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 Degree Level: Master's
 Collection: UNT Theses and Dissertations
A 018μm Cmos Transmitter for Ecg Signals
Electrocardiography (ECG) signal transmitter is the device used to transmit the electrical signals of the heart to the remote machine. These electrical signals are ECG signals caused due to electrical activities in the heart. ECG signals have very low amplitude and frequency; hence amplification of the signals is needed to strengthen the signal. Conversion of the amplified signal into digital information and transmitting that information without losing any data is the key. This information is further used in monitoring the heart.
The Acute Hormonal Response to the Kettlebell Swing Exercise
The purpose of this investigation was to examine the acute hormonal response to a bout of kettlebell swing exercise. Ten healthy men (19-30 y, 23.6 ± 3.5 y, 174.6 ± 5.7 cm, 78.7 ± 9.9 kg) who were engaged in resistance training at least twice per week but were inexperienced with kettlebell swings participated in this study. Participants were familiarized with the kettlebell swing exercise during an initial visit. During the subsequent experimental protocol visit, participants performed 12 rounds of 30 seconds of 16-kg kettlebell swings alternated with 30 seconds of rest. Heart rate (HR) and rating of perceived exertion (RPE) were measured at the end of every round of swings. Fasted blood samples were collected pre-exercise (PRE), immediately post (IP), 15 minutes post (P15), and 30 minutes post exercise (P30) and analyzed for total testosterone (T), growth hormone (GH), cortisol, and lactate concentrations. Participants completed a total of 227 ± 23 swings (average swings per round: 19 ± 2). HR and RPE increased significantly (P < 0.05) throughout the exercise protocol. Lactate concentrations were significantly increased at all post exercise time points compared to PRE. T was significantly increased at IP compared to PRE. GH was significantly increased at IP, P15, and P30 compared to PRE. Cortisol was significantly increased at IP and P15 compared to PRE. 12 rounds of 30 seconds of kettlebell swing exercise induced an acute increase in T, GH, and cortisol concentrations in resistance trained men. Additionally, this exercise protocol induced a large increase in HR and lactate concentration. Thus, the kettlebell swing exercise might provide an effective method for simultaneous endurance and resistance training.
An Age-based Etic Analysis of Orthographic Variation in Computer-mediated French Discourse
This study examines orthographic variation in synchronous computer-mediated French discourse. All nontraditional variations of selected frequently occuring items are quantified in order to provide an etic (i.e., from an external perspective) analysis. The primary variable of interest is age since this study focuses on providing a comparison of chat participants in their twenties versus those in their fifties. The widespread claim is that younger people communicate using more informal and/or nontraditional forms than older people; however, the results of the present study suggest that this is not always the case. The main finding of the present study is that the twentysomethings and the fiftysomethings produce the nontraditional orthography in a similar fashion in 52.2% of the terms, and in a non-similar fashion in 47.8% of the terms. Following the presentation and discussion of the results, directions for future research are provided.
Characterization of Viscoelastic Properties of a Material Used for an Additive Manufacturing Method
Recent development of additive manufacturing technologies has led to lack of information on the base materials being used. A need arises to know the mechanical behaviors of these base materials so that it can be linked with macroscopic mechanical behaviors of 3D network structures manufactured from the 3D printer. The main objectives of my research are to characterize properties of a material for an additive manufacturing method (commonly referred to as 3D printing). Also, to model viscoelastic properties of Procast material that is obtained from 3D printer. For this purpose, a 3D CAD model is made using ProE and 3D printed using Projet HD3500. Series of uniaxial tensile tests, creep tests, and dynamic mechanical analysis are carried out to obtained viscoelastic behavior of Procast. Test data is fitted using various linear and nonlinear viscoelastic models. Validation of model is also carried out using tensile test data and frequency sweep data. Various other mechanical characterization have also been carried out in order to find density, melting temperature, glass transition temperature, and strain rate dependent elastic modulus of Procast material. It can be concluded that melting temperature of Procast material is around 337°C, the elastic modulus is around 0.7-0.8 GPa, and yield stress is around 16-19 MPa.
A Comparison of Picture to Word Training and Word to Word Training on Native English Speaking College Students’ Acquisition of Italian Vocabulary
The current study assessed the effects of two teaching stimulus presentations, i.e. picture to word and word to word, used to teach second language vocabulary to college students. It also evaluated the emergence of untaught relations when picture to word and word to word were used separately as a teaching strategy. The findings showed picture to word training resulted in more untaught relations. Several aspects such time allotted for online quizzes, experimental and teaching arrangements and vocabulary complexity were suggested for future research.
A Comprehensive Modeling Framework for Airborne Mobility
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Mobility models serve as the foundation for evaluating and designing airborne networks. Due to the significant impact of mobility models on the network performance, mobility models for airborne networks (ANs) must realistically capture the attributes of ANs. In this paper, I develop a comprehensive modeling framework for ANs. The work I have done is concluded as the following three parts. First, I perform a comprehensive and comparative analysis of AN mobility models and evaluate the models based on several metrics: 1) networking performance, 2) ability to capture the mobility attributes of ANs, 3) randomness levels and 4) associated applications. Second, I develop two 3D mobility models and realistic boundary models. The mobility models follow physical laws behind aircraft maneuvering and therefore capture the characteristics of aircraft trajectories. Third, I suggest an estimation procedure to extract parameters in one of the models that I developed from real flight test data. The good match between the estimated trajectories and real flight trajectories also validate the suitability of the model. The mobility models and the estimation procedure lead to the creation of “realistic” simulation and evaluation environment for airborne networks.
The Current State of Us Higher Education Social Media Policies with Regard to Teaching and Learning: a Document Review Needs Assessment
In the world we live in today, having a social media account such as Facebook, LinkedIn, Twitter, or Google+ has become deeply ingrained in our society. The old way of networking with who you knew or who knew your family is no longer in play for many people. In the times in which we live, much personal and professional networking is completed via social media. The old way of networking had unwritten rules of engagement which, basically, were to be respectful and not cause any embarrassment within the network. Rules for best practice engagement are still evolving for this new way of using social media for personal and professional networking, which is the premise for the current study which addresses: the gap in U.S. university social media policies, with regard to teaching and learning. In order to gauge the policy interlude, a sample of over 49 U.S. university social media policies were gathered for a comprehensive document analysis. The Google search engine was used to find the policies, next the qualitative software NVivo10 was used to procure and analyze the policies. Additionally, triangulation was performed by three member checking volunteer investigators. The results of the study, disclosed that current policies are intended to train faculty and staff, in the legal and proper manner, in which the universities expect their employees to positively represent the sampled universities.
Design and Analysis of Novel Verifiable Voting Schemes
Free and fair elections are the basis for democracy, but conducting elections is not an easy task. Different groups of people are trying to influence the outcome of the election in their favor using the range of methods, from campaigning for a particular candidate to well-financed lobbying. Often the stakes are too high, and the methods are illegal. Two main properties of any voting scheme are the privacy of a voter’s choice and the integrity of the tally. Unfortunately, they are mutually exclusive. Integrity requires making elections transparent and auditable, but at the same time, we must preserve a voter’s privacy. It is always a trade-off between these two requirements. Current voting schemes favor privacy over auditability, and thus, they are vulnerable to voting fraud. I propose two novel voting systems that can achieve both privacy and verifiability. The first protocol is based on cryptographical primitives to ensure the integrity of the final tally and privacy of the voter. The second protocol is a simple paper-based voting scheme that achieves almost the same level of security without usage of cryptography.
