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  Partner: UNT College of Arts and Sciences
 Collection: UNT Scholarly Works
A Priori Assessment of the Stereoelectronic Profile of Phosphines and Phosphites

A Priori Assessment of the Stereoelectronic Profile of Phosphines and Phosphites

Date: March 15, 2003
Creator: Cooney, Katharine D.; Cundari, Thomas R., 1964-; Hoffman, Norris W.; Pittard, Karl A.; Temple, M. Danielle & Zhao, Yong
Description: This article discusses research that has demonstrated the utility of a rigorously calibrated, molecular mechanics/semiempirical quantum mechanical protocol for developing stereoelectronic (Tolman) maps for phosphine ligands. A computational analysis of alkyl and aryl phosphines in common usage suggests that these ligands are quite similar stereoelectronically. A noticeable gap int he Tolman map for common phosphines is observed for large, electron-poor phosphines. Several candidates meeting these criteria were identified, the most promising of which is P(t-C₄F₉)₃. Phosphines in which the phosphorus participates in a ring, which comprise a very small subset of reported phosphines, have very interesting stereoelectronic properties, particularly those in which the ligating phosphorus is part of a three-membered ring. In terms of steric properties, the symmetric deformation coordinate proposed by Orpen and co-workers on the basis of crystallographic studies is calculated with sufficient accuracy using PM3(tm) to allow good confidence in predictions of novel phosphines. For quantification of the electronic properties of phosphines, the authors analyzed changes in the CO stretching frequency upon changing the ancillary phosphine ligands.
Contributing Partner: UNT College of Arts and Sciences
Probability flux as a method for detecting scaling

Probability flux as a method for detecting scaling

Date: April 5, 2010
Creator: Ignaccolo, Massimiliano; Grigolini, Paolo & West, Bruce J.
Description: In this article, the authors introduce a new method for detecting scaling in time series. The method uses the properties of the probability flux for stochastic self-affine processes and is called the 'probability flux analysis' (PFA). The advantages of this method are: 1) it is independent of the finiteness of the moments of the self-affine process; 2) it does not require a binning procedure for numerical evaluation of the probability density function. These properties make the method particularly efficient for heavy tailed distributions in which the variance is not finite, for example, in Lévy α-stable processes. This utility is established using a comparison with the 'diffusion entropy' (DE) method.
Contributing Partner: UNT College of Arts and Sciences
A Problem of Publics and the Curious Case at Texas

A Problem of Publics and the Curious Case at Texas

Date: 2010
Creator: Skinnell, Ryan
Description: This article discusses a problem of publics and the curious case of Texas.
Contributing Partner: UNT College of Arts and Sciences
Projectile charge-state dependence of K-shell ionization by silicon ions: A comparison of Coulomb ionization theories for direct ionization and electron capture with x-ray production data

Projectile charge-state dependence of K-shell ionization by silicon ions: A comparison of Coulomb ionization theories for direct ionization and electron capture with x-ray production data

Date: October 1977
Creator: McDaniel, Floyd Del; Duggan, Jerome L.; Basbas, George; Miller, P. D. & Lapicki, G.
Description: This article discusses projectile charge-state dependence of K-shell ionization by silicon ions. X-ray production cross sections measured in K-shell ionization of ₂₁Sc, ₂₂Ti, ₂₉Cu, and ₃₂Ge by 52-MeV ₁₄²⁸Si(+q) projectiles with q=7 to 14 are reported, which demonstrate, through their charge-state dependence, the validity of a recently developed electron-capture theory with a reduced binding effect. Furthermore, the data provide evidence for the applicability of the perturbed stationary-state theory of direct ionization for values of 0.44 ≤ Z₁/Z₂ ≤ 0.67.
Contributing Partner: UNT College of Arts and Sciences
Projectile-charge-state dependence of target L-shell ionization by 1.86-MeV/amu fluorine and silicon ions and 1.8-MeV/amu chlorine ions

Projectile-charge-state dependence of target L-shell ionization by 1.86-MeV/amu fluorine and silicon ions and 1.8-MeV/amu chlorine ions

Date: April 1979
Creator: McDaniel, Floyd Del; Toten, R. S.; Peterson, J. L.; Duggan, Jerome L.; Wilson, S. R.; Gressett, J. D. et al
Description: This article discusses projectile-charge-state dependence of target L-shell ionization by 1.86-MeV/amu and silicon ions and 1.8-MeV/amu chlorine ions. Lα x-ray-production cross sections have been measured for solid targets of ₆₀Nd, ₆₇Ho, and ₇₉Au for 1.86-MeV/amu ₉¹⁹F and ₁₄²⁸Si, and 1.8-MeV/amu ₁₇³⁵Cl ions as a function of the incident charge state. From the projectile-charge-state dependence of the cross sections, both direct-ionization and electron-capture contributions were extracted for a comparison to Coulomb ionization theories. The data provide supporting evidence for the theory of electron capture with a reduced binding effect. With standard fluorescence and Coster-Kronig yields uncorrected for multiple-ionization effects, the direct ionization theories did not simultaneously reproduce the projectile-Z₁ and target-Z₂ dependences of the data.
Contributing Partner: UNT College of Arts and Sciences
The Promise and Perils of Transformative Research

