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12 Études Caractéristiques, Opus 2, by Adolf von Henselt: A Pedagogical Guide with Practical Exercises on Selected Etudes
Adolf von Henselt (1814–1889) was one of the most renowned German pianists and composers of his day. The majority of his compositions are for the piano, one of his most successful being the set of Piano Études, Op. 2. It consists of twelve etudes, each of which is designed for developing a particular technique. Henselt's etudes are as demanding as Chopin's and Liszt's, so this pedagogical guide is designed for advanced-level students. Henselt uses many finger extensions and stretches larger than an octave, which may be difficult for smaller hands to play, but proper flexibility and relaxation should enable all students to play them. This dissertation describes the specific technique for six selected etudes and provides exercises to help students learn each technique effectively. The selected etudes—Nos. 1, 2, 3, 6, 9, and 11—were chosen to cover all three technical levels of less-advanced, advanced, and very advanced as well as a variety of musical styles and technical challenges.
"The '91 Roos"
The ‘91 Roos is a sports documentary focused in Killeen, Texas. exploring the 1991 Killeen Kangaroos high school football team and their journey to their city's one and only state championship in football. Killeen is a small central Texas town that is directly adjacent and provides support to Ft Hood, one of the world's largest military bases. With the Persian Gulf War raging in 1991, soldiers that lived in Killeen were being sent off to fight, leaving the city almost like a ghost town. In October 1991, the Luby's Massacre occurred in Killeen, bringing the already depleted city further down by tragedy. At the time, this was the worst mass shooting in US history. This high school football team went on a fairy tale type of run during their 1991 season, resulting in winning a state title and bringing big hope back to a small town in need. Using direct interviews, narration and archival footage, this film provides an emotional yet inspirational look at a small town football team and their improbable season.
3D Printed Self-Activated Carbon Electrodes for Supercapacitor Applications
This study investigated a new approach to achieving high energy density supercapacitors (SCs) by using high surface area self-activated carbon from waste coffee grounds (WCGs) and modifying 3D printed electrodes' porous structure by varying infill density. The derived activated carbons' surface area, pore size, and pore volume were controlled by thermally treating the WCGs at different temperatures (1000˚C, 1100˚C, and 1200˚C) and post-treating with HCL to remove water-soluble ashes and contaminants that block activated carbon pores. Surface area characterization revealed that the carbon activated at 1000˚C had the highest surface of 1173.48 m2 g-1, and with the addition of HCL, the surface area increased to 1209.35 m2 g-1. This activated carbon was used for fabricating the electrodes based on the surface area and having both micropores and macropores, which are beneficial for charge storage. Direct ink writing (DIW) method was utilized for 3D printing SC electrodes and changing the electrode structure by increasing the infill densities at 30%, 50%, and 100%. Upon increasing the infill densities, the electrodes' mass increased linearly, porosity decreased, and the total surface area increased for the 30% and 50% infill electrodes but decreased for the 100% infill electrode. Cyclic voltammetry (CV) test on the assembled SC showed the highest specific capacitance and energy density of 5.81 F g-1 and 806.93 mWh kg-1 at 10 mV s-1, respectively, for the electrode printed at 50% infill density.
3D Printing of Zinc Anode for Zinc Ion Batteries
Recently, 3D printing has received increasing attention for the fabrication and assembly of electrodes for batteries due to the freedom of creating structures in any shape or size, porosity, flexibility, stretchability, and chemistry. Particularly, zinc ion batteries (ZIBs) are favored due to high safety, cheap materials cost, and high volumetric capacity (5,849 mAh/cm3), however, rapid evaporation of Zn due to low melting temperature has limited its 3D printability via conventional laser-based additive manufacturing technique. Here, we develop a printable ink for the fabrication of flexible and 3D printed Zn anode with varied surface areas using the direct ink writing (DIW) method. Our 3D printed porous and high surface area Zn anode structures effectively suppressed the dendrite growth while providing high Zn ion diffusion towards the cathode to significantly enhance the performance of ZIB. By varying filament distancing and path, we 3D printed zinc anode structures with different active surface areas, surface area to volume ratio, porosity, flexible and multiple layer structures that can be incorporated on any device. Carbon in the composite improved conductivity, and mechanical stability of 3D printed zinc anode. Our 3D printed composite anodes allowed flexible designing of batteries surpassing conventional battery designs such as coin cells or pouch cells and can be used to design printed energy storage systems.
The Abraham Solvation Model Used for Prediction of Solvent-Solute Interactions and New Methods for Updating Parameters
The Abraham solvation model (ABSM) is an experimentally derived predictive model used to help predict various solute properties. This work covers various uses for the ABSM including predicting molar enthalpies of vaporization, predicting solvent coefficients for two new solvents (2,2,5,5-tetramethyloxolane and diethyl carbonate), predicting values for multiple new ionic liquids (ILs). This work also introduces a novel method for updating IL ABSM parameters by updating cation- and anion-specific values using linear algebra and binary matrices.
"Access Points"
Access Points explores the different relationships that humans have to land, focusing on the various ways that the area known as the Wichita Mountains Wildlife Refuge is used, appreciated, and preserved by disparate groups. The natural beauty of this Wildlife Refuge and its striking appearance amidst encircling plains makes it a popular destination for many groups of people, including the local rock-climbing community and generations of indigenous peoples whose connection with this land is as deep as it is longstanding. While climbing organizations have long had to negotiate access and rules regarding climbing within the park, members of the Kiowa community negotiate a much different relationship to a natural area that is now managed by the United States government. These disparate voices, identities, and ways of thinking about land all impact the modern-day Wildlife Refuge in terms of its appearance, individuals' access to the land, and the conservation efforts happening there.
Accessibility and Pedagogical Value in Virtuosic American Trombone Solo Literature: A Performance Guide to "Divertimento for Trombone and Band" (2012) by Jack Stamp
This dissertation is an examination of Divertimento for Solo Trombone and Wind Band by renowned wind band composer and conductor Jack Stamp. The result of this study is the illumination of a 21st-century composition for solo trombone and band that is made accessible for future performers, accomplished by constructing original musical exercises that are influenced by current trombone pedagogical materials that have either been edited, annotated or created by current performers and pedagogues such as Joseph Alessi, Brad Edwards and Michael Mulcahy. The piece also incorporates 20th -century American wind band influences. The careful selection of pedagogical materials serves the purpose of making this challenging solo accessible for the advanced academic trombonist and can serve as a template for surveying advanced literature of the present and future. Additionally, the pedagogical materials selected for use in this dissertation were considered based on their value in the present academic trombone repertory. Thus, this performance guide reflects on the validity of the modern trombone pedagogical literature to guide a performer's study, interpretation, and performance of a 21st-century work for solo trombone.
Accommodating People Safety Curriculum for Deaf and Hard of Hearing Students
Children with disabilities are three to four times more likely to be abused than their non-disabled peers due to the impact of challenges related to behavior, cognition, language, social skills, and communication skills. In September of 2018, the Council for Exceptional Children (CEC) specifically noted the need to establish maltreatment prevention and response curricula and promote research and advocacy surrounding maltreatment of children with disabilities. One common curriculum recommended is Kidpower®. While Kidpower® shows promise in increasing people safety skills and offers some basic accommodations for use with disabled populations, a complete accommodation plan for deaf or hard of hearing students has not been developed. The purpose of this study was to explore how Kidpower® curriculum could be accommodated to meet the unique needs of deaf and hard of hearing students from the perspective of the deaf education community, including deaf adults, deaf education teachers, deaf education teacher preparation faculty, and parents with deaf or hard of hearing children. A combination of focus groups and interviews were utilized to review lessons and homework from the Kidpower® curriculum. Participants gave feedback on obstacles and ideas for accommodations and modifications that would mediate the challenges. Data were inductively coded and analyzed for themes. Findings indicated the deaf education community believes the curriculum needs media components, language modifications and teaching strategies, enhanced visual information, and representation of people and situations related to the lives of deaf and hard of hearing children to be an effective curriculum for this population.
