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Synthetic and Structural Chemistry of Ligand-substituted Triosmium Clusters and a Rhenium(i) Complex
The reaction of 2-[(diphenylphosphino)methyl]-6-methylpyridine (PN) with Os3(CO)12-n(MeCN)n [where n = 0 (1), 1 (2), 2 (3)] has been investigated. Os3(CO)12 reacts with PN in the presence of Me3NO to afford the clusters Os3(CO)11(1-PN) (4) and 1,2-Os3(CO)10(1-PN)2 (5). X-ray diffraction analyses confirm the equatorial coordination of the phosphine(s) in 4 and 5, with the two phosphines in the latter cluster exhibiting a 1,2-trans orientation about the Os-Os vector that contains the two ligands. Treatment of the MeCN-substituted cluster Os3(CO)11(MeCN) and PN (1:1 ratio) in CH2Cl2 gives clusters 4 and 5, in addition to HOs3(η1-Cl)(CO)10(1-PN) (6) as a result of competitive activation of the reaction solvent. Cluster 6 contains 48e- and the diffraction structure reveals the presence of axial chloride and equatorial phosphine ligands which are located on adjacent osmium atoms. The bridging hydride ligand in 6 spans the Cl,P-substituted Os-Os vector. The reaction of Os3(CO)10(MeCN)2 with PN furnishes 5, 6, and 1,1-Os3(CO)10(2-PN) (7) in yields that are dependent on the reagent stoichiometry and reaction solvent. The solid-state structure of 7 confirms the chelation of the PN ligand to a single osmium atom via the pyridine and phosphine moieties at axial and equatorial sites, respectively. The bonding in 7 relative to other possible stereoisomers has been explored by DFT calculations, and the diffraction structure is computed as the thermodynamically most stable form of this cluster. Cluster 4 is photosensitive and CO loss gives 7, in addition to the formation of the dihydride H2Os3(CO)8[µ-CH(NC5H3)CH2PPh2] (8), whose origin derives from the double metalation of the C-6 methyl group of the PN ligand in 7. Photolysis of 7 yields 8 without detectable observation of the expected intermediate hydride HOs3(CO)9[µ-CH2(NC5H3)CH2PPh2]. The PN ligand in 7 undergoes P-C bond activation in toluene at 110 °C to afford the 50e cluster Os3(CO)9(µ-C6H4)(µ-PPh), which contains face-capping benzyne and phosphinidene moieties. The bonding between the benzyne moiety and the opened Os3 frame in 9 has been examined computationally, and these data are discussed relative to and π bonding contributions from the metalated aryl ring to the cluster polyhedron. Thermolysis of BrRe(CO)5 with 4-(2,2-dimethylhydrazino)dimethylhydrazone-3(Z)-penten-2-one in toluene at 70 °C furnishes the new β-diketimine-substituted complex fac-BrRe(CO)3[(Me2NNCMe)2CH2] (1) in 50-70 isolated yield. Product 1 is also obtained in comparable yield when the same reactants are irradiated at 366 nm at room temperature in fluid solution. Treatment of the parent ligand with the "lightly stabilized" rhenium compound fac-BrRe(CO)3(THF)2 affords 1 as the sole observable rhenium product. Complex 1 has been characterized in solution by IR and 1H NMR spectroscopy, and the molecular structure has been determined by single-crystal X-ray diffraction analysis.
The Ideological Appropriation of La Malinche in Mexican and Chicano Literature
La Malinche is one of the most controversial figures in Mexican and Chicano literature. The historical facts about her life before and after the Spanish Conquest are largely speculative. What is reliably known is that she had a significant role as translator, which developed into something of mythic proportions. The ideological appropriation of her image by three authors, Octavio Paz, Laura Esquivel and Cherríe Moraga, are explored in this thesis. The full extent of the proposed rendition of La Malinche by Octavio Paz is the basis of the second chapter. The conclusion drawn by Paz, in The Labyrinth of Solitude (1950) is that La Malinche is what he calls la chingada [the raped/violated one] and proposes that all women are always open to conquest, sexually and otherwise. Laura Esquivel's novel Malinche (2006) is a re-interpretation that focuses on the tongue as the source of power and language as the ultimate source of autonomy for La Malinche. This aspect of La Malinche and the contrast of Paz's understanding are the basis of the third chapter of this thesis. Cherríe Moraga, in Loving in the War Years (1983), proposes that if women are to be traitors, it is not each other that they should betray but their cultural roles as mothers and wives. She writes that in order to avoid being the one who is passively colonized, women often times become el chingón. However, ultimately women are free of these limiting dichotomous roles are able to autonomously define themselves in a way that goes beyond these labels. This is only possible when La Malinche is re-interpreted by these by different authors.
A Vehicle-collision Learning System Using Driving Patterns on the Road
Demand of automobiles are significantly growing despite various factors, steadily increasing the average number of vehicles on the road. Increase in the number of vehicles, subsequently increases the risk of collisions, characterized by the driving behavior. Driving behavior is influenced by factors like class of vehicle, road condition and vehicle maneuvering by the driver. Rapidly growing mobile technology and use of smartphones embedded with in-built sensors, provides scope of constant development of assistance systems considering the safety of the driver by integrating with the information obtained from the vehicle on-board sensors. Our research aims at learning a vehicle system comprising of vehicle, human and road by employing driving patterns obtained from the sensor data to develop better systems of safety and alerts altogether. The thesis focusses on utilizing together various data recorded by the in-built embedded sensors in a smartphone to understand the vehicle motion and dynamics, followed by studying various impacts of collision events, types and signatures which can potentially be integrated in a prototype framework to detect variations, alert drivers and emergency responders in an event of collision.
