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 Collection: UNT Theses and Dissertations
Mineola

Mineola

Date: December 2015
Creator: Cater, Lauren
Description: Mineola is a poetic, observational, immersive documentary centered in the town of Mineola, Texas. The film provides an intimate, first person perspective of different locations in the town as well as underlying subversive beliefs and traditions. The film’s authoritative perspective guides the viewer not only in a direction of observation but personal connection to nostalgia of small communities.
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Longitudinal Prevalence of Disordered Eating and Weight Control Behaviors in Female Collegiate Athletes

Longitudinal Prevalence of Disordered Eating and Weight Control Behaviors in Female Collegiate Athletes

Date: December 2015
Creator: Thompson, Alexandra J.
Description: Female collegiate athletes have been established as a high-risk group for the development of eating disorders due to the high prevalence rates of clinical and subclinical eating disorders, which have ranged from 1.9% to 16.6% and 4.0% to 26.1%, respectively. Collegiate athletes appear to meet criteria for ED-NOS more often than anorexia or bulimia nervosa, and frequently engage in pathogenic weight control behaviors (e.g., dieting, excessive exercise). To date, only a few studies have examined the long-term stability of eating disorders in collegiate female athletes. The current study investigated the prevalence of eating disorders (i.e., eating disordered, symptomatic, and asymptomatic) and pathogenic weight control behaviors (e.g, binging, vomiting, laxative use) in 325 NCAA-DI female collegiate gymnasts and swimmers/divers across two time points – the beginning of their competitive seasons (Time 1) and during the final two weeks of their competitive seasons (Time 2). By Time 2, 90% of the athletes classified as eating disordered at Time 1 (n = 20) maintained clinical or subclinical eating disturbances. Of the 83 athletes originally symptomatic, 37.3% remained so and 10.8% became eating disordered. Significantly more athletes became satisfied with their bodies over the course of the season than became dissatisfied. The athletes reported ...
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Effects of Child Development Associate Credential System 20 on Candidate Success Rates

Effects of Child Development Associate Credential System 20 on Candidate Success Rates

Date: December 2015
Creator: Davis, Travis J.
Description: The purpose of this research was to identify the impact of process changes that have been made to the Child Development Associate (CDA) credential, which is a beginning early childhood teacher credential that focuses on competency based standards widely seen as necessary for early childhood teachers to possess. The process in which early childhood teachers receive their credential changed in 2013 with the implementation of CDA credential 2.0. Changes included taking a computerized exam and the implementation of a professional development specialist conducting an on-site classroom observation. In order to determine the impact that CDA 2.0 had on teacher credentialing success rates, a mixed-method sequential design was employed. First, existing data sets of success rates from a national scholarship program were reviewed. Following, interviews with CDA credential seekers were conducted. Findings revealed that while candidate success rates increased for those receiving CDA credentials under the 2.0 system, the actual number of candidates receiving scholarships to pursue the CDA credential through the national scholarship program decreased. Qualitative analysis of the semi-structured interviews indicated that three areas that impacted CDA 2.0 candidate success rates were the professional education programs and instructors, the CDA Exam, and Professional Development Specialists. This is the first ...
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The Role of Crystallographic Texture in Achieving Low Friction Zinc Oxide Nanolaminate Films

The Role of Crystallographic Texture in Achieving Low Friction Zinc Oxide Nanolaminate Films

Date: December 2015
Creator: Mojekwu, Nneoma
Description: Metal oxide nanolaminate films are potential high temperature solid lubricants due to their ability to exhibit significant plasticity when grain size is reduced to the nanometer scale, and defective growth structure is achieved by condensation of oxygen vacancies to form intrinsic stacking faults. This is in contrast to conventional microcrystalline and single crystal oxides that exhibit brittle fracture during loading in a sliding contact. This study emphasizes the additional effect of growth orientation, in particular crystallographic texture, on determining the sliding friction behavior in nanocolumnar grain zinc oxide films grown by atomic layer deposition. It was determined that zinc oxide low (0002) versus higher (101 ̅3) surface energy crystallographic planes influenced the sliding friction coefficient. Texturing of the (0002) grains resulted in a decreased adhesive component of friction thereby lowering the sliding friction coefficient to ~0.25, while the friction coefficient doubled to ~0.5 with increasing contribution of surface (101 ̅3) grains. In addition, the variation of the x-ray grazing incident angle from 0.5° to 5° was studied to better understand the surface grain orientation as a function of ZnO layer thickness in one versus four bilayer nanolaminates where the under layer (seed layer) was load-bearing Zn(Ti,Zr)O3.
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Does Instructional Delivery Method in an Elective Business Class Impact Student Achievement with Respect to Gender, Race and Socio-economic Status in a Selected Texas Public School District?

