Description: This article discusses the solubility of phenylacetic acid in binary solvent mixtures. Abstract: Solubilities are reported for phenylacetic acid at 25.0 °C in binary mixtures of carbon tetrachloride with cyclohexane, n-heptane, n-octane, or isooctane and mixtures of cyclohexane with n-heptane or isooctane. The results are compared to the predictions of equations developed previously for solubility in systems of purely nonspecific interactions, with phenylacetic acid considered as either monomeric or dimeric molecules in solution. The dimer model provided the more accurate predictions and described the 15-fold range of solubilities in the carbon tetrachloride + isooctane system to within a maximum deviation of 15%.

Description: This article comments on the prediction of gas chromatographic retention behavior with mixed liquid phases.

Description: This article discusses L- and M-shell x-ray production. Abstract: L- and M-shell x-ray production cross sections have been measured for thin solid targets of neodymium, gadolinium, holmium, ytterbium, gold and lead by 25-MeV ₆¹²C(q)+ (q=4,5,6) and by 32-MeV ₈¹⁶O(q)+ (q=5,7,8). The cross sections were determined from measurements made with thin targets (less than 2.25 μg/cm2). For projectiles with one or two K-shell vacancies, the target x-ray production cross sections were found to be enhanced over those for projectiles without a K-shell vacancy. The sum of direct ionization to the continuum (DI) plus electron capture (EC) to the L,M,N,... shells and EC to the K shell of the projectile have been extracted from the data. The results are compared to the predictions of first Born theories, i.e., plane-wave Born approximation for DI and Oppenheimer-Brinkman-Kramers formula of Nikolaev for EC, and to the ECPSSR that accounts for energy loss and Coulomb deflection of the projectile as well as for relativistic and perturbed stationary states of inner-shell electrons.

Description: This note extends a certain combinatorics problem of I. Tomescu.

Description: This article discusses carbon K-shell x-ray and Auger-electron production in hydrocarbons and carbon oxides by 0.6-2.0-MeV protons. Abstract: Carbon K-shell x-ray and Auger-electron-production cross sections are reported for 0.6-2.0-MeV protons incident on CH4 (methane), C2H2 (acetylene), n-C4H10 (normal butane), i-C4H10 (isobutane), C6H6 (benzene), CO, and CO2. A variable-geometry end-window proportional counter with an alternative procedure for the determination of its transmission was used in collection of the x-ray data. A constant-energy-mode π/4 parallel-plate electrostatic analyzer served in the detection of Auger electrons. K-shell Auger-electron-production cross sections are compared with the predictions of the first Born theory and the perturbed-stationary-state theory which accounts for energy-loss, Coulomb deflection, and relativistic effects (ECPSSR). These data show fair agreement with the ECPSSR theory when the chemical shifts, of the carbon K-shell binding energy in molecules, are included in the calculations. This agreement is even better after effects of intramolecular scattering are considered. Validity of the geometrical model by Matthews and Hopkins [Phys. Rev. Lett. 40, 1326(1978)] is established after a scrutiny of the inelastic cross sections for scattering of Auger-electrons within the molecule and their effective dislocation out of the detector's window. The x-ray cross sections show particularly strong variations with the target molecular ...