Synthetic Peptides Model Instability of Cardiac Myosin Subfragment-2
Hypertrophic cardiomyopathy (HCM), a heart-related abnormality, is the most prevalent cause of sudden death in young athletes at sporting events. A cluster of cardiomyopathy mutations are localized in β-cardiac myosin at the N-terminal region of subfragment-2. Using resonance energy transfer probes, a synthetic peptide model system was developed to study stability of the coiled coil (S2 fragment) structure by determining monomer-dimer equilibrium of the peptide. Fluorescence resonance energy transfer and MacroModel software suite were used to obtain distance measurements along with measurement of coiled coil formation. The model peptide was used to characterize the effects of disease-causing-mutations and examine potential candidate drugs (polyamines) to counteract effects of mutations causing HCM. Distance measurements between donor and acceptor probes obtained by computational simulation and fluorescence resonance energy transfer (FRET) were consistent. Measurements also agreed with simulations of unlabeled wildtype, indicating coiled coil structural stability of the peptide. Interaction of the site-specific antibody with the peptide strongly inhibited dimerization and destabilized coiled coil structure of the peptide. Presence of negatively charged glutamate residues in the region of subfragment-2 strongly suggested a potential interaction site for positively charged polyamines. Binding of certain polyamines, such as poly-L-Lysine 11 residues and poly-D-Lysine 17 residues, demonstrated the ability to enhance dimerization and improve stability of the coiled coil structure, while some other polyamines were shown to have insignificant impact on the structure. In an attempt to characterize the effect of HCM-causing-mutations, peptides containing E924K mutation and lethal mutation E930 deletion were synthesized. Fluorescence resonance probes were conjugated to the mutant peptides to determine coiled coil formation. Results obtained from both dynamic simulations and resonance energy transfer experiments indicated that these mutations strongly inhibit dimerization, and thus, destabilize coiled coil structure of the peptide. Further experiments were conducted using heterodimers containing a chain of wildtype and a chain of mutant peptide. Both E924K & Edel930 mutations destabilized coiled coil formation and prevented dimerization. This peptide model system would provide a promising tool for drug development targeting HCM-causing-mutations along the S2 region of myosin.
Blueline Concerto: Critical Essay
The purpose of this critical essay is two-fold. First, the essay presents a detailed critical analysis of my original composition, Blueline Concerto for bass trombone and wind ensemble. Second, using Blueline Concerto, the essay presents preliminary findings of my study to develop an approach to composing that takes into account the musicians' health, specifically regarding noise induced hearing loss (NIHL). Through various hypothesized composition- and orchestral-based approaches, I test effectiveness on changes in NIHL risk while also noting that artistic merit and compositional integrity is preserved.
A Study of Mechanisms to Engineer Fine Scale Alpha Phase Precipitation in Beta Titanium Alloy, Beta 21S
Metastable b-Ti alloys are titanium alloys with sufficient b stabilizer alloying additions such that it's possible to retain single b phase at room temperature. These alloys are of great advantage compared to a/b alloys since they are easily cold rolled, strip produced and can attain excellent mechanical properties upon age hardening. Beta 21S, a relatively new b titanium alloy in addition to these general advantages is known to possess excellent oxidation and corrosion resistance at elevated temperatures. A homogeneous distribution of fine sized a precipitates in the parent b matrix is known to provide good combination of strength, ductility and fracture toughness. The current work focuses on a study of different mechanisms to engineer homogeneously distributed fine sized a precipitates in the b matrix. The precipitation of metastable phases upon low temperature aging and their influence on a precipitation is studied in detail. The precipitation sequence on direct aging above the w solvus temperature is also assessed. The structural and compositional evolution of precipitate phase is determined using multiple characterization tools. The possibility of occurrence of other non-classical precipitation mechanisms that do not require heterogeneous nucleation sites are also analyzed. Lastly, the influence of interstitial element, oxygen on a precipitation during the oxidation of Beta 21S has been determined. The ingress of oxygen and its influence on microstructure have also been correlated to measured mechanical properties.
Design, Synthesis and Screening of Homoleptic and Heteroleptic Platinum(ii) Pyridylazolate Complexes for N-type Semiconducting and Light-emitting Devices
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A series of heteroleptic and homoleptic platinum(II) complexes has been synthesized and characterized towards their use in thin film devices such as organic light-emitting diodes (OLEDs) and organic thin film transistors (OTFTs). Pyridylpyrazolate- and pyridyltetrazolate-containing ligands were selected due to their structural rigidity and ease of functionalization. Single-crystal x-ray diffraction studies of two selected heteroleptic complexes show strong aggregation with preferential stacking into vertical columns with a varying degree of overlap of the neighboring square planar molecular units. It is shown that the close proximity of the molecules to one another in the stack increases semiconducting character, phosphorescence quantum yields, and shorter radiative lifetimes. The potential for these materials towards incorporation into high-efficiency doping free white OLEDs (DFW-OLEDs) for solid-state lighting and display applications has been realized and will be expanded upon by present and future embodiments of materials in this thesis.
Programming for the Latino Youth: a Content Analysis of Prime Time Television Programs By Three Spanish-language Broadcast Networks
This study reviews U.S. Spanish-language broadcast networks' prime time programming content targeted to the Latino youth audience. It explores the relationship between the Latino youth and prime time programming by Spanish-language broadcast networks and how they seek to attract this market as is reflected in the characteristics and quantity of their content and preferred formats by using the strategic management theory. This study identifies the amount and type of prime time programming that was catered to the Latino youth audience between 2003 and 2012 by the three major Spanish-language networks: Univision, Telemundo, and Telefutura. An observed pattern reveals that prime time programming targeting Latino teenagers is relatively smaller and older in comparison to programming delivered through the general programming.
This thesis consists of a collection of poems and a critical preface. The preface is a discussion of Elizabeth Bishop's descriptive mode, as demonstrated by three of her poems: "Sandpiper," "The Monument," and "Santarém." I argue for Bishop's descriptions as creative acts, and examine the gestures that help her make the reader aware of the shaping power she exercises.
