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Description:
U.S. Army Corps of Engineers (USACE) regulates fill of jurisdictional waters of the United States including wetlands. Recent USACE regulations set a threshold of impacts to wetlands at one-half acre. Impact area can be determined by Global Positioning System (GPS) measurement of wetland boundary and Geographic Information System (GIS) calculation of impact area. GPS point selection methods include (1) equal time interval, (2) transect and (3) intuition. Four two-acre shapes were measured with e…
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Description:
The purpose of this study was to explore the efficacy of using a computer word processing program in the assessment of written expression with college-bound individuals who had been diagnosed with a learning disability (LD) and/or attention-deficit/hyperactivity disorder (ADHD). Fifty-six (35 eleventh and 21 twelfth) graders, attending a private college-preparatory school for students with LD and/or ADHD, were administered the Spontaneous Writing composite of the Test of Written Expression - Th…
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Description:
Repetitive verbal patterns of speech are a trait associated with high-functioning autism (HFA). For some, this higher-order restricted, repetitive behavior impedes learning, social opportunities, and access to work environments. Despite emerging motivation for establishing social relationships, some individuals with HFA lack the behavioral prerequisites to establish meaningful relationships. The purpose of this study is to demonstrate the effectiveness of teaching interaction to decrease hig…
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Description:
Photophysical properties of an array of various polyaromatic hydrocarbons were benchmarked with B3LYP, M06 and B97D methods coupled with Pople and CEP-31G(d) basis sets. Results from the benchmark show the importance of diffuse basis sets when modeling the electronic properties of highly conjugated systems and provide qualitative reliable accuracy with certain levels of theory. B97D and M06 are applied to modeling pyrene adducts governed by non-covalent interactions in both gaseous and condense…
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Description:
This work discusses the C-H bond activation by transition metal complexes using various computational methods. First, we performed a DFT study of oxidative addition of methane to Ta(OC2H4)3A (where A may act as an ancillary ligand) to understand how A may affect the propensity of the complex to undergo oxidative addition. Among the A groups studied, they can be a Lewis acid (B or Al), a saturated, electron-precise moiety (CH or SiH), a σ-donor (N), or a σ-donor/π-acid (P). By varying A, we seek…
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Description:
Computational methods were employed to investigate catalytic processes. First, DFT calculations predicted the important geometry metrics of a copper–nitrene complex. MCSCF calculations supported the open-shell singlet state as the ground state of a monomeric copper nitrene, which was consistent with the diamagnetic character deduced from experimental observations. The calculations predicted an elusive terminal copper nitrene intermediate. Second, DFT methods were carried out to investigate the …
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Description:
Electronic commerce was expected to grow exponentially, but the actual rate of growth in recent years has been disappointing. Recent surveys of perceptions of the development of electronic commerce clearly focus our attention on the perception and fear of computer crime as the major cause of this disappointing growth pattern. The thesis critiques existing private law solutions to this problem and argues from a normative theory on “the commons” for the application of new public law enforcement s…
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Description:
Kurt Vonnegut's early science fiction novels depict societies and characters that, as in the real world, have become callous and downtrodden. These works use supercomputers, aliens, and space travel, often in a comical manner, to demonstrate that the future, unless people change their concepts of humanity, will not be the paradise of advanced technology and human harmony that some may expect. In fact, Vonnegut suggests that the human condition may gradually worsen if people continue to look fur…
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Description:
With the spread of the Human Immuno-Deficiency Virus and sexually transmitted diseases, it is extremely important for sexually active individuals to protect themselves properly if they decide to engage in sexual intercourse. Knowledge of HIV and the Acquired Immune Deficiency Syndrome has been associated with safer sexual practices, but knowledge alone does not totally explain risky sexual practices. This study examined how 154 college students' knowledge of HIV/AIDS, relationship status, perce…
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Description:
The United States government began paying pensions to disabled Union veterans before the Civil War ended in April 1865. By 1890 its pension programs included any Union veteran who had fought in the Civil War, regardless of his financial means, as well as surviving family members, including mothers, fathers, brothers, and sisters. Union veterans did not hesitate to "wave the bloody shirt" in their attempts to liberalize pension laws. Pension programs for Confederate veterans were much slower to …
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Description:
Resonance energy transfer was employed to study the conformational changes of actomyosin during ATP hydrolysis. To calibrate the technique, the parameters for resonance energy transfer were defined. With conformational searching algorithms to predict probe orientation, the distances measured by resonance energy transfer are highly consistent with the atomic models, which verified the accuracy and feasibility of resonance energy transfer for structural studies of proteins and oligonucleotides.
