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Journal of Applied Rehabilitation Counseling, Volume 45, Number 4, Winter 2014
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. In the current special issue (Vol. 45, No.4) of JARC, which focused on the issues related to Ex-Offender Population and Employment, the following six articles were included: - Vulnerability and Marginalization of Adult Ex-Offenders with Disabilities in Community and Employment Reintegration (Debra A. Harley, Becky Cabe, Ralph Woolums, and Tyra Turner-Whittaker) - Engaging Employers and Business in the Hiring of Individuals with Criminal Records (J. Gordon Swensen, John Rakis, Melanie G. Snyder, and Randall E. Loss) - Disability, Race and Ex-Offender Status: The Tri-vector Challenge to Employment (Sonja Feist-Price, Lisa Lavergne, and Michelle Davis) - How Gender of Ex-Offenders Influences Access to Employment Opportunities (Rebecca L. Richardson and Shawn M. Flower) - Aging, Incarceration, and Employment Prospects: Recommendations for Practice and Policy Reform (Tina Maschi, Keith Morgen, Kimberly Westcott, Deborah Viola, and Lindsay Koskinen) - Ex-Offenders in Rural Settings Seeking Employment (Glacia Ethridge, Paige N. Dunlap, Quintin Boston, and Bridget H. Staten). digital.library.unt.edu/ark:/67531/metadc488198/
Journal of Applied Rehabilitation Counseling, Volume 45, Number 3, Fall 2014
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. In the current issue (Vol. 45, No.3) of JARC, the following four articles were included: - Animal-Assisted Therapy for Fetal Alcohol Spectrum Disorder (Brooke Vincent, Caley Kropp, and Andrew M. Byrne) - Adult Ex-Offender Population and Employment: A Synthesis of the Literature on Recommendations and Best Practices (Debra A. Harley) - Colorectal Cancer and Rehabilitation Counseling (Robert Hewes and Bernard J. Graney) - The Human Animal Bond: Applications for Rehabilitation Professionals (Denise Silcox, Yuleinys A. Castillo, and Bruce J. Reed). digital.library.unt.edu/ark:/67531/metadc463546/
Immunohistochemistry of the Gills of the Channel Catfish Ictalurus Punctatus: Cells and Neurochemicals That May Be Involved in the Control of Cardioventilatory Reflexes
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In teleost fishes the neurochemicals involved in sensing and responding to hypoxia are unresolved. Serotonergic branchial neuroepithelial cells (NECs) are putative O2 chemoreceptors believed to be homologous to the neural crest (NC) derived APUD (amine-precursor uptake and decarboxylation) pulmonary NECs and carotid body type-1 glomus cells. Branchial NECs contain serotonin (5-HT), thought to be central to the induction of the hypoxic cardioventilatory reflexes. However, application of 5-HT in vivo does not elicit cardioventilatory reflexes similar to those elicited by hypoxia. But previous in vitro neural recordings from glossopharyngeal (IX) afferents innervating O2 chemoreceptors in the trout gill show the same discharge response to hypoxic conditions as does that of acetylcholine (ACh) application. This evidence strongly supports the cholinergic hypothesis of chemoreceptor impulse origin rather than a serotonergic-induced impulse origin model. We therefore hypothesized that NECs contain ACh among other neurochemicals in cells belonging to the APUD series. Although serotonergic branchial NECs did not colocalize with ACh using immunohistochemical methods, several populations of ACh and/or tyrosine hydroxylase (TH) (catecholaminergic) positive, dopamine (DA) negative, cells were found throughout the second gill arch of the channel catfish Ictalurus punctatus. In addition, the NC derivation marker zn-12 labelled the HNK-1-like epitope (Human natural killer) expressed by lamellar pillar cells’ collagen column-associated pillar cell adhesion molecules (CC-PCAMs), evidence confirming their hypothesized NC origin. digital.library.unt.edu/ark:/67531/metadc407757/
Tribological Behavior of Spark Plasma Sintered Tic/graphite/nickel Composites and Cobalt Alloys
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Monolithic composites are needed that combine low friction and wear, high mechanical hardness, and high fracture toughness. Thin films and coatings are often unable to meet this engineering challenge as they can delaminate and fracture during operation ceasing to provide beneficial properties during service life. Two material systems were synthesized by spark plasma sintering (SPS) and were studied for their ability to meet these criteria. A dual hybrid composite was fabricated and consisted of a nickel matrix for fracture toughness, TiC for hardness and graphite for solid/self‐lubrication. An in‐situ reaction during processing resulted in the formation of TiC from elemental Ti and C powders. The composition was varied to determine its effects on tribological behavior. Stellite 21, a cobalt‐chrome‐molybdenum alloy, was also produced by SPS. Stellite 21 has low stacking fault energy and a hexagonal phase which forms during sliding that both contribute to low interfacial shear and friction. Samples were investigated by x‐ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive x‐ray spectroscopy (EDS), and electron back‐scattered diffraction (EBSD). Tribological properties were characterized by pin on disc tribometry and wear rates were determined by profilometry and abrasion testing. Solid/self‐lubrication in the TiC/C/Ni system was investigated by Raman and Auger mapping. A tribofilm, which undergoes a stress‐induced phase transformation from polycrystalline graphite to amorphous carbon, was formed during sliding in the TiC/C/Ni system that is responsible for low friction and wear. TiC additions help to further decrease wear. Stellite 21 was also found to exhibit acceptably low friction and wear properties arising from the presence of Cr23C6 in the matrix and work hardening of the cobalt and chromium during sliding. digital.library.unt.edu/ark:/67531/metadc407776/
A Comprehensive Modeling Framework for Airborne Mobility
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Mobility models serve as the foundation for evaluating and designing airborne networks. Due to the significant impact of mobility models on the network performance, mobility models for airborne networks (ANs) must realistically capture the attributes of ANs. In this paper, I develop a comprehensive modeling framework for ANs. The work I have done is concluded as the following three parts. First, I perform a comprehensive and comparative analysis of AN mobility models and evaluate the models based on several metrics: 1) networking performance, 2) ability to capture the mobility attributes of ANs, 3) randomness levels and 4) associated applications. Second, I develop two 3D mobility models and realistic boundary models. The mobility models follow physical laws behind aircraft maneuvering and therefore capture the characteristics of aircraft trajectories. Third, I suggest an estimation procedure to extract parameters in one of the models that I developed from real flight test data. The good match between the estimated trajectories and real flight trajectories also validate the suitability of the model. The mobility models and the estimation procedure lead to the creation of “realistic” simulation and evaluation environment for airborne networks. digital.library.unt.edu/ark:/67531/metadc407760/
Boosting for Learning From Imbalanced, Multiclass Data Sets
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In many real-world applications, it is common to have uneven number of examples among multiple classes. The data imbalance, however, usually complicates the learning process, especially for the minority classes, and results in deteriorated performance. Boosting methods were proposed to handle the imbalance problem. These methods need elongated training time and require diversity among the classifiers of the ensemble to achieve improved performance. Additionally, extending the boosting method to handle multi-class data sets is not straightforward. Examples of applications that suffer from imbalanced multi-class data can be found in face recognition, where tens of classes exist, and in capsule endoscopy, which suffers massive imbalance between the classes. This dissertation introduces RegBoost, a new boosting framework to address the imbalanced, multi-class problems. This method applies a weighted stratified sampling technique and incorporates a regularization term that accommodates multi-class data sets and automatically determines the error bound of each base classifier. The regularization parameter penalizes the classifier when it misclassifies instances that were correctly classified in the previous iteration. The parameter additionally reduces the bias towards majority classes. Experiments are conducted using 12 diverse data sets with moderate to high imbalance ratios. The results demonstrate superior performance of the proposed method compared to several state-of-the-art algorithms for imbalanced, multi-class classification problems. More importantly, the sensitivity improvement of the minority classes using RegBoost is accompanied with the improvement of the overall accuracy for all classes. With unpredictability regularization, a diverse group of classifiers are created and the maximum accuracy improvement reaches above 24%. Using stratified undersampling, RegBoost exhibits the best efficiency. The reduction in computational cost is significant reaching above 50%. As the volume of training data increase, the gain of efficiency with the proposed method becomes more significant. digital.library.unt.edu/ark:/67531/metadc407775/