Designing Tools to Probe the Calcium-dependent Function of Arabidopsis Tonneau2
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Plants possess unique features in many aspects of development. One of these features is seen in cell wall placement during cytokinesis, which is determined by the position of the preprophase band (PPB) and the subsequent expansion of the phragmoplast that deposits the new cell wall. During phragmoplast expansion, the phragmoplast tracks to the cortical division site, which was delineated by the PPB. Thus the position of the PPB determines the orientation of the division plane. In Arabidopsis thaliana, TONNEAU2 (TON2) is required for PPB formation and has been shown to interact with a type A subunit of the PP2A phosphatase in the yeast two-hybrid system. In Arabidopsis tonneau2 (ton2) mutants, abnormalities of the cortical microtubule cytoskeleton, such as disorganization of the interphase microtubule array and lack of PPB formation before mitosis markedly affects cell shape and arrangement as well as overall plant morphology. Loss of dcd1/add1, the maize ton2 homologues gives rise to a similar phenotype in Zea mays. The TON2 protein has two EF hand domains which are calcium-binding sites. Since calcium has been known to play key roles in several areas of plant functioning, the following question was raised: “Does calcium binding contribute to the localization and function of TONNEAU at the PPB?” To address this question, a series of constructs were generated to determine if TON2 binds calcium. Additionally, Ca2+ binding sites were mutated in constructs containing the TON2 gene fused to GFP or YPF. These constructs were then transformed into ton2 mutant plants and the localization of TON2 fusion protein and whether the construct is capable of rescuing the mutant phenotype were observed. Although, localization of TON2 to the PPB was not observed, the presence of the constructs were confirmed in the transformed plants using selection markers and by observing fluorescence under a confocal microscope.
Determination of Molecular Descriptors for Illegal Drugs by Gc-fid Using Abraham Solvation Model
The Abraham solvation parameter model is a good approach for analyzing and predicting biological activities and partitioning coefficients. The general solvation equation has been used to predict the solute property (SP) behavior of drug compounds between biological barriers. Gas chromatography (GC) retention time can be used to predict molecular descriptors, such as E, S, A, B & L for existing and newly developed drug compounds. In this research, six columns of different stationary phases were used to predict the Abraham molecular descriptors more accurately. The six stationary phases used were 5% phenylmethyl polysiloxane, 6% cyanopropylphenyl 94% dimethylpolysiloxane, 5% diphenyl 95% dimethylpolysiloxane, 100% dimethylpolysiloxane, polyethylene glycol and 35% diphenyl 65% dimethylpolysiloxane. Retention times (RT) of 75 compounds have been measured and logarithm of experimental average retention time Ln(RTexp) are calculated. The Abraham solvation model is then applied to predict the process coefficients of these compounds using the literature values of the molecular descriptors (Acree Compilation descriptors). Six correlation equations are built up as a training set for each of the six columns. The six equations are then used to predict the molecular descriptors of the illegal drugs as a test set. This work shows the ability to extract molecular information from a new compound by utilizing commonly used GC columns available with the desired stationary phases. One can simply run the new compound in GC using these columns to get the retention time. Plugging in the retention time into the developed equations for each of the column will predict the molecular descriptors for the test compound and will give some information about the properties of the compound.
Dramatizing Lynching and Labor Protest: Case Studies Examining How Theatre Reflected Minority Unrest in the 1920S and 30S
Theatre is widely unrecognized for the compelling influence it has held in society throughout history. In this thesis, I specifically examine the implications surrounding the social protest theatre of black and Jewish American minority communities in the first half of the twentieth century. I discuss how their historical circumstance, culture, and idiosyncratic natures caused them to choose agitated propaganda theatre as an avenue for protest. I delve into the similarities in circumstance, but their theatre case studies separate the two communities in the end. I present case studies of each community, beginning with anti-lynching plays of the 1920s that were written by black American playwrights both in response to white supremacist propaganda theatre and to assert a dignified representation of the black community. However, their plays and protest movement never developed a larger popular following. My next minority theatre case study is an examination of 1930s Jewish labor drama created in protest of popular anti-Semitic theatre and poor labor conditions. The Jewish community differs from the black community in their case because the racist propaganda was produced by a man who was Jewish. Another difference is that their protest theatre was on the commercial stage by this point because of a rise in a Jewish middle class and improvement of circumstance. Both the Jewish protest theatre and labor reform movements were more successful. My conclusion is a summation of black and Jewish American theatre of the era with a case study of collaboration between the communities in George Gershwin’s operetta about black Americans, Porgy and Bess. I conclude that these two communities eventually departed from circumstance and therefore had differing theatrical, political, and social experiences in America during the 1930s.
Dynamic Precipitation of Second Phase Under Deformed Condition in Mg-nd Based Alloy
Magnesium alloys are the lightweight structural materials with high strength to weigh ratio that permits their application in fuel economy sensitive automobile industries. Among the several flavors of of Mg-alloys, precipitation hardenable Mg-rare earth (RE) based alloys have shown good potential due to their favorable creep resistance within a wide window of operating temperatures ranging from 150°C to 300°C. A key aspect of Mg-RE alloys is the presence of precipitate phases that leads to strengthening of such alloys. Several notable works, in literature, have been done to examine the formation of such precipitate phases. However, there are very few studies that evaluated the effect stress induced deformation on the precipitation in Mg-RE alloys. Therefore, the objective of this work is to examine influence of deformation on the precipitation of Mg-Nd based alloys. To address this problem, precipitation in two Mg-Nd based alloys, subjected to two different deformation conditions, and was examined via transmission electron microscopy (TEM) and atom probe tomography (APT). In first deformation condition, Md-2.6wt%Nd alloy was subjected to creep deformation (90MPa / 177ºC) to failure. Effect of stress-induced deformation was examined by comparing and contrasting with precipitation in non-creep tested specimens subjected to isothermal annealing (at 177ºC). In second condition, Mg-4.0Y-3.0Nd-0.5Zr (wt %) or WE43 alloy (with comparable Nd content as model Mg-Nd system) was subjected to hot rolling deformation at a sub-solvus temperature.
The Effect of Menthol on Nicotine Metabolism: a Cross Species Evaluation
The effect of menthol on nicotine metabolism was examined in liver S9 fractions of four different species and in the in vivo mouse model. The purpose of this study was to investigate three parameters: (1) biotransformation of nicotine to cotinine in various species (human, mouse, rat and trout) using in vitro methods; (2) to determine if the addition of menthol with nicotine altered biotransformation of nicotine to cotinine; (3) and to assess similar parameters in an in vivo mouse model. The major findings of this study include: (1) mice appear to metabolize nicotine, over time, in a manner similar to humans; (2) menthol decreased cotinine production, over time, after a single dose in mice; and (3) menthol increased cotinine production, over time, after repeated doses, in mice.
