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  Partner: UNT Libraries
 Collection: UNT Theses and Dissertations
Modeling the role of blogging in librarianship

Modeling the role of blogging in librarianship

Date: August 2007
Creator: Stephens, Michael
Description: This phenomenological study examines the motivations and experiences of librarians who author professionally-focused Weblogs. I constructed a model of librarianship based on Wilson and Buckland. The results show a close fit between librarian bloggers and the ideals of the field as expressed by two primary library and information science philosophers. A Web survey generated 239 responses to demographic and open-ended questions. Using the results of the survey, I analyzed demographic data and performed a phenomenological analysis of the open-ended questions. A list of category responses was generated from each set of answers via the coding of descriptive words and phrases. Results indicated the motivations of librarian bloggers are based around themes of sharing, participation in community, and enhanced professional development. Respondents reported feeling more connected to the profession and to colleagues across the world because of blogging. Respondents perceived the librarian blogosphere as a community with both positive aspects - feedback, discussion, and support - and negative aspects - insular voices, divides between technologists and librarians, and generational rifts. Respondents also reported an increased ability to keep current, improved writing skills, and opportunities to speak and contribute to professional journals.
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Modeling Transition Metal Catalysts for Small Molecule Activation and Functionalization

Modeling Transition Metal Catalysts for Small Molecule Activation and Functionalization

Date: May 2013
Creator: Figg, Travis M.
Description: There is a high demand for the development of processes for the conversion of ubiquitous molecules into industrially useful commodities. Transition metal catalysts are often utilized for the activation and functionalization of small organic molecules due to their diverse nature and proven utility with a myriad of chemical transformations. The functionalization of methane (CH4) and dinitrogen (N2) to methanol (CH3OH) and ammonia (NH3) respectively is of particular interest; however, both methane and dinitrogen are essentially inert due to the inherit strength of their bonds. In this dissertation a series of computational studies is performed to better understand the fundamental chemistry behind the functionalization of methane and the activation of dinitrogen in a homogeneous environment. A catalytic cycle is proposed for the oxy-functionalization of methane to methanol. The cycle consists of two key steps: (1) C-H activation across a metal-alkoxide bond (M-OR), and (2) regeneration of the M-OR species through an oxy-insertion step utilizing external oxidants. The C-H activation step has been extensively studied; however, the latter step is not as well understood with limited examples. For this work, we focus on the oxy-insertion step starting with a class of compounds known to do C-H activation (i.e., Pt(II) systems). Computational studies ...
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Modeling Transition Metal Chemistry for Catalytic Functionalization of Molecules

Modeling Transition Metal Chemistry for Catalytic Functionalization of Molecules

Date: August 2011
Creator: Morello, Glenn
Description: The diversity of transition metal complexes allows for a wide range of chemical processes to be mediated by the metal, from catalysis to surface chemistry. Investigations into the structure and electronic configuration of transition metal complexes allow for tuning of desired species by modifications to the ligands and/or metals to achieve more efficient thermodynamics and kinetics for the process of interest. Transition metals, often used in catalysts for a number of important processes, require detailed descriptions of intermediates, transition states and products to fully characterize a reaction mechanism(s) in order to design more active and efficient catalysts. Computational investigations into inorganic catalysts are explored with the aim of understanding the activity of each species and how modifications of supporting ligands, co-ligands and metals vary the interaction along the reaction pathway. Reported results give important insight into the development of the most active complexes in addition to determining the least active complexes to aid experimental development. This report first investigates the mechanisms of two unique transfer reactions: 1) formation of low coordinate nickel-nitrene ((P~P)Ni=NR; P~P = 1,2-bis(dihydrophosphino)-ethane or 1,2-bis(difluoromethylphosphino)-ethane) complexes as catalysts for nitrogen atom transfer and 2) oxidation of a triphosphorus niobium complex, [(η2-P3SnPh3)Nb(OMe)3], for the transfer of the phosphorus ...
Contributing Partner: UNT Libraries
Modeling utilization of planned information technology

Modeling utilization of planned information technology

Date: May 2000
Creator: Stettheimer, Timothy Dwight
Description: Implementations of information technology solutions to address specific information problems are only successful when the technology is utilized. The antecedents of technology use involve user, system, task and organization characteristics as well as externalities which can affect all of these entities. However, measurement of the interaction effects between these entities can act as a proxy for individual attribute values. A model is proposed which based upon evaluation of these interaction effects can predict technology utilization. This model was tested with systems being implemented at a pediatric health care facility. Results from this study provide insight into the relationship between the antecedents of technology utilization. Specifically, task time provided significant direct causal effects on utilization. Indirect causal effects were identified in task value and perceived utility constructs. Perceived utility, along with organizational support also provided direct causal effects on user satisfaction. Task value also impacted user satisfaction in an indirect fashion. Also, results provide a predictive model and taxonomy of variables which can be applied to predict or manipulate the likelihood of utilization for planned technology.
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Modeling wild type and mutant glutathione synthetase.

Modeling wild type and mutant glutathione synthetase.