American Indian Worldviews, Risk Perceptions and Disaster Planning: an Exploratory Study
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It is commonly assumed that when confronted with an imminent hazard that people will react rationally, and prepare for, or at least attempt to avoid, danger from pending disasters. However, this conventional wisdom is not as evident as it appears. People prepare for, react to, or take social action to avoid hazards when they perceive the risk of danger to be threatening enough to warrant action, providing one has the will, insight and resources to do so. However, not all people perceive risks similarly. Risk is perceived differently by different people which affects risk perception and responses to hazards. This dissertation explores the relationships between American Indian worldviews, risk perceptions and disaster planning. To carry out this research 28 American Indians were interviewed. The sample consists of 14 American Indians residing in a rural are on the northern plains and 14 urban American Indians. The results only partially support that worldview is linked to risk perception and subsequent disaster planning. Other factors found to relate to risk perception and disaster planning for this non-representative sample of American Indians include various forms of social vulnerability. digital.library.unt.edu/ark:/67531/metadc407742/
Molecular and Functional Characterization of Medicago Truncatula Npf17 Gene
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Legumes are unique among plants for their ability to fix atmospheric nitrogen with the help of soil bacteria rhizobia. Medicago truncatula is used as a model legume to study different aspects of symbiotic nitrogen fixation. M. truncatula, in association with its symbiotic partner Sinorhizobium meliloti, fix atmospheric nitrogen into ammonia, which the plant uses for amino acid biosynthesis and the bacteria get reduced photosynthate in return. M. truncatula NPF1.7 previously called MtNIP/LATD is required for symbiotic nitrogen fixing root nodule development and for normal root architecture. Mutations in MtNPF1.7 have defects in these processes. MtNPF1.7 encodes a member of the NPF family of transporters. Experimental results showing that MtNPF1.7 functioning as a high-affinity nitrate transporter are its expression restoring chlorate susceptibility to the Arabidopsis chl1-5 mutant and high nitrate transport in Xenopus laevis oocyte system. However, the weakest Mtnip-3 mutant allele also displays high-affinity nitrate transport in X. laevis oocytes and chlorate susceptibility to the Atchl1-5 mutant, suggesting that MtNPF1.7 might have another biochemical function. Experimental evidence shows that MtNPF1.7 also functions in hormone signaling. Constitutive expression of MtNPF1.7 in several species including M. truncatula results in plants with a robust growth phenotype. Using a synthetic auxin reporter, the presence of higher auxin in both the Mtnip-1 mutant and in M. truncatula plants constitutively expressing MtNPF1.7 was observed. Previous experiments showed MtNPF1.7 expression is hormone regulated and the MtNPF1.7 promoter is active in root and nodule meristems and in the vasculature. Two potential binding sites for an auxin response factors (ARFs) were found in the MtNPF1.7 promoter. Chromatin immunoprecipitation-qRT-PCR confirmed MtARF1 binding these sites. Mutating the MtARF1 binding sites increases MtNPF1.7 expression, suggesting a mechanism for auxin repression of MtNPF1.7. Consistent with these results, constitutive expression of an ARF in wild-type plants partially phenocopies Mtnip-1 mutants’ phenotypes. digital.library.unt.edu/ark:/67531/metadc407747/
Witchcraft: a Targeted Societal Discrimination Against Women in Northern Ghana
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A combination of aging and poverty is becoming dominant in African society today, at a time when African countries are expected to be recovering from poverty, and are projected to house the economic growth of the next century. The emergence of aging in African context and the aging of the world population will expose the weakness of the current mechanisms used for older people around the world. As economies grow around the world, the distribution gap between the affluent and the poor widens, and the constant struggles for wealth, power, and social status, amidst scarce resources, continue to be sustained. To remain in charge of economic resources, the powerful few devise means to disenfranchise the weak, and witchcraft accusation is one of such tools used in Northern Ghana today. A new wave of witchcraft accusation has caught the attention of many in Northern Ghana. These victims with certain socioeconomic characteristics appear helpless and without defense against such accusations. As a result, they suffer untold hardships and are often compelled to leave their homes and to reside in camps reserved for witches. This study was undertaken to identify those sociodemographic characteristics, which are commonly shared by witchcraft accusation victims. These sociodemographic characteristics can be used to predict those who are most likely to be discriminated against using accusations of witchcraft in Northern Ghana. As age places more strain on existing systems and as more people survive into old age with inadequate healthcare, more accusations may be predicted to occur against the elderly, unless enough government intervention is used to address the present redistribution of income in third world countries. digital.library.unt.edu/ark:/67531/metadc407752/
Photochemical and Photophysical Properties of Mononuclear and Multinuclear Closed Shell D10 Coinage Metal Complexes and Their Metallo-organometallic Adducts
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This dissertation covers the studies of two major topics: the photochemistry of mononuclear and multinuclear gold(I) complexes and synthetic approaches to tailor photophysical properties of cyclic trinuclear d10 complexes. First a detailed photochemical examination into the photoreactivity of neutral mononuclear and multinuclear gold(I) complexes is discussed, with the aim of gold nanoparticle size and shape control for biomedical and catalysis applications. Next is a comprehensive systematic synthetic approach to tailor the photophysical properties of cyclic trinuclear d10 complexes. This synthetic approach includes an investigation of structure-luminescence relationships between cyclic trinuclear complexes, an examination into their π-acid/π-base reactivity with heavy metal cations and an exploration into the photophysical properties of new heterobimetallic cyclic trinuclear complexes. These photophysical properties inspections are used to screen materials for their employment in molecular electronic devices such as organic light-emitting diodes (OLEDs) and thin film transistors (OTFTs). digital.library.unt.edu/ark:/67531/metadc407759/
Origin and Role of Factor Viia
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Factor VII, the initiator of the extrinsic coagulation cascade, circulates in human plasma mainly in its zymogen form, Factor VII and in small amounts in its activated form, Factor VIIa. However, the mechanism of initial generation of Factor VIIa is not known despite intensive research using currently available model systems. Earlier findings suggested serine proteases Factor VII activating protease, and hepsin play a role in activating Factor VII, however, it has remained controversial. In this work I estimated the levels of Factor VIIa and Factor VII for the first time in adult zebrafish plasma and also reevaluated the role of the above two serine proteases in activating Factor VII in vivo using zebrafish as a model system. Knockdown of factor VII activating protease did not reduce Factor VIIa levels while hepsin knockdown reduced Factor VIIa levels. After identifying role of hepsin in Factor VII activation in zebrafish, I wanted to identify novel serine proteases playing a role in Factor VII activation. However, a large scale knockdown of all serine proteases in zebrafish genome using available knockdown techniques is prohibitively expensive. Hence, I developed an inexpensive gene knockdown method which was validated with IIb gene knockdown, and knockdown all serine proteases in zebrafish genome. On performing the genetic screen I identified 2 novel genes, hepatocytes growth factor like and prostasin involved in Factor VII activation. digital.library.unt.edu/ark:/67531/metadc407814/
Designing Tools to Probe the Calcium-dependent Function of Arabidopsis Tonneau2