The Effects of a Human Trafficking Prevention Workshop Package on Participant Written and Simulation Responses
This study evaluated the effects of a community workshop designed to teach community members about human trafficking prevention. Participants were trained to identify the critical and non-critical features of human trafficking and safe ways to respond to identified trafficking situations. A pre-post treatment design was used to assess the effects of a community workshop across written and verbal target behaviors. This included written responses as well as simulation assessments across five different trafficking scenarios. Results indicate that all participants engaged in more correct responding within the written assessment and asked specific relevant questions with greater confidence within the simulation assessment following training. However, social media and empathy responses following the workshop did not differ from baseline. This study is one of the first empirical studies aimed at formally evaluating the effects of human trafficking prevention workshops. Results are discussed in the context of instructional design, measurement of outcomes, and interdisciplinary collaboration.
Effects of Airway Pressure, Hypercapnia, and Hypoxia on Pulmonary Vagal Afferents in the Alligator (Alligator Misssissippiensis)
The American alligator (Alligator mississippiensis) is an aquatic diving reptile with a periodic breathing pattern. Previous work has identified pulmonary stretch receptors (PSR), both rapidly- and slowly-adapting, and intrapulmonary chemoreceptors (IPCs) that modulate breathing patterns in alligators. The purpose of the present study was to identify the effects of prolonged lung inflation and deflation (simulated dives) on PSR and/or IPC firing characteristics in the alligator. The effects of airway pressure, hypercapnia, and hypoxia on dynamic and static responses of pulmonary stretch receptors (PSR) were studied in juvenile alligators (mean mass = 246 g) at 24°C. Receptor activity appeared to be a mixture of slowly-adapting PSRs (SARs) and rapidly-adapting PSRs (RARs) with varying thresholds and degrees of adaptation, but no CO2 sensitivity. Dives were simulated in order to character receptor activity before, during, and after prolonged periods of lung inflation and deflation. Some stretch receptors showed a change in dynamic response, exhibiting inhibition for several breaths after 1 min of lung inflation, but were unaffected by prolonged deflation. For SAR, the post-dive inhibition was inhibited by CO2 and hypoxia alone. These airway stretch receptors may be involved in recovery of breathing patterns and lung volume during pre- and post-diving behavior and apneic periods in diving reptiles. These results suggest that inhibition of PSR firing following prolonged inflation may promote post-dive ventilation in alligators.
Emerging Ed-tech and Accessibility
Recent developments in the field of education have led to a proliferation of educational technologies (or “ed-tech”), yet access to educational content for students with special needs remains a challenge. This research study aims to assess the current state of accessibility in emerging ed-tech and to identify barriers in enabling educational content to be born accessible. Detailed discussions with various ed-tech platforms revealed less of a need for technical tools, but a more prevailing need for knowledge and education around accessibility – what it means and how best to incorporate accessibility into their platforms. The more experienced teams advocate incorporating accessibility into product development right from the design phase, while the younger teams expressed challenges in navigating accessibility laws and the dire need for easy-to-follow guidelines and best practices. A detailed review of educators' content creation processes reveals multiple dependencies in the ecosystem of ed-tech where partnerships and compatibilities are crucial in enabling accessibility throughout the process. Likewise, an urgent need exists for increasing awareness of accessibility among instructors authoring educational content using emerging ed-tech.
Energy Harvesting Wireless Piezoelectric Resonant Force Sensor
The piezoelectric energy harvester has become a new powering option for some low-power electronic devices such as MEMS (Micro Electrical Mechanical System) sensors. Piezoelectric materials can collect the ambient vibrations energy and convert it to electrical energy. This thesis is intended to demonstrate the behavior of a piezoelectric energy harvester system at elevated temperature from room temperature up to 82°C, and compares the system’s performance using different piezoelectric materials. The systems are structured with a Lead Magnesium Niobate-Lead Titanate (PMN-PT) single crystal patch bonded to an aluminum cantilever beam, Lead Indium Niobate-Lead Magnesium Niobate-Lead Titanate (PIN-PMN-PT) single crystal patch bonded to an aluminum cantilever beam and a bimorph cantilever beam which is made of Lead Zirconate Titanate (PZT). The results of this experimental study show the effects of the temperature on the operation frequency and output power of the piezoelectric energy harvesting system. The harvested electrical energy has been stored in storage circuits including a battery. Then, the stored energy has been used to power up the other part of the system, a wireless resonator force sensor, which uses frequency conversion techniques to convert the sensor’s ultrasonic signal to a microwave signal in order to transmit the signal wirelessly.
Evaluating the Content and Tone of Mental Health News Coverage in Market 40: a Content Analysis of Selected Internet Stories From Las Vegas Broadcasting News Outlets
The purpose of this research study is to analyze mental health related content on the three network affiliated stations in Las Vegas, Nevada. Online web stories from broadcast stations are analyzed in terms of the content and tone. These areas of analysis relate directly to the mass communication theories agenda setting and framing. Historically, mental health news reports have included content and tone that together can potentially create and further stigmatizing sentiments about those with mental illnesses. This study utilizes a chi square test to determine if a relationship exists between the three network affiliated stations, four a priori coded mental health content categories, and a rating of the overall tone using a value dimensions scale. Supplemental analyses include frequency evaluations of what has been called “people-first” versus “non-people first” language. By analyzing mental health related content at these three stations in the Las Vegas market this study aims to add heuristic value to the study of mental health reporting in broadcast news. This study will allow for additional research to further test relationships between stations, content, and tone in the Las Vegas and other news markets. Ultimately, this study provides analysis and discussion of the important role of agenda setting and framing in the news industry as it relates to the coverage of mental health related content.
Examining E-loyalty Model in Social Shopping Websites: the Impact of Social Shopping Website Quality on E-loyalty Formation
The purpose of this study is to examine the formation of customer e-loyalty to a social shopping website. The formation of customer e-loyalty to a social shopping website is examined based on cognitive-affective-conative-action loyalty framework. This study proposes that customer e-loyalty is strongly associated with website quality, e-satisfaction and participation. Seven website attributes (i.e., visual aesthetics, navigation, efficiency, user friendliness, security/privacy, entertainment and community driveness) identified in previous research are employed to measure website quality that affects e-loyalty formation. There are 449 data collected from a southwestern university in the U.S., but only the responses from 333 Pinterest users are used to test the hypotheses. Exploratory factor analysis is used to identify dimensionality of social shopping website attributes, and multiple regression and linear regression analysis are conducted to test hypotheses in this study. Results of the study indicate that five significant factors including efficiency, user friendliness, security/privacy, entertainment and community driveness are directly associated with customer e-loyalty. Indeed, such website quality factors as the determinant of cognitive e-loyalty directly affect overall customer satisfaction (affective e-loyalty), customer purchase/return intention to the website (conative e-loyalty), and customer participation, positive eWOM and co-shopping (action e-loyalty). The findings of this study have provided evidence that social shopping website quality dimensions are directly associated with customer e-loyalty to the website. Also, the findings have shown important implications to ensure quality website attributes to increase customer loyalty to a social shopping website.
