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Interfacial Electrochemistry of Copper and Spectro-Electrochemical Characterization of Oxygen Reduction Reaction

Interfacial Electrochemistry of Copper and Spectro-Electrochemical Characterization of Oxygen Reduction Reaction

Date: August 2011
Creator: Yu, Kyle Kai-Hung
Description: The first part of this dissertation highlights the contents of the electrochemical characterization of Cu and its electroplating on Ru-based substrates. The growth of Ru native oxide does diminish the efficiency of Cu plating on Ru surface. However, the electrochemical formed irreversible Ru hydrate dioxide (RuOxHy) shows better coverage of Cu UPD. The conductive Ru oxides are directly plateable liner materials as potential diffusion barriers for the IC fabrication. The part II of this dissertation demonstrates the development of a new rapid corrosion screening methodology for effective characterization Cu bimetallic corrosion in CMP and post-CMP environments. The corrosion inhibitors and antioxidants were studied in this dissertation. In part III, a new SEC methodology was developed to study the ORR catalysts. This novel SEC cell can offer cheap, rapid optical screening results, which helps the efficient development of a better ORR catalyst. Also, the SEC method is capable for identifying the poisoning of electrocatalysts. Our data show that the RuOxHy processes several outstanding properties of ORR such as high tolerance of sulfation, high kinetic current limitation and low percentage of hydrogen peroxide.
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Exploration Of Energy And Area Efficient Techniques For Coarse-grained Reconfigurable Fabrics

Exploration Of Energy And Area Efficient Techniques For Coarse-grained Reconfigurable Fabrics

Date: December 2011
Creator: Yadav, Anil
Description: Coarse-grained fabrics are comprised of multi-bit configurable logic blocks and configurable interconnect. This work is focused on area and energy optimization techniques for coarse-grained reconfigurable fabric architectures. In this work, a variety of design techniques have been explored to improve the utilization of computational resources and increase energy savings. This includes splitting, folding, multi-level vertical interconnect. In addition to this, I have also studied fully connected homogeneous and heterogeneous architectures, and 3D architecture. I have also examined some of the hybrid strategies of computation unit’s arrangements. In order to perform energy and area analysis, I selected a set of signal and image processing benchmarks from MediaBench suite. I implemented various fabric architectures on 90nm ASIC process from Synopsys. Results show area improvement with energy savings as compared to baseline architecture.
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Diffusion Of Location Based Services And Targeting Us Hispanics: A Case Study

Diffusion Of Location Based Services And Targeting Us Hispanics: A Case Study

Date: December 2011
Creator: Yepez, Jennifer
Description: This study reviews factors that identify U.S. Hispanics as being an ideal target market for adopting Location Based Services (LBS). By using the diffusion of innovation theory, an observed pattern of Hispanics’ adoption of technology, advertisements, smartphones and various smartphone value-added services reveals U.S. Hispanics to be more likely to adopt LBS than non-Hispanics. The study also identifies the top U.S. cell phone wireless providers and analyzes their marketing position towards U.S. Hispanics. AT&T, Sprint, T-Mobile and Verizon are noted as marketing their services to U.S. Hispanics via in-culture messages and campaigns. The four wireless providers also utilize LBS as a profitable tool and market LBS to their customers, regardless of ethnicity.
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Exploring Hidden Student Perceptions About College-going Culture At House Bill 400 Schools In The Dallas Fort Worth Metroplex

Exploring Hidden Student Perceptions About College-going Culture At House Bill 400 Schools In The Dallas Fort Worth Metroplex

Date: December 2011
Creator: Willis II, Roderick C.
Description: In accordance with the Texas Higher Education Coordinating Boards’ Closing the Gaps by 2015, this research study analyzed self-reported perceptions about college-going culture from students (n = 151) who attended four House Bill 400 schools serving Latino and African American communities in the Dallas-Fort Worth Metroplex. This study utilized exploratory factor analysis (EFA) with a maximum likelihood extraction technique to identify hidden perceptions (latent factors) that account for common variance among student perceptions about college-going culture. The study also tested the validity and inter-item reliability of the 15-item College-Going Culture Survey used in data collection. The parallel analysis, EFA, and Cronbach’s ? identified two latent factors of Verified College Potential (? = .70) and College Capital Awareness (? = .71) that, together, explained 40.1% of students’ perceptions. The two factors were non-significantly negatively correlated (r = -.495, p = .354). By utilizing the two latent constructs, a 10-item revised College-Going Culture Survey is recommended to improve the inter-item reliability coefficient from ? = .46 to ? = .77. Descriptive statistics revealed that Latino and African-American students affirmed aspects of the college-going culture at HB 400 schools. However, latent factors suggest the possibility that students who reportedly feel most encouraged to ...
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Factors Affecting Faculty Use Of Learning Object Repositories: An Exploratory Study Of Orange Grove And Wisc-online

Factors Affecting Faculty Use Of Learning Object Repositories: An Exploratory Study Of Orange Grove And Wisc-online