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Plants possess unique features in many aspects of development. One of these features is seen in cell wall placement during cytokinesis, which is determined by the position of the preprophase band (PPB) and the subsequent expansion of the phragmoplast that deposits the new cell wall. During phragmoplast expansion, the phragmoplast tracks to the cortical division site, which was delineated by the PPB. Thus the position of the PPB determines the orientation of the division plane. In Arabidopsis thaliana, TONNEAU2 (TON2) is required for PPB formation and has been shown to interact with a type A subunit of the PP2A phosphatase in the yeast two-hybrid system. In Arabidopsis tonneau2 (ton2) mutants, abnormalities of the cortical microtubule cytoskeleton, such as disorganization of the interphase microtubule array and lack of PPB formation before mitosis markedly affects cell shape and arrangement as well as overall plant morphology. Loss of dcd1/add1, the maize ton2 homologues gives rise to a similar phenotype in Zea mays. The TON2 protein has two EF hand domains which are calcium-binding sites. Since calcium has been known to play key roles in several areas of plant functioning, the following question was raised: “Does calcium binding contribute to the localization and function of TONNEAU at the PPB?” To address this question, a series of constructs were generated to determine if TON2 binds calcium. Additionally, Ca2+ binding sites were mutated in constructs containing the TON2 gene fused to GFP or YPF. These constructs were then transformed into ton2 mutant plants and the localization of TON2 fusion protein and whether the construct is capable of rescuing the mutant phenotype were observed. Although, localization of TON2 to the PPB was not observed, the presence of the constructs were confirmed in the transformed plants using selection markers and by observing fluorescence under a confocal microscope. digital.library.unt.edu/ark:/67531/metadc407800/
Functional Characterization of Mtnip/latd’s Biochemical and Biological Function
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Symbiotic nitrogen fixation occurs in plants harboring nitrogen-fixing bacteria within the plant tissue. The most widely studied association is between the legumes and rhizobia. In this relationship the plant (legumes) provides the bacteria (rhizobia) with reduced carbon derived from photosynthesis in exchange for reduced atmospheric nitrogen. This allows the plant to survive in soil, which is low in available of nitrogen. Rhizobia infect and enter plant root and reside in organs known as nodules. In the nodules the bacteria fix atmospheric nitrogen. The association between the legume, Medicago truncatula and the bacteria Sinorhizobium meliloti, has been studied in detail. Medicago mutants that have defects in nodulation help us understand the process of nitrogen fixation better. One such mutant is the Mtnip-1. Mtnip-1 plants respond to S. meliloti by producing abnormal nodules in which numerous aberrant infection threads are produced, with very rare rhizobial release into host plant cells. The mutant plant Mtnip-1 has an abnormal defense-like response in root nodules as well as defects in lateral root development. Three alleles of the Mtnip/latd mutants, Mtnip-1, Mtlatd and Mtnip-3 show different degrees of severity in their phenotype. Phylogenetic analysis showed that MtNIP/LATD encodes a protein belonging to the NRT1(PTR) family of nitrate, peptide, dicarboxylate and phytohprmone transporters. Experiments with Mtnip/latd mutants demonstrats a defective nitrate response associated with low (250 μM) external nitrate concentration rather than high (5 mM) nitrate concentration. This suggests that the mutants have defective nitrate transport. To test if MtNIP/LATD was a nitrate transporter, Xenopus laevis oocytes and Arabidopsis thaliana mutant plants Atchl1-5, defective in a major nitrate transporter AtNRT1.1(CHL1), were used as surrogate expression systems. Heterologous expression of MtNIP/LATD in X. laevis oocytes and Atchl1-5 mutant plants conferred on them the ability to take up nitrate from external media with high affinity, thus demonstrating that MtNIP/LATD was a high affinity nitrate transporter. Km for MtNIP/LATD was determined to be approximately160 μM in the X. laevis system and 113 μM in the Arabidopsis Atchl1-5 mutant lines thus supporting the previous observation of MtNIP/LATD being a high affinity nitrate transporter. X. laevis expressing the mutant Mtnip-1 and Mtlatd, were unable to transport nitrate. However X. laevis oocytes, expressing the less severe mutant allele Mtnip-3 were able to transport nitrate suggesting another role of the Mtnip/latd besides high affinity nitrate transport. Experimental evidence suggested that MtNIP/LATD might transport another substrate beside nitrate. MtNIP/LATD levels are regulated by phytohormones. Experiments performed with ABA (abscisic acid), IAA (indole acetic acid) and histidine as substrates in X. laevis system show that the MtNIP/LATD mRNA injected oocytes efflux IAA but do not transport histidine or ABA. When wild type A17 and mutant Mtnip-1 and Mtnip-3 plants, grown in the presence of different sources of nitrogen were screened in herbicide chlorate, a structural analog of nitrate, the A17 and Mtnip-3 mutant showed levels of susceptibility that was different from mutant Mtnip-1 lines. Evidence suggested that the amount of chlorate transported into the plants were regulated by the C:N status of the A17 and Mtnip-3 plants. This regulation was missing in the Mtnip-1 lines thus suggesting a sensor function of MtNIP/LATD gene. digital.library.unt.edu/ark:/67531/metadc407822/
Journal of Applied Rehabilitation Counseling, Volume 45, Number 2, Summer 2014
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. This edition of JARC sought to high light international trends in contexts such as Asia, India, South Africa, Taiwan, and Uruguay. In the current issue (Vol. 45, No.2), the following articles were included: -International Rehabilitation Points of Impact. (Jenelle S. Pitt & Quintin Boston) -Disability and the Asian Culture. (Kenny K. Yan, Michael P. Accordino, Daniel L. Boutin, & Keith B. Wilson) -Investigating Educators' Views of Sexuality, HIV and AIDS Education in Working with Students with Disabilities in South African Schools(Julia S. Louw, John Kosciulek, & Roy K. Chen) -Vocational Rehabilitation Services in Uruguay: A Rehabilitation Counseling Perspective. (Paola Premuda-Conti & Heber da Cunha) -Beyond Discipline-based Expertise: Preparing Global Leaders in Rehabilitation. (Allen Lewis, Kristin Graham, Abbas Quamar) -Disability in India: The Role of Gender, Family, and Religion. (Shabana Anees) -International Collaborative Cross-Cultural Teaching Project: United States and Taiwan. (Frances W. Siu, Martin G. Brodwin, I-Chun Huang, Erin R. Brodwin, & Christiaan Kier) digital.library.unt.edu/ark:/67531/metadc307523/
The Story of North Texas : from Texas Normal College, 1890, to the University of North Texas system, 2001
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A history of the institution of the University of North Texas, featuring photographs of people and events on campus and charting its development from the Texas Normal College to its role in the sciences, mathematics, humanities, social sciences and teacher education, amongst others. digital.library.unt.edu/ark:/67531/metadc287876/
Design, Synthesis and Screening of Homoleptic and Heteroleptic Platinum(ii) Pyridylazolate Complexes for N-type Semiconducting and Light-emitting Devices
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A series of heteroleptic and homoleptic platinum(II) complexes has been synthesized and characterized towards their use in thin film devices such as organic light-emitting diodes (OLEDs) and organic thin film transistors (OTFTs). Pyridylpyrazolate- and pyridyltetrazolate-containing ligands were selected due to their structural rigidity and ease of functionalization. Single-crystal x-ray diffraction studies of two selected heteroleptic complexes show strong aggregation with preferential stacking into vertical columns with a varying degree of overlap of the neighboring square planar molecular units. It is shown that the close proximity of the molecules to one another in the stack increases semiconducting character, phosphorescence quantum yields, and shorter radiative lifetimes. The potential for these materials towards incorporation into high-efficiency doping free white OLEDs (DFW-OLEDs) for solid-state lighting and display applications has been realized and will be expanded upon by present and future embodiments of materials in this thesis. digital.library.unt.edu/ark:/67531/metadc283853/
The Enemy of My Enemy Is What, Exactly? the British Flanders Expedition of 1793 and Coalition Diplomacy
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The British entered the War of the First Coalition against Revolutionary France in 1793 diplomatically isolated and militarily unprepared for a major war. Nonetheless, a French attack on the Dutch Republic in February 1793 forced the British to dispatch a small expeditionary force to defend their ally. Throughout the Flanders campaign of 1793, the British expeditionary force served London as a tool to end British isolation and enlist Austrian commitment to securing British war objectives. The 1793 Flanders campaign and the Allied war effort in general have received little attention from historians, and they generally receive dismissive condemnation in general histories of the French Revolutionary Wars. This thesis examines the British participation in the 1793 Flanders campaign a broader diplomatic context through the published correspondence of relevant Allied military and political leaders. Traditional accounts of this campaign present a narrative of defeat and condemn the Allies for their failure to achieve in 1793 the accomplishments of the sixth coalition twenty years later. Such a perspective obscures a clear understanding of the reasons for Allied actions. This thesis seeks to correct this distortion by critically analyzing the relationship between British diplomacy within the Coalition and operations in Flanders. Unable to achieve victory on their own strength, the British used their expeditionary force in Flanders as diplomatic leverage to impose their objectives on the other powers at war with France. digital.library.unt.edu/ark:/67531/metadc283820/
José Antonio Gómez´s Versos Para Órgano (Section I): a Practical Guide for Performance