Exploring the Impacts of Fashion Blog Type and Message Type on Female Consumer Response Towards the Brand
The current study examines the influences of blog type and blog message type on consumers’ perceptions of brand credibility and brand similarity. Additionally, the study seeks to understand the interaction effects of blog type and message type on brand credibility and brand similarity and on consumer engagement with a blog. The findings reveal that message type, specifically product message, is an important consideration when marketers want to illustrate similarities between the brand and consumers. Additionally, it was found that product messages should be considered when encouraging consumer engagement with a blog. However, blog type did not have an effect on consumer perceptions of brand credibility and similarity or consumer engagement.
Facebook Brand Page: an Exploratory Study of Facebook Brand Page Attributes and Their Influence on Purchase Intentions
This study explored attributes of a Facebook brand page (FBP). Seven variables were derived from the framework and applied to FBPs. The goals of this research were to discover which attributes contribute to a successful FBP, determine which attributes increase purchase intentions, and help marketers determine where to focus their efforts. A total of 421 surveys were gathered from men and women ages 18 and older. The methods of this research included factor analysis and multiple regression analysis. Results yielded two loading factors for the trustworthiness variable and supported hypotheses of trustworthiness increasing purchase intentions. It was also discovered that participation positively influences purchase intentions. It is advised that information content be monitored to avoid information overload.
Facebook Marketing for Fashion Apparel Brands: Effect of Other Consumer Postings and Type of Brand Comment on Brand Trust and Purchase Intention
Social networking sites are a major networking tool for consumer interactions as they provide a platform for communication, socialization, and learning activity. Subsequently, social media has become an important marketing tool for advertising companies’ messages. As a result, fashion brands such as H&M and Victoria’s Secret started to show more brand ads on Facebook. Facebook is one of the most powerful social networking sties due to its ability to reach to broad consumer groups through a brand page. However, research regarding this topic is limited as the social networking sites is relatively a new phenomenon. Therefore, the purpose of this research is to examine the effect of the brand’s comments in attenuating (enhancing) negative (positive) influence of other consumer’s postings on brand trust and purchase intention of other consumer’s postings on social media. Findings from this study revealed that there is no moderating effect of brand comments of the relationship between other consumer’s postings and brand trust, while positive other consumer’s postings has a significant effect on consumers’ brand trust. Also, there were no significant differences among other consumer’s postings, brand comments and purchase intention relationships. These findings add to the previous literature explains that brand should interact with consumers frequently in order to induce positive other consumer’s postings to develop brand trust. By using the consumer socialization theory to investigate Facebook marketing, this study provides insights and information on consumer attitudes and behaviors related to Facebook brand page.
The Glass Is Neither Half Full Nor Empty, It Is Shattered: a Prospective Study of Shattered Assumptions Theory and Psychological Flexibility
Shattered assumptions theory posits that each individual has a core set of assumptions about the world and the self, often termed the assumptive world which includes: the world is a benevolent place, the world is meaningful, and the self is worthy. Experiencing a traumatic event is believed to lead individuals to question these assumptions in light of the new contradictory information that causes the assumptive world to shatter, leaving the individual to rebuild a more negative perception of the world and themselves. This rebuilding of a fragile new set of core beliefs is believed to be a cause of posttraumatic stress disorder (PTSD) symptoms. Although shattered assumptions theory has been widely accepted in the field of trauma psychology, the shattering of the assumptive world has not been empirically supported due to measurement issues and poor research designs. The current study implemented a prospective design to assess a new measure of the individual’s assumptive world when there is an intervening trauma. In a college sample (N = 336), individuals who experienced a traumatic event over the course of the semester (n = 40) evidenced decreases in optimism in their assumptive worlds, in comparison to individuals who did not experience a traumatic event. The results suggest there is a limited shattering of the assumptive world for those who experienced a traumatic event. Applications, limitations and future directions are discussed.
Grace After Fire: an Analysis of Table Talk: Color Me Camo-realities of Female Veterans
Beginning May of 2013 and ending in September, I worked with Grace After Fire (Grace), a virtual nonprofit organization that focuses on issues related to female veterans. Grace’s mission is to provide female veterans with the means to gain knowledge, insight and self-renewal. Grace’s mission is accomplished through peer support and resource referral. The aim of my thesis project was to conduct an analysis of Grace’s peer support system, Table Talk: Color Me Camo (Table Talk). Because Table Talk is a fairly new program for Grace, just over a year old, the outreach coordinators were eager to learn: 1) if they were indeed meeting their mission of empowering female veterans, and 2) the point-of-view of the peer facilitators who conduct Table Talk. To help Grace gain perspective, I interviewed women who had previously attended Table Talk, as well as peer facilitators responsible for coordinating the peer support system-all of whom are female veterans. The following is their story.
Hermanos De Raza: Alonso S Perales and the Creation of the Lulac Spirit
There were two great ambitions in the life of Alonso S. Perales: the first was to help his people, the Mexican-Americans; the second was to help all of mankind. To pursue this first ambition, Perales became very active as a major political leader who supported civil rights and the abolishment of racial discrimination. Many viewed him as a defender of la raza (the Mexican-American race) and one of the most influential Mexican-Americans of his time. As such, Perales devoted most of his work to defending Mexican-Americans and battling charges that Mexicans were an inferior people and a social problem. He participated in various Civil Rights organizations and was one of the founders of the League of United Latin American Citizens (LULAC). This author argues that without Perales’ involvement, LULAC would have never existed. This work solely focuses on Perales’ life from the late 1920s to the early 1930s. It begins by examining Perales’ roots and his first involvement with Mexican-American civil rights. It then covers his role in the origin of LULAC, specifically its predecessor organization, the League of Latin American Citizens. Furthermore, this work explores Perales’ involvement in the defeat of the 1930 Box Bill and his role in the American electoral missions in Nicaragua between 1928 and 1932. Lastly, this work examines why LULAC has forgotten Perales. The main goal is to shed light on this often neglected aspect of Mexican-American history and hopefully to bring forth the importance and impact that Perales’ work had on la raza not only in Texas but nationwide.
Historical and Theological Backgrounds of the Whore of Babylon in Revelation 17 & 18 in a Jewish Context
I argue that some ancient Jewish sects, specifically the community at Qumran and the early Christians, did in fact write against, speak out against, and interpret ancient tests as being against their fellow Jews, the Temple, Jerusalem or all three. Given the time in which these occurred, I argue that those sects believed that the Roman Empire would be means in which their god would punish/destroy Jews that did not believe as they did, the Temple that did not represent what they thought it should, and Jerusalem as they believed it had become a sinful city. I examine the writings and persons of the Greek Bible. I examine specifics such as the Parable of the Tenants and demonstrate that this was delivered against Jewish leadership and the Olivet Discourse that, like the book of Jubilees, presents a series of tribulations that will fall on a wicked generation, specifically the one living in Jerusalem during the first century C.E. I also demonstrate how the motif of these writings affected the book of Revelation. I examine the prophetic books of the Hebrew Bible and show how the author used them as allusions in regards to the Whore of Babylon that appear in the book of Revelation. In doing so, I demonstrate that the Whore of Babylon is correctly identified as the city of Jerusalem. Additionally I show that the author used Babylon, the ancient foe of Israel, as a metaphor to demonstrate what he believed Israel had become. Lastly, I examine the author, a man named John, and the social world he lived in and the time he wrote during. I demonstrate that the commonly held belief of persecution against the early Christians and the use of Roman religion, such as the imperial cult, has been over stated and has led not only to a misinterpretation of chapters 17 and 18 in the book of Revelation, but they have led to an overall misunderstanding of the book as a whole.