Comparative Phyto-uptake Across Distribution Coefficients of Pharmaceutical Compounds and Aquatic Macrophytes: Carbamazepine and Amiodarone Uptake in Lemna Spp
Few studies have been conducted on the effectiveness of phytoremediation of pharmaceutical compounds, although the persistent and non-acutely toxic nature of many of these compounds in today's water bodies may yield an ideal application for this practice. To quantify the potential effectiveness of plant uptake, kinetic and proportional bioconcentration factors (BCFk, and BCFp, respectively) in nanograms (ng) carbamazepine and amiodarone per gram (g) wet weight plant tissue for Lemna spp. were determined utilizing a 14-day continuous flow-through study. Samples were analyzed using isotope dilution liquid chromatography-tandem mass spectrometry (ID-LC-MS/MS) running in positive ion mode. Kinetic BCF was estimated at 0.538, while proportional BCF was estimated at 0.485. Kinetic BCF for the amiodarone study was estimated at 23.033, whereas proportional BCF was estimated at 41.340. Possible contamination of the C18 column and peristaltic pump failure may have impacted uptake results. In light of variability and current lack of research in the field, this work should be considered exploratory rather than conclusive.
The Masculinity Masquerade: the Portrayal of Men in Modern Advertising
The depiction of gender in advertising is a topic of continuous discussion and research. The present study adds to past findings with an updated look at how men are represented in U.S. advertising media and the real effects these portrayals have on the male population under the theoretical framework of hegemony and social cognitive theory. This research is triangulated with a textual analysis of the ads found in the March 2013 editions of four popular print publications and three focus group sessions separated by sex (two all-male, one all-female), each of which is composed of a racially diverse group of undergraduate journalism and communications students from a large Southwestern university. The results of the textual analysis reveal little ethnic or physical diversity among male figures in advertising and distinguish six main profiles of masculinity, the most frequent of which is described as the "sophisticated man." The focus groups identify depictions of extreme muscularity and stereotypical male incompetence as the most negative representations, while humorous and hyperbolic portrayals of sexual prowess and hyper-masculinity are viewed positively as effective means of marketing to men.
Synthesis and Design of Microwave Filters and Duplexers with Single and Dual Band Responses
In this thesis the general Chebyshev filter synthesis procedure to generate transfer and reflection polynomials and coupling matrices were described. Key concepts such as coupled resonators, non-resonant nodes have been included. This is followed by microwave duplexer synthesis. Next, a technique to design dual band filter has been described including ways to achieve desired return loss and rejection levels at specific bands by manipulating the stopbands and transmission zeros. The concept of dual band filter synthesis has been applied on the synthesis of microwave duplexer to propose a method to synthesize dual band duplexers. Finally a numerical procedure using Cauchy method has been described to estimate the filter and duplexer polynomials from measured responses. The concepts in this thesis can be used to make microwave filters and duplexers more compact, efficient and cost effective.
Corrosion Protection of Aerospace Grade Magnesium Alloy Elektron 43™ for Use in Aircraft Cabin Interiors
Magnesium alloys exhibit desirable properties for use in transportation technology. In particular, the low density and high specific strength of these alloys is of interest to the aerospace community. However, the concerns of flammability and susceptibility to corrosion have limited the use of magnesium alloys within the aircraft cabin. This work studies a magnesium alloy containing rare earth elements designed to increase resistance to ignition while lowering rate of corrosion. The microstructure of the alloy was documented using scanning electron microscopy. Specimens underwent salt spray testing and the corrosion products were examined using energy dispersive spectroscopy.
Media and Corporate Social Responsibility: How Leading Business Magazines Frame a Controversial Concept
Corporate social responsibility (CSR) is an emerging concept that continues to play a controversial role in the business world. Different CSR theories and ethical foundations inform different approaches to embedding socially responsible behavior into today's business functions. As technology, globalization, and economic challenges change the corporate world, the meaning and application of CSR also changes. While no empirical evidence of CSR's impact on performance exists, many corporations operate under the assumption that CSR holds significant value. This study examines the framing of CSR in stories published by leading business magazines between 2008 and 2012. By examining the presentation of CSR concepts, the resulting analysis can provide important conclusions for corporations, public relations practitioners, mass media, and consumers. This study resulted in a hierarchical pyramid of frames that organizes the framing of CSR in business magazines into three layers: category, motivation, and classification as either responsible behavior or irresponsible behavior. These results lead to recommendations for future CSR research, including the need for quantitative evidence of a connection or disconnection between CSR and profitability.
Environmental Philosophy and the Ethics of Terraforming Mars: Adding the Voices of Environmental Justice and Ecofeminism to the Ongoing Debate
Questions concerning the ethics of terraforming Mars have received some attention from both philosophers and scientists during recent decades. A variety of theoretical approaches have been supplied by a number of authors, however research pursuant to this thesis has indicated at least two major blindspots in the published literature on the topic. First, a broad category of human considerations involving risks, dangers, and social, political, and economic inequalities that would likely be associated with efforts to terraform Mars have been woefully overlooked in the published literature to date. I attempt to rectify that oversight by employing the interpretive lens of environmental justice to address questions of environmental colonialism, equality in terms of political participation and inclusion in decision making structures, risks associated with technological progressivism, and responses to anthropogenic climate change. Only by including the historically marginalized and politically disenfranchised "voices," of both humans and nonhumans, can any future plan to terraform Mars be deemed ethical, moral or just according to the framework provided by environmental justice. Furthermore, broader political inclusion of this sort conforms to what ecofeminist author Val Plumwood calls the "intentional recognition stance" and provides an avenue through which globally societies can include nonanthropocentric considerations in decision making frameworks both for questions of terraforming Mars and also for a more local, contemporary set of environmental issues. The second blindspot I seek to correct concerns motivations for attempting terraforming on Mars previously inadequately philosophically elaborated in the published discourse. Specifically, the nonanthropocentric considerations postulated in the second chapter by various authors writing about terraforming, and elaborated in third with regard to environmental justice, reach their culmination in an ecofeminist ethic of care, sustainability, reproduction, and healthy growth which I uniquely elaborate based on a metaphorical similarity to the relationship between a gardener and a garden. Although at first glance, this metaphor may appear overly domineering, or uncritically paternalistic, I argue a deep understanding of its implications will be eminently beneficial for discussions of what is moral, good, right, and just to do regarding not only whether or not to terraform Mars, but for contemporary environmental concerns as well. Ultimately, extreme caution and a robust precautionary principle are the moral prescriptions arrived at in this thesis for the near term future. Until a sustainable civilization and just society can be established and effectively maintained, efforts to terraform and colonize another planet are practically certain to produce as much that is undesirable as that which might be good.
