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 Decade: 2010-2019
 Collection: UNT Theses and Dissertations
Designing Tools to Probe the Calcium-dependent Function of Arabidopsis Tonneau2

Designing Tools to Probe the Calcium-dependent Function of Arabidopsis Tonneau2

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Date: December 2013
Creator: Oremade, Oladapo O.
Description: Plants possess unique features in many aspects of development. One of these features is seen in cell wall placement during cytokinesis, which is determined by the position of the preprophase band (PPB) and the subsequent expansion of the phragmoplast that deposits the new cell wall. During phragmoplast expansion, the phragmoplast tracks to the cortical division site, which was delineated by the PPB. Thus the position of the PPB determines the orientation of the division plane. In Arabidopsis thaliana, TONNEAU2 (TON2) is required for PPB formation and has been shown to interact with a type A subunit of the PP2A phosphatase in the yeast two-hybrid system. In Arabidopsis tonneau2 (ton2) mutants, abnormalities of the cortical microtubule cytoskeleton, such as disorganization of the interphase microtubule array and lack of PPB formation before mitosis markedly affects cell shape and arrangement as well as overall plant morphology. Loss of dcd1/add1, the maize ton2 homologues gives rise to a similar phenotype in Zea mays. The TON2 protein has two EF hand domains which are calcium-binding sites. Since calcium has been known to play key roles in several areas of plant functioning, the following question was raised: “Does calcium binding contribute to the localization and function ...
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Determinants of Citizens’ 311 Use Behaviors: 311 Citizen-initiated Contact, Contact Channel Choice, and Frequent Use

Determinants of Citizens’ 311 Use Behaviors: 311 Citizen-initiated Contact, Contact Channel Choice, and Frequent Use

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Date: May 2015
Creator: Wu, Wei-Ning
Description: Facing increasingly complex policy issues and diminishing citizen satisfaction with government and service performance, managing the quality of citizen relationship management has become a main challenge for public managers. Solutions to complex policy problems of service performance and low level of citizen participation often must be developed by encouraging citizens to make their voices heard through the various participation mechanisms. Reflecting on this need, the municipal governments in the U.S. have developed centralized customer systems for citizen relationship management. 311 centralized customer system (named 311 in this study) has the functions of citizen-initiated contact, service-coproduction, and transaction, and many local governments launch 311 to maintain or enhance their relationship with the public. Using 311 is an easy and free technically for citizens, but ensuring some degree of citizen engagement and citizens’ 311 use has been challenging for local public managers of municipalities. Despite calls for the importance of 311 in the service and information delivery process, fair treatment and access to use of governmental information, citizen participation, government responsiveness, and citizen satisfaction, to the best of our understanding, no empirical studies explore citizens’ 311 behaviors in the micro and individual level in the field of public administration. This dissertation provides ...
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Determinants of Mental Health Problems Among College Students

Determinants of Mental Health Problems Among College Students

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Date: December 2010
Creator: Mirbaha-Hashemi, Fariba
Description: Many college students have reported struggling with mental health problems while dealing with challenging demands of college. The initial theoretical framework for this research was Pearlin's stress process model (SPM). Building on the SPM, the three additional mediating variables of perceived control, meaninglessness, and financial worries were added to create a composite model for the research. Mental health outcomes in the model were measured by a comprehensive range of factors, which included: psychological distress, suicide, substance abuse, and anger. Data were collected from a non-probability convenience sample of 463 undergraduate students attending a large state supported university in the southwestern region of the United States. Among the social status variables measured, being married, female, and white were significant predictors of poor mental health in the sampled college students. Poor self-image, feeling of meaninglessness, and worrying about current and future finances were significant mediating variables. Poor mental health could make individuals overwhelmed and discouraged. This is a formula for failure in college. The results of this study contribute to a better understanding of the correlates of mental health problems among college students. A greater understanding means that families and college administrations will have better ideas about how to intervene to reduce ...
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Developing Policy for a Tech Program Based on Understanding Organizational Practices

Developing Policy for a Tech Program Based on Understanding Organizational Practices