Acenaphthene and 1,10-Phenanthroline-Fused Βeta-Functionalized Porphyrins
A series of acene-fused porphyrins and 1,10-phenanthroline-fused porphyrins were synthesized and characterized via NMR spectroscopy and mass spectrometry. The acene-fused porphyrins exhibit unique optoelectronic properties, most notably they exhibit highly red-shifted absorption bands. The 1,10-phenanthroline-fused porphyrins are of interest for their ability to bond to as variety of metals to form chelation complexes.
Achievement Motivation Theory as a Model for Explaining College Athletes' Grit
This study examined the direct and indirect associations of the perceived coach-created motivational climate, athletes' implicit theory, and athletes' achievement goal orientation in relation to their levels of grit. Five hundred twenty-three Division I and II collegiate student-athletes (male = 246, female = 277) from five institutions across the south-central and southeast areas of the United States completed self-report measures assessing the previously described constructs. The measurement model fit the data well (SRMR = .055; CFI = .938; RMSEA = .067) and demonstrated invariance across the male and female athletes. The structural model demonstrated adequate fit (SRMR = .088; CFI = .918; RMSEA = .068). All direct and indirect paths in the model were significant in the expected direction, with the exception of the direct path from entity theory to ego goal orientation and the indirect path from ego-involving climate to ego goal orientation through entity theory, which were both non-significant. The mastery-incremental constructs accounted for 65% of the variance in grit. Results indicate that achievement motivation theory is an appropriate framework through which to examine grit, and achievement motivation constructs may be significant antecedents of grit's development. Limitations and future directions are discussed.
Activating Artistry: Community Engagement Resources and Teaching Artist Strategies for the Bassoonist
This document examines current practices and opportunities in the music performance field related to artistic citizenship, community engagement, and the field of teaching artistry. The relationship of musicians to their audiences and communities has shifted significantly in the twenty-first century, and there is an increasing need to redefine the essential skills of the professional musician. Derived from the field of teaching artistry, the concept of "activating artistry" suggests that our greatest strength and power as artists lies in drawing out individual artistic expression in other people, and it is with this power that artists as a workforce can create meaningful change in society. This intention could be manifested in many different contexts during the course of a given music career, however, developing the tool kit necessary for engaging in such work is not widely emphasized in the training of musicians. What tools can be provided for students and professionals to help them navigate both traditional and evolving career paths in music? How are bassoonists doing as a field in addressing the imperative of community engagement and artistic citizenship? How might we explore more collaborative ways to engage with our diverse communities – ways that value their perspectives? These questions guide an exploration of current practices in the bassoon field, with an overall goal of providing practical examples, resources, and inspiration for engaging in the work of activating artistry. Central to the discussion is the intersection of the professional bassoonist with the teaching artist field. Examples of lesson plans/strategies and ideas for curating educational performances demonstrate potential uses of the bassoon and its repertoire in teaching artist residencies and other community engagement settings.
Activation of Small Molecules by Transition Metal Complexes via Computational Methods
The first study project is based on modeling Earth abundant 3d transition-metal methoxide complexes with potentially redox-noninnocent ligands for methane C–H bond activation to form methanol (LnM-OMe + CH4 → LnM–Me + CH3OH). Three types of complex consisting of tridentate pincer terpyridine-like ligands, and different first-row transition metals (M = Ti, V, Cr, Mn, Fe, Co, Ni, and Cu) were modeled to elucidate the reaction mechanism as well as the effect of the metal identity on the thermodynamics and kinetics of a methane activation reaction. The calculations showed that the d electron count of the metal is a more significant factor than the metal's formal charge in controlling the thermodynamics and kinetics of C–H activation. These researches suggest that late 3d-metal methoxide complexes that favor σ-bond metathesis pathways for methane activation will yield lower barriers for C–H activation, and are more profitable catalyst for future studies. Second, subsequently, on the basis of the first project, density functional theory is used to analyze methane C−H activation by neutral and cationic nickel-methoxide complexes. This study identifies strategies to further lower the barriers for methane C−H activation through evaluation of supporting ligand modifications, solvent polarity, overall charge of complex, metal identity and counterion effects. Overall, neutral low coordinate complexes (e.g. bipyridine) are calculated to have lower activation barriers than the cationic complexes. For both neutral and cationic complexes, the methane C−H activation proceed via a σ-bond metathesis rather than an oxidative addition/reductive elimination pathway. Neutralizing the cationic catalyst models by a counterion, BF4-, has a considerable impact on reducing the methane activation barrier free energy. Third, theoretical studies were performed to explore the effects of appended s-block metal ion crown ethers upon the redox properties of nitridomanganese(V) salen complexes, [(salen)MnV(N)(Mn+-crown ether)]n+, where, M = Na+, K+, Ba2+, Sr2+ for 1Na, 1K, 1Ba, 1Sr …
Acute and Sublethal Impacts of Crude Oil Photo-Induced Toxicity in an Early Life Stage Marine Fish (Sciaenops ocellatus) and Invertebrate (Americamysis bahia)
We investigated the modifying effects of ultraviolet (UV) light and chemical dispersant (Corexit 9500A) on crude oil toxicity in juvenile mysids (≤ 24 h) (Americamysis bahia) and larval red drum (24-72 hpf) (Sciaenops ocellatus). These results demonstrate that crude oil toxicity significantly increases with co-exposure to environmentally relevant UV levels in both species, indicating photo-induced toxicity. This toxicity was further exacerbated by the application of chemical dispersants which increased the dissolution and concentration of oil-derived polycyclic aromatic hydrocarbons (PAHs) in test solutions. To better understand the mechanisms and initiating events of this observed photo-induced toxicity, the incidence of apoptotic cell death and global transcriptomic changes were assessed in larval red drum (24-72 hpf) following co-exposure to crude oil and UV. These results showed that co-exposure to UV and low concentrations of crude oil (<1 µg/L ∑PAH50) induced apoptotic cell death in skin and eye tissue and altered transcriptomic pathways related to visual processing and dermatological disease. To link these cellular and molecular impacts of photo-induced toxicity to apical endpoints of ecological performance, sublethal impacts to growth, metabolic rate, and visually mediated behaviors were explored in larval red drum at 2 developmental stages. These results suggested that earlier life stages may be more sensitive to photo-induced toxicity and that growth and development, particularly of sensory systems, can be sensitive targets of photo-induced toxicity. Together, these studies provide novel insights into the photo-induced toxicity of crude oil in aquatic organisms and can be used to inform future ecological risk assessments.