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José Antonio Gómez is an important figure in Mexican music history and his works are considered representative of the beginning of Mexico´s Independent era. Some musicians are familiar with Gómez´s choral output but his organ music is rarely considered. Due to the lack of an edition of Gómez´s Versets for Organ, a practical guide was found needed to aid its performance. This study is based on performance, analysis, and direct work on the only known source for it. The first chapter, Introduction, presents the argument for an edited version of the first part of the manuscript as a performance guide. The second provides biographical information on the composer. The third chapter discusses the background for the original performance of the Versets for Organ. Chapter 4 provides performance considerations for the works. The edition of the manuscript is included in chapter 5. digital.library.unt.edu/ark:/67531/metadc283837/
The Useful Arts
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This creative nonfiction dissertation is a series of braided narratives that chronicle the author's career as a trombonist in the John Smith Ensemble. As an amateur trombonist, the author is shocked to be hired as a professional musician for an orchestra that plays on PBS and at Carnegie Hall. She quickly realizes, however, that the job requires her to play the trombone quietly in front of an unplugged microphone while a CD recording of another, more talented trombonist is blasted out toward an unknowing audience. The job also requires the author to tour around America. The scenes of from this tour are braided with scenes wherein she reflects on her life as a professional fake musician and her past failed attempts at getting a job. digital.library.unt.edu/ark:/67531/metadc283812/
Challenge the Silence
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This collection of personal essays about incest, abuse, and depression explores the lasting effects of an invisible childhood. The essays follow the protagonist from the age of five to her early twenties. Her brother, at a young age, becomes sexually abusive of her and her sisters, and her parents fail to protect their daughters. The family is divided as the older girls strive to defend their little sisters, while their parents attempt to excuse their son. When her brother is finally sent away, the protagonist is left to salvage what remains of her relationships with her parents. digital.library.unt.edu/ark:/67531/metadc283840/
Between Comancheros and Comanchería: a History of Fort Bascom, New Mexico
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In 1863, Fort Bascom was built along the Canadian River in the Eroded Plains of Territorial New Mexico. Its unique location placed it between the Comanches of Texas and the Comancheros of the Sangre de Cristo Mountains. This post was situated within Comanchería during the height of the United States Army's war against the Southern Plains Indians, yet it has garnered little attention. This study broadens the scholarly understanding of how the United States Army gained control of the Southwest by examining the role Fort Bascom played in this mission. This includes an exploration of the Canadian River Valley environment, an examination of the economic relationship that existed between the Southern Plains Indians and the mountain people of New Mexico, and an account of the daily life of soldiers posted to Fort Bascom. This dissertation thus provides an environmental and cultural history of the Canadian River Valley in New Mexico, a social history of the men stationed at Fort Bascom, and proof that the post played a key role in the Army's efforts to gain control of the Southern Plains Indians. This study argues that Fort Bascom should be recognized as Texas' northern-most frontier fort. Its men were closer to the Comanche homeland than any Texas post of the period. Its records clearly show that the Army used Fort Bascom as a key forward base of operations against Comanches and Kiowas. An examination of Bascom's post returns, daily patrols, and major expeditions allows its history to provide a useful perspective on the nineteenth-century American Southwest. digital.library.unt.edu/ark:/67531/metadc283832/
Southern Roots, Western Foundations: the Peculiar Institution and the Livestock Industry on the Northwestern Frontier of Texas, 1846-1864
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This dissertation challenges Charles W. Ramsdell's needless war theory, which argued that profitable slavery would not have existed west of the 98th meridian and that slavery would have died a natural death. It uses statistical information that is mined from the county tax records to show how slave-owners on the northwestern frontier of Texas raised livestock rather than market crops, before and during the Civil War. This enterprise was so strong that it not only continued to expand throughout this period, but it also became the foundation for the recovery of the Texas economy after the war. digital.library.unt.edu/ark:/67531/metadc283818/
Journal of Applied Rehabilitation Counseling, Volume 45, Number 1, Spring 2014
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. In the current issue (Vol. 45, No.1), the following four articles were included: -National Module for Helping Individuals with Physical Disabilities in Disaster Events. (Amani A. Kettaneh and John R. Slevin) -Assessing and Exploring Racial Identity Development in Therapy: Strategies to Use with Black Consumers. (Erin F. Barnes, Joseph M. Williams, and Frances R. Barnes) -Collaboration Between Rehabilitation Counselors and Secondary Educational Institutions to Optimize Successful Outcomes for High School Students with Disabilities.(Katherine M. Kline & Charity Anne Kurz) -Applying a Resiliency Model to Community Reintegration and Needs in Families with Traumatic Brain Injury: Implications for Rehabilitation Counselors.(Christina Dillahunt-Aspillaga, Julianne Agonis-Frain, Ardis Hanson, Michael Frain, Melanie Sosinski, and Sarah Ehlke) -Compassion & Self-compassion: Exploration of Utility as Potential Components of the Rehabilitation Counseling Profession. (Susan Stuntzner). digital.library.unt.edu/ark:/67531/metadc283779/
Isidore of Seville's Etymologies : the Complete English Translation of Isidori Hispalensis Episcopi Etymologiarum Sive Originum Libri XX
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This book contains St. Isidore's work translated from the Latin by Priscilla Throop with an index. Saint Isidore of Seville (c.560-636) was Archbishop of Seville for more than three decades and has the reputation of being one of the great scholars of the early Middle Ages. This translation is based on Wallace M. Lindsay’s edition of Isidori Hispalensis episcopi etymologiarum sive originum (Oxford, 1911). For his edition, Lindsay used all available 8th century manuscripts and fragments, as well as some from the 9th century. digital.library.unt.edu/ark:/67531/metadc276255/
Journal of Applied Rehabilitation Counseling, Volume 44, Number 4, Winter 2013
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. In the current issue (Vol. 44, No.4), the following five articles were included: -Conceptualizing the Use of Cognitive Interventions Among Persons with Intellectual Disabilities Who Experience Depression (Abdoulaye Diallo, Shawn P. Saladin, Darlene A.G. Groomes, Jerome Fischer, & Sandra Hansmann). -Stages of Displacement: The Immigration Experience of Latinos (Cynthia Serrata & Jerry Fischer). -A Guide for Working with Vocational Rehabilitation Clients with Acquired Brain Injury Using the International Classification of Functioning Model (Saara T. Grizzell & Julie F. Smart). -Combat to College: Cognitive Fatigue as a Challenge in Iraq and Afghanistan War Veterans with Traumatic Brain Injury: Pilot Study Survey Results (Dan Smee, Sandra Buenrostro, Thomas Garrick, Shoba Sreenivasan, & Linda E. Weinberger). -Agency Type as Predictor of Employment Outcomes for Persons with Visual Impairments: Current Trends and Considerations(Eniko Rak). digital.library.unt.edu/ark:/67531/metadc276256/
Expression of G-protein Coupled Receptors in Young and Mature Thrombocytes and Knockdown of Gpr18 in Zebrafish
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In this study, a novel method based on biotinylated antibodies and streptavidin coated magnetic beads was used to separate the thrombocyte subpopulations from zebrafish whole blood. DiI-C18, a lipophilic dye, labels only young thrombocytes when used at low concentrations. Commercially available biotinylated anti-Cy3 antibody was used to label the chromophore of DiI-C18 on the young thrombocytes and streptavidin coated magnetic beads were added subsequently, to separate young thrombocytes. The remaining blood cells were probed with custom-made biotinylated anti-GPIIb antibody and streptavidin magnetic beads to separate them from other cells. Further, thrombocytes are equivalents of mammalian platelets. Platelets play a crucial role in thrombus formation. The G-protein coupled receptors (GPCRs) present on the platelet surface are involved during platelet activation and aggregation processes. So, thrombocytes were studied for the presence of GPCRs. The GPCR mRNA transcripts expressed in the young and mature thrombocytes were subjected to densitometry analysis and pixel intensities of the bands were compared using one way ANOVA. This analysis did not show significant differences between the young and mature GPCR mRNA transcripts but identified a novel GPCR, GPR18 that was not reported in platelets earlier. To study the function of this GPCR, it was knocked down using GPR18 specific antisense morpholino and vivo morpholino. The immunofluorescence experiment indicated the presence of GPR18 on thrombocytes. The results of the assays, such as, time to occlusion (TTO) and time to aggregation (TTA) in response to N-arachidonyl glycine (NAG) as an agonist, showed prolongation of time in GPR18 larval and adult morphants respectively, suggesting that GPR18 plays a role in thrombus formation in zebrafish. In conclusion, our results indicate that GPR18 may be present in zebrafish thrombocytes, it may be involved in thrombus formation and that NAG may be an agonist at GPR18 on thrombocytes. digital.library.unt.edu/ark:/67531/metadc271881/