Does Instructional Delivery Method in an Elective Business Class Impact Student Achievement with Respect to Gender, Race and Socio-economic Status in a Selected Texas Public School District?

Date: December 2015
Creator: Moore, Eldridge D.
Description: The problem that guided this study was a socio-constructivist view of education via online learning. Based in the extant literature, a deficiency existed that directly correlated online learning closing the academic achievement gap between student populations. In other words, schools invested in technology; however, few empirical data sets existed that established a connection between technology integration and the academic achievement of different student groups. The purpose of this pooled regression analysis study was to determine whether the method of class instruction effected academic achievement gaps between three subpopulations based on gender, race, and SES. Specifically, this study examined whether gender, race, and SES could predict semester grades within and across traditional, blended, and online course instructional methods. The dependent variable for this study was student success in the form of an end-of-unit test grade designed to evaluate student understanding of the curriculum. The independent variables included student gender, ethnicity, and SES. Quantitative data were collected through an analysis of Public Education Information Management System (PEIMS) data and student end-of-unit exam grades. The research suggests one combined interaction, [gender x race] in the traditional learning environment, is statistically significant while several independent interactions are significant. Those independent interactions are TAKS scores, ...
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Fundamental Studies of Copper Corrosion in Interconnect Fabrication Process and Spectroscopic Investigation of Low-k Structures

Fundamental Studies of Copper Corrosion in Interconnect Fabrication Process and Spectroscopic Investigation of Low-k Structures

Date: December 2015
Creator: Goswami, Arindom
Description: In the first part of this dissertation, copper bimetallic corrosion and its inhibition in cleaning processes involved in interconnect fabrication is explored. In microelectronics fabrication, post chemical mechanical polishing (CMP) cleaning is required to remove organic contaminants and particles left on copper interconnects after the CMP process. Use of cleaning solutions, however, causes serious reliability issues due to corrosion and recession of the interconnects. In this study, different azole compounds are explored and pyrazole is found out to be a potentially superior Cu corrosion inhibitor, compared to the most widely used benzotriazole (BTA), for tetramethyl ammonium hydroxide (TMAH)-based post CMP cleaning solutions at pH 14. Micropattern corrosion screening results and electrochemical impedance spectroscopy (EIS) revealed that 1 mM Pyrazole in 8 wt% TMAH solution inhibits Cu corrosion more effectively than 10 mM benzotriazole (BTA) under same conditions. Moreover, water contact angle measurement results also showed that Pyrazole-treated Cu surfaces are relatively hydrophilic compared to those treated with BTA/TMAH. X-ray photoelectron spectroscopy (XPS) analysis supports Cu-Pyrazole complex formation on the Cu surface. Overall Cu corrosion rate in TMAH-based highly alkaline post CMP cleaning solution is shown to be considerably reduced to less than 1Å/min by addition of 1 mM Pyrazole. In ...
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The Impact of Computational Methods on Transition Metal-containing Species

