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  Partner: UNT Libraries
 Degree Discipline: Physics
 Collection: UNT Theses and Dissertations
Broad-band Light Emission From Ion Implanted Silicon Nanocrystals Via Plasmonic and Non-plasmonic Effects for Optoelectronics

Broad-band Light Emission From Ion Implanted Silicon Nanocrystals Via Plasmonic and Non-plasmonic Effects for Optoelectronics

Date: December 2012
Creator: Singh, Akhilesh K.
Description: Broad band light emission ranging from the ultraviolet (UV) to the near infrared (NIR) has been observed from silicon nanoparticles fabricated using low energy (30-45 keV) metal and non-metal ion implantation with a fluence of 5*1015 ions/cm2 in crystalline Si(100). It is found from a systematic study of the annealing carried out at certain temperatures that the spectral characteristics remains unchanged except for the enhancement of light emission intensity due to annealing. The annealing results in nucleation of metal nanoclusters in the vicinity of Si nanoparticles which enhances the emission intensity. Structural and optical characterization demonstrate that the emission originates from both highly localized defect bound excitons at the Si/Sio2 interface, as well as surface and interface traps associated with the increased surface area of the Si nanocrystals. The emission in the UV is due to interband transitions from localized excitonic states at the interface of Si/SiO2 or from the surface of Si nanocrystals. The radiative efficiency of the UV emission from the Si nanoparticles can be modified by the localized surface plasmon (LSP) interaction induced by the nucleation of silver nanoparticles with controlled annealing of the samples. The UV emission from Si nanoclusters are coupled resonantly to the LSP ...
Contributing Partner: UNT Libraries
Theoretical and Experimental Investigations of Peg Based Thermo Sensitive Hydro Microgel

Theoretical and Experimental Investigations of Peg Based Thermo Sensitive Hydro Microgel

Date: December 2012
Creator: Chi, Chenglin
Description: Poly ethylene glycol (PEG) based microgels were synthesized and investigated. The PEG microgel has the same phase transition as the traditional poly N-isopropylacrylamide (PNIPAM). As a good substitute of PNIPAM, PEG microgel exhibits many advantages: it is easier to control the lower critical solution temperature (LCST) of the microgel by changing the component of copolymers; it has a more solid spherical core-shell structure to have a double thermo sensitivity; it is straightforward to add other sensitivities such as pH, magnetic field or organic functional groups; it readily forms a photonic crystal structure exhibiting Bragg diffraction; and, most importantly, the PEG microgel is biocompatible with human body and has been approved by FDA while PNIPAM has not. PEG microgels with core-shell structure are synthesized with a two-step free radical polymerization and characterized with DLS, SLS and UV–Vis. The dynamic mechanics of melting and recrystallizing of the PEG core-shell microgel are presented and discussed. Photonic crystals of PEG microgels were synthesized and characterized. The crystal can be isolated in a thin film or a bulk column. The phase transition of PEG microgel was simulated with the mean field theory. The enthalpy and entropy of phase transition can be estimated from the best ...
Contributing Partner: UNT Libraries
Microwave Cavity Method for Measuring Plasma Properties

Microwave Cavity Method for Measuring Plasma Properties

Date: August 1969
Creator: Freeman, Ronald H.
Description: This discussion is concerned primarily with communications blackout during spacecraft entry into a planetary atmosphere. The gas in the shock layer, between shock wave and vehicle surface, ionizes from the intense heating which takes place in the bow shock wave and a viscous region of high gas enthalpy. This ionization may persist throughout the subsequent flow over the vehicle and into the wake, thus completely engulfing the vehicle and its communications elements. The problem will be to simulate a plasma model that will be of interest for hypervelocity reentry vehicles and to provide meaningful expressions for the various plasma parameters of interest (electron density, electron temperature, collision frequency, etc.) in terms of the microwave measurables (amplitude, phase shifts, frequency shifts, polarization, etc.)
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A Vacuum Tube for an Electrostatic Generator

A Vacuum Tube for an Electrostatic Generator

Date: August 1966
Creator: Pool, John Reginald
Description: The purpose of this study has been to construct two accelerating tubes with small beam apertures for the Van de Graaff, modifying the prototype tube designed and tested by Wiley (20), to design and construct a vacuum system for evacuating the tubes, and to determine the characteristics of the tube under operating conditions while installed in the generator.
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The Diurnal Variation of Cosmic Radiation

The Diurnal Variation of Cosmic Radiation

Date: August 1965
Creator: Fowler, Brooks C.
Description: The primary purpose of this investigation was to study the diurnal variation of cosmic-ray intensity.
Contributing Partner: UNT Libraries
Design and Testing of a Positive Ion Accelerator and Necessary Vacuum System

Design and Testing of a Positive Ion Accelerator and Necessary Vacuum System

Date: August 1953
Creator: McKay, Vern A.
Description: This thesis is a study of the design and testing of a positive ion accelerator and necessary vacuum system.
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Electrical Conductivity in Thin Films

Electrical Conductivity in Thin Films

Date: May 1973
Creator: Meyer, Frederick Otto
Description: This thesis deals with electrical conductivity in thin films. Classical and quantum size effects in conductivity are discussed including some experimental evidence of quantum size effects. The component conductivity along the applied electric field of a thin film in a transverse magnetic field is developed in a density matrix method.
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A Study of the Celestial Gamma-ray Flux

A Study of the Celestial Gamma-ray Flux

Date: June 1967
Creator: Keath, Edwin P. (Edwin Paul),1938-
Description: This thesis is a study of the celestial gamma-ray flux. It reviews several of the proposed mechanisms for producing high energy gamma rays and describes several of the attempts to detect their presence. Also included is a short historical review of the spark chamber, along with a qualitative description of its operation.
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The Temperature Dependence of Magnetic Susceptibility of Galvinoxyl

The Temperature Dependence of Magnetic Susceptibility of Galvinoxyl

Date: January 1968
Creator: Martin, John R.
Description: The twofold purpose of this investigation was to design and construct an apparatus for direct magnetic susceptibility measurements as a function of temperature and to provide the complete susceptibility characterization of the free radical galvinoxyl in the room temperature-liquid nitrogen range.
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Temperature Dependence of the Magnetic Susceptibility of the Organic Free Radical Galvinoxyl

Temperature Dependence of the Magnetic Susceptibility of the Organic Free Radical Galvinoxyl

Date: August 1965
Creator: Morphew, Sam W.
Description: This thesis examines temperature dependence of magnetic susceptibility of the organic free radical galvinoxyl.
Contributing Partner: UNT Libraries