Immunohistochemistry of the Gills of the Channel Catfish Ictalurus Punctatus: Cells and Neurochemicals That May Be Involved in the Control of Cardioventilatory Reflexes
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In teleost fishes the neurochemicals involved in sensing and responding to hypoxia are unresolved. Serotonergic branchial neuroepithelial cells (NECs) are putative O2 chemoreceptors believed to be homologous to the neural crest (NC) derived APUD (amine-precursor uptake and decarboxylation) pulmonary NECs and carotid body type-1 glomus cells. Branchial NECs contain serotonin (5-HT), thought to be central to the induction of the hypoxic cardioventilatory reflexes. However, application of 5-HT in vivo does not elicit cardioventilatory reflexes similar to those elicited by hypoxia. But previous in vitro neural recordings from glossopharyngeal (IX) afferents innervating O2 chemoreceptors in the trout gill show the same discharge response to hypoxic conditions as does that of acetylcholine (ACh) application. This evidence strongly supports the cholinergic hypothesis of chemoreceptor impulse origin rather than a serotonergic-induced impulse origin model. We therefore hypothesized that NECs contain ACh among other neurochemicals in cells belonging to the APUD series. Although serotonergic branchial NECs did not colocalize with ACh using immunohistochemical methods, several populations of ACh and/or tyrosine hydroxylase (TH) (catecholaminergic) positive, dopamine (DA) negative, cells were found throughout the second gill arch of the channel catfish Ictalurus punctatus. In addition, the NC derivation marker zn-12 labelled the HNK-1-like epitope (Human natural killer) expressed by lamellar pillar cells’ collagen column-associated pillar cell adhesion molecules (CC-PCAMs), evidence confirming their hypothesized NC origin.
In-store Event Needs and Technology Use Among Half Price Books Customers
Half Price Books, Records, Magazines, Inc. (HPB), fills a unique niche by selling a variety of new, used and rare merchandise primarily in their chain of 116 stores in sixteen states and online. The company has noticed increased mobile device use among customers in their stores while sales have declined in recent years. To remain viable HPB is attempting to adapt to market forces in a timely manner while remaining continually interested in growth and innovation. A major part of adapting, growing, and innovating is the adoption and astute utilization of technology in-store and a more complete understanding of their customers’ activities and preferences. The goal is to make Half Price Books a more technologically savvy destination for shopping, community events, and entertainment. One purpose of this study is to give the company a better idea of how customers use technology in searching for merchandise including information searches generated in-store from mobile devices and how customers use the internet to find merchandise prior to and following their experiences in HPB’s stores. Another important purpose is to also determine what kinds of events such as book signings, poetry readings and other special events customers would like to see at Half Price Books, since the company has indicated a strong desire to provide fun and memorable experiences as well as products. The major research aims of this study are (1) To explore how customers use technology in searching for books in relation to two Half Price Books locations in Arlington, Texas and (2) To determine what customers want in terms of in-store events at these same locations.
Josephus’ Jewish War and the Causes of the Jewish Revolt: Re-examining Inevitability
The Jewish revolt against the Romans in 66 CE can be seen as the culmination of years of oppression at the hands of their Roman overlords. The first-century historian Josephus narrates the developments of the war and the events prior. A member of the priestly class and a general in the war, Josephus provides us a detailed account that has long troubled historians. This book was an attempt by Josephus to explain the nature of the war to his primary audience of predominantly angry and grieving Jews. The causes of the war are explained in different terms, ranging from Roman provincial administration, Jewish apocalypticism, and Jewish internal struggles. The Jews eventually reached a tipping point and engaged the Romans in open revolt. Josephus was adamant that the origin of the revolt remained with a few, youthful individuals who were able to persuade the country to rebel. This thesis emphasizes the causes of the war as Josephus saw them and how they are reflected both within The Jewish War and the later work Jewish Antiquities. By observing the Roman provincial administration spanning 6-66 CE, I argue that Judaea had low moments sprinkled throughout the time but in 66 there was something particularly different, according to Josephus. Josephus presents the governors and other important characters in the war in a very distinct way through rhetoric, narrative, and other methodology. The idea of a beginning to this revolt, no matter how obscure or hidden by Josephus, is the reason I want to examine the works of Josephus the historian.
Laser Surface Modification on Az31b Mg Alloy for Bio-wettability
Laser surface modification of AZ31B Magnesium alloy changes surface composition and roughness to provide improved surface bio-wettability. Laser processing resulted in phase transformation and grain refinement due to rapid quenching effect. Furthermore, instantaneous heating and vaporization resulted in removal of material, leading the textured surface generation. A study was conducted on a continuum-wave diode-pumped ytterbium laser to create multiple tracks for determining the resulting bio-wettability. Five different laser input powers were processed on Mg alloy, and then examined by XRD, SEM, optical profilometer, and contact angle measurement. A finite element based heat transfer model was developed using COMSOL multi-physics package to predict the temperature evolution during laser processing. The thermal histories predicted by the model are used to evaluate the cooling rates and solidification rate and the associated changes in the microstructure. The surface energy of laser surface modification samples can be calculated by measuring the contact angle with 3 different standard liquid (D.I water, Formamide, and 1-Bromonaphthalen). The bio-wettability of the laser surface modification samples can be conducted by simulated body fluid contact angle measurement. The results of SEM, 3D morphology, XRD, and contact angle measurement show that the grain size and roughness play role for wetting behavior of laser processing Mg samples. Surface with low roughness and large grain size performs as hydrophilicity. On the contrast, surface with high roughness and small grain size performs as hydrophobicity.
The Measurement of the Third-order Elastic Constants for La3ga5sio14 (Lgs) and La3ga55ta05o14 (Lgt) Single Crystal
Recently, the development of electronic technology towards higher frequencies and larger band widths has led to interest in finding new piezoelectric materials, which could be used to make filters with larger pass band widths and oscillators with better frequency stability. Langasite (La3Ga5SiO14, LGS) and its isomorphs have enticed considerable attention of researchers as a potential substrate material for piezoelectric device applications because of its high frequency stability and fairly good electromechanical coupling factors for acoustic wave devices. Nonlinear effect including drive level dependence, mode coupling, force-frequency effect and electroelasic effect are critical for the design of these devices. Third-order elastic constants (TOEC) play an important role in a quantitative analysis of these nonlinear effects. In particular these elastic constants are of great importance when the BAW (Bulk Acoustic Wave) and SAW (Surface Acoustic Wave) sensors of force, acceleration and so on are designed. Until now Langasite (LGS) and Langatate (LGT) crystal resonators have been qualified in terms of quality factor, temperature effect, isochronism defect and material quality. One of the most important advantages of those crystals is that they will not undergo phase transitions up to its melting temperature of 1450°. Presently there is no data on TOEC of LGT crystals. Our objective is to create an experimental procedure to measure and collect the complete set of third-order elastic constants of Langasite (La3Ga5SiO14) and Langatate (La3Ga5.5Ta0.5O14) crystals and compare the new values for langasite with values previously reported.