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Date: May 2016
Creator: Machado Perez, Luis Daniel
Description: This thesis contributes to research that informs the studies of organizational management and organizational anthropology. It examines the internal hierarchy and organizational practices of a Tech Company and describes how findings contributed to policy recommendations aimed towards supporting a “guild” model for organizational success. The data collecting and research were undertaken while working as an employee of the Tech Program and subsequent analysis continued past the end of that phase of work. Methods included semi-structured interviews which captured the sentiments and understandings of employees within the organization, and a questionnaire which revealed sentiments and experiences from former employees. These were buttressed with participant observation engaged through a participatory action research methodology. Findings add to the work directed towards understanding the effect of Founder’s Syndrome within organizations. Additionally, this thesis contributes to a growing body of research centered on best practices for fostering positive organizational growth by creating lines of communication from front-line employees to management level employers.
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Development of an Instrument to Measure the Level of Acceptability and Tolerability of  Cyber Aggression: Mixed-Methods Research on Saudi Arabian Social Media Users

Development of an Instrument to Measure the Level of Acceptability and Tolerability of Cyber Aggression: Mixed-Methods Research on Saudi Arabian Social Media Users

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Date: May 2016
Creator: Albar, Ali A
Description: Cyber aggression came about as a result of advances in information communication technology and the aggressive usage of the technology in real life. Cyber aggression can take on many forms and facets. However, the main focus of this study is cyberbullying and cyberstalking through information sharing practices that might constitute digital aggressive acts. Human aggression has been extensively investigated. Studies focusing on understanding the causes and effects that can lead to physical and digital aggression have shown the prevalence of cyber aggression in different settings. Moreover, these studies have shown strong relationship between cyber aggression and the physiological and physical trauma on both perpetrators and their victims. Nevertheless, the literature shows a lack of studies that could measure the level of acceptance and tolerance of these dangerous digital acts. This study is divided into two main stages; Stage one is a qualitative pilot study carried out to explore the concept of cyber aggression and its existence in Saudi Arabia. In-depth interviews were conducted with 14 Saudi social media users to collect understanding and meanings of cyber aggression. The researcher followed the Colaizzi’s methods to analyze the descriptive data. A proposed model was generated to describe cyber aggression in social media ...
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Development of Indium Oxide Nanowires as Efficient Gas Sensors

Development of Indium Oxide Nanowires as Efficient Gas Sensors

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Date: December 2011
Creator: Gali, Pradeep
Description: Crystalline indium oxide nanowires were synthesized following optimization of growth parameters. Oxygen vacancies were found to impact the optical and electronic properties of the as-grown nanowires. Photoluminescence measurements showed a strong U.V emission peak at 3.18 eV and defect peaks in the visible region at 2.85 eV, 2.66 eV and 2.5 eV. The defect peaks are attributed to neutral and charged states of oxygen vacancies. Post-growth annealing in oxygen environment and passivation with sulphur are shown to be effective in reducing the intensity of the defect induced emission. The as-grown nanowires connected in an FET type of configuration shows n-type conductivity. A single indium oxide nanowire with ohmic contacts was found to be sensitive to gas molecules adsorbed on its surface.
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Development of Silicon Nanowire Field Effect Transistors

Development of Silicon Nanowire Field Effect Transistors

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Date: December 2011
Creator: Nukala, Prathyusha
Description: An economically reliable technique for the synthesis of silicon nanowire was developed using silicon chloride as source material. The 30-40 micron long nanowires were found to have diameters ranging from 40 – 100 nm. An amorphous oxide shell covered the nanowires, post-growth. Raman spectroscopy confirmed the composition of the shell to be silicon-dioxide. Photoluminescence measurements of the as-grown nanowires showed green emission, attributed to the presence of the oxide shell. Etching of the oxide shell was found to decrease the intensity of green emission. n-type doping of the silicon nanowires was achieved using antimony as the dopant. The maximum dopant concentration was achieved by post-growth diffusion. Intrinsic nanowire parameters were determined by implementation of the as-grown and antimony doped silicon nanowires in field effect transistor configuration.
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Device Engineering for Enhanced Efficiency from Platinum(II) Phosphorescent OLEDs

Device Engineering for Enhanced Efficiency from Platinum(II) Phosphorescent OLEDs