Acute Endocrine Responses to Rest Redistribution with Heavier Loads in Resistance-Trained Men
The purpose of this study was to investigate endocrine responses to redistribution with heavier loads (RR+L) during back squat (BS) exercise in resistance-trained men. Ten men (mean±SE; 23±2 years, 175.6±2.0 cm, 78.0±3.4 kg, 4±1 training years) were assigned using randomization to either RR+L (4 sets of (2×5 repetitions) of BS with 30 s intra-set and 90 s inter-set rest using 75% of their 1RM) or traditional sets (TS; 4 sets of 10 repetitions of BS with 120 s inter-set rest using 70% of their 1RM). Fasted blood samples were collected pre-exercise (PRE), immediately post-exercise (IP), and 5 (+5), 15 (+15), and 30 (+30) minutes post-exercise to analyze the concentrations of testosterone (T), growth hormone (GH), cortisol (C), and blood lactate (BL). Two-way ANOVAs with repeated measures were used (p≤0.05). A main effect of condition (p=0.023) was observed for BL (RR+L; 5.9±0.5 vs TS; 6.7±0.4 mmol/L). A main effect of time point (p≤0.001) was observed for T, GH, C, and BL. T was greater at IP (8.8±1.1), +5 (9.0±1.1), +15 (8.5±1.0), and +30 (8.0±1.0) than PRE (7.1±0.8 ng/mL). GH was greater at IP (58.3±12.7), +5 (62.8±12.7), +15 (67.9±13.3), and +30 (52.8±11.2) than PRE (3.6±1.6 µIU/mL). C was greater at +15 (25.5±2.9) and +30 (25.6±2.7) than PRE (20.0±2.7 µg/dL). BL was greater at IP (8.6±0.6), +5 (8.2±0.6), +15 (7.4±0.5), and +30 (5.8±0.5) than PRE (1.4±0.2 mmol/L). RR+L resulted in lower BL but no differences in T, GH, and C responses compared to TS. Thus, practitioners may incorporate RR+L without affecting endocrine responses.
Acute Toxicity of Crude Oil Exposures to Early Life Stage Teleosts: Contribution of Impaired Renal Function and Select Environmental Factors
Oil spills are well-known adverse anthropogenic events, as they can induce severe impacts on the environment and negative economic consequences. Still, much remains to be learned regarding the effects of crude oil exposure to aquatic organisms. The objectives of this dissertation were to fill some of those knowledge gaps by examining the effects of Deepwater Horizon (DWH) crude oil exposure on teleost kidney development and function. To this end, I analyzed how these effects translate into potential osmoregulatory impairments and investigated the interactive effects of ubiquitous natural factors, such as dissolved organic carbon (DOC) and ultraviolet (UV) light, on acute crude oil toxicity. Results demonstrated that acute early life stage (ELS) crude oil exposure induces developmental defects to the primordial kidney in teleost fish (i.e., the pronephros) as evident by alterations in: (1) transcriptional responses of key genes involved in pronephros development and function and (2) alterations in pronephros morphology. Crude oil-exposed zebrafish (Danio rerio) larvae presented defective pronephric function characterized by reduced renal clearance capacity and altered filtration selectivity, factors that likely contributed to the formation of edema. Latent osmoregulatory implications of crude oil exposure during ELS were observed in red drum (Sciaenops ocellatus) larvae, which manifested reduced survival in hypoosmotic waters, likely due to defective pronephros development and function. Finally, DOC-UV co-exposure slightly reduced acute crude oil photo-enhanced toxicity in red drum larvae. This dissertation provided novel information regarding crude oil toxicity that can be incorporated into environmental risk assessment and management for future oil spills.
Adaptation and Validation of the Athletic Identity Measurement Scale for Use with Musicians
Identity is a powerful concept that influences behavior and health. For over thirty years, researchers in sport psychology have been using the Athletic Identity Measurement Scale (AIMS) as a research instrument providing insights into the relationships between athletic identity and health variables. While musician identity is recognized as an important factor to be investigated in relation to occupational health, there are no known robust instruments like the AIMS in music psychology research. The current study aimed to adapt and validate the athletic identity measurement scale for use with musicians. The AIMS history includes episodes of modifications for performance enhancement of the instrument that resulted in five different models. The validation process includes evaluating the psychometrical properties across all five models. The sample included student musicians and non-student musicians (N = 1040). The traditional confirmatory factor analysis (CFA) and the maximum likelihood (ML) estimation method were used. The exploratory structural equation modeling (ESEM) and robust weighted least squares (WLS) was utilized to explore a new method of estimation that was known to resolve issues consistent with the CFA and ML method. The goodness-of-fit indices of CFA and ESEM were compared. The results showed that the MIMS is a reliable and valid instrument for use with musicians. The factor structure and the goodness-of fit-indices were discussed across all the models of MIMS.
The Adaptation of Saxophone-Like Phrasing into the Improvisatory and Compositional Vocabulary of Jazz Guitar: A Comparative Analysis of Phrasing, Articulation, and Melodic Design in the Styles of Jimmy Raney, Jim Hall, and John Scofield
This study investigates how different guitarists introduced saxophone-like phrasing into the improvisatory and compositional vocabulary of jazz guitar through their collaborations with saxophonists. This research presents a comparative analysis of phrasing, articulation, and melodic design in solo improvisations. The mixed approach to this study includes analysis of motives, voice leading, articulation, length of phrases, melodic contour, and the execution of bebop vocabulary on the guitar. The findings are based on original transcriptions from significant recordings by guitar-saxophone pairs. These highlight the similarities between and adaptations of musical devices from saxophonists Stan Getz, Jimmy Giuffre, and Joe Lovano into the jazz guitar styles of Jimmy Raney, Jim Hall, and John Scofield. This study supports the argument that the evolution of modern jazz guitar playing is directly connected to the adaptation of saxophone-like phrasing at an improvisatory and compositional level. It also shows that the concept of style in jazz flows between different instruments' lineages. Understanding these findings provides a more complex and accurate concept of the development of style in jazz.
Adaptive Slot Location in the Design of Slotted Microstrip Multi-Frequency Antenna for Radionavigation and Radiolocation Applications
In light of incidents and concerns regarding the vulnerability of the global positioning system (GPS), the main purpose of the thesis is to look at alternative systems for radio guidance and to put up a serious study on such alternatives with receive and transmit antenna. There is also the need to design such antennas with multiple frequencies to offer robustness in the unlikely event that such adversarial attacks on the GPS happen. The basis on which such alternative antennas are designed is a slotted microstrip. The characteristics of the slot or slots on the microstrip are analyzed by mapping their exact locations on the patch and then noting the resultant center frequencies, the return losses, and the bandwidth. The activities associated with this also focus on the design, fabrication, validation, and characterization of one or more slotted antennas prototypes. The measurement of the antenna prototypes does confirm several frequencies that coexist to see applications, in aeronautical radionavigation, fixed-mobile radionavigation, and radiolocation. The antennas could also feature in a wide-area augmentation system (WAAS), satellite ground link system (SGLS) as well as in surveillance and precision approach radars. Some variations of the antenna are deployed in the areas of law enforcement, surveillance, and unmanned aerial vehicle (UAV). Applications of the antenna in an unmanned ground vehicle (UGV) are feasible due to its multiple resonant frequencies. Radiolocation and radionavigation antennas have also been known to be mounted in UAVs or on tethered balloons along the borders of the United States to detect low-flying aircraft in support of drug interdiction programs.