A Comparative Study of Non Linear Conjugate Gradient Methods
We study the development of nonlinear conjugate gradient methods, Fletcher Reeves (FR) and Polak Ribiere (PR). FR extends the linear conjugate gradient method to nonlinear functions by incorporating two changes, for the step length αk a line search is performed and replacing the residual, rk (rk=b-Axk) by the gradient of the nonlinear objective function. The PR method is equivalent to FR method for exact line searches and when the underlying quadratic function is strongly convex. The PR method is basically a variant of FR and primarily differs from it in the choice of the parameter βk. On applying the nonlinear Rosenbrock function to the MATLAB code for the FR and the PR algorithms we observe that the performance of PR method (k=29) is far better than the FR method (k=42). But, we observe that when the MATLAB codes are applied to general nonlinear functions, specifically functions whose minimum is a large negative number not close to zero and the iterates too are large values far off from zero the PR algorithm does not perform well. This problem with the PR method persists even if we run the PR algorithm for more iterations or with an initial guess closer to the actual minimum. To improve the PR algorithm we suggest finding a better weighing parameter βk, using better line search method and/or using specific line search for certain functions and identifying specific restart criteria based on the function to be optimized.
Ability of Offenders with Psychopathic Traits to Simulate Cognitive and Affective Empathy
The accurate assessment of psychopathy constitutes a critical component of forensic assessments addressing offender populations. Among the core characteristics of psychopathy, the interpersonal component of deception and empathic deficits are prominently observed in offenders with psychopathic traits. Given the negative consequences of being classified as a psychopath, offenders may be likely to minimize their psychopathic traits. In particular, no research has investigated whether offenders with psychopathic traits are able to simulate empathy in an effort to mask their cognitive or affective empathy deficits (e.g., lack of remorse about offenses). The present study aims to contribute to the literature with regard to the simulation of empathy. Using a mixed between- and within-subjects design, 81 male detainees were placed into (a) a low psychopathy group, (b) a moderate psychopathy group, or (c) a high psychopathy group based on the Psychopathy Checklist – Revised. For the within-subjects component, all offenders answered empathy questionnaires under genuine and simulation conditions. Results indicate the sample possessed cognitive empathy, but did not display affective empathy under genuine instructions. Under simulation instructions, participants significantly increased their scores on several empathy measures. The implications of simulated empathy and comparisons between groups regarding simulation abilities are discussed.
Challenge the Silence
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This collection of personal essays about incest, abuse, and depression explores the lasting effects of an invisible childhood. The essays follow the protagonist from the age of five to her early twenties. Her brother, at a young age, becomes sexually abusive of her and her sisters, and her parents fail to protect their daughters. The family is divided as the older girls strive to defend their little sisters, while their parents attempt to excuse their son. When her brother is finally sent away, the protagonist is left to salvage what remains of her relationships with her parents.
Finding Terroir in Southwest Iowa
Terroir combines the physical landscape of the vineyard with the grapevines and the methods and techniques used to produce wine from the grapes. This study used a GIS to identify the characteristics of the physical landscape in Pottawattamie, Mills, Montgomery, Fremont, and Page counties in southwestern Iowa. The components were combined in the GIS using a weighted linear index to identify areas suitable for vineyard development and to identify the general characteristics of the area. Vineyard owners were interviewed to help determine the weighting system to use in the GIS and to determine their perceptions of how the physical landscape impacts their vineyards, as well as to determine what grape varieties they plant in their vineyards and their decisions on making wine from these grapes. This information was collected to identify whether the vineyard owners had developed a sense of place for their vineyards and how this sense might aid them in the development of a terroir for their wines. The resulting perceptions about the individual wineries were then considered in conjunction with the results from the GIS modeling to understand how the physical landscape influences the concepts of sense of place and terroir in southwest Iowa. The physical landscape of southwest Iowa was fairly uniform, as were the grape varietals planted in the vineyards. This created a measure of similarity among the wineries, while individuality between wineries was then created by the wine-makers as they used different techniques to produce wine from the grapes. This allows each winery to develop a sense of place, yet be part of a larger sense of place that encompasses multiple wineries within the area.