Interspecimen Study of Bone to Relate Macromechanical, Nanomechanical and Compositional Changes Across the Femoral Cortex of Bone
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Mechanics of bone is widely studied and researched, mainly for the study of fracture. This has been done mostly on a macro scale. In this work hierarchical nature of bone has been explored to investigate bone mechanics in more detail. Flexural test were done to classify the bones according to their strength and deflection. Raman spectroscopy analysis was done to map the mineralization, collagen crosslinking changes across the thickness of the bone. Nanoindentation was done to map indentation hardness and indentation modulus across femoral cortex of the bone. The results indicate that the composition of the bone changes across the thickness of the femoral cortex. The hypothesis is confirmed as increase in mineralization, carbonate to phosphate ratio and collagen crosslinking shows the effect as increased indentation hardness and modulus and decreased deflection. digital.library.unt.edu/ark:/67531/metadc271868/
Investigating Postpartum Depression in Southern Rural Egypt and Effects of Sertraline on Fsh and Lh Gene Expression on Fathead Minnows Using Rt-pcr
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Postpartum depression (PPD) is a major health problem that affects many women worldwide. In Egypt, PPD is neglected despite the expected high prevalence rate among women during the transition period after the Egyptian revolution. This research investigated the prevalence, risk factors, and interventions of postpartum depression in southern rural Egypt. Interviews were conducted with 57 participants recruited from public and private hospitals. Questionnaires and the Arabic version of the Edinburgh Postnatal Depression Scale were administered. The prevalence of PPD is 73.7%. PPD is associated with low income and age at childbirth. Most participants regarded screening mothers after childbirth for PPD as effective; in comparison to, antidepressants that were regarded by most participants as ineffective. Women in southern rural Egypt prefer high number of pregnancies, so investigating the influence of sertraline, an antidepressant medication, on female hormones becomes important. In this research, fathead minnows were exposed to 3 and 10 ppb sertraline for 7 days. Real-time Polymerase Chain Reaction was used to detect the change in gene expression of the Follicle-stimulating hormone (FSH) and luteinizing hormone (LH). Results showed that a down regulation at the 10 ppb was evident on the LH and to a lesser extent on FSH. Our results increased levels of sertraline inhibited GnRH which influenced expression of LH and FSH. digital.library.unt.edu/ark:/67531/metadc271865/
My Crown Is in My Heart, Not on My Head: Heart Burial in England, France, and the Holy Roman Empire From Medieval Times to the Present
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Heart burial is a funerary practice that has been performed since the early medieval period. However, relatively little scholarship has been published on it in English. Heart burial began as a pragmatic way to preserve a body, but it became a meaningful tradition in Western Europe during the medieval and early modern periods. In an anthropological context, the ritual served the needs of elites and the societies they governed. Elites used heart burial not only to preserve their bodies, but to express devotion, stabilize the social order and advocate legitimacy, and even gain heaven. Heart burial assisted in the elite Christian, his or her family, and society pass through the liminal period of death. Over the centuries, heart burial evolved to remain relevant. The practice is extant to the present day, though the motivations behind it are very different from those of the medieval and early modern periods. digital.library.unt.edu/ark:/67531/metadc271809/
Warrior Women in Early Modern Literature
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Fantasies about warrior women circulated in many forms of writing in early modern England: travel narratives such as Sir Walter Ralegh's The Discoverie of Guiana (1595) portray Amazon encounters in the New World; poems like Edmund Spenser's The Faerie Queene (1596) depict women's skill with a spear; and the plays of Shakespeare, John Fletcher, and others stage the adventurous feats of women on the battlefield. In this dissertation, I analyze the social anxieties that emerge when warrior women threaten gender hierarchies in the patriarchal society of early modern England. The battlefield has traditionally been a site for men to prove their masculinity against other men, so when male characters find themselves submitting to a sword-wielding woman, they are forced to reimagine their own masculine identities as they become the objects acted upon by women. In their experience of subjectivity, these literary warrior women often allude to the historical Queen Elizabeth I, whose reign destabilized ideas about gender and power in the period. Negative evaluations of warrior women often indicate anxiety about Elizabeth as an Amazon-like queen. Thus, portrayals of warrior women often end with a celebration of patriarchal dominance once the male characters have successfully contained the threat of the warrior woman through marriage or death. I argue that these depictions of containment indicate a common desire to maintain patriarchal superiority during and after Elizabeth's reign. digital.library.unt.edu/ark:/67531/metadc271872/
Primary Cilia in the Oligodendrocyte Lineage
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oligodendrocytes migrate from the corpus callosum into the overlying cortex. The incidence of cilia did not change markedly across age groups, and did not vary consistently with the number of processes per cell, which was used as an indication of the maturation stage of OPCs and young OLs. The mean percent of Olig1 immunopositive (Olig1+) cells having cilia across ages was 33.1% + 16.5%, with all ages combined. In O4+ cells of these mice, 56.7 + 3.6% had primary cilia. If it is the case that adult OLs do not have cilia, the point in the lineage when primary cilia are lost is still unknown. Adult mice that had been injected with cyclopamine to block cilia-dependent Shh signaling were examined to determine whether the rate of generating new OPCs was influenced. In the CC of control mice, the numerical density of Olig1+/BrdU+ cells was 1.29 + 0.07/mm2 was reduced to 0.68 + 0.38/mm2 in the cyclopamine-injected group, and the numerical density of all BrdU+ cells (including both Olig1+ and Olig1- cells) of 4.55 + 1.50/mm2 in the control group was reduced to 3.14 + 1.27/mm2 in the cyclopamine-injected group. However, there were only 2 mice in each group and the differences were not statistically significant. digital.library.unt.edu/ark:/67531/metadc271828/
Effect of Retting on Surface Chemistry and Mechanical Performance Interactions in Natural Fibers for High Performance Polymer Composites
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Sustainability through replacement of non-renewable fibers with renewable fibers is an ecological need. Impact of transportation costs from South-east Asia on the life cycle analysis of the composite is detrimental. Kenaf is an easily grown crop in America. Farm based processing involves placing the harvested crop in rivers and ponds, where retting of the fibers from the plant (separation into fibers) can take 2 weeks or more. The objective of this thesis is to analyze industrially viable processes for generating fibers and examine their synergistic impact on mechanical performance, surface topography and chemistry for functional composites. Comparison has been made with commercial and conventional retting process, including alkali retting, enzymatic retting, retting in river and pond water (retting occurs by natural microbial population) with controlled microbial retting. The resulting kenaf fibers were characterized by dynamic mechanical analysis (DMA), Raman spectroscopy (FT-Raman), Fourier transform infrared spectroscopy (FT-IR), polarized optical microscopy (POM), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM) optical fluorescence microscopy, atomic force microscopy (AFM) and carbohydrate analysis. DMA results showed that pectinase and microbe treated fibers have superior viscoelastic properties compared to alkali retting. XPS, Raman, FT-IR and biochemical analysis indicated that the controlled microbial and pectinase retting was effective in removing pectin, hemicellulose and lignin. SEM, optical microscopy and AFM analysis showed the surface morphology and cross sectional architecture were preserved in pectinase retting. Experimental results showed that enzymatic retting at 48 hours and controlled microbial retting at 72 hours yield uniform and superior quality fibers compared to alkali and natural retting process. Controlled microbial retting is an inexpensive way to produce quality fibers for polymer composite reinforcement. digital.library.unt.edu/ark:/67531/metadc271883/
