 x 104 mm3/N·m and 5.5 x 104 mm3/N·m, respectively. The nanocomposites exhibit a 74 % increase in Young’s modulus with 0.5 wt. % of FRGO, and an increase in glass transition and thermal degradation temperatures. digital.library.unt.edu/ark:/67531/metadc699889/
 Synthesis Strategies and a Study of Properties of Narrow and Wide Band Gap Nanowires
 Various techniques to synthesize nanowires and nanotubes as a function of growth temperature and time were investigated. These include growth of nanowires by a chemical vapor deposition (CVD) system using vaporliquidsolid (VLS) growth mechanism and electrochemical synthesis of nanowires and nanotubes. Narrow band gap InSb Eg = 0.17 eV at room temp) nanowires were successively synthesized. Using a phase diagram, the transition of the nanowire from metallic semiconducting semimetallic phase was investigated. A thermodynamic model is developed to show that the occurrence of native defects in InSb nanowires influenced by the nanowire growth kinetics and thermodynamics of defect formation. Wide band gap ZnO (Eg = 3.34 eV) and In2O3 (3.7 eV) were also synthesized. ZnO nanowires and nanotubes were successfully doped with a transition metal Fe, making it a Dilute Magnetic Semiconductor of great technological relevance. Structural and electronic characterizations of nanowires were studied for different semiconducting, metallic and semimetallic nanowires. Electron transport measurements were used to estimate intrinsic material parameters like carrier concentration and mobility. An efficient gas sensing device using a single In2O3 nanowire was studied and which showed sensitivity to reducing gas like NH3 and oxidizing gas like O2 gas at room temperature. The efficiency of the gas sensing device was found to be sensitive to the nature of contacts as well as the presence of surface states on the nanowire. digital.library.unt.edu/ark:/67531/metadc499984/
 Synthesis, Characterization, Structural, and Optical Properties of Zinc Oxide Nanostructures Embedded in Silicon Based Substrates
 Structural and optical properties of ZnO nanostructures synthesized by low energy ion implantation technique were examined. ZnO molecular ions were implanted into Si/SiO2 substrates at room temperature and then furnace annealed under different temperatures and environments. In all asimplanted samples only Zn nanostructures with varying diameters distributed into the Si/SiO2 matrices were observed. No trace of ZnO was found. The distributions of Zn nanostructures in Si/SiO2 closely matched results from Stopping and Range of Ions in Matter (SRIM) simulations. During annealing at 750 oC, Zn diffused both toward and away from the surface of the substrate and combine with oxygen to form ZnO nanostructures. At higher annealing temperatures ZnO bonding started to break down and transfer to zinc silicate (Zn2SiO4), and at 900 oC the ZnO was completely converted into Zn2SiO4. The average sizes of Zn/ZnO nanostructures depended on the ion fluence. If the fluence increased the average sizes of nanostructures also increased and vice versa. For room temperature photoluminescence (RTPL), bandedge emission in the ultraviolet (UV) region was observed from all samples annealed at 700 oC/750 oC and were slightly blue shifted as compare to bulk ZnO. Donorbound exciton (D,X) and acceptorbound exciton (A,X) transitions were observed in low temperature photoluminescence (PL). The lifetime of both donorbound excitonic emission (D, X) and acceptorbound excitonic emission (A, X) were found to be in the picosecond (ps) range. digital.library.unt.edu/ark:/67531/metadc500222/
 The Effects of Residual Gases on the Field Emission Properties of Zno, Gan, Zns Nanostructures, and the Effects of Light on the Resistivity of Graphene
 In this dissertation, I present that at a vacuum of 3×107 Torr, residual O2, CO2, H2 and Ar exposure do not significantly degrade the field emission (FE) properties of ZnO nanorods, but N2 exposure significantly does. I propose that this could be due to the dissociation of N2 into atomic nitrogen species and the reaction of such species with ZnO. I also present the effects of O2, CO2, H2O, N2, H2, and Ar residual gas exposure on the FE properties of GaN and ZnS nanostructure. A brief review of growth of ZnO, GaN and ZnS is provided. In addition, Cs deposition on GaN nanostructures at ultrahigh vacuum results in 30% decrease in turnon voltage and 60% in work function. The improvement in FE properties could be due to a Csinduced spacecharge layer at the surface that reduces the barrier for FE and lowers the work function. I describe a new phenomenon, in which the resistivity of CVDgrown graphene increases to a higher saturated value under light exposure, and depends on the wavelength of the light—the shorter the wavelength, the higher the resistivity. Firstprinciple calculations and theoretical analysis based on density functional theory show that (1) a water molecule close to a graphene defect is easier to be split than that of the case of no defect existing and (2) there are a series of metastable partially disassociated states for an interfacial water molecule. Calculated disassociation energies are from 2.5 eV to 4.6 eV, that match the experimental observation range of light wavelength from visible to 254 nm UV light under which the resistivity of CVDgrown graphene is increased. digital.library.unt.edu/ark:/67531/metadc500202/
 Effects of Quantum Coherence and Interference

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Quantum coherence and interference (QCI) is a phenomenon that takes place in all multilevel atomic systems interacting with multiple lasers. In this work QCI is used to create several interesting effects like lasing without inversion (LWI), controlling group velocity of light to extreme values, controlling the direction of propagation through nonlinear phase matching condition and for controlling the correlations in field fluctuations. Controlling group velocity of light is very interesting because of many novel applications it can offer. One of the unsolved problems in this area is to achieve a slow and fast light which can be tuned continuously as a function of frequency. We describe a method for creation of tunable slow and fast light by controlling intensity of incident laser fields using QCI effects. Lasers are not new to the modern world but an extreme ultraviolet laser or a xray laser is definitely one of the most desirable technologies today. Using QCI, we describe a method to realize lasing at high frequencies by creating lasing without inversion. Role of QCI in creating correlations and anticorrelations, which are generated by vacuum fluctuations, in a three level lambda system coupled to two strong fields is discussed. digital.library.unt.edu/ark:/67531/metadc500094/  How Cooperative Systems Respond to External Forces