Multi-year Operation Effect of Geothermal Heat Exchanger on Soil Temperature for Unt Zero Energy Lab
Ground source heat pump (GSHP) uses earth’s heat to heat or cool space. Absorbing heat from earth or rejecting heat to the earth, changes soil’s constant temperature over the multiple years. In this report we have studied about Soil temperature change over multiple years due to Ground loop heat exchanger (GLHE) for Zero Energy Research Laboratory (ZØE) which is located in Discovery Park, University of North Texas, Denton, TX. We did 2D thermal analysis GLHP at particular Depth. For simulation we have used ANSYS workbench for pre-processing and FLUENT ANYS as solver. TAC Vista is software that monitors and controls various systems in ZØE. It also monitors temperature of water inlet/outlet of GLHE. For Monitoring Ground temperatures at various depths we have thermocouples installed till 8ft from earth surface, these temperatures are measured using LabVIEW. From TAC Vista and LabVIEW Reading’s we have studied five parameters in this report using FLUENT ANSYS, they are; (1) Effect of Time on soil Temperature change over Multi-years, (2) Effect of Load on soil temperature change over Multi-years, (3) Effect of Depth on soil temperature change over Multi-years, (4) Effect of Doubling ΔT of inlet and outlet of GLHE on soil temperature change over multi-years and (5) Effect on soil temperature change for same ZØE Laboratory, if it’s in Miami, Florida. For studying effect of time on soil temperature change for multi-years, we have varied heating and cooling seasons. We have four cases they are Case A: GSHP always “ON” (1) 7 months cooling and 5 month cooling and (2) 257 days are cooling and 108 days heating. Case B: GSHP “OFF” for 2 months (1) 7 months cooling and 3 months heating and (2) 6 months cooling and 4 month heating. For Studying Effect of Load on soil temperature change over multi-years, we have considered maximum temperature difference between inlet and outlet for heating and cooling season for simulation. For studying effect of doubling ΔT of inlet and outlet of GLHE, we have doubled the temperature difference between inlet and outlet of GLHP. There will be soil temperature change over year at various depths. For studying Effect of Depth on soil temperature change for multi-years, we have consider 5 depths, they are 4ft, 6ft, 8ft, 110ft and 220ft. The Densities of soil are known from site survey report of ZØE GSHP manufacturers till depth of 13ft. For studying effect of soil temperature over multi-years for same ZØE in Miami, Florida, we have considered equivalent cooling and heating season from weather data for past one year and assuming same number of days of cooling and heating for next 20 years we have simulated for soil temperature change.
Overcapacity is a self-reflexive, personal journey film that explores the filmmaker's exploration of his lifelong problem with obesity and health. The film follows his progress as he discusses his weight problem with his partner and parents as well as works with a personal trainer and doctor in an effort to affect a lifestyle change while also confronting issues that have led to and perpetuate his current health situation.
Parameter Estimation Using Consensus Building Strategies with Application to Sensor Networks
Sensor network plays a significant role in determining the performance of network inference tasks. A wireless sensor network with a large number of sensor nodes can be used as an effective tool for gathering data in various situations. One of the major issues in WSN is developing an efficient protocol which has a significant impact on the convergence of the network. Parameter estimation is one of the most important applications of sensor network. In order to model such large and complex networks for estimation, efficient strategies and algorithms which take less time to converge are being developed. To deal with this challenge, an approach of having multilayer network structure to estimate parameter and reach convergence in less time is estimated by comparing it with known gossip distributed algorithm. Approached Multicast multilayer algorithm on a network structure of Gaussian mixture model with two components to estimate parameters were compared and simulated with gossip algorithm. Both the algorithms were compared based on the number of iterations the algorithms took to reach convergence by using Expectation Maximization Algorithm.Finally a series of theoretical and practical results that explicitly showed that Multicast works better than gossip in large and complex networks for estimation in consensus building strategies.
Paul and Slavery: a Conflict of Metaphor and Reality
The debate on Paul’s views on slavery has ranged from calling him criminal in his enforcement of the status quo to rallying behind his idea of equal Christians in a community. In this thesis I blend these two major views into the idea that Paul supported both the institution of slavery and the slave by legitimizing the role of the slave in Christian theology. This is done by reviewing the mainstream views of slavery, comparing them to Paul’s writing, both the non-disputed and disputed, and detailing how Paul’s presentation of slavery differed from mainstream views. It is this difference which protects the slave from their master and brings attention to the slave’s actions and devotion. To Paul, slavery was a natural institution which should be emulated Christian devotion. He did not challenge the Romans but called for Christians to challenge the mainstream views of the roles of slavery in the social hierarchy of their communities.
Perceived Parent-child Relationship Quality’s Moderation Effect on the Acculturation-wellbeing Relationship Among Young Adults From Immigrant Families
The current study examined relationships among acculturation, parent-child relationship quality, and selected wellbeing indicators (health-related quality of life, life satisfaction, anxiety, depression, and stress) among a group of young adults from immigrant families of Asian and Hispanic descent. The first goal of the current study was to replicate previous research demonstrating a mixed relationship between acculturation and the wellbeing indicators. The second was to explain this relationship by testing for a moderation effect of parental care on the acculturation-wellbeing relationship. An examination of differences between members of the two ethnic groups on all measured variables served an exploratory purpose. Participants included 204 participants of Asian (N =80) and Hispanic (N = 124) descent who came from an immigrant family, or a family in which at least one parent was born outside of the U.S. Eligible respondents were also current students at the University of the North Texas who fell within the age range of 18-24, and the data for the current study was selected from a larger dataset (N = 1064). Results indicated that higher acculturation levels had a positive effect on each wellbeing indicator. Father Care and Mother Care were found to be significantly positively correlated with most outcome variables but neither parental care variable moderated the acculturation-wellbeing relationship. Asian and Hispanic participants differed on a number of predicting and outcome variables. Implications of the findings, limitations, and future directions are discussed.
Phototoxic Effects of Titanium Dioxide Nanoparticles on Daphnia Magna
Titanium dioxide nanoparticles (TiO2-NP) are one of the most abundantly utilized nanomaterials in the world. Studies have demonstrated the mechanism of acute toxicity in TiO2-NP to be the production of reactive oxygen species (ROS) leading to oxidative stress and mortality in exposed organisms. It has also been demonstrated that the anatase crystalline conformation is capable of catalyzing the cleavage of water molecules to further increase the concentration of ROS in the presence of ultraviolet radiation. This photoenhanced toxicity significantly lowers the toxicity threshold of TiO2-NP to environmentally relevant concentrations (ppb). The goal of this study was to determine whether dietary uptake and accumulation of TiO2-NP in the aquatic filter feeder Daphnia magna resulted in photoenhanced toxicity. D. magna and S. caprincornatum were exposed to aqueous solutions of 20ppm and 200ppm TiO2-NP for 24hrs and then transferred to clean moderately hard water. Samples were taken at various time points, dried, and TiO2 quantified using ICP-MS. Toxicity assays were run on D. magna using three TiO2-NP (20ppm, 200ppm) exposure protocols and two ultraviolet radiation treatments. The first exposure group was exposed to aqueous solutions of TiO2-NP for the duration of the test. The second exposure group was exposed to TiO2-NP for an hour and then transferred to clean water. The third exposure group was fed S. capricornatum that had been allowed to adsorb TiO2-NP. All samples were then placed in an outdoor UV exposure system and exposed to either full spectrum sunlight (with UV) or filtered sunlight (no UV). Here we show that TiO2 uptake peaked at one hour of exposure likely due to sedimentation of the particles out of suspension, thus decreasing bioavailability for the duration of the test. Interetsingly, when D. magna were moved to clean water, aqueous concentrations of TiO2 increase as a result of depuration from the gut tract. Data also suggests these excreted particles were bioavailable and re-consumed by D. magna. These data will contribute to the understanding of TiO2-NP environmental fate and toxicity.
