Kinetic Studies of Hydroxyl and Hydrogen Atom Reactions
Description:
Gas phase kinetics of the reactions involving hydroxyl radical and hydrogen atom were studied using experimental and ab initio theoretical techniques. The rate constant for the H + H2S reaction has been measured from 298 to 598 K by the laser photolysis/resonance fluorescence (LP-RF) technique. The transition state theory (TST) analysis coupled with the measurements support the suggestion that the reaction shows significant curvature in the Arrhenius plot. The LP-RF technique was also used to…
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Date:
May 2002
Creator:
Hu, Xiaohua
Partner:
UNT Libraries