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Description:
Supply chain management (SCM) is an area that offers organizations significant opportunities for both cost reductions and revenue enhancement. In their article, "Supply Chain Management: Implementation Issues and Research Opportunities," Lambert, Cooper and Pagh defined SCM as the "integration of key business processes from end user through original suppliers that provides products, services, and information that add value for customers and other stakeholders." Adopting and implementing appr…
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Description:
The following premise is based on the ideas of social theorists who have contributed to understanding the importance of image in society. This proposal argues that political participation is susceptible to exploitation in the form of conspicuous consumption as defined by Thorstein Veblen. The analyses that follow will test the degree to which Americans who demonstrate more traditional forms of conspicuous consumption also tend to show more activity in political venues. While the correlation …
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Description:
This dissertation proposes to delineate the criteria for determining the constitutionality of public school dress codes based on an examination of relevant case law. The study addresses the following underlying questions: (1) Do students have a constitutional right to freedom of choice regarding their personal dress and grooming in public schools? (2) If so, what is the origin of the right? (3) What justification does a school district need in order to intrude upon the right? (4) Does the e…
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Description:
In a world that is increasingly united in time and distance, I examine why the world is increasingly divided socially, economically, and digitally. Using data for 35 variables from 93 countries, I separate the countries into groups of 31 each by gross domestic product per capita. These groups of developed, lesser developed and least developed countries are used in comparative analysis. Through a review of relevant literature and tests of bivariate correlation, I select eight key variables that …
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Description:
The purpose of this study was to determine the construct validity of self-reported historical walking, running, and jogging (WRJ) activity. The criterion measure was concurrent performance on a maximal treadmill test. Subjects completed a medical exam and treadmill test between the years 1976 and 1985, and completed a follow-up questionnaire in 1986. Questionnaire included an item that assessed WRJ for each year from 1976 through 1985. Data analysis included Spearman correlations, partial corre…
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Description:
This work discusses in detail the history of, and processes associated with the construction of baroque era trumpets then and now. The work addresses metallurgy, tools, construction methods, and playing characteristics of instruments built with old techniques and modern techniques.
Description:
This thesis presents a research effort aimed at developing using construction methods and techniques in army tactical shelter. The beginning step focuses on developing and identifying different activities and work breakdown structure applicable in shelter prototype. The next step focuses on identifying resource allocation. This include allocate resources based on the delivered project as per alternative one and for the second alternative as optimization, resource allocation modified and tried t…
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Description:
This study examined consumer attitude towards adding branded quick-service items on domestic airline in-flight menus with the aim of assessing the variables of perceived customer value and customer satisfaction. A random sample of one hundred sixteen frequent flyers residing in the United States participated in the study. An examination of consumer attitude towards branded quick-service menu items if introduced on domestic in-flight menus was performed. Multiple regression analysis was used to …
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Description:
With the reliability requirements of automobile microelectronics pushing towards near 0 ppb levels of failure control, halide induced corrosion issues in wire bonded devices have to be tightly controlled to achieve such a high reliability goal. With real-time corrosion monitoring, for the first time we demonstrated that the explosive H2 evolution coupled with the oxygen reduction reaction, occurring at the critical Al/Cu interfaces, is the key driving force for the observed aggressive corrosion…
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Description:
Counselor education programs are charged with the responsibility to train students to be effective counselors. Despite relative consistency in academic and clinical experiences, some students are less effective than others. It was the intent of this research to investigate possible relationships which may exist between students' background and experiences and their levels of demonstrated counselor effectiveness as measured by the Counselor Rating Form - Short Version (CRF-S) and the Supervisor …
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Description:
A Country With No Name is a collection of thirty-four poems with a preface explaining the style and influences of the author. The preface defends plain-language techniques in poetry, using W.H. Auden, Wislawa Szymborska, and Paul Simon as examples of poets who take a similar approach. The poems range in topic from personal and familial to societal and abstract. The main subjects encompass interpersonal relationships, romantic and otherwise, and larger concerns, such as the effects of war and m…
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Description:
The first diamond mine in North America was discovered in 1906 when John W. Huddleston found two diamonds on his farm just south of Murfreesboro in Pike County, Arkansas. Experts soon confirmed that the diamond-bearing formation on which Huddleston made his discovery was the second largest of its kind and represented 25 percent of all known diamond-bearing areas in the world. Discovery of the field generated nearly a half century of speculative activity by men trying to demonstrate and exploit …
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Description:
Toward the end of his life, from 1908 to 1909, Gustav Mahler (1860-1911) composed Das Lied von der Erde (The song of the earth). This piece is a cycle of six song movements based on seven poems selected from Die chinesische Flötem - Nachdichtungen chinesischer Lyrik (The Chinese flute - free adaptation of Chinese lyric poetry) by Hans Bethge. The Chinese verse was written by Li-Po (numbers 1, 3, 4 and 5), Tchang-Tsi (number 2), and Mong-Kao-Jen and Wang-Wei (combined in number 6). Subsequent…
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