The Girl Disappeared: the Prostitute of La Isla De Santa Flora
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The novella, The Girl Disappeared, focuses on the life of Emalia, a street kid from Mexico. She is taken from the streets of Veracruz and forced into a life of prostitution on the fictitious island of La Isla de Santa Flora. The primary conflict that drives the action of the story is her pending choice between escaping her life of slavery and saving another young woman who is on the verge of being forced into a life of prostitution as well. The novella, as a literary piece, dwells on the question of character agency and explores the multilayered nature of code switching. Language for these women becomes a tool in their struggle against their captives and a means of self-preservation, or sanctuary, as they use their growing bilingualism to foment a limited agency, to act in their own defense. digital.library.unt.edu/ark:/67531/metadc271917/
Zinc Oxide Nanoparticles for Nonlinear Bioimaging, Cell Detection and Selective Cell Destruction
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Light matter interactions have led to a great part of our current understanding of the universe. When light interacts with matter it affects the properties of both the light and the matter. Visible light, being in the region that the human eye can "see," was one of the first natural phenomenon we used to learn about our universe. The application of fundamental physics research has spilled over into other fields that were traditionally separated from physics, being considered two different sciences. Current physics research has applications in all scientific fields. By taking a more physical approach to problems in fields such as chemistry and biology, we have furthered our knowledge of both. Nanocrystals have many interesting optical properties. Furthermore, the size and properties of nanocrystals has given them applications in materials ranging from solar cells to sunscreens. By understanding and controlling their interactions with systems we can utilize them to increase our knowledge in other fields of science, such as biology. Nanocrystals exhibit optical properties superior to currently used fluorescent dyes. By replacing molecular dyes with nanoparticles we can reduce toxicity, increase resolution and have better cellular targeting abilities. They have also shown to have toxicity to cancer and antibacterial properties. With the understanding of how to target specific cells in vitro as well as in vivo, nanoparticles have the potential to be used as highly cell specific nanodrugs that can aid in the fight against cancer and the more recent fight against antibiotic resistant bacteria. This dissertation includes our work on bioimaging as well as our novel drug delivery system. An explanation of toxicity associated with ZnO nanoparticles and how we can use it and the nonlinear optical properties of ZnO for nanodrugs and nanoprobes is presented. digital.library.unt.edu/ark:/67531/metadc271908/
Novel Role of Trypsin in Zebrafish
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It has been shown previously in our laboratory that zebrafish produce trypsin from their gills when they are under stress, and this trypsin is involved in thrombocyte activation via PAR2 during gill bleeding. In this study, I investigated another role of the trypsin that is secreted from zebrafish. This investigation has demonstrated a novel role of trypsin in zebrafish. Not only did this investigation demonstrate the role of trypsin in zebrafish behavior, but also it showed that PAR2 might be the receptor that is involved in trypsin-mediated behavioral response. In addition, we have shown that Gq and ERK inhibitors are able to block the trypsin pathway and prevent the escaping behavior. Finally, the results of this investigation suggest that the cells that respond to trypsin are surface cells, which have an appearance similar to that of neuromast cells. digital.library.unt.edu/ark:/67531/metadc271771/
Electrochemically Deposited Metal Alloy-silicate Nanocomposite Corrosion Resistant Materials
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Zinc-nickel ?-phase silicate and copper-nickel silicate corrosion resistant coatings have been prepared via electrochemical methods to improve currently available corrosion resistant materials in the oil and gas industry. A layered silicate, montmorillonite, has been incorporated into the coatings for increased corrosion protection. For the zinc nickel silicate coatings, optimal plating conditions were determined to be a working pH range of 9.3 -9.5 with a borate based electrolyte solution, resulting in more uniform deposits and better corrosion protection of the basis metal as compared to acidic conditions. Quality, strongly adhering deposits were obtained quickly with strong, even overall coverage of the metal substrate. The corrosion current of the zinc-nickel-silicate coating is Icorr = 3.33E-6 for a borate based bath as compared to a zinc-nickel bath without silicate incorporation (Icorr = 3.52E-5). Step potential and direct potential methods were examined, showing a morphological advantage to step potential deposition. The effect of borate addition was examined in relation to zinc, nickel and zinc-nickel alloy deposition. Borate was found to affect the onset of hydrogen evolution and was examined for absorption onto the electrode surface. For copper-nickel silicate coatings, optimal conditions were determined to be a citrate based electrolytic bath, with pH = 6. The solutions were stable over time and strong adhering, compact particle deposits were obtained. The corrosion current of the copper-nickel-silicate coatings is Icorr = 3.86E-6 (copper-nickel coatings without silicate, Icorr = 1.78E-4). The large decrease in the corrosion current as the silicate is incorporated into the coating demonstrates the increase in corrosion resistance of the coatings with the incorporation of silicates. digital.library.unt.edu/ark:/67531/metadc271794/
Journal of Applied Rehabilitation Counseling, Volume 44, Number 3, Fall 2013
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. In the current issue (Vol. 44, No.3), the following five articles were included: -Fostering Resilience in Consumers. (By: Natalie A. Buse & Eileen J. Burker). -Use of Evidence-based Practice in Rehabilitation Counseling: Facilitating Recovery and Community Integration for Persons with Schizophrenia. (By Vickie R. Carpenter, Charles Bernacchio, & Eileen J. Burker) -A Pragmatic Approach to Cultural Competency in Vocational Rehabilitation: The Case of Hmong Americans. (By: Joshua D. Southwick, Lillian K. Duran, & Jared C. Schultz) -Family Systems Changes Following Traumatic Brain Injury: Adult Sibling Perspectives. (By: Charles D. Degeneffe, Lynn M. Gagne, & Mark Tucker) -Factors Affecting Vocational Rehabilitation Service Use Among Latino Men with HIV/AIDS: A National Perspective. (By: Paul A. Datti, Liza M. Conyers, & K.B. Boomer). digital.library.unt.edu/ark:/67531/metadc226890/
Water-soluble Phosphors for Hypoxia Detection in Chemical and Biological Media
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Water-soluble Pt(II) phosphors exist predominantly for photophysical studies. However, fewer are known to be candidates for cisplatin derivatives. If such a molecule could exist, it would be efficient at not only destroying the cancerous cells which harm the body, but the destruction would also be traceable within the human body as it occurred. Herein, research accomplished in chemistry describes the photophysical properties of a water-soluble phosphor. Spectroscopically, this phosphor is unique in that it possesses a strong green emission at room temperature in aqueous media. Its emission is also sensitive to the gaseous environment. These properties have been expanded to both analytical and biological applications. Studies showing the potential use of the phosphor as a heavy metal remover from aqueous solutions have been accomplished. The removal of toxic heavy metals was indicated by the loss of emission as well as the appearance of a precipitate. The gaseous sensitivity was elicited to be used as a potential cancerous cell biomarker. In vivo studies were accomplished in a wide variety of species, including bacteria (E. coli), worms (C. elegans), small crustaceans (Artemia), and fish (D. rerio and S. ocellatus). The phosphor in question is detectable in all of the above. This fundamental research lays the foundation for further expansion into bioinorganic chemistry, and many other possible applications. digital.library.unt.edu/ark:/67531/metadc177252/
American Blitzkrieg: Courtney Hodges and the Advance Toward Aachen (August 1 - September 12, 1944)