Additive Friction Stir Deposition of Al-Ce Alloys for Improved Strength and Ductility
Additive friction stir deposition (AFSD) is a solid-state additive manufacturing (AM) technique that breaks down large constituent particles into more refined and uniformly disturbed microstructure. AFSD was used to print Al-Ce alloys. Current commercial Al-alloys upon elevated temperatures go through dissolution and coarsening of strengthening precipitates causing mechanical degradation of these alloys. Al-Ce alloys do not have this issue as cerium's low solubility restricts dissolution into the aluminum matrix at elevated temperatures, thus giving great thermal stability to the microstructure. Al-Ce alloys lack solid solubility that affects the solid solution strengthening and precipitation strengthening. Al-Ce alloys have limitation at room temperature as they can only reach a maximum of ~65 MPa yield strength. Elements like magnesium have been added to alloy to enable solid solution strengthening, and scandium to enable precipitation strengthening to improve strength before going through the AFSD process. By adding new elements to the Al-Ce alloys, an increase in the yield strength from ~60 MPa to ~200 MPa was achieved before AFSD. The casted alloys form coarse particles that reach 300 µm in size; resulting in stress concentration that causes material fracture before necking, giving >10% ductility. AFSD breaks down these coarse particles to increase strength and ductility increases. The particles were broken down to >20 µm which increased the ductility to 10%. The results of this research shows that Al-Ce alloys are able to reach commercial aluminum alloy mechanical standards of 400 MPa ultimate tensile strength and 10% ductility at room temperature for aerospace applications.
Additive Manufacturing of AZ31B Magnesium Alloy via Friction Stir Deposition
Additive friction stir deposition (AFSD) of AZ31B magnesium alloy was conducted to examine evolution of grain structure, phases, and crystallographic texture. AFSD was carried out using a hollow tool made from tool steel at a constant rotational velocity of 400 rpm on the AZ31B base plate. Bar stock of AZ31B was utilized as a feed material. The linear velocity of the tool was varied in the range of 4.2-6.3 mm/s. The feed rate of the material had to be maintained at a half value compared to the corresponding linear velocity for the successful deposition. The layer thickness and length of the deposits were kept constant at 1 mm and 50 mm respectively. The tool torque and actuator force values were recorded during the process and for calculation of the average input energy for each processing condition. Temperature during the AFSD experiments was monitored using a type k thermocouple located 4 mm beneath the deposition surface at the center of the deposition track. The average input energy values showed a decreasing trend with increasing tool linear velocity. The temperature values during deposition were ∼0.7 times the liquidus of the alloy. The deposited material then was examined by laser microscope and profilometer, X-ray diffraction, scanning electron microscopy, electron back scatter diffraction (EBSC), contact angle measurement and micro hardness tests. The AFSD AZ31B samples showed reduction in areal surface roughness with an increase in the tool linear velocity. The X-ray spectra revealed increase in the intensity of prismatic planes of α-Mg phase with increase in tool linear velocity. AFSD of AZ31B Mg alloy resulted in shifting of the grain size from a broader and courser distribution within the feed material to a tighter distribution. Moreover, EBSD observations confirmed the refinement in grain size distribution as well as the presence of predominantly prismatic texture …
Adjustments in Business Operations during the COVID-19 Pandemic: An Analysis of Natural and Cultural Resource Sites in Texas
This research expands the theoretical concept of human adjustment to floods established by Gilbert F. White and incorporates his adjustment concept to examine the range of adjustments in business operations adopted by Texas' natural and/or cultural resources sites during the first year of the COVID-19 pandemic. This mixed-methods study consisted of an online survey with a follow-up semi-structured phone interview. The survey data was analyzed using descriptive statistics and the interview data was inductively coded for thematic analysis as well as quantitative and qualitative content analyses. Specifically, this study identifies the adjustment measures undertaken by these entities to maintain business operations while reducing the virus spread; analyses the direct and indirect factors influencing adjustment measures; examines new business opportunities that emerged from these adjustments; and evaluates whether the impact of COVID-19 on these entities varied in terms of entity characteristics. Findings indicate that cultural and/or natural resource sites implemented adjustments to maintain their fiscal stability and/or to protect human health; these serve as direct underlying motivating factors for these entities. To support these direct measures, indirect factors influenced the operations thus required adjustments such as staffing, volunteers, technology, funding, and donations. Additionally, new opportunities in business practices emerged while implementing these adjustments such as networking, maintenance, and virtual options. Across all entity types, virtual programs was a key adjustment addressing both fiscal and health concerns. From these adjustments, this study provides recommendations for cultural and/or natural resource sites to implement to improve resilience to future extreme events.
The Administration of Unemployment Relief by the State of Texas during the Great Depression, 1929-1941
During the Great Depression, for the first time in its history, the federal government provided relief to the unemployed and destitute through myriad New Deal agencies. This dissertation examines how "general relief" (direct or "make-work") from federal programs—primarily the Emergency Relief and Construction Act (ERCA) and Federal Emergency Relief Administration (FERA)—was acquired and administered by the government of Texas through state administrative agencies. These agencies included the Chambers of Commerce (1932-1933), Unofficial Texas Relief Commission (1933), Texas Rehabilitation and Relief Commission (1933), Official Texas Relief Commission (1933-1934), Texas Relief Commission Division of the State Board of Control (1934), and the Department of Public Welfare (1939). Overall, the effective administration of general relief in the Lone Star State was undermined by a political ideology that persisted from, and was embodied by, the "Redeemer" Constitution of 1876.
Adolescent Self-Theories of Singing Ability within the Choral Hierarchy
The purpose of this study was to explore adolescent self-views of singing ability through both implicit theories and self-concept meaning systems. A secondary purpose of this study was to examine these self-views specifically in the context of a choral hierarchy. Using a researcher-designed survey instrument, I gathered data from middle- and high-school students currently enrolled in a choir program organized in a hierarchical structure. I analyzed descriptive statistics of survey responses to items designed to measure implicit theories of singing ability, singing self-concept, and goal orientation. I also examined differences among participants by ensemble placement in implicit theory and self-concept scores, correlation between implicit theory and self-concept, and whether implicit theory, self-concept, goal orientation, or current enrollment could predict future enrollment decisions. In addition to these quantitative measures, I coded open-ended responses to two failure scenarios and examined participant responses by ensemble and gender. Both implicit theory and self-concept scores were higher for participants at the top of the choral hierarchy than at the bottom. Open-ended responses, however, did not align with the implicit theory scale and a number of students presented a false growth mindset. Open-ended responses also indicated that failure scenarios were likely to result in an altered view of the self and shame in placement in an ensemble at the bottom of the choral hierarchy. The means scores for participants in the middle- and high-school ensembles in both implicit theory and self-concept were significantly different, with participants in the high-school ensembles having higher scores in both constructs. Implicit theory and self-concept were significantly related, and self-concept, goal orientation, and current enrollment significantly predicted future enrollment decisions.
Adoption of Credit-Hour Reductions in Master of Divinity Programs at the Association of Theological Schools Member Institutions: An Event History Analysis
Seminaries in the United States have for more than two centuries sought to equip ministerial leaders for service within the community of faith. And yet these institutions have traditionally been the focus of very little quantitative research. This lack of data is particularly noteworthy given the existential crises many seminaries currently face, especially regarding their flagship Master of Divinity (MDiv) programs. Among seminary leadership, a common response to declining MDiv enrollment has been to decrease the length of the program, which historically required at least 90 credit hours. The purpose of this quantitative study was to explore change at the Association of Theological Schools member institutions (AMIs) between 2000–2019 through the lens of these credit-hour reductions. Longitudinal data from 113 AMIs were analyzed to examine the relationship between a variety of financial, enrollment, and institutional characteristics and the likelihood that an AMI would reduce its required MDiv credit hours. Results from an event history analysis revealed that, all else being equal, experiencing an increase in total revenues reduced an AMI's likelihood of making a reduction, while being a middle-age institution (founded 1870–1959) and having a higher percentage of peer institutions that made a change increased the likelihood of making a reduction. These findings, which well fit with existing theory on resource dependence and institutionalization, provide seminary leaders with objective data by which they can better understand the financial and cultural pressures impacting change at their institutions.