Date: December 2011
Creator: Xu, Hong
Description: The purpose of this study was to identify factors that motivate or impede faculty use of learning object repositories (LORs). The unified theory of acceptance and use of technology (UTAUT) served as the theoretical framework for this study. Both quantitative and qualitative approaches were used in the study to explore two research questions relating to factors affecting faculty use of LORs. Research subjects were faculty and instructional staff users from two LORs: Orange Grove and Wisc-Online. This study was a two-phase design study. In Phase I, I conducted 13 interviews and analyzed data by a content analysis method. Phase II of the study was designed based on the results of Phase I. I collected data by a survey instrument from 38 respondents and analyzed the data by descriptive statistics and analysis of variance in Phase II. The results of the study indicated 22 factors as motivators for faculty use of LORs and 13 factors as barriers for faculty use of LORs. The study is the first to identify factors affecting faculty use of LORs from actual faculty users’ perspectives based on UTAUT. The study’s findings contribute to understanding the reasons that faculty use or do not use LORs and provide ...
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The Klezmer Influence in Paul Schoenfield’s Klezmer Rondos

The Klezmer Influence in Paul Schoenfield’s Klezmer Rondos

Access: Use of this item is restricted to the UNT Community.
Date: December 2011
Creator: Trimble, Mark
Description: Paul Schoenfield’s Klezmer Rondos is a work for flute, male vocalist, and orchestra revised in 1994 according to the score given to me by the composer. A review of current research in klezmer heritage music is the starting point to place Klezmer Rondos in the context of art music infused with klezmer flavor. Klezmer music can be defined as the instrumental folk music of Eastern European Jews, however because of its adaptability and quality of assimilating other cultures within it, this heritage music is constantly in flux. By looking at the research in this field, I describe how the sound of klezmer music has evolved and how popular notions have been formed. The body of this research explores the main musical aspects of Klezmer Rondos that can be tied to the klezmer tradition: scales and thematic materials, improvisatory elements, ornamentation, and instrumentation. Klezmer Rondos moves beyond a simple arrangement of vernacular music for orchestra; it is a fusion of contemporary art music with the elements of klezmer style.
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Rehlet Iraqi (An Iraqi Journey)

Rehlet Iraqi (An Iraqi Journey)

Date: August 2011
Creator: Wahbeh, Fadi
Description: Rehlet Iraqi was created to depict an Iraqi refugee family’s struggle after fleeing war-torn Iraq. Their struggle is highlighted with hope and high expectations for a better life within the United States. This film emphasizes the toll that emigration has on the life of a family before and after their arrival to Grand Rapids, Michigan.
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Comparative Analysis Of 105 Higher Education Doctoral Programs In The United States

Comparative Analysis Of 105 Higher Education Doctoral Programs In The United States

Date: December 2011
Creator: Valerin, Marcus P.
Description: The mission types of 105 current doctoral programs in higher education and the extent to which their missions have changed since a similar study was conducted by Dressel and Mayhew in 1974 was studied. The curricula offerings of these programs by degree type (e.g., Ed.D. & Ph.D.) were compared with Fife’s 1991 findings. Finally, the study examined the various modes of instruction (e.g., classroom, online, cohort, blended) these programs utilize. The population was the 131 U.S. higher education doctoral program coordinators or directors who were identified using the ASHE Higher Education Program Directory. A total of 46 hosted Ed.D. programs and 59 hosted Ph.D. programs for a combined total of 105 doctoral programs. An electronic survey, developed by utilizing an expert panel and the cognitive interviewing technique, was sent to each participant. A total of 46 hosted Ed.D. programs and 59 hosted Ph.D. programs for a combined total of 105 doctoral programs. A total of 77 institutions (59%) returned usable questionnaires, and six other universities (5%) indicated their doctoral higher education programs no longer existed. Twenty-three of the responding institutions identified with a research-focused mission; 25 institutions identified with a practitioner-based mission; and 28 institutions identified with both types of ...
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Temporal Properties Of Dynamic Processes On Complex Networks

Temporal Properties Of Dynamic Processes On Complex Networks

Date: December 2011
Creator: Turalska, Malgorzata A.
Description: Many social, biological and technological systems can be viewed as complex networks with a large number of interacting components. However despite recent advancements in network theory, a satisfactory description of dynamic processes arising in such cooperative systems is a subject of ongoing research. In this dissertation the emergence of dynamical complexity in networks of interacting stochastic oscillators is investigated. In particular I demonstrate that networks of two and three state stochastic oscillators present a second-order phase transition with respect to the strength of coupling between individual units. I show that at the critical point fluctuations of the global order parameter are characterized by an inverse-power law distribution and I assess their renewal properties. Additionally, I study the effect that different types of perturbation have on dynamical properties of the model. I discuss the relevance of those observations for the transmission of information between complex systems.
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Baroque Elements In The Piano Sonata, Opus 9 By Paul Creston

Baroque Elements In The Piano Sonata, Opus 9 By Paul Creston

Date: December 2011
Creator: Watanabe, Chie
Description: Paul Creston (1906-1985) was one of the most significant American composers from the middle of the twentieth century. Though Creston maintained elements of the nineteenth-century Romantic tradition and was categorized as a “Neo-Romantic” or “20th-century traditionalist,” many of Creston’s compositions contain elements of Baroque music. His Piano Sonata, Opus 9 provides significant examples of Baroque elements, while already foreshadowing his mature style. The purpose of this study is to explore Baroque elements in the compositional language of Paul Creston’s Piano Sonata, Opus 9. All four movements of the Piano Sonata will be examined in regards to its stylistic features associated with Baroque practices. These features mainly consist of rhythm, texture, imitative writing, and repeated phrase structure. Each category of the study will include comparisons of Domenico Scarlatti’s keyboard sonatas with Creston’s sonata. Through an examination of the Piano Sonata and its Baroque elements, this study hopes to inspire renewed interest in the work among musicians and to help the performer give a more stylistically coherent, and accurate, performance.
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