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This is an analysis of combat operations of US First Army under the command of Courtney Hodges, between August 1 and September 12, 1944, with an emphasis upon 1st, 4th, 9th, and 30th Divisions. However, other formations are necessarily discussed in order to maintain context. Indeed, many historians have failed to emphasize the complex interdependent nature of these efforts, and the traditional narrative has been distorted by inadequate situational awareness. This study argues that the army's operations were exceedingly difficult, resulting in approximately 40,000 casualties over a six week period. Although historians claim that the Germans were essentially defeated by the end of July, and that the Allied advance was subsequently halted by logistical difficulties, the official combat records clarify that logistical shortages were a tertiary factor, as the enemy remained capable of strong resistance. Consequently, defensive efforts were the primary factor hindering the advance, in conjunction with deteriorating weather conditions, rugged terrain, and surprisingly severe traffic congestion. Although this was mobile warfare, military theorists have overestimated the effectiveness of mechanization and underestimated the potential for antitank defenses. Ultimately, this study asserts that First Army was the primary American combat formation, and historians have exaggerated the importance of George Patton's Third Army. Therefore, in order to understand an American way of war, the combat operations of First Army deserve far more attention than they have previously received. This narrative thus emphasizes forgotten battles, including: Tessy, St. Sever, Tete, Perriers, Mayenne, Ranes, Flers, Mace, Elbeuf, Mantes, Corbeil, Sevran, Mons, Cambrai, Philippeville, Dinant, and Aubel. digital.library.unt.edu/ark:/67531/metadc177245/
Nonparametric Estimation of Receiver Operating Characteristic Surfaces Via Bernstein Polynomials
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Receiver operating characteristic (ROC) analysis is one of the most widely used methods in evaluating the accuracy of a classification method. It is used in many areas of decision making such as radiology, cardiology, machine learning as well as many other areas of medical sciences. The dissertation proposes a novel nonparametric estimation method of the ROC surface for the three-class classification problem via Bernstein polynomials. The proposed ROC surface estimator is shown to be uniformly consistent for estimating the true ROC surface. In addition, it is shown that the map from which the proposed estimator is constructed is Hadamard differentiable. The proposed ROC surface estimator is also demonstrated to lead to the explicit expression for the estimated volume under the ROC surface . Moreover, the exact mean squared error of the volume estimator is derived and some related results for the mean integrated squared error are also obtained. To assess the performance and accuracy of the proposed ROC and volume estimators, Monte-Carlo simulations are conducted. Finally, the method is applied to the analysis of two real data sets. digital.library.unt.edu/ark:/67531/metadc177212/
Aphorismen, Capriccio, and Heptameron for Piano Solo By Jürg Baur: a Performer's Guide
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The purpose of this dissertation is to give instruction regarding the performance of three important piano works by Jürg Baur (1918-2010). Aphorismen, Capriccio, and Heptameron stand out as his most significant piano works both because of their length and because of their pianistic complexity. Since Baur had a successful career as both teacher and composer during his lifetime, his acclaimed works received many honors in Germany. His works can be performed by intermediate to advanced students. Intermediate students can easily offer simpler pieces like Aphorismen in competitions, while pieces like Capriccio and Heptameron better are suited to a more advanced level. Although some of his compositions are difficult to perform compared with other modern German works, Baur's music is more accessible. In the article, "Auf der Spuren der alten Zeit" Baur is quoted to state that Paul Hindemith and Bela Bartok's music influenced his own compositional ideas. However, although Baur is a modern composer, he didn't write in a totally atonal style, but rather attempted to broaden tonality. While Heptameron is atonal, Aphorismen and Capriccio give the impression of tonality, thus they are more accessible to the audience. I was fortunate enough to study Aphorismen with Baur as well as receiving advice for performance of Capriccio and some movements of Heptameron. Therefore, I gained a primary source of instruction, particularly in regards to pedal markings, rhythmic indications, voice balancing, finger suggestions, articulation markings, and tone of musical expression. In this dissertation, I include my own instructions (accepted by the composer) along with the composer's intentions. digital.library.unt.edu/ark:/67531/metadc177239/
A New Chromophoric Organic Molecule Toward Improved Molecular Optoelectronic Devices
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The characterization of 2,3,6,7,10,11-hexabromotriphenylene, Br6TP, is presented toward its potential use as an n-type organic semiconductor and metal-free room temperature phosphor. The crystal structure shows both anisotropic two-dimensional BrBr interactions and inter-layer ?-stacking interactions. Photophysical characteristics were evaluated using solid-state photoluminescence and diffuse reflectance spectroscopies, revealing significantly red-shifted excitations in the visible region for the yellow solid material (compared to ultraviolet absorption bands for the colorless dilute solutions). Correlation of spectral, electrochemical, and computational data suggest the presence of an n-type semiconducting behavior due to the electron-poor aromatic ring. The material shows excellent thermal stability as demonstrated by thermogravimetric analysis and infrared spectra of a thin film deposited by thermal evaporation. The potential for Br6TP and its analogues toward use in several types of photonic and electronic devices is discussed. digital.library.unt.edu/ark:/67531/metadc177207/
Dolores Dyer: Women's Basketball and the American Dream
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Dolores Dyer played from 1952-1953 for the Texas Cowgirls, a barnstorming women's basketball team that provided a form of entertainment popular throughout the United States in that era. The story of Dyer's life demonstrates how a woman could attempt to achieve the American dream—a major theme in American history—through success in athletic competition. Dyer's participation with the Texas Cowgirls also provides a look into the circumstances that limited women's participation in professional sport during the mid-twentieth century. Women's sports studies, although some are very thorough, have gaps in the research, and women's barnstorming basketball is one of the areas often overlooked. In light of this gap, this thesis relies on a variety of sources, including primary documents from unpublished collections, archived materials, and original oral histories from several members of the Texas Cowgirls team. This thesis contains analysis of the socioeconomic factors that influenced Dolores Dyer's maturation into a professional basketball player, examines what the American dream meant to her, and evaluates the extent to which she achieved it. Overall, it constructs a social history that can serve as a foundational source for further study of women in sports during the twentieth century. digital.library.unt.edu/ark:/67531/metadc177246/
Investigation of Novel Electrochemical Synthesis of Bioapatites and Use in Elemental Bone Analysis
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In this research, electrochemical methods are used to synthesize the inorganic fraction of bone, hydroxyapatite, for application in biological implants and as a calibration material for elemental analysis in human bone. Optimal conditions of electrochemically deposited uniform apatite coatings on stainless steel were investigated. Apatite is a ceramic with many different phases and compositions that have beneficial characteristics for biomedical applications. Of those phases hydroxyapatite (HA) is the most biocompatible and is the primary constituent of the inorganic material in bones. HA coatings on metals and metal alloys have the ability to bridge the growth between human tissues and implant interface, where the metal provides the strength and HA provides the needed bioactivity. The calcium apatites were electrochemically deposited using a modified simulated body fluid adjusted to pH 4-10, for 1-3 hours at varying temperature of 25-65°C while maintaining cathodic potentials of -1.0 to -1.5V. It was observed that the composition and morphology of HA coatings change during deposition by the concentration of counter ions in solution, pH, temperature, applied potential, and post-sintering. The coatings were characterized by powder x-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. The precipitated powders from the experiment were also characterized, with results showing similarities to biological apatite. There is a need for quantitative elemental analysis of calcified biological matrices such as bone and teeth; however there are no suitable calibration materials commercially available for quantitative analysis. Matrix-matched standards are electrochemically synthesized for LA-ICP-MS analysis of human bone. The synthetic bioapatite is produced via a hydrothermal electrochemical process using a simulated body fluid solution to form hydroxyapatite. Additional bioapatite standards are synthesized containing trace amounts of metals. The x-ray diffraction of the synthesized standards shows an increase in cell volume for the crystal structure from 0.534 to 0.542 nm3 with the substitution of metals into the crystal structure. The analyte concentration and recoveries for the synthesized standards and reference materials were determined by ICP-MS with % RSD below 6.3% and limits of detection below 1.2 ng/mL for trace metals. The electrochemically synthesized bioapatite was also compared to standard reference materials with X-ray diffraction, FTIR, and Raman spectroscopy. Optimum laser ablation parameters were determined for the standards and human bone. The synthesized standards were homogeneous and the reproducibility for the isotope concentrations determined by LA-ICP-MS was between 3-10 % compared to 10-35% for SRM 1486 Bone Meal and SRM 1486 Bone Ash. A quantitative method has been developed for 2D mapping using LA-ICP-MS and the matrix-matched standards of metal-doped biopaptite to characterize metal concentrations in human bone. Laser ablation parameters for the method are refined resulting in concentration (ug/g) contour map measurements for each isotope measured in the human bone. Essential and non-essential metals, Al, Ca, Cu, Fe, Pb, and Zn are quantitatively mapped using these parameters. Limit of detection for the metals in the bone range from 0.001 to 0.08 ug/g. The LA-ICP-MS analysis method developed proves to be a straightforward and simple method for quantitative analysis of human bone. digital.library.unt.edu/ark:/67531/metadc177191/