 Cooperative interactions permeate through nature, bringing about emergent behavior and complexity. Using a simple cooperative model, I illustrate the mean field dynamics that occur at the critical point of a second order phase transition in the framework of Langevin equations. Through this formalism I discuss the response, both linear and nonlinear, to external forces. Emphasis is placed on how information is transferred from one individual to another in order to facilitate the collective response of the cooperative network to a localized perturbation. The results are relevant to a wide variety of systems, ranging from nematic liquid crystals, to flocks and swarms, social groups, and neural networks. digital.library.unt.edu/ark:/67531/metadc500014/
 An Electro Magnetostatic Field for Confinement of Charged Particle Beams and Plasmas
 A system is presented that is capable of confining an ion beam or plasma within a region that is essentially free of applied fields. An Artificially Structured Boundary (ASB) produces a spatially periodic set of magnetic field cusps that provides charged particle confinement. Electrostatic plugging of the magnetic field cusps enhances confinement. An ASB that has a small spatial period, compared to the dimensions of a confined plasma, generates electro magnetostatic fields with a short range. An ASBlined volume thus constructed creates an effectively field free region near its center. It is assumed that a nonneutral plasma confined within such a volume relaxes to a MaxwellBoltzmann distribution. Space charge based confinement of a second species of charged particles is envisioned, where the second species is confined by the space charge of the first nonneutral plasma species. An electron plasma confined within an ASBlined volume can potentially provide confinement of a positive ion beam or positive ion plasma. Experimental as well as computational results are presented in which a plasma or charged particle beam interact with the electro magnetostatic fields generated by an ASB. A theoretical model is analyzed and solved via selfconsistent computational methods to determine the behavior and equilibrium conditions of a relaxed plasma. The equilibrium conditions of a relaxed two species plasma are also computed. In such a scenario, space charge based electrostatic confinement is predicted to occur where a second plasma species is confined by the space charge of the first plasma species. An experimental apparatus with cylindrical symmetry that has its interior surface lined with an ASB is presented. This system was developed by using a simulation of the electro magnetostatic fields present within the trap to guide mechanical design. The construction of the full experimental apparatus is discussed. Experimental results that show the characteristics of electron beam transmission through the experimental apparatus are presented. A description of the experimental hardware and software used for trapping a charged particle beam or plasma is also presented. digital.library.unt.edu/ark:/67531/metadc500001/
 Novel SemiConductor Material Systems: Molecular Beam Epitaxial Growth and Characterization
 Semiconductor industry relies heavily on silicon (Si). However, Si is not a directband gap semiconductor. Consequently, Si does not possess great versatility for multifunctional applications in comparison with the direct bandgap IIIV semiconductors such as GaAs. To bridge this gap, what is ideally required is a semiconductor material system that is based on silicon, but has significantly greater versatility. While sparsely studied, the semiconducting silicides material systems offer great potential. Thus, I focused on the growth and structural characterization of ruthenium silicide and osmium silicide material systems. I also characterized iron silicon germanide films using extended xray absorption fine structure (EXAFS) to reveal phase, semiconducting behavior, and to calculate nearest neighbor distances. The choice of these silicides material systems was due to their theoretically predicted and/or experimentally reported direct band gaps. However, the challenge was the existence of more than one stable phase/stoichiometric ratio of these materials. In order to possess the greatest control over the growth process, molecular beam epitaxy (MBE) has been employed. Structural and film quality comparisons of asgrown versus annealed films of ruthenium silicide are presented. Structural characterization and film quality of MBE grown ruthenium silicide and osmium silicide films via in situ and ex situ techniques have been done using reflection high energy electron diffraction, scanning tunneling microscopy, atomic force microscopy, crosssectional scanning electron microscopy, xray photoelectron spectroscopy, and micro Raman spectroscopy. This is the first attempt, to the best of our knowledge, to grow osmium silicide thin films on Si(100) via the template method and compare it with the regular MBE growth method. The pros and cons of using the MBE template method for osmium silicide growth are discussed, as well as the structural differences of the asgrown versus annealed films. Future perspectives include further studies on other semiconducting silicides material systems in terms of growth optimization and characterization. digital.library.unt.edu/ark:/67531/metadc490047/
 Field Dependence of Optical Properties in Quantum Well Heterostructures Within the Wentzel, Kramers, and Brillouin Approximation