Examining the Role of Latitude and Differential Insolation in Asymmetrical Valley Development
Valley development through erosional processes typically tends to create symmetrical valleys. Over time, water cuts through the substrate to create valleys, gorges, and canyons for which the sides are the valley are evenly sloped. However, there are anomalies to this process. Asymmetrical valleys have been well-documented even in areas of uniform substrate or little tectonic uplift. One proposed explanation for the asymmetry of these valleys is differential insolation. This may lead to different microclimates from one slope to another which alter the rate and extent of erosion. Since the differences in received insolation vary with latitude (especially in streams that flow along an east/west axis), it follows that the degree of asymmetry should also vary with latitude if differential insolation is a primary driving factor in the development of these valleys. To evaluate if insolation plays a role in the development of asymmetrical valleys, this study examines variability in asymmetry across 447 valleys in nine study areas located at different latitudes. The degree of asymmetry for each valley was measured by using 30 meter resolution digital elevation models (DEMs) to determine the slope angle of each side of the valley. Asymmetry was measured by computing a ratio of the average slope angle for each side of the valley (larger value divided by smaller). If the resulting value is one, the valley is deemed symmetrical. As the value increases, the degree of asymmetry increases. This investigation found that contrary to expectations, valleys at lower latitudes tend to have a higher degree of asymmetry than those at higher latitudes, which suggests that differential insolation does not play a major role in the development of these valleys. Instead, this study found that high altitudes and low latitudes are more frequently associated with a higher degree of asymmetry. These unexpected findings open the door to new avenues of investigation into the causes of asymmetrical valley development.
Repetition and Difference: Parodic Narration in Kander and Ebb's "The Scottsboro Boys"
The American musical team John Kander and Fred Ebb created many celebrated works, yet musicologists have carried out little research on those works. This study examines the role of music in the parodic narration of Kander and Ebb's final collaboration, The Scottsboro Boys. Kander and Ebb use minstrelsy to tell the story of the historic Scottsboro Boys trials with actors portraying the Scottsboro Boys as minstrels; at the same time, they employ a number of devices to subvert minstrelsy stereotypes and thereby comment on racism. Drawing on African American literary theory, sociolinguistics, and Bakhtin's dialogism, this study illuminates how Signifyin(g), a rhetorical tradition used to encode messages in some African American communities, is the primary way the actors playing the Scottsboro Boys subvert through minstrelsy. This study not only contributes to the discussion of Signifyin(g) in African American musicals and theatre as a tool of subversion, but also provides an example of non-African American creators—Kander and Ebb—using Signifyin(g) devices. They use these in the music and the book; in particular, Kander and Ebb do some Signifyin(g) on Stephen Foster's plantation melodies.
Metabolic Engineering in Plants to Control Source/sink Relationship and Biomass Distribution
Traditional methods like pruning and breeding have historically been used in crop production to divert photoassimilates to harvested organs, but molecular biotechnology is now poised to significantly increase yield by manipulating resource partitioning. It was hypothesized that metabolic engineering in targeted sink tissues can favor resource partitioning to increase harvest. Raffinose Family Oligosaccharides (RFOs) are naturally occurring oligosaccharides that are widespread in plants and are responsible for carbon transport, storage and protection against cold and drought stress. Transgenic plants (GRS47, GRS63) were engineered to generate and transport more RFOs through the phloem than the wild type plants. The transgenic lines produced more RFOs and the RFOs were also detected in their phloem exudates. But the 14CO2 labeling and subsequent thin layer chromatography analysis showed that the RFOs were most likely sequestered in an inactive pool and accumulate over time. Crossing GRS47 and GRS63 lines with MIPS1 plants (that produces more myo-inositol, a substrate in the RFO biosynthetic pathway) did not significantly increase the RFOs in the crossed lines. For future manipulation of RFO degradation in sink organs, the roles of the endogenous α-galactosidases were analyzed. The alkaline α-galactosidases (AtSIP1 and AtSIP2 in Arabidopsis) are most likely responsible for digesting RFOs in the cytoplasm and may influence the ability to manipulate RFO levels in engineered plants. Atsip1/2 (AtSIP1/AtSIP2 double-knockout plants) were generated and phenotypically characterized based on seed germination patterns, flowering time, and sugar content to observe the impact on RFO sugar levels. The observations and analysis from these lines provide a basis for further insight in the manipulation of resource allocation between source and sink tissues in plants for future research.
The Enemy of My Enemy Is What, Exactly? the British Flanders Expedition of 1793 and Coalition Diplomacy
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The British entered the War of the First Coalition against Revolutionary France in 1793 diplomatically isolated and militarily unprepared for a major war. Nonetheless, a French attack on the Dutch Republic in February 1793 forced the British to dispatch a small expeditionary force to defend their ally. Throughout the Flanders campaign of 1793, the British expeditionary force served London as a tool to end British isolation and enlist Austrian commitment to securing British war objectives. The 1793 Flanders campaign and the Allied war effort in general have received little attention from historians, and they generally receive dismissive condemnation in general histories of the French Revolutionary Wars. This thesis examines the British participation in the 1793 Flanders campaign a broader diplomatic context through the published correspondence of relevant Allied military and political leaders. Traditional accounts of this campaign present a narrative of defeat and condemn the Allies for their failure to achieve in 1793 the accomplishments of the sixth coalition twenty years later. Such a perspective obscures a clear understanding of the reasons for Allied actions. This thesis seeks to correct this distortion by critically analyzing the relationship between British diplomacy within the Coalition and operations in Flanders. Unable to achieve victory on their own strength, the British used their expeditionary force in Flanders as diplomatic leverage to impose their objectives on the other powers at war with France.
Investigation of an Investment Casting Method Combined with Additive Manufacturing Methods for Manufacturing Lattice Structures
Cellular metals exhibit combinations of mechanical, thermal and acoustic properties that provide opportunities for various implementations and applications; light weight aerospace and automobile structures, impact and noise absorption, heat dissipation, and heat exchange. Engineered cell topologies enable one to control mechanical, thermal, and acoustic properties of the gross cell structures. A possible way to manufacture complex 3D metallic cellular solids for mass production with a relatively low cost, the investment casting (IC) method may be used by combining the rapid prototyping (RP) of wax or injection molding. In spite of its potential to produce mass products of various 3D cellular metals, the method is known to have significant casting porosity as a consequence of the complex cellular topology which makes continuous fluid's access to the solidification interface difficult. The effects of temperature on the viscosity of the fluids were studied. A comparative cost analysis between AM-IC and additive manufacturing methods is carried out. In order to manufacture 3D cellular metals with various topologies for multi-functional applications, the casting porosity should be resolved. In this study, the relations between casting porosity and processing conditions of molten metals while interconnecting with complex cellular geometries are investigated. Temperature, and pressure conditions on the rapid prototyping – investment casting (RP-IC) method are reported, thermal stresses induced are also studied. The manufactured samples are compared with those made by additive manufacturing methods.