Adoption of Innovation in a Community College Environment: User Perceptions of Virtual Reality (VR) Technology among Students Studying Emergency Medical Service (EMS)
This research study examined the implementation of an extended reality (XR) lab on a community college campus to facilitate student and faculty access to immersive learning resources. The study, conducted during one skills day, involved 46 students and was designed to understand if integrating immersive VR into emergency medical technician (EMT) education could enhance learner confidence and motivation, develop problem-solving and analytical thinking skills, and thus connecting the classroom learning with real-world application. The majority of participants reported increased motivation and engagement, alongside improvements in learning outcomes like knowledge retention and skill development. Applying the unified theory of acceptance and use of technology (UTAUT) model revealed performance expectancy, effort expectancy, social influence, and facilitating conditions as key determinants of VR adoption in EMT education. While no significant overall performance enhancement was observed, VR training showed potential to boost motivation, confidence, and specific performance aspects. Furthermore, student perceptions towards VR in EMT education were largely positive, thereby suggesting its utility in immersive scenario training, skill acquisition in a risk-free environment, enhancing learner engagement, and real-world situational preparedness. VR demonstrated promise as a transformative tool in EMT education, necessitating further research to fully exploit its potential in diverse learning environments.
Adoption of Wearable Devices by Older Adults
This dissertation is organized in a traditional format while including three essays that address specific research questions. Essay 1 examined the relationship between physical activity and community engagement and their effect on mental well-being among older men and women. Data from National Health and Aging Trends Study (NHATS) from 2018 to 2020 were explored and the posited relationships were tested. This essay provides empirical support that older adults who are reasonably active and involved in the community have greater mental well-being than those who isolate themselves. Essay 2 provides insight into older adults' motivation to improve their physical activity through the use of a fitness tracker. The key finding from this study is that wearables, especially fitness trackers, can significantly facilitate increased physical activity. Essay 3 is a mixed-methods study to understand older adults' perception of the usefulness of fitness trackers and interaction with such devices. Findings suggest that to increase the adoption of fitness trackers among older adults, makers could improve the esthetics and quality of the wristband in addition to the battery life of the tracker.
Adult Attachment Anxiety and Relationship Satisfaction: The Role of Dedication and Constraint Commitment
Adult attachment has been found to play an important role for romantic relationship satisfaction. Specifically, the existent literature generally suggests that attachment anxiety is negatively related to relationship satisfaction. However, the underlying mechanism for this link still needs further exploration. The present study examined the direct and indirect effect of attachment anxiety on relationship satisfaction via two distinct relationship commitment variables: constraint commitment and dedication commitment. The final sample included 146 unmarried participants who were in a romantic relationship for at least three months. Results of multiple regression analyses on the indirect effect model indicated that attachment anxiety had a significant direct effect on relationship satisfaction as well as a significant indirect effect on relationship satisfaction via constraint commitment. However, the hypothesized indirect effect through dedication commitment was not supported. Findings are discussed from the adult attachment perspective. Counseling implications, limitations, and future research directions are outlined.
Adult Attachment, Perceived Social Support, and Problematic Video Gaming Behavior
With the growing popularity in video games, there has been increased concerns over the prolonged exposure to the entertainment medium. Problematic gaming is defined as a pattern of gaming behavior that causes significant impairment in personal, social, other important areas of functioning, often characterized by preoccupation and loss of interest in other areas. This study examined how problematic gaming behaviors may be influenced by insecure adult attachment and perceived social support from differing sources. It was hypothesized that avoidant attachment would have a significant direct and indirect effect (via perceived social support) on problematic gaming. In addition, perceived social support from online friends and from offline friends were hypothesized to moderate the relationship between attachment and problematic gaming, Participants were recruited from both SONA (n = 151) and Amazon's Mturk (n = 264) to complete an online research questionnaire that measured variables of interest. Results indicated that the direct and indirect effects of attachment avoidance on problematic gaming were supported in both subsamples but the moderator effects were not. Further exploratory analysis found that anxious attachment demonstrated a similar pattern as avoidant attachment, but with a significant moderator effect of perceived social support from online friends (enhance) on the attachment anxiety and problematic gaming relation. Additionally, anhedonia and depressive symptoms were found to be significantly correlated with problematic gaming. Limitations, future research directions, and clinical implications are discussed.
Adult Attachment, Racial-Ethnic Identity, Racial-Ethnic Socialization, and Subjective Wellbeing
The current study aimed to explore the direct effect of insecure adult attachment on subjective wellbeing and its indirect effect via racial-ethnic identity. Additionally, the present study examined the extent to which racial-ethnic socialization practices may moderate adult attachment and racial-ethnic identity link. The final sample included 213 emerging adults (M = 20.94; SD = 2.96) with diverse racial-ethnic backgrounds. PROCESS Model 4 and 1 were used to examine the direct and indirect effect of insecure attachment on subjective wellbeing via racial-ethnic identity variables and the interaction effect between insecure attachment and racial-ethnic socialization on racial-ethnic identity variables. Results indicated the direct effect of insecure attachment on subjective wellbeing but did not support hypotheses for the indirect effect of insecure attachment on subjective wellbeing via the racial-ethnic identity variables. Additionally, results indicated that overt socialization buffered the negative impact of attachment avoidance on racial-ethnic identity exploration. Furthermore, racial-ethnic identity variables and subjective wellbeing significantly differed across racial-ethnic groups and socioeconomic statuses. Findings provide insight on the distinct concepts of attachment and racial-ethnic identity as they highlight inter- and intra-personal components, respectively. Mental health professionals may utilize overt socialization to help clients develop a sense of purpose and meaning related to their identity. Limitations, future research directions, and counseling implications are discussed.
Advanced Cathodes for High Energy Density Lithium Sulfur Battery
A systematic development of 2D alloy catalyst with synergistic performance of high lithium polysulfide (LiPS) binding energy and efficient Li+ ion/electron conduction is presented. The first section of work found that Li+ ions can flow through the percolated ion transport pathway in polycrystalline MoS2, while Na+ and K+ ions can easily flow through the percolated 1D ion channel near the grain boundaries. An unusually high ionic conductivity of extrinsic Li+, Na+, and K+ ions in 2D MoS2 film exceeding 1 S/cm was measured that is more than two orders of magnitude higher than those of conventional solid ionic materials, including 2D ionic materials. The second section of this dissertation focus on catalyzing the transformation of LiPSs to prevent the shuttle effect during the battery cycling by synthesizing 2H (semiconducting) – 1T (metallic) mixed phase 2D Mo0.5W0.5S2 alloy on CNF paper, using two step sputtering and sulfurization method. The lithium sulfur (Li-S) battery cell assembled with the 2D Mo0.5W0.5S2/CNF/S cathode shows a high specific capacity of 1228 mAh g-1 at 0.1C and much higher cyclic stability over 4 times as compared to the pristine cathodes. The high LiPSs binding energy of catalyst efficiently prevents the shuttling effect and corrosion of Li anode after long term stability test for over 400 cycles. The defect engineered MoWS catalyst on CNF showed significantly enhanced polysulfide transformation resulting in specific capacity of 1586 mAh g-1 at 0.05C for the full cell Li-S battery and much higher cyclic stability over 1000 cycles. Stacked layers of D-MoWS-CNF-S cathodes can result in an increased sulfur loading up to 10 mg cm-2 with highest achievable areal capacity of 13.5 mAh/cm2. The efficient sulfur utilization and reduced negative-to-positive capacity (N/P) ratio by D-MoWS catalyst significantly increased the gravimetric energy density to the highest reported value of 1090 Wh kg-1 w.r.t …
Advanced Distributed Optimization and Control Algorithms: Theory and Applications
Networked multi-agent systems have attracted lots of researchers to develop algorithms, techniques, and applications.A multi-agent networked system consists of more than one subsystem (agent) to cooperately solve a global problem with only local computations and communications in a fully distributed manner. These networked systems have been investigated in various different areas including signal processing, control system, and machine learning. We can see massive applications using networked systems in reality, for example, persistent surveillance, healthcare, factory manufacturing, data mining, machine learning, power system, transportation system, and many other areas. Considering the nature of those mentioned applications, traditional centralized control and optimization algorithms which require both higher communication and computational capacities are not suitable. Additionally, compared to distributed control and optimization approaches, centralized control, and optimization algorithms cannot be scaled into systems with a large number of agents, or guarantee performance and security. All of the limitations of centralized control and optimization algorithms motivate us to investigate and develop new distributed control and optimization algorithms in networked systems. Moreover, convergence rate and analysis are crucial in control and optimization literature, which motivates us to investigate how to analyze and accerlate the convergence of distributed optimization algorithms.