 This dissertation is a theoretical treatment of the electric field dependence of optical properties such as Quantum Confined Stark (QCS) shifts, Photoluminescence Quenching (PLQ), and Excitonic Mixing in quantum well heterostructures. The reduced spatial dimensionality in heterostructures greatly enhances these optical properties, more than in three dimensional semiconductors. Charge presence in the quantum well from doping causes the potential to bend and deviate from the ideal square well potential. A potential bending that varies as the square of distance measured from the heterostructure interfaces is derived selfconsistently. This potential is used to solve the timeindependent Schrodinger equation for bound state energies and wave functions within the framework of the Wentzel, Kramers, and Brillouin (WKB) approximation. The theoretical results obtained from the WKB approximation are limited to wide gap semiconductors with large split off bands such as gallium arsenidegallium aluminum arsenide and indium gallium arsenide—indium phosphide. Quantum wells with finite confinement heights give rise to an energy dependent WKB phase. External electric and magnetic fields are incorporated into the theory for two different geometries. For electric fields applied perpendicular to the heterostructure multilayers, QCS shifts and PLQ are found to be in excellent agreement with the WKB calculations. Orthogonality between electrons and holes gives rise to interband mixing in the presence of an external electric field. On the contrary, intraband mixing between light and heavy holes is not sufficiently accounted for in the WKB approximation. digital.library.unt.edu/ark:/67531/metadc330576/
 Lshell Xray production cross sections of ₂₉Cu, ₃₂Ge, ₃₇Rb, ₃₈Sr, and ₃₉Y and Mshell Xray production cross sections of ₇₉Au, ₈₂Pb, ₈₃Bi, ₉₀Th, and ₉₂U by 70200 keV protons
 Lshell xray production cross sections have been measured for thin targets of 29Cu, 32Ge, 37Rb, 38Sr, and 39Y. Mshell xray production cross sections have been measured for thin targets of 79Au, 82Pb, 83Bi, 90Th, and 92U. All targets were irradiated with a beam of H+ ions with energies in a range from 70 to 200 keV. Experimental cross sections are compared to other measurements at higher energies and to first Born (Plane Wave Born Approximation for direct ionization and OppenheimerBrinkmanKramersNikolaev approximation for electron capture) and the ECPSSR (Energy loss, Coulomb deflection, Perturbed Stationary State calculations with Relativistic effects) theoretical cross sections. digital.library.unt.edu/ark:/67531/metadc330628/
 Detection of the Resonant Vibration of the Cellular Membrane Using Femtosecond Laser Pulses
 An optical detection technique is developed to detect and measure the resonant vibration of the cellular membrane. Biological membranes are active components of living cells and play a complex and dynamic role in life processes. They are believed to have oscillation modes of frequencies in the range of 1 to 1000 GHz. To measure such a highfrequency vibration, a linear laser cavity is designed to produce a train of femtosecond pulses of adjustable repetition rate. The method is then directly applied to liposomes, "artificial membrane", stained with a liphophilic potential sensitive dye. The spectral behavior of a selection of potential sensitive dyes in the membrane is also studied. digital.library.unt.edu/ark:/67531/metadc331235/
 Nonlinear Absorption Initiated LaserInduced Damage in [Gamma]Irradiated Fused Silica, Fluorozirconate Glass and Cubic Zirconia
 The contributions of nonlinear absorption processes to laserinduced damage of three selected groups of transparent dielectrics were investigated. The studied materials were irradiated and nonirradiated fused silica, doped and undoped fluorozirconate glass and cubic zirconia stabilized with yttria. The laserinduced damage thresholds, prebreakdown transmission, and nonlinear absorption processes were studied for several specimens of each group. Experimental measurements were performed at wavelengths of 1064 nm and 532 nm using nanosecond and picosecond Nd:YAG laser pulses. In the irradiated fused silica and fluorozirconate glasses, we found that there is a correlation between the damage thresholds at wavelength λ and the linear absorption of the studied specimens at λ/2. In other words, the laserinduced breakdown is related to the probability of all possible twophoton transitions. The results are found to be in excellent agreement with a proposed twophotoninitiated electron avalanche breakdown model. In this model, the initial "seed" electrons for the formation of an avalanche are produced by twophoton excitations of E' centers and metallic impurity levels which are located within the bandgaps of irradiated Si02 and fluorozirconate glasses, respectively. Once the initial electrons are liberated in the conduction band, a highly absorbing plasma is formed by avalanche impact ionization. The resultant heating causes optical damage. In cubic zirconia, we present direct experimental evidence that significant energy is deposited in the samples at wavelength 532 nm prior to electron avalanche formation. The mechanism is found to be due to formation of color centers (F+ or F° centers) by the twophoton absorption process. The presence of these centers was directly shown by transmission measurements. The twophoton absorption (2PA) process was independently investigated and 2PA coefficients obtained. The accumulated effects of the induced centers on the nonlinear absorption measurements were also considered and the 2PA coefficients were measured using short pulses where this effect is negligible. At room temperature, the color centers slowly diffuse out of the irradiated region. The density of these centers was monitored as a function of time. The initial distribution of the centers was assumed to have a Gaussian profile. For this model the diffusion equation was solved exactly and the diffusion constant obtained. digital.library.unt.edu/ark:/67531/metadc331327/
 Microwave Spectra of ¹³C Isotopic Species of Methyl Cyanide in the Ground, v₈=1 and v₈=2 Vibrational States