Pocky Wenches Versus La Pauvre Femme: Medical Perceptions of Venereal Disease in Seventeenth-century England and France
In early modern Europe, syphilis tormented individuals regardless of social standing. The various stages of infection rendered individuals with visible chancres or “pocky” marks throughout their body. The tertiary stage signaled the spreading of the disease from the infected parts into the brain and cardiovascular system, eventually leading to dementia and a painful death. Beginning with the initial medical responses to venereal disease in the sixteenth century and throughout the early modern period, medical practitioners attempted to identify the cause of syphilis. During the seventeenth century, English practitioners maintained that women were primarily responsible for both the creation and transmission of syphilis. In England, venereal disease became the physical manifestation of illicit sexual behavior and therefore women with syphilis demonstrated their sexual immorality. Contrastingly, French medical practitioners refrained from placing blame on women for venereal infection. The historiography of early modern discourse on venereal disease fails to account for this discrepancy between English and French perceptions of syphilis in the seventeenth century. This thesis seeks to fill the gap in this historiography and suggest why French practitioners abstained from singling out women as the primary source of venereal infection by suggesting the importance that cultural influences and religious practices had toward shaping medical perceptions. The cultural impact of the querelle des femmes and Catholic practices in France plausibly influenced the better portrayal of women within the medical treatises of seventeenth-century France when compared to Protestant England.
The Political, Economic, and Military Decline of Venice Leading Up to 1797
This thesis discusses the decline of the Venetian nobility, the collapse of the Venetian economy, and the political results of the surrender of the Venetian Republic to Napoleon Bonaparte in 1797. Topics include the formation of Venice, Venetian domination of trade, the class system in Venice prior to 1797, the collapse of the aristocracy, feudalism in Venice, Venice’s presence in the Adriatic and Aegean seas, and the rise of the middle class within the provisional democratic government. Very few historians have attempted to research the provisional democracy of Venice and how the political and class structure of Venice changed as a result of the collapse of the Republic in 1797. Using primary sources, including government documents and contemporary histories, one can see how the once dominant noble class slowly fell victim to economic ruin and finally lost their role in the political leadership of Venice all together. During this same period, the middle class went from only holding secretarial jobs within the government, to leaders of a modern democratic movement. On top of primary research, several secondary sources helped in explaining the exclusivity of the noble class and their journey from economic dominance to economic ruin and the administrative consequences of this decline for the people of the Republic. This thesis aims to fill gaps in recent research concerning Venetian political history and specifically the period between the surrender of Venice on 12 May 1797, and the signing of the Treaty of Campo Formio, in which France awarded Venice to Austria, on 18 October 1797.
Reclaiming the Flock: Innocent Iii, the 1215 Canon and the Role of the Sacraments in Reforming the Catholic Church
This thesis traces the changes in the sacraments of Baptism and the Eucharist from 400-1215 and posits that Innocent III’s Fourth Lateran Council solidified and clarified these sacraments from diversified practices and customs to a single Catholic orthodoxy in order to reclaim centralized papal power to the Roman Catholic Church. Tracing the history of the Catholic Church’s baptismal and Eucharistic rites encounters a number of logistical obstacles because they were not administered by means of a Western Church-prescribed ritual until the early thirteenth century, primarily because such a prescription did not exist. Even after the First Council of Nicaea where Christian doctrine was better defined, an allowable margin of license remained within Latin orthodoxy, specifically when it came to the practice and administration of the sacraments. Before the establishment of a finite canon the sacramental procedures of the Western Church relied heavily on the local bishops and monks who openly adopted their own preferential liturgies and ritual practices. This fragmentation took the power away from the Holy See in Rome and instead fostered the idea that regional practices were superior. The foundation of their varied interpretations can be traced back to a number of theologians ranging from the early second century tracts of Justin Martyr to Augustine in the late fourth century. Upon the inauguration of Pope Innocent III in 1198, however, the Church adopted a policy of zero tolerance for practices, rituals and individuals that it deemed heretical. Through a series of papal bulls that even began in the first months of Innocent’s reign, he initiated an attempt to eradicate regional inconsistencies and to create a more streamlined orthodoxy. This movement was fully realized in the year before Innocent’s death with the creation of the 1215 Canon in which Catholic Church leaders from around the world defined, explained and mandated sacramental ritual, as well as the expectations for the priests and clerics who administered them. The canon was a compilation of reformed laws for the Church of the Latin West, almost all of which can be directly traced to Innocent’s own decretals and papal bulls. This canon used Biblical references as well as Roman Church and apostolic tradition to define these rites and the role of those who administered them. The goal of Innocent’s reform was to redirect and update the canonical practices within Catholic orthodoxy, while at the same time it helped to identify and extinguish, Christian sects and princes who refused the divinely ordained and irrefutable power of the Catholic Church in Western Europe.
Redeeming the Betrayer: Elgar’s Portrayal of Judas in the Apostles
Despite its generally agreed importance, very little has been written about The Apostles. Even among the extant publications that address The Apostles, scholars have focused on its history and development, its reception, or analytical descriptions of its surface themes. The aim of this study will therefore be to provide neither a biography of Elgar, nor an account of the genesis of the work, but to analyze The Apostles in a manner that will achieve a deeper understanding of the oratorio. Chapter 1 explores the complexities that surround Judas and the different ways in which he was perceived throughout history. Then, through my analysis of the surface motives in Chapter 2 and their significance in relation to the large-scale harmonic structure in Chapter 3, I will suggest that Elgar does not denigrate Judas as the betrayer of Christ in The Apostles, but rather depicts him as a tragic yet crucial figure in achieving the redemption of mankind, and through this Judas himself is redeemed.
Rickshaw Man
This documentary film tells the story of Mohammad in India, and Mike in the United States, who are separated by social, economic, cultural, linguistic and religious differences, and yet there is an inanimate object that connects them-the rickshaw. The film examines how rickshaw men are viewed and treated by the society they live in and also illuminates the threads of commonality between these two men to show that they are not so different from each other after all.