The Impact of Computational Methods on Transition Metal-containing Species

Date: December 2015
Creator: Wang, Jiaqi
Description: Quantum chemistry methodologies can be used to address a wide variety of chemical problems. Key to the success of quantum chemistry methodologies, however, is the selection of suitable methodologies for specific problems of interest, which often requires significant assessment. To gauge a number of methodologies, the utility of density functionals (BLYP, B97D, TPSS, M06L, PBE0, B3LYP, M06, and TPSSh) in predicting reaction energetics was examined for model studies of C-O bond activation of methoxyethane and methanol. These species provide excellent representative examples of lignin degradation via C-O bond cleavage. PBE0, which performed better than other considered DFT functionals, was used to investigate late 3d (Fe, Co, and Ni), 4d (Ru, Rh, and Pd), and 5d (Re, Os, and Ir) transition metal atom mediated Cβ -O bond activation of the β–O–4 linkage of lignin. Additionally, the impact of the choice of DFT functionals, basis sets, implicit solvation models, and layered quantum chemical methods (i.e., ONIOM, Our Own N-layered Integrated molecular Orbital and molecular Mechanics) was investigated for the prediction of pKa for a set of Ni-group metal hydrides (M = Ni, Pd, and Pt) in acetonitrile. These investigations have provided insight about the utility of a number of theoretical methods in ...
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Shame Due to Heterosexism, Self-esteem and Perceived Stress: Correlates of Psychological Quality of Life in a Lesbian, Gay and Bisexual Sample

Shame Due to Heterosexism, Self-esteem and Perceived Stress: Correlates of Psychological Quality of Life in a Lesbian, Gay and Bisexual Sample

Date: December 2015
Creator: Bonds,Stacy E.
Description: Sexual minorities experience higher levels of stress than heterosexuals, which in turn affects coping and psychological quality of life (PQOL). Although many sexual minorities remain mentally healthy, a higher prevalence of mental disorders among members of the lesbian, gay and bisexual (LGB) communities exists; thus, LGB PQOL becomes an important area to examine. Several key factors are related to PQOL: shame due to heterosexism, self-esteem and perceived stress. Using minority stress model, I hypothesized that shame due to heterosexism and perceived stress are negatively correlated with PQOL, while self-esteem is positively correlated with PQOL. I hypothesized that collectively shame due to heterosexism, self-esteem and perceived stress account for a significant proportion of the variance in PQOL, that self-esteem moderates the relationship between perceived stress and PQOL and that age moderates the relationship between shame due to heterosexism and PQOL. I calculated Pearson product-moment correlation coefficient and found shame due to heterosexism was negatively correlated with PQOL (r(146) = -.21, p = .009), perceived stress was negatively correlated with PQOL (r (146) = -.69, p < .001) and self-esteem was positively correlated with PQOL (r(146) = .72, p < .001). I conducted a regression analysis and found our model accounted for ...
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On City Identity and Its Moral Dimensions

On City Identity and Its Moral Dimensions

Date: December 2015
Creator: Epting, Shane Ray
Description: The majority of people on Earth now live in cities, and estimates hold that 60 percent of the world’s cities have yet to be built. Now is the time for philosophers to develop a philosophy of the city to address the forthcoming issues that urbanization will bring. In this dissertation, I respond to this need for a philosophy of the city by developing a theory of city identity, developing some of the theory’s normative implications, illustrating the theory with a case study, and outlining the nature and future of philosophy of the city more generally. Indeed, this dissertation is only a part of my larger project of founding and institutionalizing this new field of both academic and socially-engaged philosophical activity. Throughout the history of the discipline, other areas such a personal identity have received numerous considerations, along with the concept of identity as an abstraction. For example, there is a bounty of research addressing problems pertaining to how objects and people retain an identity over time and claims about identity in general. While one could argue that cities are not any different than any other object, such an account fails to consider that a city’s dynamic nature makes it dissimilar ...
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Guidelines for Greening (Renovation) of Existing Homes

Guidelines for Greening (Renovation) of Existing Homes

Date: December 2015
Creator: Shaikh, Gilman Yusuf
Description: This Thesis is aimed at evaluating the options of renovation for an existing residential building to make it more energy efficient. The various aspects in the basic structures of residential homes are discussed in order to help the user identify the areas of the house for which renovation is required to improve the energy efficiency of the building. These aspects include doors, roof and wall in addition to various systems of electrical wiring, mechanical systems of ventilation, heating and cooling and plumbing systems for the efficient flow of water throughout the house. The renovation options have been described in detail to provide as many possibilities to the user as possible. The building taken for renovation is a 1953 suburban home which has been awarded the honor of being the first building to be labeled as Zero Energy Home in its vicinity. This has made the home so efficient that its expenditure of energy has become equivalent to its energy generation, therefore, cancelling each other out and creating an estimate of zero energy.
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