 The problem of the quadrupole interaction occurring in a vibratingrotating C₃v symmetric top molecule has been studied in detail. The quadrupole interaction has been treated as another perturbation term to a general frequency expression accounting for the vibratingrotating interaction of the molecule so that a complete frequency formula is obtained for both interactions, and from which hyperfine spectral components are predicted and measured. The hyperfine transitions in the ground, and v₈=1 and v₈=2 excited vibrational states of the ¹³C isotopes of methyl cyanide have been investigated in the frequency range 1772 GHz, primarily in the low J transitions (0≤J≤3). The study of the ground state of isotope i3CH3i3CN, and the v₈=1, v₈=2 excited vibrational states for all the isotopes have been conducted here for the first time. A substantial perturbation has been discovered and discussed at the ΔJ=3→4 transitions within the Kl=1 sets in the v₈=1 mode for isotopes ¹³CH₃CN and CH₃¹³CN. A total of 716 hyperfine transitions have been assigned from measurements, only 7 of which have been measured previously. A total of 84 molecular constants have been reported; 70 of these constants are derived for the first time from microwave data. digital.library.unt.edu/ark:/67531/metadc332039/
 Cooperationinduced Criticality in Neural Networks
 The human brain is considered to be the most complex and powerful informationprocessing device in the known universe. The fundamental concepts behind the physics of complex systems motivate scientists to investigate the human brain as a collective property emerging from the interaction of thousand agents. In this dissertation, I investigate the emergence of cooperationinduced properties in a system of interacting units. I demonstrate that the neural network of my research generates a series of properties such as avalanche distribution in size and duration coinciding with the experimental results on neural networks both in vivo and in vitro. Focusing attention on temporal complexity and fractal index of the system, I discuss how to define an order parameter and phase transition. Criticality is assumed to correspond to the emergence of temporal complexity, interpreted as a manifestation of nonPoisson renewal dynamics. In addition, I study the transmission of information between two networks to confirm the criticality and discuss how the network topology changes over time in the light of Hebbian learning. digital.library.unt.edu/ark:/67531/metadc283813/
 Electron Density and Collision Frequency Studies Using a Resonant Microwave Cavity as a Probe
 Electron densities and collision frequencies were obtained on a number of gases in a dc discharge at low pressures (0.702mm of Hg). These measurements were performed by microwave probing of a filament of the dc discharge placed coaxially in a resonant cavity operating in a TM₀₁₀ mode. The equipment and techniques for making the microwave measurements employing the resonant cavity are described. One of the main features of this investigation is the technique of differentiating the resonance signal of the loaded cavity in order to make accurate measurements of the resonant frequency and halfpower point frequencies. digital.library.unt.edu/ark:/67531/metadc279091/
 Magnetomorphic Oscillations in Zinc
 In making this study it is important to search for ways to enhance and, if possible, make detection of MMO signals simpler in order that this technique for obtaining FS measurements may be extended to other materials. This attempt to improve measurement techniques has resulted in a significant discovery: the eddycurrent techniques described in detail in a later section which should allow MMO to be observed and sensitively measured in many additional solids. The second major thrust of the study has been to use the newly discovered eddycurrent technique in obtaining the first indisputable observation of MMO in zinc. digital.library.unt.edu/ark:/67531/metadc279266/
 QuantumConfined CdS Nanoparticles on DNA Templates
 As electronic devices became smaller, interest in quantumconfined semiconductor nanostructures increased. Selfassembled mesoscale semiconductor structures of IIVI nanocrystals are an especially exciting subject because of their controllable band gap and unique photophysical properties. Several preparative methods to synthesize and control the sizes of the individual nanocrystallites and the electronic and optical properties have been intensively studied. Fabrication of patterned nanostructures composed of quantumconfined nanoparticles is the next step toward practical applications. We have developed an innovative method to fabricate diverse nanostructures which relies on the size and a shape of a chosen deoxyribonucleic acid (DNA) template. digital.library.unt.edu/ark:/67531/metadc279352/
 Structural and Photoelectron Emission Properties of Chemical Vapor Deposition Grown Diamond Films
 The effects of methane (CH4), diborone (B2H6) and nitrogen (N2) concentrations on the structure and photoelectron emission properties of chemical vapor deposition (CVD) polycrystalline diamond films were studied. The diamond films were grown on singlecrystal Si substrates using the hottungsten filament CVD technique. Raman spectroscopy and xray photoelectron spectroscopy (XPS) were used to characterize the different forms of carbon in the films, and the fraction of sp3 carbon to sp3 plus sp2 carbon at the surface of the films, respectively. Scanning electron microscopy (SEM) was used to characterize the surface morphology of the films. The photoelectron emission properties were determined by measuring the energy distributions of photoemitted electrons using ultraviolet photoelectron spectroscopy (UPS), and by measuring the photoelectric current as a function of incident photon energy. digital.library.unt.edu/ark:/67531/metadc279053/
 On Delocalization Effects in Multidimensional Lattices
