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  Partner: UNT Libraries
 Department: Department of Chemistry
 Collection: UNT Theses and Dissertations
Mercury-sensitized Photochemical Reactions of Isopropyl Alcohol

Mercury-sensitized Photochemical Reactions of Isopropyl Alcohol

Date: 1956
Creator: Brady, William Thomas
Description: The nature and scope of this problem is to determine from the irradiation of isopropyl alcohol with 2537 A, the behavior and mechanism of the reaction, since it is known that a reaction does occur.
Contributing Partner: UNT Libraries
The Photolysis of Ethyllithium and Triethylaluminum

The Photolysis of Ethyllithium and Triethylaluminum

Date: January 1970
Creator: Brewer, Terry Lowell
Description: The majority of interest in organolithium and organoaluminum compounds has centered around their potency as polymerization catalysts.
Contributing Partner: UNT Libraries
Layered Double Hydroxides and the Origins of Life on Earth

Layered Double Hydroxides and the Origins of Life on Earth

Access: Use of this item is restricted to the UNT Community.
Date: May 2001
Creator: Brister, Brian
Description: A brief introduction to the current state of research in the Origins of Life field is given in Part I of this work. Part II covers original research performed by the author and co-workers. Layered Double Hydroxide (LDH) systems are anion-exchanging clays that have the general formula M(II)xM(III)(OH)(2x+2)Y, where M(II) and M(III) are any divalent and trivalent metals, respectively. Y can be nearly any anion, although modern naturally occuring LDH systems incorporate carbonate (CO32-), chloride (Cl-), or sulfate (SO42-) anions. Intercalated cobalticyanide anion shows a small yet observable deviation from local Oh symmetry causing small differences between its oriented and non-oriented infrared spectra. Nitroprusside is shown to intercalate into 2:1 Mg:Al LDH with decomposition to form intercalated ferrocyanide and nitrosyl groups of an unidentified nature. The [Ru(CN)6]4- anion is shown to intercalate into layered double hydroxides in the same manner as other hexacyano anions, such as ferrocyanide and cobalticyanide, with its three-fold rotational axis perpendicular to the hydroxide sheets. The square-planar tetracyano-nickelate(II), -palladate(II), and platinate(II) anions were intercalated into both 2:1 and 3:1 Mg:Al layered double hydroxides (LDH). The basal spacings in the 2:1 hosts are approximately 11 Å, indicating that the anions are inclined approximately 75 degrees relative to ...
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Layered Double Hydroxides: Synthesis, Characterization, and Interaction of Mg-Al Systems with Intercalated Tetracyanonickelate(II)

Layered Double Hydroxides: Synthesis, Characterization, and Interaction of Mg-Al Systems with Intercalated Tetracyanonickelate(II)

Date: August 2004
Creator: Brister, Fang Wei
Description: The square-planar tetracyanonickelate(II) anion was intercalated into 2:1 and 3:1 Mg-Al layered double hydroxide systems (LDHs). In the 2:1 material, the anion holds itself at an angle of about 30° to the layers, whereas in the 3:1 material it lies more or less parallel to the layers. This is confirmed by orientation effects in the infrared spectra of the intercalated materials and by X-ray diffraction (XRD) data. The measured basal spacings for the intercalated LDH hosts are approximately 11 Å for the 2:1 and approximately 8 Å for the 3:1. The IR of the 2:1 material shows a slight splitting in the ν(CN) peak, which is suppressed in that compound's oriented IR spectrum, indicating that at least some of the intercalated anion's polarization is along the z-axis. This effect is not seen in the 3:1 material. A comparison between chloride LDHs and nitrate LDHs was made with respect to intercalation of tetracyanonickelate(II) anions. Both XRD data and atomic absorption spectroscopy (AAS) data of the LDH tetracyanonickelates confirms that there are no significant differences between the products from the two types of starting materials. The presence of a weak ν(NO) peak in the IR spectra of those samples made from nitrate ...
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A Comparison of the Achievements of Science and Non-Science Majors Enrolled in General Chemistry at North Texas State College

A Comparison of the Achievements of Science and Non-Science Majors Enrolled in General Chemistry at North Texas State College

Date: 1951
Creator: Brogdon, Billie R.
Description: It is the specific purpose of this investigation to determine the difference, if any, in the amount of practical, everyday chemistry learned by the science majors as opposed to the non-science majors enrolled in general chemistry at the North Texas State College during the school year 1950-1951.
Contributing Partner: UNT Libraries
A Chemical Analysis of the Peanut

A Chemical Analysis of the Peanut

Date: 1940
Creator: Brown, Carlos L.
Description: The object of this paper is to make an analysis of the mineral and food content of the peanut and to compare them with a balanced food.
Contributing Partner: UNT Libraries
Synthesis and Screening of a Combinatorial Peptide Library for Ligands to Target Transferrin: Miniaturizing the Library

Synthesis and Screening of a Combinatorial Peptide Library for Ligands to Target Transferrin: Miniaturizing the Library

Date: August 2010
Creator: Brown, Jennifer Marie
Description: Combinatorial libraries are used in the search for ligands that bind to target proteins. Fmoc solid-phase peptide synthesis is routinely used to generate such libraries. Microwave-assisted peptide synthesis was employed here to decrease reaction times by 80-90%. Two One-Bead-One-Compound combinatorial libraries were synthesized on 130μm beads (one containing 750 members and the other 16, 807). The use of smaller solid supports would have many important practical advantages including; increased library diversity per unit mass, smaller quantities of library needed to generate hits, and screening could be conducted by using a standard flow cytometer. To this end, a miniaturized peptide library was synthesized on 20 μm beads to demonstrate proof of principle. A small sample from the 16,807-member library was screened against transferrin-AlexaFluro 647, a protein responsible for iron transport in vivo. A number of hits were identified and sequenced using techniques coupling nanomanipulation with nanoelectrospray mass spectrometry.
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A Study of Some 1-alkyl-1,2-dihydro-3-hydroxybenzo[g]quinoxaline-5,10-diones

A Study of Some 1-alkyl-1,2-dihydro-3-hydroxybenzo[g]quinoxaline-5,10-diones

Date: August 1960
Creator: Brown, Jerry
Description: The experiment in this thesis involves a study of some 1-alkyl-1,2-dihydro-3-hydroxybenzo[g]quinoxaline-5,10-diones.
Contributing Partner: UNT Libraries
Mercury-Sensitized Photochemical Reactions of Isopropyl Alcohol

Mercury-Sensitized Photochemical Reactions of Isopropyl Alcohol

Date: August 1955
Creator: Brown, Robert Wade
Description: This thesis discusses the mercury-sensitized photochemical reactions of isopropyl alcohol.
Contributing Partner: UNT Libraries
The Synthesis and Reduction of Some N-Phenacylpyridines

The Synthesis and Reduction of Some N-Phenacylpyridines

Date: 1950
Creator: Bryants, Burl E.
Description: This study explores the synthesis and reduction of some n-phenacylpyridines and is an investigation of various derivatives.
Contributing Partner: UNT Libraries