Advanced Stochastic Signal Processing and Computational Methods: Theories and Applications
Compressed sensing has been proposed as a computationally efficient method to estimate the finite-dimensional signals. The idea is to develop an undersampling operator that can sample the large but finite-dimensional sparse signals with a rate much below the required Nyquist rate. In other words, considering the sparsity level of the signal, the compressed sensing samples the signal with a rate proportional to the amount of information hidden in the signal. In this dissertation, first, we employ compressed sensing for physical layer signal processing of directional millimeter-wave communication. Second, we go through the theoretical aspect of compressed sensing by running a comprehensive theoretical analysis of compressed sensing to address two main unsolved problems, (1) continuous-extension compressed sensing in locally convex space and (2) computing the optimum subspace and its dimension using the idea of equivalent topologies using Köthe sequence. In the first part of this thesis, we employ compressed sensing to address various problems in directional millimeter-wave communication. In particular, we are focusing on stochastic characteristics of the underlying channel to characterize, detect, estimate, and track angular parameters of doubly directional millimeter-wave communication. For this purpose, we employ compressed sensing in combination with other stochastic methods such as Correlation Matrix Distance (CMD), spectral overlap, autoregressive process, and Fuzzy entropy to (1) study the (non) stationary behavior of the channel and (2) estimate and track channel parameters. This class of applications is finite-dimensional signals. Compressed sensing demonstrates great capability in sampling finite-dimensional signals. Nevertheless, it does not show the same performance sampling the semi-infinite and infinite-dimensional signals. The second part of the thesis is more theoretical works on compressed sensing toward application. In chapter 4, we leverage the group Fourier theory and the stochastical nature of the directional communication to introduce families of the linear and quadratic family of displacement operators that …
Advances to Convolutional Neural Network Architectures for Prediction and Classification with Applications in the First Dimensional Space
In the vast field of signal processing, machine learning is rapidly expanding its domain into all realms. As a constituent of this expansion, this thesis presents contributive work on advancements in machine learning algorithms by building on the shoulder of giants. The first chapter of this thesis contains enhancements to a CNN (convolutional neural network) for better classification of heartbeat arrhythmia. The network goes through a two stage development, the first being augmentations to the network and the second being the implementation of dropout. Chapter 2 involves the combination of CNN and LSTM (long short term memory) networks for the task of short-term energy use data regression. Exploiting the benefits of two of the most powerful neural networks, a unique, novel neural network is created to effectually predict future energy use. The final section concludes this work with directions for future works.
Aerodynamic Optimization of a 2D Airfoil for Rotary-Wing Aircraft at Mars Atmospheric Conditions
The interest toward Mars exploration has been considerably increasing due to also the successful deployment of the Perseverance rover and the continuous tests developed by SpaceX's launch vehicle, Starship. While the Mars 2020 mission is currently in progress, the first controlled flight on another planet have been proven in April 2021 with the vertical take-off and landing of the Ingenuity rotorcraft on Mars. In addition, the rotorcraft Dragonfly is expected to achieve the same endeavor in Titan, the largest moon of Saturn, by 2036. Continuous efforts have been oriented toward the development of new technologies and aircraft configurations to improve the performance of current proposed designs to achieve powered flight in different planetary bodies. This thesis work is a preliminary study to develop a comprehensive analysis over the generation of optimum airfoil geometries to achieve vertical flight in environments where low Reynolds numbers and Mach number equal to 0.2 and 0.5.
After-Sales Service Contracting for Excellence in Life-Cycle Cost Management: Numerical Experiments and Systematic Review of Analytical Models
This research adds to the literature and provides insight to practice via three essays that increase understanding about the applications and consequences of the two new approaches to the after-sales service governance: warranty contract and performance-based contracts. First, we attempted to enhance our knowledge of the modeling of the after-sales service process. In the first essay, the research papers with analytical models of after-sales services to present current trends, issues, and future research directions in the literature are classified. In the second essay, the effect of the warranty contract on the supplier's product quality improvement efforts in the context of capital goods is examined. Three sets of optimization models reveal that the existence of a warranty improves product quality. In the third essay, the performance-based contract is examined in the context of the warranty contract. The numerical experimentations conducted demonstrate that the performance-based contract is superior to the warranty contract in terms of the supplier's product quality efforts and the customer's total cost of after-sales services. The alignment of incentives based on the product performance tackles the issues presented in the traditional after-sales service contracting. Collectively, the three studies presented in this research expand our understanding of after-sales service contracts. Thus, the research presents managerial implications and adds to the existing body of knowledge in after-sales service research.
Air Breathing Fish: Development of Air Breathing in Bristlenose Plecos (Ancistrus cirrhosus)
The bristlenose pleco (Ancistrus cirrhosus) is a species of armored catfish in the Loricariidae family that breathes air facultatively when the aquatic environment becomes hypoxic. The bristlenose pleco uses its highly vascularized stomach as an air breathing organ. The two main goals of this developmental study were to determine the size of onset of air breathing and to determine the frequency of air breathing behavior in bristlenose plecos from juveniles to adults. Developing juveniles reach functional maturity within four to six months of hatching and grow to an adult size of eight to ten cm in length. To examine the developmental timing for the onset of air breathing, we tested different sized juveniles beginning at one cm up until 8 cm in length. The developmental timing for the onset of air breathing was measured by exposing each fish to a slowly decreasing aquatic oxygen content from 100% air saturation down to 8% air saturation. Fish were first able to breathe air at just over 2 cm and 1 gram in mass. There was a weak negative correlation between fish length and % air saturation at which air breathing began. When exposed to 15% air saturation, frequency of air breathing was negatively correlated with fish length. Armored catfish are becoming an invasive species in the southern US, outcompeting local fauna potentially because of this adaptation. This research provides important insight into the development of the air breathing adaptation that may allow these fish to outcompete the others.
Air Corridors: Concept, Design, Simulation, and Rules of Engagement
Air corridors are an integral part of the advanced air mobility infrastructure. They are the virtual highways in the sky for transportation of people and cargo in the controlled airspace at an altitude of around 1000 ft. to 2000 ft. above the ground level. This paper presents fundamental insights into the design of air corridors with high operational efficiency as well as zero collisions. It begins with the definitions of air cube, skylane or track, intersection, vertiport, gate, and air corridor. Then, a multi-layered air corridor model is proposed. Traffic at intersections is analyzed in detail with examples of vehicles turning in different directions. The concept of capacity of an air corridor is introduced along with the nature of distribution of locations of vehicles in the air corridor and collision probability inside the corridor are discussed. Finally, the results of simulations of traffic flows are presented.