The Promise and Perils of Transformative Research

Date: March 2012
Creator: Frodeman, Robert & Holbrook, J. Britt
Description: This report is on the workshop 'Transformative Research: Ethical and Societal Implications'. Workshop conversations cluster under the four headings of the history and definitions, promotion, evaluation, and integration of transformative research (TR): 1. History and Definitions: The National Science Board's 2007 report (NSB-07-32) on transformative research called for more effort directed at defining TR. The present report offers additional context and clarity regarding meanings of the term. But it also argues that there are virtues in leaving the term open to multiple interpretations. 2. Promotion: The report welcomes new mechanisms for promoting TR, such as NSF 'CREATIV' grants. It embraces additional means for promoting TR, such as increased emphasis on interdisciplinary research, and explores how different interpretations of how TR occurs imply different strategies for promoting TR. It also calls for increased attention to the broader societal impacts of TR at the levels of policy, of NSF programs, and of individual research projects. 3. Evaluation: The report emphasizes the need to develop means for evaluating attempts to promote TR. It also concludes that research should be directed toward evaluating transformative research at the project level. 4. Integration: The report suggests that consideration of the broader societal impacts of TR be ...
Contributing Partner: UNT College of Arts and Sciences
Propagation of 0π pulses in a gas of three-level atoms

Propagation of 0π pulses in a gas of three-level atoms

Date: June 15, 2011
Creator: Sun, Dong; Sariyanni, Zoe-Elizabeth; Das, Sumanta & Rostovtsev, Yuri V.
Description: In this article, the authors have theoretically studied the pulsed regime of electromagnetically induced transparency. In particular, simulations of propagation of Gaussian and 0π copropagating laser pulses in a medium consisting of three-level Λ atoms have been performed. It has been found that even at the two-photon resonance, the length of propagation for the 0π pulses is much smaller than the one for the Gaussian probe pulses. Using the dark and bright basis, the authors explain this behavior. Some possible applications are discussed.
Contributing Partner: UNT College of Arts and Sciences
Publisher's Note: Beyond the Death of Linear Response: 1/f Optimal Information Transport [Phys. Rev. Lett. 105,040601 (2010)]

Publisher's Note: Beyond the Death of Linear Response: 1/f Optimal Information Transport [Phys. Rev. Lett. 105,040601 (2010)]

Date: August 3, 2010
Creator: Aquino, Gerardo; Bologna, Mauro; Grigolini, Paolo & West, Bruce J.
Description: This is a Publisher's Note for the article 'Beyond the Death of Linear Response: 1/f Optimal Information Transport' [Phys. Rev. Lett. 105, 040601 (2010)].
Contributing Partner: UNT College of Arts and Sciences
A Putative Transporter is Essential for Integrating Nutrient and Hormone Signaling with Lateral Root Growth and Nodule Development in Medicago truncatula

A Putative Transporter is Essential for Integrating Nutrient and Hormone Signaling with Lateral Root Growth and Nodule Development in Medicago truncatula

Date: 2010
Creator: Yendrek, Craig R.; Lee, Yi-Ching; Morris, Viktoriya; Liang, Yan; Pislariu, Catalina I.; Burkart, Graham et al
Description: This article discusses a putative transporter for integrating nutrient and hormone signaling with lateral root growth and nodule development in Medicago truncatula. Legume root architecture involves not only elaboration of the root system by the formation of lateral roots but also the formation of symbiotic root nodules in association with nitrogen-fixing soil rhizobia. The Medicago truncatula LATD/NIP gene plays an essential role in the development of both primary and lateral roots as well as nodule development. We have cloned the LATD/NIP gene and show that it encodes a member of the NRT1(PTR) transporter family. LATD/NIP is expressed throughout the plant. pLATD/NIP-GFP promoter-reporter fusions in transgenic roots establish the spatial expression of LATD/NIP in primary root, lateral root and nodule meristems and the surrounding cells. Expression of LATD/NIP is regulated by hormones, in particular by abscisic acid which has been previously shown to rescue the primary and lateral root meristem arrest of latd mutants. latd mutants respond normally to ammonium but have defects in responses of the root architecture to nitrate. Taken together, these results suggest that LATD/NIP may encode a nitrate transporter or transporter of another compound.
Contributing Partner: UNT College of Arts and Sciences
Quantification of emotional bias by an Emotional-Gain Model

Quantification of emotional bias by an Emotional-Gain Model

Date: July 18, 2011
Creator: Tam, Nicoladie D.
Description: This article accompanies a poster presentation on the quantification of emotional bias by an Emotional-Gain model. The authors have developed a computational model that quantifies emotion objectively based on neurobiological mechanisms that increases the chance of survival in the real world. This model is based on the EMOTION-I and EMOTION-II models with the extension of proportionality hypothesis added to the desirable gain signal to these models.
Contributing Partner: UNT College of Arts and Sciences