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  Partner: UNT Libraries
 Degree Discipline: Chemistry
 Degree Level: Doctoral
 Collection: UNT Theses and Dissertations
Syntheses of Antimetabolites

Syntheses of Antimetabolites

Date: January 1970
Creator: Clifton, George Gil
Description: In these studies several different types of antimetabolites were synthesized, and their biological effects were examined in various assay systems. More extensive investigations were done in microbial systems in which many of the compounds proved to be inhibitory to growth, and attempts were made to determine the mode of biochemical action by adding supplements of the appropriate natural metabolite.
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Magnetic Exchange in Oxovanadium(IV) Complexes with N-Salicylideneamino Acids

Magnetic Exchange in Oxovanadium(IV) Complexes with N-Salicylideneamino Acids

Date: January 1968
Creator: Hu, James Hung-Jen
Description: Copper(II) and oxovanadium(IV) ions resemble one another magnetically in having one unpaired electron in their complexes irrespective of their geometrical structures and bond types involved. Copper(II) complexes with antiferromagnetic exchange are well known. On the contrary, antiferromagnetic exchange in oxovanadium(IV) complexes is rather new and not well established. Very few oxovanadium(IV) complexes have been reported to have this anomalous magnetic property. In the investigation of the magnetic properties of oxovanadium(IV) complexes, we have successfully prepared two series of new oxovanadium(IV) complexes with N-salicylideneamino acids.
Contributing Partner: UNT Libraries
Discontinuous Thermal Expansions and Phase Transformations in Crystals at Higher Temperatures

Discontinuous Thermal Expansions and Phase Transformations in Crystals at Higher Temperatures

Date: 1967
Creator: Hsu, Yuan Tsun
Description: The purpose of this investigation is to make more detailed studies of transformations. Fourteen compounds have been examined by high temperature X-ray diffraction for this purpose. The investigations have been carried out in such a way as to reveal: 1. the existence of transformations, 2. the influence of polarizability on thermal expansion, 3. the anisotropy of expansion, and 4. the discontinuity of thermal expansion.
Contributing Partner: UNT Libraries
Rational Design of Metal-organic Electronic Devices: a Computational Perspective

Rational Design of Metal-organic Electronic Devices: a Computational Perspective

Access: Use of this item is restricted to the UNT Community.
Date: December 2012
Creator: Chilukuri, Bhaskar
Description: Organic and organometallic electronic materials continue to attract considerable attention among researchers due to their cost effectiveness, high flexibility, low temperature processing conditions and the continuous emergence of new semiconducting materials with tailored electronic properties. In addition, organic semiconductors can be used in a variety of important technological devices such as solar cells, field-effect transistors (FETs), flash memory, radio frequency identification (RFID) tags, light emitting diodes (LEDs), etc. However, organic materials have thus far not achieved the reliability and carrier mobility obtainable with inorganic silicon-based devices. Hence, there is a need for finding alternative electronic materials other than organic semiconductors to overcome the problems of inferior stability and performance. In this dissertation, I research the development of new transition metal based electronic materials which due to the presence of metal-metal, metal-?, and ?-? interactions may give rise to superior electronic and chemical properties versus their organic counterparts. Specifically, I performed computational modeling studies on platinum based charge transfer complexes and d10 cyclo-[M(?-L)]3 trimers (M = Ag, Au and L = monoanionic bidentate bridging (C/N~C/N) ligand). The research done is aimed to guide experimental chemists to make rational choices of metals, ligands, substituents in synthesizing novel organometallic electronic materials. Furthermore, the ...
Contributing Partner: UNT Libraries
Nuclear Magnetic Resonance Spectra of Some 1,2,4-triazoles

Nuclear Magnetic Resonance Spectra of Some 1,2,4-triazoles

Date: January 1967
Creator: Creagh, Linda Truitt
Description: In the work undertaken here, NMR has been used to ascertain the structure of some 1,2,4-triazoles. The investigation provides information concerning the structure of potentially tautomeric triazoles such as hydroxy- and aminotriazole. Connected with this aspect of triazole chemistry is the larger problem of mesohydric tautomerism. The present study also yields information for a comparison of substituent effects in triazoles, N-heteroaromatic substances and benzene.
Contributing Partner: UNT Libraries
Conformationally Stable Cyclohexyllithium Compounds

Conformationally Stable Cyclohexyllithium Compounds

Date: January 1968
Creator: Selman, Charles Melvin
Description: Organolitnium compounds have been employed in synthetic worK for many years. However only during the last decade has much progress been made in establishing the mechanistic pathways for the reactions of these compounds.
Contributing Partner: UNT Libraries
The Electrochemical Properties of the Mercury/lithium Nitrate-potassium Nitrate Eutectic Interface

The Electrochemical Properties of the Mercury/lithium Nitrate-potassium Nitrate Eutectic Interface

Date: August 1968
Creator: Flinn, David R.
Description: The original purpose of this investigation was to attempt to apply the coulostatic method directly to a molten salt system. The inability to duplicate the reported capacity data for this system resulted in an investigation of the probable cause of this discrepancy between the data obtained by these different methods (14, 15).
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Kinetics and Mechanism Study of Diphenylketene Cycloadditions

Kinetics and Mechanism Study of Diphenylketene Cycloadditions

Date: August 1967
Creator: O'Neal, Hubert Ronald
Description: From a review of the published work in the field of cycloadditions, it is evident that further research is needed to establish the mechanism of ketene cycloadditions. This work was initiated with the intent of obtaining kinetic data which will contribute to the elucidation of the mechanism of ketene cycloadditions.
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The Stereochemistry of the Cycloaddition of Unsymmetrical Phenyl Ketenes to Cyclopentadiene

The Stereochemistry of the Cycloaddition of Unsymmetrical Phenyl Ketenes to Cyclopentadiene

Date: May 1970
Creator: Parry, Fred H.
Description: This dissertation is a study involving the synthesis and chemistry of arylhaloketenes and cyclopentadiene cycloadducts, and a study of the cycloadduct isomer distribution was begun.
Contributing Partner: UNT Libraries
High Temperature Enthalpies of the Lead Halides: Enthalpies and Entropies of Fusion

High Temperature Enthalpies of the Lead Halides: Enthalpies and Entropies of Fusion

Date: June 1970
Creator: Linsey, Clarence W.
Description: The objectives of this investigation were: 1. To establish calorimetrically the transition temperature for the orthorhombic to cubic transition exhibited by PbF₂ and to determine the enthalpy of this transition. 2. To determine if the solid-solid phase transitions claimed in the literature for PbCl₂, PbF₂, PbBr₂, and PbI₂ were of thermodynamic importance, and if so, to determine the enthalpies of transition. 3. To determine if the discontinuous thermal expansions reported by Hsu for the lead halides were of thermodynamic importance. 4. To obtain reliable heat content data for the lead halides in both the solid and liquid states.
Contributing Partner: UNT Libraries
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