Alexander Campbell and the Power of Education
This educational biography is a study of Alexander Campbell's (1788-1866) educational activities and educational thinking. These activities included the following: his creation of Buffalo Seminary; advocacy for common schools at the Virginia State Constitutional Convention of 1829-1830; participation in the Western Literary Institute and College of Professional Teachers of Cincinnati, Ohio (an organization for educators); speeches on education and common schools; founding Bethany College in present-day Bethany, West Virginia; and his discussion of educational issues in his journal, the Millennial Harbinger. The study explores how Campbell's unique early-life affected his future educational life. His early-life included intensive study under his highly educated father, home-training in Christian piety, and studying for a time at the University of Glasgow. The study focuses especially upon Campbell's involvement in the College of Teachers, his founding of Bethany College, and his major educational ideas. Some of Campbell's major educational emphases include: the need for public education; human knowledge as a national resource; moral education; lifelong learning; female education; student interest; a broad and holistic conception of education; a focus on early childhood education; utilitarian education; and the power of education. This study concludes that the overarching theme of education as power pervades Campbell's educational thinking.
Alexandria Ocasio-Cortez: Media Coverage of Age, Gender, and Ethnicity in the 116th Congress
This study focuses on Alexandria Ocasio-Cortez, the U.S. Representative for New York's 14th Congressional District, and how news media portray her based on her gender, age, and ethnicity, which still play essential roles in the political system in the United States. The analysis of previous academic research, newspaper articles from the New York Times and the Washington Post (June 1, 2018 to June 30, 2019) and framing and feminist theories are used to evaluate coverage of Alexandria Ocasio-Cortez. The newspaper stories are examined based on the framing of traits including being the youngest woman ever elected to Congress, being Latina, and being one the most progressive politicians in the Congress. The main objective of this study is to shed light on a topic that at this moment in time is more relevant than ever because the 116th Congress has the highest number of women and women of color in U.S. history. I examine media coverage that Rep. Alexandria Ocasio-Cortez receives for stereotypical frames, so that, overall, all women running or holding public office may receive unbiased and more balanced media coverage. This study also intends to hold media outlets accountable for the way they portray different candidates because it has a significant influence on the voting population.
Algebraic Trait for Structurally Balanced Property of Node and Its Applications in System Behaviors
This thesis targets at providing an algebraic method to indicate network behaviors. Furthermore, for a signed-average consensus problem of the system behaviors, event-triggering signed-average algorithms are designed to reduce the communication overheads. In Chapter 1, the background is introduced, and the problem is formulated. In Chapter 2, notations and basics of graph theory are presented. It is known that the terminal value of the system state is determined by the initial state, left eigenvector and right eigenvector associated with zero eigenvalue of the Laplacian matrix. Since there is no mathematical expression of right eigenvector, in Chapter 3, mathematical expression of right eigenvector is given. In Chapter 4, algebraic trait for structurally balanced property of a node is proposed. In Chapter 5, a method for characterization of collective behaviors under directed signed networks is developed. In Chapter 6, dynamic event-triggering signed-average algorithms are proposed and proved for the purpose of relieving the communication burden between agents. Chapter 7 summarizes the thesis and gives future directions.
All for the Greater Good: A Strategic, Tactical, and Operational Level Analysis of Supply Chain Goal and Incentive Alignment
Goal and incentive alignment are a means of establishing collaborative behavior in supply chains. Essay 1 examines goal and incentive alignment at the strategic level in the purchasing process. It employs survey research in conjunction with structural equation modelling to examine the source selection strategy as a means of aligning the goals of the offeror with those of the buyer. Essay 2 examines goal and incentive alignment at the tactical level. It uses discrete event simulation to explore how the pursuit of localized profit objectives affects the global profitability of a supply chain. Lastly, Essay 3 examines goal and incentive alignment at the operational level. By employing a hybrid simulation approach to model a complex product refurbishment process, this research demonstrates that evaluating subprocesses based solely on their throughput does not equate to greater cost savings for the company at the focal point of this case study. These essays contribute to the body of knowledge in several ways. To the best of the author's knowledge, Essay 1 demonstrates the first empirical linkage, in the realm of public procurement, between the fear of a bid protest and the appropriateness of the sourcing strategy. Similarly, Essay 2 represents the first adaptation of Sterman's Beer Game to a format in which the value of products increases while they travel downstream. It also stands as the first research to quantitively explore the value of supply chain cooperation as a function of relative position in a supply chain. Lastly, the methodology employed in Essay 3 answers calls for research as they pertain to the need for case studies from industry, as well as the need to preserve the ‘real-world' context in complex, industry-based problems.
"All things at once": A Retrospective Qualitative Examination of the Parental Racial Ethnic Socialization Practices Experienced by Multiracial/Multiethnic Individuals
The purpose of this phenomenological study was to explore how individuals from different multiracial/multiethnic groups experience and process the phenomenon of parental racial ethnic socialization (RES). Critical multiracial race theory, critical race theory, and bioecological systems theory offered a conceptual framework to how RES is often presented and processed. This study was guided by two research questions: (1) What are the experiences of RES among multiracial individuals? and (2) How do multiracial individuals process the parental racial ethnic socialization they were offered? Nine qualitative, one-on-one, semistructured interviews were conducted with individuals from three different multiracial/multiethnic groups. Results revealed that experiences of RES varied along with how participants processed RES. Three subthemes and one theme emerged related to the RES experiences of participants. For some participants lack of conversations were evident in their RES, which meant that conversations surrounding multiraciality and other racialized topics were not present. Other participants disclosed the subtheme of preparedness as part of their RES experience, while others mentioned the importance of environment to their RES experience. Additionally, the theme of changes over time arose, demonstrating how different life events can impact RES experiences. As for how multiracial/multiethnic individuals process RES experiences, the main theme of identity arose with three subthemes. Participants felt that the lack of awareness/knowledge parents had about potential multiracial experiences left them feeling confused about how to navigate their multiple heritages.
"Allegro de Concert," op. 46, by Frédéric Chopin: A Performance Guide
Frédéric Chopin produced a remarkable body of piano works. Even though most of his works are essential repertoire in piano literature, some of them remain less familiar. One such significant work is the Allegro de Concert in A major, op. 46, which was apparently intended to be the first movement of a third piano concerto. Despite the praise the work has received, it is rarely heard, and references to performance are lacking in the scholarly literature. Some reasons include the substantial technical challenges, such as risky skips, trills in double notes, thick harmonic textures, complex passagework, and the perpetual motion. This study provides a performance guide for the Allegro de Concert, looking at various perspectives of an informed musical performance. The historical backstory of the intended third concerto and a detailed form analysis demonstrate that the work has a combined form, incorporating elements of both concerto and sonata-allegro form. The chapter on performance presents the technical issues and a comparative analysis of various editions and arrangements of this work to inspire musical ideas and suggest appropriate solutions to the musical and technical difficulties.
