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  Partner: UNT Libraries
 Department: Department of Chemistry
 Collection: UNT Theses and Dissertations
Synthesis and Study of Certain Amino Acids Containing the Pyridine Ring

Synthesis and Study of Certain Amino Acids Containing the Pyridine Ring

Date: January 1969
Creator: Sanders, Edward Henry
Description: This study reported herein involves the synthesis and determination of certain biological activities of 4,5-dihydroxy-2-pyridinealanine and the synthesis of 3-pyridine-N-methylalanine.
Contributing Partner: UNT Libraries
Water-soluble Phosphors for Hypoxia Detection in Chemical and Biological Media

Water-soluble Phosphors for Hypoxia Detection in Chemical and Biological Media

Access: Use of this item is restricted to the UNT Community.
Date: December 2012
Creator: Satumtira, Nisa Tara
Description: Water-soluble Pt(II) phosphors exist predominantly for photophysical studies. However, fewer are known to be candidates for cisplatin derivatives. If such a molecule could exist, it would be efficient at not only destroying the cancerous cells which harm the body, but the destruction would also be traceable within the human body as it occurred. Herein, research accomplished in chemistry describes the photophysical properties of a water-soluble phosphor. Spectroscopically, this phosphor is unique in that it possesses a strong green emission at room temperature in aqueous media. Its emission is also sensitive to the gaseous environment. These properties have been expanded to both analytical and biological applications. Studies showing the potential use of the phosphor as a heavy metal remover from aqueous solutions have been accomplished. The removal of toxic heavy metals was indicated by the loss of emission as well as the appearance of a precipitate. The gaseous sensitivity was elicited to be used as a potential cancerous cell biomarker. In vivo studies were accomplished in a wide variety of species, including bacteria (E. coli), worms (C. elegans), small crustaceans (Artemia), and fish (D. rerio and S. ocellatus). The phosphor in question is detectable in all of the above. This fundamental ...
Contributing Partner: UNT Libraries
The Synthesis of 5-Alkyl-5-(2-Thienylmethyl)-Barbituric Acids

The Synthesis of 5-Alkyl-5-(2-Thienylmethyl)-Barbituric Acids

Date: 1947
Creator: Scarbrough, Martha Nell
Description: This thesis describes the synthesis of a series of 5-alkyl-5-(2-thienylmethyl)-barbituric acids.
Contributing Partner: UNT Libraries
A Study of the Bromination Products of Phenylmercaptoacetic Acid

A Study of the Bromination Products of Phenylmercaptoacetic Acid

Date: August 1954
Creator: Schimelpfenig, Clarence William
Description: This investigation was begun in order to determine the nature of the 104 degree melting compound prepared by Ashmore and to determine which isomers and their relative amounts are produced during bromination of phenylmercaptoacetic acid.
Contributing Partner: UNT Libraries
A Quantitative Chemical Examination of Surface Well Water from the Three Principal Geological Divisions of Denton County

A Quantitative Chemical Examination of Surface Well Water from the Three Principal Geological Divisions of Denton County

Date: August 1936
Creator: Schnably, John Robert
Description: A sample of the surface-well water was taken from an area of the predominating soil of each of the three geological regions of Denton County, Texas, and a chemical analysis of each sample was made. This thesis deals with the area from which the samples were taken, the methods of analysis used, and the results of the analysis.
Contributing Partner: UNT Libraries
A Determination of the Value of Sulphur Dioxide as a Dehydrating Agent for Sweet Potatoes

A Determination of the Value of Sulphur Dioxide as a Dehydrating Agent for Sweet Potatoes

Date: 1941
Creator: Scogin, Everett Robert
Description: The purpose of this experiment was to determine the value of sulphur dioxide as a dehydrating agent for sweet potatoes.
Contributing Partner: UNT Libraries
An NMR Study of 2-Ethylbutyllithium/Lithium 2-Ethyl-1-butoxide Mixed Aggregates, Lithium Hydride/Lithium 2-Ethyl-1-butoxide Mixed Aggregates, n-Pentyllithium Aggregates, and n-Pentyllithium/Lithium n-Pentoxide Mixed Aggregates

An NMR Study of 2-Ethylbutyllithium/Lithium 2-Ethyl-1-butoxide Mixed Aggregates, Lithium Hydride/Lithium 2-Ethyl-1-butoxide Mixed Aggregates, n-Pentyllithium Aggregates, and n-Pentyllithium/Lithium n-Pentoxide Mixed Aggregates

Access: Use of this item is restricted to the UNT Community.
Date: December 2005
Creator: Sellers, Nicole
Description: A 13C and 6Li variable temperature NMR study of 2-ethylbutyllithium/lithium 2-ethyl-1-butoxide mixed aggregates formed from reacting 2-ethyl-1-butanol with 2-ethylbutyllithium in two O/Li ratios of 0.2/1 and 0.8/1. The 0.2/1 sample resulted in two 2-ethylbutyllithium/lithium 2-ethyl-1-butoxide mixed aggregates and seven lithium hydride/lithium 2-ethyl-1-butoxide mixed aggregates. The lithium hydride mixed aggregates were also studied using selective 1H decoupling experiments. The 0.8/1 sample resulted in six 2-ethylbutyllithium/lithium 2-ethyl-1-butoxide mixed aggregates and five lithium hydride/lithium 2-ethyl-1-butoxide mixed aggregates. A low temperature 13C NMR spectroscopy study of n-pentyllithium indicated three aggregates, most likely a hexamer, an octamer, and a nonamer. A low temperature 13C NMR study of an 0.2/1 O/Li ratio sample of n-pentyllithium mixed with 1-pentanol resulted in three n-pentyllithium/lithium n-pentoxide aggregates mixed aggregates along with the three n-pentyllithium aggregates. 13C NMR data for this mixture gave inconclusive results whether or not lithium hydride/lithium alkoxide mixed aggregates were present in the sample.
Contributing Partner: UNT Libraries
Conformationally Stable Cyclohexyllithium Compounds

Conformationally Stable Cyclohexyllithium Compounds

Date: January 1968
Creator: Selman, Charles Melvin
Description: Organolitnium compounds have been employed in synthetic worK for many years. However only during the last decade has much progress been made in establishing the mechanistic pathways for the reactions of these compounds.
Contributing Partner: UNT Libraries
A Mineral Analysis of the Henrietta Water Supply

A Mineral Analysis of the Henrietta Water Supply

Date: 1941
Creator: Selvidge, R. F.
Description: The water which supplies the city of Henrietta, Clay County, Texas, is obtained from the Little Wichita River. A concrete dam was built across the river at a point about a mile and a half north of town.
Contributing Partner: UNT Libraries
Barbituric Acids as Anticonvulsants.  IV.  5-Substituted-Mercapto Derivatives of 5-Phenylbarbituric Acids.

Barbituric Acids as Anticonvulsants. IV. 5-Substituted-Mercapto Derivatives of 5-Phenylbarbituric Acids.

Date: 1951
Creator: Shahan, Howard Wayne
Description: This study involves compounds of the barbituric acid series are well known for their use as anesthetics and sedatives.
Contributing Partner: UNT Libraries