 A cubic lattice with random parameters is reduced to a linear chain by the means of the projection technique. The continued fraction expansion (c.f.e.) approach is herein applied to the density of states. Coefficients of the c.f.e. are obtained numerically by the recursion procedure. Properties of the nonstationary second moments (correlations and dispersions) of their distribution are studied in a connection with the other evidences of transport in a onedimensional Mori chain. The second moments and the spectral density are computed for the various degrees of disorder in the prototype lattice. The possible directions of the further development are outlined. The physical problem that is addressed in the dissertation is the possibility of the existence of a nonAnderson disorder of a specific type. More precisely, this type of a disorder in the onedimensional case would result in a positive localization threshold. A specific type of such nonAnderson disorder was obtained by adopting a transformation procedure which assigns to the matrix expressing the physics of the multidimensional crystal a tridiagonal Hamiltonian. This Hamiltonian is then assigned to an equivalent onedimensional tightbinding model. One of the benefits of this approach is that we are guaranteed to obtain a linear crystal with a positive localization threshold. The reason for this is the existence of a threshold in a prototype sample. The resulting linear model is found to be characterized by a correlated and a nonstationary disorder. The existence of such special disorder is associated with the absence of Anderson localization in specially constructed onedimensional lattices, when the noise intensity is below the nonzero critical value. This work is an important step towards isolating the general properties of a nonAnderson noise. This gives a basis for understanding of the insulator to metal transition in a linear crystal with a subcritical noise. digital.library.unt.edu/ark:/67531/metadc278868/
 Scanning Tunneling Microscopy of Epitaxial Diamond (110) and (111) Films and Field Emission Properties of Diamond Coated Molybdenum Microtips
 The growth mechanism of chemical vapor deposition (CVD) grown homoepitaxial diamond (110) and (111) films was studied using ultrahigh vacuum (UHV) scanning tunneling microscopy (STM). In addition, the field emission properties of diamond coated molybdenum microtips were studied as a function of exposure to different gases. digital.library.unt.edu/ark:/67531/metadc279160/
 Scaling Behaviors and Mechanical Properties of Polymer Gels
 Polymer gels undergo a volume phase transition in solvent in response to an infinitesimal environmental change. This remarkable phenomenon has resulted in many potential applications of polymer gels. The understanding of its mechanical properties has both scientific and technological importance. For this purpose, we have developed a novel method for measuring Poisson's ratio, which is one of the most important parameters determining the mechanical property of gels. Using this method, Poisson's ratio in Nisopropyacrylamide (NIPA) and polyacrylamide (PAAM) gels has been studied. digital.library.unt.edu/ark:/67531/metadc279278/
 Accelerator Mass Spectrometry Studies of Highly Charged Molecular Ions
 The existence of singly, doubly, and triply charged diatomic molecular ions was observed by using an Accelerator Mass Spectrometry (AMS) technique. The mean lifetimes of 3 MeV boron diatomic molecular ions were measured. No isotopic effects on the mean lifetimes of boron diatomic molecules were observed for charge state 3+. Also, the mean lifetime of SiF^3+ was measured. digital.library.unt.edu/ark:/67531/metadc279004/
 Experimental Synchronization of Chaotic Attractors Using Control
 The focus of this thesis is to theoretically and experimentally investigate two new schemes of synchronizing chaotic attractors using chaotically operating diode resonators. The first method, called synchronization using control, is shown for the first time to experimentally synchronize dynamical systems. This method is an economical scheme which can be viably applied to low dimensional dynamical systems. The other, unidirectional coupling, is a straightforward means of synchronization which can be implemented in fast dynamical systems where timing is critical. Techniques developed in this work are of fundamental importance for future problems regarding high dimensional chaotic dynamical systems or arrays of mutually linked chaotically operating elements. digital.library.unt.edu/ark:/67531/metadc278971/
 Charge State Dependence of MShell XRay Production in 67Ho by 212 MeV Carbon Ions
 The charge state dependence of Mshell xray production cross sections of 67HO bombarded by 212 MeV carbon ions with and without Kvacancies are reported. The experiment was performed using an NEC 9SDH2 tandem accelerator at the Ion Beam Modification and Analysis Laboratory of the University of North Texas. The high charge state carbon ions were produced by a postaccelerator stripping gas cell. Ultraclean holmium targets were used in ionatom collision to generate Mshell x rays at energies from 1.05 to 1.58 keV. The xray measurements were made with a windowless Si(Li) xray detector that was calibrated using radiative sources, particle induced xray emission (PIXE), and the atomic field bremsstrahlung (AFB) techniques. digital.library.unt.edu/ark:/67531/metadc278725/
 Deterministic Brownian Motion
 The goal of this thesis is to contribute to the ambitious program of the foundation of developing statistical physics using chaos. We build a deterministic model of Brownian motion and provide a microscpoic derivation of the FokkerPlanck equation. Since the Brownian motion of a particle is the result of the competing processes of diffusion and dissipation, we create a model where both diffusion and dissipation originate from the same deterministic mechanism  the deterministic interaction of that particle with its environment. We show that standard diffusion which is the basis of the FokkerPlanck equation rests on the Central Limit Theorem, and, consequently, on the possibility of deriving it from a deterministic process with a quickly decaying correlation function. The sensitive dependence on initial conditions, one of the defining properties of chaos insures this rapid decay. We carefully address the problem of deriving dissipation from the interaction of a particle with a fully deterministic nonlinear bath, that we term the booster. We show that the solution of this problem essentially rests on the linear