Rational Design of Metal-organic Electronic Devices: a Computational Perspective
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Organic and organometallic electronic materials continue to attract considerable attention among researchers due to their cost effectiveness, high flexibility, low temperature processing conditions and the continuous emergence of new semiconducting materials with tailored electronic properties. In addition, organic semiconductors can be used in a variety of important technological devices such as solar cells, field-effect transistors (FETs), flash memory, radio frequency identification (RFID) tags, light emitting diodes (LEDs), etc. However, organic materials have thus far not achieved the reliability and carrier mobility obtainable with inorganic silicon-based devices. Hence, there is a need for finding alternative electronic materials other than organic semiconductors to overcome the problems of inferior stability and performance. In this dissertation, I research the development of new transition metal based electronic materials which due to the presence of metal-metal, metal-?, and ?-? interactions may give rise to superior electronic and chemical properties versus their organic counterparts. Specifically, I performed computational modeling studies on platinum based charge transfer complexes and d10 cyclo-[M(?-L)]3 trimers (M = Ag, Au and L = monoanionic bidentate bridging (C/N~C/N) ligand). The research done is aimed to guide experimental chemists to make rational choices of metals, ligands, substituents in synthesizing novel organometallic electronic materials. Furthermore, the calculations presented here propose novel ways to tune the geometric, electronic, spectroscopic, and conduction properties in semiconducting materials. In addition to novel material development, electronic device performance can be improved by making a judicious choice of device components. I have studied the interfaces of a p-type metal-organic semiconductor viz cyclo-[Au(µ-Pz)]3 trimer with metal electrodes at atomic and surface levels. This work was aimed to guide the device engineers to choose the appropriate metal electrodes considering the chemical interactions at the interface. Additionally, the calculations performed on the interfaces provided valuable insight into binding energies, charge redistribution, change in the energy levels, dipole formation, etc., which are important parameters to consider while fabricating an electronic device. The research described in this dissertation highlights the application of unique computational modeling methods at different levels of theory to guide the experimental chemists and device engineers toward a rational design of transition metal based electronic devices with low cost and high performance. digital.library.unt.edu/ark:/67531/metadc177188/
Americans Who Would Not Wait: The American Legion of the Canadian Expeditionary Force, 1915-1917
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This dissertation examines the five battalions of the Canadian Expeditionary Force designated as the American Legion. Authorized in Canada between 1915 and 1917, these units were formed to recruit volunteers from the United States to serve in the Canadian Overseas Contingent during the First World War. This work reviews the organization of Canada’s militia and the history of Anglo-American relations before examining the Canadian war effort, the formation of the American Legion, the background of its men, and the diplomatic, political, and constitutional questions that it raised. Much of the research focuses on the internal documents of its individual battalions (the 97th, 211th, 212th, 213th and 237th) and the papers of Reverend Charles Bullock now housed at the Public Archives of Canada. Documentation for the diplomatic furor the American Legion caused comes largely through the published diplomatic documents, British Foreign Office records held at the Public Record Office at Kew, and United States Department of State files at the National Archives at College Park, Maryland. The most useful sources for American Legion correspondence are the Beaverbrook papers held at the House of Lords Record Office, the papers of Canadian Prime Minister Sir Robert Laird Borden, and those of the Governor-General, the Duke of Connaught found in the Public Archives of Canada. During its brief existence the American Legion precipitated diplomatic and political problems in the United States, the United Kingdom, and the Dominion of Canada. Among the issues raised by the controversy surrounding the American Legion were: the relationship between the dominion government in Canada and the British government; the structural problems of imperial communications; the rise of a Canadian national identity and the desire for greater autonomy; and, the nature of citizenship and expatriation. This dissertation is also a long overdue account of the thousands of United States citizens who left their homes and families to join the American Legion in order to fight another country’s war. digital.library.unt.edu/ark:/67531/metadc177171/
Journal of Applied Rehabilitation Counseling, Volume 44, Number 2, Summer 2013
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. In the current issue (Vol. 44, No.2), the following four articles were included: -Ethical Implications of Confirmation Bias in the Rehabilitation Counseling Relationship. (Jennifer J. Wright-McDougal and Paul J. Toriello) -Determinants of Health Care Access after Spinal Cord Injury. (Veronica Umeasiegbu). -Predicting Employment Outcomes of Asian Americans with Depressive/Mood Disorder from the RSA National Data File. (Jame L. Schaller, Nancy K. Yang, Eun Ji, & Nina Zuna) -The Importance of Positive Client-Staff Social Interactions in Inpatient Psychiatric Rehabilitation Programs. (Danielle R. Critten, Jill L. Bezyak, & Juliet H. Fried). digital.library.unt.edu/ark:/67531/metadc172367/
Journal of Applied Rehabilitation Counseling, Volume 44, Number 1, Spring 2013
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. In the current issue (Vol. 44, No.1), the following five articles were included: -Coordination in Transition Planning: The IEP/IPE Interface (Daniel Steere and Caroline DiPipi-Hoy) -Families and Uncertainty: Using Problematic Integration Theory in Transition Services (Lori Magnuson) -Independent Living Services for Deaf and Hard of Hearing Students: Results of a Nationwide Survey of School Programs (Pamela Luft) -The Apple iPadTM as an Innovative Employment Support for Young Adults with Autism Spectrum Disorder and Other Developmental Disabilities (Doris Adams Hill, Leigh Belcher, Holly E. Brigman, Scott Renner, and Brooke Stephens) -Predictors of Employment and College Attendance Outcomes for Youth in Transition: Implications for Policy and Practice (Fabricio E. Balcazar, Ashmeet Oberoi, and Joanna M. Keel). digital.library.unt.edu/ark:/67531/metadc155610/
Journal of Applied Rehabilitation Counseling, Volume 43, Number 4, Winter 2012
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Journal of Applied Rehabilitation Counseling is the official publication of the National Rehabilitation Counseling Association (NRCA). The JARC is published quarterly, Spring, Summer, Fall and Winter. JARC is a journal of opinion and research in professional rehabilitation counseling and addresses the needs of individuals employed in a wide variety of work settings and with wide-ranging professional interests. In the current issue (Vol. 43, No.4), the following five articles were included: -Professional Bereavement: A Qualitative Examination of Rehabilitation Counselors in Grief (Alan Davis, Shawn Saladin, Sandy Hansmann, and Nicole Velgersdyk). -Posttraumatic Growth: Helping Clients Overcome Trauma (Sena Moran, Eileen Burker, and Judy Schmidt) -Vocational Experiences of College-Educated Individuals with Visual Impairments (Mary-Anne M. Joseph and Mona Robinson) -Psychosocial Aspects of Parenting a Child with Autism (Cynthia A. Serrata) -Predictors of Employment Among Native Americans (Corinne E. Harrington, Chung-Fan Ni, Diane Liebert, Felicia Wilkins-Turner, and Valerie Ellien) digital.library.unt.edu/ark:/67531/metadc155609/
Set for Life: a Novel
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This collection of six chapters is an excerpt from a novel based on the book of Job, as told through the viewpoint of a contemporary woman from Texas. A preface exploring the act of starting over, fictionally and creatively, precedes the chapters. digital.library.unt.edu/ark:/67531/metadc149574/
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