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  Partner: UNT Libraries
 Department: Department of Chemistry
 Collection: UNT Theses and Dissertations
Infrared Studies of Group VIB metal Carbonyl Derivatives

Infrared Studies of Group VIB metal Carbonyl Derivatives

Date: August 1971
Creator: Brown, Richard Arthur
Description: With three different proposals for the bonding in metal carbonyls, it was decided to look into the situation more thoroughly in order to see what other evidence was available to support or refute any of these ideas. It became obvious that a definite contradiction existed between the kinetic evidence of various metal carbonyls, and the concept of MC bond strengths as predicted by Cotton's theory.
Contributing Partner: UNT Libraries
Mercury-Sensitized Photochemical Reactions of Isopropyl Alcohol

Mercury-Sensitized Photochemical Reactions of Isopropyl Alcohol

Date: August 1955
Creator: Brown, Robert Wade
Description: This thesis discusses the mercury-sensitized photochemical reactions of isopropyl alcohol.
Contributing Partner: UNT Libraries
The Synthesis and Reduction of Some N-Phenacylpyridines

The Synthesis and Reduction of Some N-Phenacylpyridines

Date: 1950
Creator: Bryants, Burl E.
Description: This study explores the synthesis and reduction of some n-phenacylpyridines and is an investigation of various derivatives.
Contributing Partner: UNT Libraries
De novo prediction of the ground state structure of transition metal complexes.

De novo prediction of the ground state structure of transition metal complexes.

Access: Use of this item is restricted to the UNT Community.
Date: December 2004
Creator: Buda, Corneliu
Description: One of the main goals of computational methods is to identify reasonable geometries for target materials. Organometallic complexes have been investigated in this dissertation research, entailing a significant challenge based on transition metal diversity and the associated complexity of the ligands. A large variety of theoretical methods have been employed to determine ground state geometries of organometallic species. An impressive number of transition metals entailing diverse isomers (e.g., geometric, spin, structural and coordination), different coordination numbers, oxidation states and various numbers of electrons in d orbitals have been studied. Moreover, ligands that are single, double or triple bonded to the transition metal, exhibiting diverse electronic and steric effects, have been investigated. In this research, a novel de novo scheme for structural prediction of transition metal complexes was developed, tested and shown to be successful.
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The Adsorption of Radioactive Isotopes on Precipitates

The Adsorption of Radioactive Isotopes on Precipitates

Date: January 1954
Creator: Bulloch, Newman Payne
Description: This thesis concerns the investigation of radioisotopes as indicators for precipitation reactions. As a precipitate forms in the presence of a radioisotope, adsorption may take place on its surface. If this adsorption changes markedly at the stoichiometric point it will be possible to use this variation as an indicator for the reaction.
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Nitration of Thiophene Analogs of DDT

Nitration of Thiophene Analogs of DDT

Date: February 1953
Creator: Buttram, Jack Rhea
Description: Since thiophene very often yields compounds that are analogous to benzene derivatives in general physiological properties, it was decided to attempt to prepare the nitro and amino derivatives of 1,1,1-trichloro-2,2-bis-(2-thienyl)-ethane (V) as well as the nitro and amino derivatives of 2,2,3-trichloro-1,1-bis-(2-thienyl)-butane (VI).
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Sulfur-induced Corrosion at Metal and Oxide Surfaces and Interfaces

Sulfur-induced Corrosion at Metal and Oxide Surfaces and Interfaces

Date: August 1997
Creator: Cabibil, Hyacinth (Hyacinth Liesl)
Description: Sulfur adsorbed on metallic and oxide surfaces, whether originating from gaseous environments or segregating as an impurity to metallic interfaces, is linked to the deterioration of alloy performance. This research dealt with investigations on the interactions between sulfur and iron or iron alloy metallic and oxide surfaces under ultrahigh vacuum conditions. Sulfur was either intentionally dosed from a H2S source on an atomically clean metal surface, or segregated out as an impurity from the bulk to the metal surface by annealing at elevated temperatures.
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Magnetic Properties of Oxovanadium(IV) Complexes of Substituted N-(Hydroxylalkyl) Salicylideneimines

Magnetic Properties of Oxovanadium(IV) Complexes of Substituted N-(Hydroxylalkyl) Salicylideneimines

Date: May 1972
Creator: Carey, Elbert Franklin
Description: A series of oxovanadium(IV) complexes of Schiff bases derived from substituted salicylaldehyde and aminoalcohols has been prepared and characterized. The Schiff bases coordinate through 0, N, and 0 as tridentate bivalent ligands. The primary purpose of the investigation is to describe the structure and bonding in these complexes. The subnormal magnetic properties of the complexes provide much information about both the structure and the bonding in the complexes.
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The Coupling Mechanism in the Organolithium-Organic Monofluoride Reaction

The Coupling Mechanism in the Organolithium-Organic Monofluoride Reaction

Date: May 1964
Creator: Carl, William P.
Description: In this work, the principal concern will be with the coupling reaction and it is anticipated that the other reactions referred to above will be considered further when products of the RX-R'Li reactions are discussed.
Contributing Partner: UNT Libraries
Metal (II) Complexes with N-Salicylideneamino Acids

Metal (II) Complexes with N-Salicylideneamino Acids

Date: August 1969
Creator: Carlisle, Gene Ozelle
Description: Transition metal complexes derived from Schiff bases have rendered an important contribution to the development of modern coordination chemistry. Various stable compounds have been prepared having synthetic, biological, and physicochemical interest. In particular, complexes of salicylaldimines, B-ketoamines, and closely related ligand systems have been investigated.
Contributing Partner: UNT Libraries