response of a booster to an external perturbation. This raises a longstanding problem concerned with Kubo's Linear Response Theory and the strong criticism against it by van Kampen. Kubo's theory is based on a perturbation treatment of the Liouville equation, which, in turn, is expected to be totally equivalent to a firstorder perturbation treatment of single trajectories. Since the boosters are chaotic, and chaos is essential to generate diffusion, the single trajectories are highly unstable and do not respond linearly to weak external perturbation. We adopt chaotic maps as boosters of a Brownian particle, and therefore address the problem of the response of a chaotic booster to an external perturbation. We notice that a fully chaotic map is characterized by an invariant measure which is a continuous function of the control parameters of the map. Consequently if the external perturbation is made to act on a control parameter of the map, we show that the booster distribution undergoes slight modifications as an effect of the weak external perturbation, thereby leading to a linear response of the mean value of the perturbed variable of the booster. This approach to linear response completely bypasses the criticism of van Kampen. The joint use of these two phenomena, diffusion and friction stemming from the interaction of the Brownian particle with the same booster, makes the microscopic derivation of a FokkerPlanck equation and Brownian motion, possible. digital.library.unt.edu/ark:/67531/metadc279262/
 MagnetoOptical and Chaotic Electrical Properties of nInSb
 This thesis investigation concerns the optical and nonlinear electrical properties of nInSb. Two specific areas have been studied. First is the magnetooptical study of magnetodonors, and second is the nonlinear dynamic study of nonlinear and chaotic oscillations in InSb. The magnetooptical study of InSb provides a physical picture of the magnetodonor levels, which has an important impact on the physical model of nonlinear and chaotic oscillations. Thus, the subjects discussed in this thesis connect the discipline of semiconductor physics with the field of nonlinear dynamics. digital.library.unt.edu/ark:/67531/metadc279131/
 Studies of Particles and Wave Propagation in Periodic and Quasiperiodic Nonlinear Media
 This thesis examines the properties of transmission and transport of light and charged particles in periodic or quasiperiodic systems of solid state and optics, especially the nonlinear and external field effects and the dynamic properties of these systems. digital.library.unt.edu/ark:/67531/metadc278708/
 Angular Dependence of the Stopping Processes and the Yields of Ioninduced Electron Emission from Channeled MEV Protons in <100> Silicon Foils
 The present work reports the experimental evidence of anomalous energy loss, energy straggling, and the corresponding ioninduced electron emission yields of channeled protons in silicon. digital.library.unt.edu/ark:/67531/metadc279025/
 Studies of Classically Chaotic Quantum Systems within the PseudoProbablilty Formalism
 The evolution of classically chaotic quantum systems is analyzed within the formalism of Quantum PseudoProbability Distributions. Due to the deep connections that a quantum system shows with its classical correspondent in this representation, the PseudoProbability formalism appears to be a useful method of investigation in the field of "Quantum Chaos." In the first part of the thesis we generalize this formalism to quantum systems containing spin operators. It is shown that a classicallike equation of motion for the pseudoprobability distribution ρw can be constructed, dρw/dt = (L_CL + L_QGD)ρw, which is rigorously equivalent to the quantum von NeumannLiouville equation. The operator L_CL is undistinguishable from the classical operator that generates the semiclassical equations of motion. In the case of the spinboson system this operator produces semiclassical chaos and is responsible for quantum irreversibility and the fast growth of quantum uncertainty. Carrying out explicit calculations for a spinboson Hamiltonian the joint action of L_CL and L_QGD is illustrated. It is shown that the latter operator, L_QGD makes the spin system 'remember' its quantum nature, and competes with the irreversibility induced by the former operator. In the second part we test the idea of the enhancement of the quantum uncertainty triggered by the classical chaos by investigating the analogous effect of diffusive excitation in periodically kicked quantum systems. The classical correspondents of these quantum systems exhibit, in the chaotic region, diffusive behavior of the unperturbed energy. For the Quantum Kicked Harmonic Oscillator, in the case of quantum resonances, we provide an exact solution of the quantum evolution. This proves the existence of a deterministic drift in the energy increase over time of the system considered. More generally, this "superdiffusive" excitation of the energy is due to coherent quantum mechanical tunnelling between degenerate tori of the classical phase space. In conclusion we find that some of the quantum effects resulting from this fast increase do not have any classical counterpart, they are mainly tunnelling processes. This seems to be the first observation of an effect of this kind. digital.library.unt.edu/ark:/67531/metadc278979/
 The Stopping Power of Amorphous and Channelled Silicon at All Energies as Computed with the Binary Encounter Approximation
 This thesis utilizes the binary encounter approximation to calculate the stopping power of protons penetrating silicon. The main goal of the research was to make predictions of the stopping power of silicon for lowenergy and mediumenergy channelled protons, in the hope that this will motivate experiments to test the theory developed below. In attaining this goal, different stopping power theories were compared and the binary encounter approach was applied to random (nonchannelled) and highenergy channelled protons in silicon, and these results were compared with experimental data. digital.library.unt.edu/ark:/67531/metadc279387/
 Dielectric Relaxation of Aqueous Solutions at Microwave Frequencies for 335 GHz. Using a Loaded Microwave Cavity Operating in the TM010 Mode