The Phantom Menace: the F-4 in Air Combat in Vietnam
The F-4 Phantom II was the United States' primary air superiority fighter aircraft during the Vietnam War. This airplane epitomized American airpower doctrine during the early Cold War, which diminished the role of air-to-air combat and the air superiority mission. As a result, the F-4 struggled against the Soviet MiG fighters used by the North Vietnamese Air Force. By the end of the Rolling Thunder bombing campaign in 1968, the Phantom traded kills with MiGs at a nearly one-to-one ratio, the worst air combat performance in American history. The aircraft also regularly failed to protect American bombing formations from MiG attacks. A bombing halt from 1968 to 1972 provided a chance for American planners to evaluate their performance and make changes. The Navy began training pilots specifically for air combat, creating the Navy Fighter Weapons School known as "Top Gun" for this purpose. The Air Force instead focused on technological innovation and upgrades to their equipment. The resumption of bombing and air combat in the 1972 Linebacker campaigns proved that the Navy's training practices were effective, while the Air Force's technology changes were not, with kill ratios becoming worse. However, the last three months of the campaign introduced an American ground radar system that proved more effective than Top Gun in improving air-to-air combat performance. By the end of the Vietnam War, the Air Force and Navy overcame the inherent problems with the Phantom, which were mostly of their own making.
Design and Application of Phased Array System
Since its invention, phased array has been extensively applied in both military and civil areas. The applications include target detecting and tracking, space probe communication, broadcasting, human-machine interfaces, and remote sensing. Although the phased array applications show a broad range of potential market, there are some limitations of phased array's development: high cost, complex structure, narrow bandwidth, and high power consumption. Therefore, novel ideas are needed to reduce these constraints. In this thesis, several new approaches about the design and application of phased array are presents. First, the principle of phased array and fundamental design equations are introduced. Second, a new application of phased array antenna for radar respiration measurement is presented. By integrating a 4×4 Butler matrix with four-element antenna array, there will be four distinct main beams in radiation pattern. This new approach can improve the measurement accuracy and realize a high detecting rate. Third, a compact phased array antenna system based on dual-band operations is introduced. Dual-band function can make N-antenna system obtain 2N unique radiation beams (N is an integer) and achieve a significant size reduction compared to the conventional single-band system. To verify the design concept, a four-element phased array antenna working at 5GHz and 8GHz is designed and fabricated. The measurement results make a good agreement with the simulations. Finally, a novel architecture of steering phase feeding network by using bi-directional series-fed topology is presented. This bi-directional series-fed network needs less phase shifters and realizes steering phase function by applying control voltage.
Military-diplomatic Adventurism: Communist China's Foreign Policy in the Early Stage of the Korean War (1950-1951)
The thesis studies the relations of Communist China's foreign policy and its military offensives in the battlefield in Korean Peninsula in late 1950 and early 1951, an important topic that has yet received little academic attention. As original research, this thesis cites extensively from newly declassified Soviet and Chinese archives, as well as American and UN sources. This paper finds that an adventurism dominated the thinking and decision-making of Communist leaders in Beijing and Moscow, who seriously underestimated the military capabilities and diplomatic leverages of the US-led West. The origin of this adventurism, this paper argues, lays in the CCP's civil war experience with their Nationalist adversaries, which featured a preference of mobile warfare over positional warfare, and an opportunist attitude on cease-fire. This adventurism ended only when Communist front line came to the verge of collapse in June 1951.
Learning From Each Other: Narrative Explorations of Art Museum Self-guided Materials
By engaging in collaborative arts-based and arts-informed narrative inquiry with my six-year-old daughter, we explored self-guided materials in art museums in the North Texas area. Though the field of art museum education is becoming increasingly participatory, most academic research related to self-guided materials has fallen short of exploring visitors' experiences with these materials. Furthermore, the perspectives of children have been long overlooked in academic and, at times, institutional research about family experiences in museums. Over the course of nine months, my daughter and I visited art museums and engaged with their self-guided materials, ranging from audio tours to interactive galleries. During this time we created collaborative works of art based on our experiences, which acted as both data collection and analysis in preparation for writing narratives. Our narrative explorations allowed us each to better understand our collective experiences. Though this research specifically targets self-guided materials in art museums, any educator interested in intergenerational or collaborative family learning may find both our methodologies and our conclusions to be helpful in better understanding how narratives are essential to this type of learning.
Reliability of an On-line System to Assess Physical Activity Behaviors in an Active Group of Kinesiology Undergraduate Students
Engaging in muscle strengthening activities (MSA) as part of a physical activity program offers health benefits. Although the merits of physical activity are well documented, many adults fail to meet appropriate levels as recommended in the 2008 Physical Activity Guidelines for Americans (PAGA). To get a more complete understanding on an individual's physical activity behaviors, the Tracking Resistance Exercise and Strength Training (TREST) internet based survey was developed. The purpose of the current study was to determine the test-retest reliability of TREST items. Additionally, the prevalence of participants meeting the 2008 PAGA was reported by gender. The survey was completed approximately two weeks apart by 224 (52% male) undergraduate kinesiology students. Analysis of the survey items presented TREST as a reliable instrument in assessing an individual's physical activity behavior with a focus on MSA. Among the convenience sample of 445 participants (56% male) that completed the survey in assessment #1, 73% met the 2008 PAGA minimum recommendations for MSA (>=2 days/week) and aerobic activity (>= 150 min MVPA). A more complete MSA and MVPA criteria was established (requiring MSA of all seven major muscle groups) and only 32% of participants met this guideline. In general, men engaged in aerobic exercise and MSA more than women. These results cannot be generalized due the age, activity level, and education of the study's participants. Future studies should investigate the validity of TREST items among a sample of varying fitness levels, races/ethnicities, ages, and educational levels.