Shortened in Vivo Bioconcentration Factor Testing in Cyprinus Carpio
Bioconcentration factor testing serves as the most valuable surrogate for the assessment of bioaccumulation. The assessment of potentially harmful chemicals is crucial to not only the health of aquatic environments, but to humans as well. Chemicals that possess the ability to persist in the environment or that have the potential to bioaccumulate, pose a greater risk to organisms that are exposed to these chemicals. The Organization for Economic Cooperation and Development Guideline 305 outlines specific protocols to run an accurate and reliable aquatic flow-through test. However, since its adoption in 1996, very few changes have been made to accommodate the endeavor to lowering the amount of test species to run one of these said tests. Running an aquatic flow-through test, according to 305, takes much time and money as well as numerous amounts of fish. Such burdens can be eliminated through simple modifications to the standard protocols. In this study, we propose an abbreviated study design for aquatic bioconcentration testing which effectively alleviates the burdens of running a flow-through test. Four chemicals were used individually to evaluate the usefulness of the proposed shortened design; 4-Nonyphenol, Chlorpyrifos, Musk Xylene, and DDT. The study consisted of exposing Cyprinus carpio for 7 days followed by 7 days of depuration, for a total of a 14-day study. Our results for each of the four compounds are consistent with literature values, thus, demonstrating that BCFk can be accurately predicted in an abbreviated in vivo test.
Social Support As a Moderating Factor Between Mental Health Disruption and College Adjustment in Student Veterans
Research has indicated that OEF/OIF veterans are experiencing mental health concerns following deployment. While there are increasing numbers of veterans returning to higher education institutions after discharging from the military, there is a scarcity of empirical research investigating student veterans’ experiences as they transition into college. The purpose of the current study was to examine whether social support moderates the effects of psychological distress on college adjustment among a sample of student veterans. Participants were administered a Background Information Questionnaire, measures of psychological distress (i.e., GAD-7, PHQ-9, IES-R), Multidimensional Scales of Perceived Social Support, and the Student Adjustment to College Questionnaire. Multiple regressions revealed significant main effects for the variables of interest, but analyses failed to support the hypothesis that perceived social support would moderate the effects of psychological distress on college adjustment.
Studies on High Potential Porphyrin-fullerene Supramolecular Dyads
Photoinduced electron transfer in self-assembled via axial coordination porphyrin-fullerene dyads is investigated. Fullerene functionalized with imidazole and fullerenes functionalized with pyridine are chosen as electron acceptors, while zinc pophyrin derivatives are utilized as electron donors. The electron withdrawing ability of halogen atoms make the porphyrin ring electrophilic, which explained the binding of (F20TPP)Zn with fullerene derivatives having the highest binding constant around 105M-1. Another important observation is that the fullerene imidazole binding to zinc pophyrin had higher stability than fullerene pyridine-porphyrin dyad. Computational DFT B3LYP-21G(*) calculations are used to study the geometric and electronic structures. The HOMO and LUMO was found to be located on the porphyrin and fullerene entities, respectively. Photoinduced electron transfer is investigated by the steady-state absorption and emission, differential pulse voltammetry, and nanosecond and femtosecond transient absorption studies. The measurements provided the same conclusion that the increasing number of the halogen atoms on the porphyrin ring leads to the higher binding of porphyrin-fullerene supramolecular dyads and efficient charge separation and charge recombination processes.
Studies on the Porphyrin and Phthalocyanine Modified on Sno2 Photoelectrochemical Cells
The world is facing a tough challenge regarding fulfilling human energy needs. Scientists are motivated to find alternative ways to the fossil fuel at a lower cost with little or no environmental pollution. Among the available renewable resources, the solar energy is an alternative energy to fossil fuel. Scientists are engaged in mimicking the photosynthesis to create the new energy devices such as dye sensitized solar cells. The fundamental theory and properties of the dye sensitized solar cells is given in the first chapter. In this research, the application of the different methods for surface alteration of SnO2 with water soluble porphyrins and phthalocyanine is studied. Using optical absorbance and steady state fluorescence studies, the formation of porphyrins and phthalocyanine discuss on the SnO2 surface is shown. Moreover, the different results of photoelectrochemical cells are show on chapter 2 to understand the porphyrin and phthalocyanine modified on SnO2 as electron injector. In summary, the application porphyrin and phthalocyanine of dimers as a broad band capturing photosensitized dye is discussed.
Substitution Effects of Phenothiazine and Porphyrin Dyes in Dye-sensitized Solar Cells
The details of dye sensitized solar cells was explained and phenothiazine and porphyrin based dyes were synthesized for use in DSSCs. DSSCs offer a unique and cost effective method of renewable energy. DSSCs are characterized through various tests, with the overall efficiency, η, bearing the greatest importance. Incident photon to current conversion efficiency, or IPCE, is also another important characterization of DSSCs. Effect of positioning of the cyanoacrylic acid anchoring group on ring periphery of phenothiazine dye on the performance of dye sensitized solar cells (DSSCs) is reported. The performances of the cells are found to be prominent for solar cells made out of Type-1 dyes compared to Type-2 dyes. This trend has been rationalized based on spectral, electrochemical, computational and electrochemical impedance spectroscopy results. Free-base and zinc porphyrins bearing a carboxyl anchoring group at the para, meta, or ortho positions of one of the meso-phenyl rings were synthesized for DSSCs. Photoelectrochemical studies were performed after immobilization of porphyrins onto nanocrystalline TiO2. The performance of DSSCs with the porphyrin anchoring at the para or meta position were found to greatly exceed those in the ortho position. Additionally, zinc porphyrin derivatives outperformed the free-base porphyrin analogs, including better dye regeneration efficiency for the zinc porphyrin derivatives and for the meta and para derivatives through electrochemical impedance spectroscopy studies. The overall structure-performance trends observed for the present porphyrin DSSCs have been rationalized based on spectral, electrochemical, electrochemical impedance spectroscopy and transient spectroscopy results.
Ten Years After 9/11: the Structure and Use of Intelligence Units in Local Policing
The events of September 11, 2001 marked a paradigm shift in the strategy within all levels of law enforcement in the United States. Intelligence became the watchword of the day and with it, the movement to incorporate strategic and tactical information in daily policing. Yet while the philosophy was clear, the method and manner to which agencies were left to achieve these goals was much less designed. The federal government allocated funds to assist help agencies incorporate an intelligence function in their daily operations but which agencies and to what degree remains unclear even today. This study seeks to determine the current state of use of intelligence in municipal law enforcement agencies in the State of Texas ten years after 9/11. Through use of a survey, it assesses the frequency of use of intelligence units in local police departments in the State of Texas, identifies commonalities in their structure, and determines the state of their effectiveness.
A Textual Analysis of the Closer and Saving Grace: Feminist and Genre Theory in 21St Century Television
Television is a universally popular medium that offers a myriad of choices to viewers around the world. American programs both reflect and influence the culture of the times. Two dramatic series, The Closer and Saving Grace, were presented on the same cable network and shared genre and design. Both featured female police detectives and demonstrated an acute awareness of postmodern feminism. The Closer was very successful, yet Saving Grace, was cancelled midway through the third season. A close study of plot lines and character development in the shows will elucidate their fundamental differences that serve to explain their widely disparate reception by the viewing public.
To Be the Child of the Priest
This collection of creative non-fiction essays is written from the perspective of a Protestant Christian church leader’s daughter emerging into adulthood and independence. She labors to define her relationship with God, family, and friends and to determine the complicated, but pervasive role of faith in her life while coping with depression and anxiety; a brain aneurysm and malformation among other health problems; working in an all-male environment in the Houston Chronicle Sports department; the death of her grandparents; the death of a Muslim friend in a murder-suicide shooting; and her troubled relationship with an agnostic friend. Although she expresses her doubts in each scenario, she identifies purpose in the trials and accepts the challenges that accompany being the child of the priest.