 The frequency dependence and temperature dependence of the complex dielectric constant of water is of great interest. The temperature dependence of the physical properties of water given in the literature, specific heat, thermal conductivity, electric conductivity, pH, etc. are compared to the a. c. (microwave) and d. c. conductivity of water with a variety of concentration of different substances such as HC1, NaCl, HaS04, etc. When each of these properties is plotted versus inverse absolute temperature, it can be seen that each sample shows "transition temperatures". In this work, Slater's perturbation equations for a resonant microwave cavity were used to analyze the experimental results for the microwave data. digital.library.unt.edu/ark:/67531/metadc279039/
 Model for Longrange Correlations in DNA Sequences
 We address the problem of the DNA sequences developing a "dynamical" method based on the assumption that the statistical properties of DNA paths are determined by the joint action of two processes, one deterministic, with longrange correlations, and the other random and delta correlated. The generator of the deterministic evolution is a nonlinear map, belonging to a class of maps recently tailored to mimic the processes of weak chaos responsible for the birth of anomalous diffusion. It is assumed that the deterministic process corresponds to unknown biological rules which determine the DNA path, whereas the noise mimics the influence of an infinitedimensional environment on the biological process under study. We prove that the resulting diffusion process, if the effect of the random process is neglected, is an astable Levy process with 1 < a < 2. We also show that, if the diffusion process is determined by the joint action of the deterministic and the random process, the correlation effects of the "deterministic dynamics" are cancelled on the shortrange scale, but show up in the longrange one. We denote our prescription to generate statistical sequences as the Copying Mistake Map (CMM). We carry out our analysis of several DNA sequences, and of their CMM realizations, with a variety of techniques, and we especially focus on a method of regression to equilibrium, which we call the Onsager Analysis. With these techniques we establish the statistical equivalence of the real DNA sequences with their CMM realizations. We show that longrange correlations are present in exons as well as in introns, but are difficult to detect, since the exon "dynamics" is shown to be determined by theentaglement of three distinct and independent CMM's. Finally we study the validity of the stationary assumption in DNA sequences and we discuss a biological model for the shortrange random process based on a folding mechanism of the nucleic acid in the cell nucleus. digital.library.unt.edu/ark:/67531/metadc279189/
 On Chaos and Anomalous Diffusion in Classical and Quantum Mechanical Systems
 The phenomenon of dynamically induced anomalous diffusion is both the classical and quantum kicked rotor is investigated in this dissertation. We discuss the capability of the quantum mechanical version of the system to reproduce for extended periods the corresponding classical chaotic behavior. digital.library.unt.edu/ark:/67531/metadc278244/
 Steadystate and Dynamic Probe Characteristics in a Lowdensity Plasma
 The problem with which this investigation is concerned is that of determining the steadystate and dynamic characteristics of the admittance of a metallic probe immersed in a laboratory plasma which has the low electron densities and low electron temperatures characteristic of the ionospheric plasma. The problem is separated into three related topics: the design and production of the laboratory plasma, the measurement of the steadystate properties of dc and very low frequency probe admittance, and the study of transient ion sheath effects on radio frequency probe admittance. digital.library.unt.edu/ark:/67531/metadc278232/
 Evolution of Vacancy Supersaturations in MeV Si Implanted Silicon
 Highenergy Si implantation into silicon creates a net defect distribution that is characterized by an excess of interstitials near the projected range and a simultaneous excess of vacancies closer to the surface. This defect distribution is due to the spatial separation between the distributions of interstitials and vacancies created by the forward momentum transferred from the implanted ion to the lattice atom. This dissertation investigates the evolution of the nearsurface vacancy excess in MeV Siimplanted silicon both during implantation and postimplant annealing. Although previous investigations have identified a vacancy excess in MeVimplanted silicon, the investigations presented in this dissertation are unique in that they are designed to correlate the freevacancy supersaturation with the vacancies in clusters. Freevacancy (and interstitial) supersaturations were measured with Sb (B) dopant diffusion markers. Vacancies in clusters were profiled by Au labeling; a new technique based on the observation that Au atoms trap in the presence of openvolume defects. The experiments described in this dissertation are also unique in that they were designed to isolate the deep interstitial excess from interacting with the much shallower vacancy excess during postimplant thermal processing. digital.library.unt.edu/ark:/67531/metadc277663/
 Distribution of Nighttime Fregion Molecular Ion Concentrations and 6300 Å Nightglow Morphology
 The purpose of this study is twofold. The first is to determine the dependence of the molecular ion profiles on the various ionospheric and atmospheric parameters that affect their distributions. The second is to demonstrate the correlation of specific ionospheric parameters with 6300 Å nightglow intensity during periods of magnetically quiet and disturbed conditions. digital.library.unt.edu/ark:/67531/metadc278620/
 Charge State Distributions in Molecular Dissociation
 The present work provides charge state fractions that may be used to generate TEAMS relative sensitivity factors for impurities in semiconductor materials. digital.library.unt.edu/ark:/67531/metadc278340/