Internalizing-externalizing Psychopathology and Personality Pathology As Predictors of Treatment Rejection in Substance Users
Substance use disorders (SUDs) are often comorbid with other psychopathology such as mood disorders, anxiety disorders, and personality disorders. While some research suggests individuals with comorbid psychopathology are more likely to seek substance use treatment than those with independent disorders, other studies have also shown many individuals with dual diagnoses still never seek treatment. Moreover, few studies have tried to elucidate the underlying structure of SUD treatment rejection, and instead examined it in more simplistic terms. In addition, studies have tended to examine the impact of individual disorders on treatment rejection, but have not incorporated an empirically supported approach to conceptualizing psychopathology in terms of comorbidity between broad latent dimensions referred to as internalizing (e.g., depression, anxiety) and externalizing (e.g., antisocial personality disorder, polysubstance use) psychopathology. Modeling psychopathology in terms of internalizing and externalizing psychopathology is becoming a prominent approach to understanding mental disorders, yet little research to date has investigated the effects these broad dimensions have on SUD treatment rejection. The current study utilized latent variable modeling techniques to (1) determine the latent structure of SUD treatment rejection in a large U.S. sample, and investigate whether treatment rejection is a multidimensional construct; and (2), to explore the ability of internalizing psychopathology, externalizing psychopathology, and personality pathology to predict the SUD treatment rejection factor(s). The current study relied on use of a general population sample of 43,093 individuals from the first wave of National Institute on Alcohol Abuse and Alcoholism's National Epidemiologic Survey on Alcohol and Related Conditions (NESARC) study. Support was found for the hypothesis that SUD treatment rejection would be a multidimensional construct.  Exploratory structural equation modeling indicated a three-factor model best fit the data. Operational definitions and clinical implications of these three treatment rejection factors ("Objective barriers," "Psychological barriers," and "Self-focused barriers") are discussed. Among internalizing psychopathology, externalizing psychopathology, and personality pathology, structural equation modeling identified internalizing psychopathology as the most robust predictor of these three factors for alcohol treatment rejection (n = 1063), indicating endorsement of treatment barriers increased as levels of internalizing psychopathology increased. This pattern also held true for externalizing psychopathology, while personality pathology only negatively predicted objective treatment barriers.  For drug treatment rejection (n = 562), only internalizing psychopathology significantly predicted the treatment rejection factors, indicating treatment endorsement of drug treatment barriers increased as levels of internalizing psychopathology increased. Implications of these findings and directions for future research are discussed.
Deconstructing Webern's Op 25, Drei Lieder: a Multidimensional Assessment
Webern scholarship has not comprehensively examined op. 25, drei lieder. If the selection of text for op. 25 is viewed as one work in three movements they create a ternary form (A-B-A1). To show how this form is developed in the music the author creates a new analytical system based on Schoenberg's Grundgestalt which is defined by three basic ideas: symmetry, liquidation, and variation. The relationship between the voice and accompaniment and Webern's deliberate manipulation of the text is used to reveal the use of a program which is then tied to the numerical symbolism of 2 and 3.
Andrejs Jurjāns as Symbol of Latvian Identity: Native Folk Songs in his Large-Scale Symphonic Works
This thesis presents a study of Andrejs Jurjāns' significant symphonic works as informed by a native musicologist, Professor Jānis Torgāns, and illuminates Jurjāns' role within the cosmopolitan framework of nationalism in music.
Woodrow Wilson in the Council of Four: A Re-Evaluation
It was Woodrow Wilson who played the dominant role in the Council of Four. With his dedication to the vague, often contradictory Fourteen Points, and with the power of the office of President of the United States supporting him, he determined the very nature of the treaty. Wilson's use, and misuse, of his influence over his colleagues makes him responsible for much of the final form of the Treaty of Versailles.
Dramatic Expression in Thirty Musical Settings of Goethe's "Der Erlkonig"
This study is an investigation of the dramatic expression in thirty musical settings of Goethe's "Erlkonig," to attempt to determine why the works by Franz Schubert and Carl Loewe have achieved such popularity.
A Burkeian Analysis of the Rhetoric of Gloria Steinem
The purpose of this study has been to analyze the rhetoric of Gloria Steinem in order to determine how she uses identification in her attempts to unify the members of the Women's Liberation Movement and to enlist the cooperation of others outside the movement.
Conformational Analogs of Some Phytoactive Compounds
In an effort to determine if there is a specific conformational structure which is most effective at the appropriate active physiological site, the synthesis of a group of sterically restricted analogs was undertaken. A portion of the polymethylene carbon skeleton of glutaric acid was replaced by selected aromatic carbons in benzenedicarboxylic acids to produce a series of ridged conformers, and the relative plant growth regulating properties of these derivatives were determined.
A Study of the Physical Facilities of Industrial Arts Metalworking Laboratories in the State of Texas
The purposes for conducting this study were to ascertain whether the housing for industrial arts metalworking laboratories was adequate, whether the enrollment of the school showed any correlation with the availability of a metalworking facility, and to what extent the physical facility for metalworking laboratories met current standards.
Selected Poetry of Nikki Giovanni: A Burkeian Analysis
In this study, Kenneth Burke's methods of dramatistic analysis is applied to the selected poetry of Nikki Giovanni, a Black contemporary female poet. The procedure, analysis of poetry for symbolic action, is a functional approach which focuses on the poetic language, Agency. The thesis, divided into four chapters, concentrates on discovery of the Purpose, a Black female motive, for the Act, Giovanni's poetry, in the Scene, contemporary Black America.