Alloy Design, Processing and Deformation Behavior of Metastable High Entropy Alloys
This dissertation presents an assortment of research aimed at understanding the composition-dependence of deformation behavior and the response to thermomechanical processing, to enable efficient design and processing of low stacking fault energy (SFE) high entropy alloy (HEAs). The deformation behavior and SFE of four low SFE HEAs were predicted and experimentally verified using electron microscopy and in-situ neutron diffraction. A new approach of employing a minimization function to refine and improve the accuracy of a semi-empirically derived expression relating composition with SFE is demonstrated. Ultimately, by employing the minimization function, the average difference between experimental and predicted SFE was found to be 2.64 mJ m-2. Benchmarking with currently available approaches suggests that integrating minimization functions can substantially improve prediction accuracy and promote efficient HEA design with expansion of databases. Additionally, in-situ neutron diffraction was used to present the first in-situ measurement of the interspacing between stacking faults (SFs) which were correlated with work hardening behavior. Electron transparent specimens (< ~100 nm thick) were used in order to resolve nanoscale planar faults instead of the thicker sub-sized specimens (on the order of millimeters in thickness) which exhibit the classical stages III work hardening behavior characteristic of low SFE metals and alloys. The present study demonstrates these characteristic dimensions of SFs can be tracked in real-time using neutrons or high-energy x-rays. SFs have also been shown to act as barriers to dislocation motion and thus contribute to strengthening and sustained work hardening during deformation.
Alterations in the Expression of Proteins Associated with Non-Alcoholic Fatty Liver Disease Observed in the Liver of the C57Bl/6 Wild-Type Male Mouse in Response to Exposure of Mixed Vehicle Emissions and/or High Fat Diet Consumption
Recent epidemiological studies have demonstrated a correlation between the manifestation of non-alcoholic fatty liver disease (NAFLD) and ambient air pollution levels, which is exacerbated by the presence of other risk factors, such as diabetes, dyslipidemia, obesity, and hypertension. We investigated the hypothesis that exposure to a mixture of gasoline and diesel engine emissions (MVE) coupled with the concurrent consumption of a high-fat (HF) diet promotes the development of a NAFLD phenotype within the liver. Three-month-old male C57Bl/6 mice were placed on either a low fat or HF diet and exposed via whole-body inhalation to either filtered (FA) air or MVE (30 µg PM/m3 gasoline engine emissions + 70 µg PM/m3 diesel engine emissions) 6 hr/day for 30 days. Histology revealed mild microvesicular steatosis and hepatocyte hypertrophy in response to MVE exposure alone, compared to FA controls, yielding a classification of "borderline NASH" under the criteria of the modified NAFLD active score (NAS) system. As anticipated, animals on a HF diet exhibited moderate steatosis; however, we also observed inflammatory infiltrates, hepatocyte hypertrophy, and increased lipid accumulation, with the combined effect of HF diet and MVE exposure. Immunofluorescence staining and RT-qPCR of the liver revealed the presence of lipid peroxidation, altered expression of inflammatory markers, induction of hepatic stellate cell activation biomarkers, and conversion to pyroptosis in response to MVE exposure and/or consumption of a HF diet. Our results indicate that inhalation exposure to traffic-generated air pollution initiates hepatocyte injury within the liver, exacerbates lipid accumulation and hepatocyte injury induced by the consumption of a HF diet, and alters molecular pathways associated with inflammation, fibrogenesis, and cell death, thereby contributing to the progression of NAFLD-related pathologies.
The Amalgamation of Western and Eastern Influences in Julius Schloss's "First Chinese Rhapsody"
The dissertation seeks to rediscover Julius Schloss, a German Jewish composer victimized by the Nazis. Except for the promising start of his career in his early years, Schloss suffered a hard life as an exiled refugee. However, his unusual experiences inspired him to compose two Chinese Rhapsodies during his last years of exile in Shanghai, in which he synthesized Western composition techniques and Chinese folk materials, amalgamating influences from both Western and Eastern music cultures. Focusing on Schloss's First Chinese Rhapsody, the dissertation explores how Schloss links the new to the old, the West to the East, through an analysis of the way he employs Chinese folk song material and serial polyphonic voice-leading in his post-tonal musical language. Since the Rhapsody has both serial and polyphonic voice-leading aspects, both are analyzed, showing how they are integrated in the form.
Ambient Darkness and Consumer Behavior
Ambient lighting has emerged as a key atmospheric factor influencing how consumers process environmental cues and their behaviors. However, surprisingly little research has examined how people think and feel in the dark (lower than 15 lux). This is particularly relevant given that consumers routinely work, pay bills, relax, consume and make purchases in settings with little or no light. My dissertation addresses this gap by examining how consumers regulate their goals and process information when the light is off, and how that impacts their decision making in three substantive domains: risk-taking behavior, decision quality, and persuasion. In Essay 1, I propose darkness enables risk-taking behavior, and this effect happens through the calmness and relaxation induced in the dark. One caveat is that the decisions have to be made in a familiar setting. The effect was reflected in participants' decisions to invest in riskier yet lucrative stocks, to gamble with the riskier choice, to eat at a foreign restaurant, and to choose a supplement that has potential side effects in a field experiment and three lab experiments (pre-registered). In Essay 2, I propose that when the light is off, consumers are indeed induced to adopt an effortful processing mode. Across four experiments (one field experiment, two lab experiments, and one online experiment), darkness promotes higher quality decisions across consumption contexts (financial, food, and product choices) compared to higher luminous levels. Together, this dissertation explores the intriguing phenomenon of ambient darkness and extends current understandings on ambient lighting and consumer behavior. The essays also offer robust findings through field and lab experiments with tendency and incentive-compatible outcomes.
Analysis of Compressive Sensing and Hardware Implementation of Orthogonal Matching Pursuit
My thesis is to understand the concept of compressive sensing algorithms. Compressive sensing will be a future alternate technique for the Nyquist rate, specific to some applications where sparsity property plays a major role. Software implementation of compressive sensing (CS) takes more time to reconstruct a signal from CS measurements, so we use the orthogonal matching pursuit and basis pursuit algorithms. We have used an image size of 256x256 is used for reconstruction and also implemented a field-programmable gate array (FPGA) of the orthogonal matching pursuit using an image.
An Analysis of Compressive Sensing and the Electrocardiogram
As technology has advanced, data has become more and more important. The more breakthroughs are achieved, the more data is needed to support them. As a result, more storage is required in the system's memory. Compression is therefore required. Before it can be stored, the data must be compressed. To ensure that information is not lost, efficient compression is necessary. This also makes sure that there is no redundancy in the data that is being kept and stored. Compressive sensing has emerged as a new field of compression thanks to developments in sparse optimization. Rather than relying just on compression and sensing formulations, the theory blends the two. The objective of this thesis is to analyze the concept of compressive sensing and to study several reconstruction algorithms. Additionally, a few of the algorithms were put into practice. This thesis also included a model of the ECG, which is vital in determining the health of the heart. For the most part, the ECG is utilized to diagnose heart illness, and a modified synthetic ECG can be used to mimic some of these arrhythmias.
An Analysis of Dependent Contingencies in a Triadic Interaction Using an Exchange Task to Understand Dynamic Concurrent Contingencies under Independent and Reciprocal Conditions
Although behavioral science, due to its emphasis on the use of single-subject research design, appears to focus solely on individual behaviors, behavioral scientists have a long history of lamenting the trajectory of humans, societies, and the discipline itself. Some scholars, for instance, called for our attention to expand our focus beyond individual behaviors to generate solutions for societal issues that we face. When we attempt to develop solutions for issues that require multi-level analysis, we must be cognizant of how institutional contingencies operate at the individual level. The current study analyzed triadic interactions using an exchange task in six triads. The result of this study showed that one common pattern of interactions among participants across triads was direct reciprocation between two participants. The implications of such findings, how they inform social behavior and metacontingency experiments, and future directions are discussed.
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