 Anisotropic Relaxation Time for Solids with Ellipsoidal Fermi Surfaces
 Many solids have Fermi surfaces which are approximated as ellipsoids. A comprehensive solution for the magnetoconductivity of an ellipsoid is obtained which proves the existence of a relaxation time tensor which can be anisotropic and which is a function of energy only. digital.library.unt.edu/ark:/67531/metadc278322/
 Fluorine Adsorption and Diffusion in Polycrystalline Silica
 The measurement of fluorine penetration into archeological flint artifacts using Nuclear Reaction Analysis (NRA) has been reported to be a potential dating method. However, the mechanism of how fluorine is incorporated into the flint surface, and finally transported into the bulk is not well understood. This research focuses on the study of the fluorine uptake phenomenon of flint mineral in aqueous fluoride solutions. Both theoretical and experimental approaches have been carried out. In a theoretical approach, a pipediffusion model was used to simulate the complicated fluorine transportation problem in flint, in which several diffusion mechanisms may be involved. digital.library.unt.edu/ark:/67531/metadc277986/
 TwoFold Role of Randomness: A Source of Both LongRange Correlations and Ordinary Statistical Mechanics
 The role of randomness as a generator of long range correlations and ordinary statistical mechanics is investigated in this Dissertation. The difficulties about the derivation of thermodynamics from mechanics are pointed out and the connection between the ordinary fluctuationdissipation process and possible anomalous properties of statistical systems is highlighted. digital.library.unt.edu/ark:/67531/metadc278012/
 Synthesis and Study of Engineered Heterogenous Polymer Gels
 This dissertation studies physical properties and technological applications of engineered heterogenous polymer gels. Such gels are synthesized based on modulation of gel chemical nature in space. The shape memory gels have been developed in this study by using the modulated gel technology. At room temperature, they form a straight line. As the temperature is increased, they spontaneously bend or curl into a predetermined shape such as a letter of the alphabet, a numerical number, a spiral, a square, or a fish. The shape changes are reversible. The heterogenous structures have been also obtained on the gel surface. The central idea is to cover a dehydrated gel surface with a patterned mask, then to sputterdeposit a gold film onto it. After removing the mask, a gold pattern is left on the gel surface. Periodical surface array can serve as gratings to diffract light. The grating constant can be continuously changed by the external environmental stimuli such as temperature and electric field. Several applications of gels with periodic surface arrays as sensors for measuring gel swelling ratio, internal strain under an uniaxial stress, and shear modulus have been demonstrated. The porous NIPA gels have been synthesized by suspension technique. Microstructures of newly synthesized gels are characterized by both SEM and capillary test and are related to their swelling and mechanical properties. The heterogenous porous NIPA gel shrink about 35,000 times faster than its counterpartthe homogeneous NIPA gel. Development of such fast responsive gels can result in sensors and devices applications. A new gel system with builtin anisotropy is studied. This gel system consists of interpenetrated polymer network (IPN) gels of polyacrylamide (PAAM) and Nisopropylacrylamide (NIPA). The swelling property of the anisotropy IPN gels along the prestressing direction is different from that along other directions, in contrast to conventional gels which swell isotropically. It is found that the ratio (L/D) of length (L) and diameter (D) of IPN samples has stepwise changes as the samples are heated from below the volume phase transition temperature to the above. A theoretical model is proposed and is in good agreement with the experimental results. digital.library.unt.edu/ark:/67531/metadc278503/
 Numerical Investigations of Quantum Effects of Chaos
 The quantum dynamics of minimum uncertainty wave packets in a system described by the surfacestateelectron (SSE) Hamiltonian are studied herein. digital.library.unt.edu/ark:/67531/metadc278488/
 Characterization and Field Emission Properties of Mo2C and Diamond Thin Films Deposited on Mo Foils and Tips by Electrophoresis
 In this dissertation M02C and diamond films deposited by electrophoresis on flat Mo foils and tips have been studied to determine their suitability as field emission tips. digital.library.unt.edu/ark:/67531/metadc278393/
 Z1 Dependence of IonInduced Electron Emission
 Knowledge of the atomic number (Zt) dependence of ioninduced electron emission yields (Y) can be the basis for a general understanding of ionatom interaction phenomena and, in particular, for the design of Zrsensitive detectors that could be useful, for example, in the separation of isobars in accelerator mass spectrometry. The Zx dependence of ioninduced electron emission yields has been investigated using heavy ions of identical velocity (v = 2 v0, with v0 as the Bohr velocity) incident in a normal direction on sputtercleaned carbon foils. Yields measured in this work plotted as a function of the ion's atomic number reveal an oscillatory behavior with pronounced maxima and minima. This nonmonotonic dependence of the yield on Zx will be discussed in the light of existing theories. digital.library.unt.edu/ark:/67531/metadc277977/
 Expulsion of Carriers from the DoubleBarrier Quantum Well and Investigation of Its Spectral and Transport Consequences
 In this work I investigate the expulsion of carriers from nanostructures using the doublebarrier quantum well (DBQW) as an example and discuss manifestations of this effect in the spectrum of the DBQW in absence of bias, and in the tunneling current in presence of bias. Assuming equality of the Fermi energy in all regions of the considered system, I compute the relative density of carriers localized in the DBQW and conclude that a fraction of carriers is expelled from this nanostructure. digital.library.unt.edu/ark:/67531/metadc277697/