Access: Use of this item is restricted to the UNT Community.
Date: August 2004
Creator: Dinescu, Adriana
Description: Glutathione syntethase (GS) is an enzyme that belongs to the ATP-grasp superfamily and catalyzes the second step in the biosynthesis of glutathione. GS has been purified and sequenced from a variety of biological sources; still, its exact mechanism is not fully understood. Four highly conserved residues were identified in the binding site of human GS. Additionally, the G-loop residues that close the active site during catalysis were found to be conserved. Since these residues are important for catalysis, their function was studied computationally by site-directed mutagenesis. Starting from the reported crystal structure of human GS, different conformations for the wild type and mutants were obtained using molecular dynamics technique. The key interactions between residues and ligands were detected and found to be essential for enzyme activity.
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Models to Combat Email Spam Botnets and Unwanted Phone Calls

Models to Combat Email Spam Botnets and Unwanted Phone Calls

Date: May 2008
Creator: Husna, Husain
Description: With the amount of email spam received these days it is hard to imagine that spammers act individually. Nowadays, most of the spam emails have been sent from a collection of compromised machines controlled by some spammers. These compromised computers are often called bots, using which the spammers can send massive volume of spam within a short period of time. The motivation of this work is to understand and analyze the behavior of spammers through a large collection of spam mails. My research examined a the data set collected over a 2.5-year period and developed an algorithm which would give the botnet features and then classify them into various groups. Principal component analysis was used to study the association patterns of group of spammers and the individual behavior of a spammer in a given domain. This is based on the features which capture maximum variance of information we have clustered. Presence information is a growing tool towards more efficient communication and providing new services and features within a business setting and much more. The main contribution in my thesis is to propose the willingness estimator that can estimate the callee's willingness without his/her involvement, the model estimates willingness level based ...
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Moderators of the sociocultural internalization-body dissatisfaction relationship among female undergraduates.

Moderators of the sociocultural internalization-body dissatisfaction relationship among female undergraduates.

Date: December 2009
Creator: Latimer-Kern, Kelsey M.
Description: The sociocultural model of eating pathology is an empirically-supported model explaining eating disorder etiology. The model poses that body dissatisfaction and subsequent eating pathology stems from the unrealistic standards formulated by Westernized society. Although the model has strong empirical support, variables within the model do not account for 100% of the variance in disordered eating. Thus, the current researcher attempted to explore potential moderating factors in the sociocultural model of eating disorders that may help to explain variance currently unaccounted for. In particular, the researcher focused on the relationship between sociocultural internalization and body dissatisfaction, given that this relationship has not been previously explored within the literature. Based on theoretical support, the researcher chose several potential variables to test, including perfectionism, neuroticism, body surveillance, and shame. Primary analyses tested each variable for moderating effects using hierarchical moderated regression, but no significant findings were shown. Results of post hoc analyses showed all variables had significant mediating effects, with the exception of self-oriented perfectionism. The discussion section addresses consistency with previous research, limitations of the present study, treatment implications and guidelines for future research.
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Modern Api Design and Physical Computing Techniques in Just Intonation Performance Practice

Modern Api Design and Physical Computing Techniques in Just Intonation Performance Practice

Date: May 2013
Creator: Sonnabaum, Mark
Description: approached previously by both Harry Partch and Ben Johnston, and proposes the decoupling of interface and sound production as a way forward. The design and implementation of a software instrument and a hardware prototype are described, both using a simple API for variable tuning instruments. The hardware prototype uses physical computing techniques to control the tuning of a string with a servo motor, while the software instrument exists entirely in a web browser. Finally, potential algorithms for clients of the API are presented, and the effectiveness of the hardware prototype is evaluated by measuring its pitch accuracy.
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Modern Chinese Piano Composition and Its Role in Western Classical Music: A Study of Huang An-lun's Piano Concerto No. 2 in C minor, Op. 57

Modern Chinese Piano Composition and Its Role in Western Classical Music: A Study of Huang An-lun's Piano Concerto No. 2 in C minor, Op. 57

Date: December 2006
Creator: Ng, Lok
Description: China's role in Western music is ever-expanding. Echoing the growth of classical music in China is the importance of Chinese musicians in the global music world. However, it is easy to forget that Western classical music is a foreign import to China, one that has been resisted for most of its history. The intent of this study is to evaluate the role of Chinese music in the Western classical world. This includes Western education, Western repertoire, and also a historical exploration into the mutual influence of the two styles. One Chinese composition in particular, Huang An-lun's Piano Concerto No. 2 in C minor, Op. 57, is selected to analyze the Western and Chinese elements present in the work. This analysis will shed light on the relationship of the two styles and how they amalgamate in modern Chinese music. Although Western classical music today has a strong foothold in China, Chinese contributions to piano literature are largely unknown to the West. China possesses one of the richest musical histories in the world, one which until the twentieth century has largely remained unaffected by Western elements. Its musical heritage extends over thousands of years, deeply rooted in tradition and nationalism. Over the ...
Contributing Partner: UNT Libraries
Modern Problems and Practices of Management as Revealed in Selected Contemporary American Novels

Modern Problems and Practices of Management as Revealed in Selected Contemporary American Novels

Date: May 1972
Creator: Ashley, Janelle Coleman 1941-
Description: This study is an examination of the hypothesis that selected contemporary American novels offer vivid illustrations of modern problems and practices of management as seen in business and industry. Too often, university management courses treat management processes as isolated cases in limited and static settings. Novelists, on the other hand, treat these same processes in a broader context and often deal quite subtly and perceptively with everything from the mammoth corporation to the single proprietorship. Students proposing to become businessmen, therefore, should benefit from this novelistic perspective so frequently overlooked.
Contributing Partner: UNT Libraries