A Readership Survey of the Denton Record-Chronicle
The purposes of this study were to determine the characteristics of the subscribers to the local community newspaper, to determine what the subscribers read most and what they read the least in the local publication, and to determine the role of the small newspaper within the metropolitan area.
Statesman from Texas, Roger Q. Mills
This is a biography of Roger Quarles Mills and his contributions to Texas history.
The Effects of Cultural Bias: a Comparison of the WISC-R and the WISC-III
It has been suggested that the use of standardized intelligence tests is biased against minorities. This study investigates the newly revised Wechsler Intelligence Scale for Children-III in which Wechsler states that the new scale has eliminated biased items. Comparisons of the scores on the WISC-R and the WISC-III of a clinical population of sixteen African American and eighteen Caucasian males, ages ten to sixteen, revealed significant differences between the two groups on the WISC-III. The minority scores decreased predictably from the WISC-R to the WISC-III, but the Caucasian scores increased rather than decreasing. The findings of this study do not support the predictions and goals of revision as stated in the manual of the WISC-III.
"Sorrow Whispers in the Winds" : the Republic of Texas's Commanche Indian Policy, 1836-1846
The Comanche Indians presented a major challenge to the Republic of Texas throughout its nine-year history. The presence of the Comanches greatly slowed the westward advancement of the Texas frontier, just as it had hindered the advancing frontiers of the Spaniards and Mexicans who colonized Texas before the creation of the Republic. The Indian policy of the Republic of Texas was inconsistent. Changes in leadership brought drastic alterations in the policy pursued toward the Comanche nation. The author examines the Indian policy of the Republic, how the Comanches responded to that policy, and the impact of Texan-Comanche relations on both parties.
Responses During Exercise at 90% and 100% of the Running Velocity Associated with VO2max (vVO2max)
Six male long-distance runners participated in this study to evaluate the responses to exercise at 90% and 100% vV02max. Subjects participated in five maximal exercise tests: one incremental, three tests at 90% vV02max, and one test at 100% vV02max. The results of this study demonstrate that V02max can be elicited in a constant-velocity test at 90% vV02max.
Academic Achievement: Examining the Impact of Community Type at a Small Liberal Arts College in Texas
Hierarchical regression was used to determine if high school community type is an effective predictor of academic success when controlling for demographics, prior academic achievement, socioeconomic status, and current commitment or work habits for students entering Austin College in 1992,1993, and 1994 . Findings revealed that there is a relationship between attending high school in community types of rural and independent town controlling for the effects of SAT scores, high school rank, sex, and late application deposit on first semester grade point average.
The Perception of Western Wear Status Symbols Among Western Wear Consumers
This study determined whether an association exists between the perception of western wear status symbols and demographic characteristics {i.e., gender, age, income, and education level) among Texas American Paint Horse Association members.
The Role of Gabergic Inhibition in Modulating Receptive Field Size of Cuneate Neurons
A blockade of GABAergic inhibition increases the receptive field(RF) size of most somatosensory cortex (SI) and some ventrobasal thalamus (VB) neurons. The results suggest RF size of cuneate neurons may be modulated through GABAa and GABAb receptors, independent of firing frequency.
Subcloning and Nucleotide Sequence of the xylO/PUWCMA Region from the Pseudomonas putida TOL Plasmid pDK1
The TOL plasmids of Pseudomonas putida encode enzymes required for the oxidation of toluene and other related aromatic compounds. These genes are organized into two operons, the xylUWCMABN operon (upper), and the xylXYZLTEGFJQKIH operon (lower). Here we report the nucleotide sequence of a 7107 bp segment of the TOL pDK1 plasmid encoding the region just upstream of the "upper" operon through the genes encoding xylUWCMA. Sequence analysis, comparison of base-usage patterns, codon-usage patterns, and intergenic distances between genes help support the idea that the "upper" and "lower" operons have evolved independently in different genetic backgrounds and have only more recently been brought together in TOL and related catabolic plasmids.
Effects of Performance Levels of Subject Matter Experts on Job Analysis Outcomes
Much research has been undertaken to determine how Subject Matter Expert characteristics affect job analysis outcomes. The current study seeks to discover if performance levels are related to current incumbents ratings of their positions. A group of 114 corporate associates, from two administrative positions, served as Subject Matter Experts (SME) for this study. Separate job analyses for each position were conducted using the Job Analysis Task Checklist. The results for each job were analyzed to determine if SME performance levels affected job analysis outcomes. The results for both jobs showed that there were very few differences in job analysis results as a function of SME performance levels.
Applications of Reductive Analytical Techniques in the Phrygian Settings of the Orgelbüchlein by J.S. Bach
This study aims to two problematic aspects of the Phrygian mode: a. the development of a harmonic pattern at the cadence that differs from that of the other modes and of the major and minor modes as well; b. the observation that the Phrygian scale inverts all of the intervallic properties of the Major scale. The result of these two observations is that when the reductive techniques of Heinrich Schenker are applied in the Phrygian repertory, melodic and harmonic properties are brought into conflict with each other. However, application of alternative models of the Ursatz developed by Lori Burns has certain benefits for demonstrating musical properties in the Phrygian repertory.
The History of the 389th Bombardment Group (H): a Study of the Use and Misuse of Strategic Bombers in the Second World War
This thesis describes and evaluates the successes and failures of the use of strategic bombers through the abilities of one heavy bombardment group, the 389th. It examines the different missions that determined the effectiveness of the Group. When employed in a strategic bombing role, the 389th contributed significantly to the destruction of the German war industries and transportation system. When used as a tactical bomber, a mission for which it had neither proper training nor equipment, the 389th was generally a failure.