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Date: August 2010
Creator: Li, Minghang
Description: Phosphorescent organic light emitting diodes (PHOLEDs) based on efficient electrophosphorescent dopant, platinum(II)-pyridyltriazolate complex, bis[3,5-bis(2-pyridyl)-1,2,4-triazolato]platinum(II) (Pt(ptp)2) have been studied and improved with respect to power efficiency, external efficiency, chromacity and efficiency roll-off. By studying the electrical and optical behavior of the doped devices and functionality of the various constituent layers, devices with a maximum EQE of 20.8±0.2 % and power efficiency of 45.1±0.9 lm/W (77lm/W with luminaries) have been engineered. This improvement compares to devices whose emission initially could only be detected by a photomultiplier tube in a darkened environment. These devices consisted of a 65 % bis[3,5-bis(2-pyridyl)-1,2,4-triazolato]platinum(II) (Pt(ptp)2) doped into 4,4'-bis(carbazol-9-yl)triphenylamine (CBP) an EML layer, a hole transporting layer/electron blocker of 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC), an electron transport layer of 1,3,5-tris(phenyl-2-benzimidazolyl)-benzene (TPBI), and a LiF/Al cathode. These devices show the acceptable range for warm white light quadrants and qualify to be called "warm white" even w/o adding another emissive layer. Dual EML devices composed of neat Pt(ptp)2 films emitting orange and CBP: Pt(ptp)2 film emitting blue-green produced a color rendering index (CRI) of 59 and color coordinates (CIE) of (0.47,0.49) at 1000Cd/m² with power efficiency of 12.6±0.2 lm/W and EQE of 10.8±0.2 %. Devices with two blue fluorescent emission layers as singlet ...
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Does Device Matter? Understanding How User, Device, and Usage Characteristics Influence Risky It Behaviors of Individuals

Does Device Matter? Understanding How User, Device, and Usage Characteristics Influence Risky It Behaviors of Individuals

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Date: August 2015
Creator: Negahban, Arash
Description: Over the past few years, there has been a skyrocketing growth in the use of mobile devices. Mobile devices are ushering in a new era of multi-platform media and a new paradigm of “being-always-connected”. The proliferation of mobile devices, the dramatic growth of cloud computing services, the availability of high-speed mobile internet, and the increase in the functionalities and network connectivity of mobile devices, have led to creation of a phenomenon called BYOD (Bring Your Own Device), which allows employees to connect their personal devices to corporate networks. BYOD is identified as one of the top ten technology trends in 2014 that can multiply the size of mobile workforce in organizations. However, it can also serve as a vehicle that transfers cyber security threats associated with personal mobile devices to the organizations. As BYOD opens the floodgates of various device types and platforms into organizations, identifying different sources of cyber security threats becomes indispensable. So far, there are no studies that investigated how user, device and usage characteristics affect individuals’ protective and risky IT behaviors. The goal of this dissertation is to expand the current literature in IS security by accounting for the roles of user, device, and usage characteristics ...
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Dolores Dyer: Women's Basketball and the American Dream

Dolores Dyer: Women's Basketball and the American Dream

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Date: December 2012
Creator: Roberts, Jackie
Description: Dolores Dyer played from 1952-1953 for the Texas Cowgirls, a barnstorming women's basketball team that provided a form of entertainment popular throughout the United States in that era. The story of Dyer's life demonstrates how a woman could attempt to achieve the American dream—a major theme in American history—through success in athletic competition. Dyer's participation with the Texas Cowgirls also provides a look into the circumstances that limited women's participation in professional sport during the mid-twentieth century. Women's sports studies, although some are very thorough, have gaps in the research, and women's barnstorming basketball is one of the areas often overlooked. In light of this gap, this thesis relies on a variety of sources, including primary documents from unpublished collections, archived materials, and original oral histories from several members of the Texas Cowgirls team. This thesis contains analysis of the socioeconomic factors that influenced Dolores Dyer's maturation into a professional basketball player, examines what the American dream meant to her, and evaluates the extent to which she achieved it. Overall, it constructs a social history that can serve as a foundational source for further study of women in sports during the twentieth century.
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Dream of a Thousand Keys: A Concerto for Piano and Orchestra

Dream of a Thousand Keys: A Concerto for Piano and Orchestra

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Date: May 2011
Creator: Choi, Da Jeong
Description: Dream of a Thousand Keys is a concerto for piano and orchestra, which consists of four movements presenting multiple dimensional meanings as suggested by the word "key." I trace the derivation of Korean traditional rhythmic cycles and numerical sequences, such as the Fibonacci series, that are used throughout the work, and explore the significant role of space between the soloist and piano that are emphasized in a theatrical aspect of the composition. The essay addresses the question of musical contrasts, similarities, and metamorphosis. Lastly, I cover terms and concepts of significant 21st-century compositional techniques that come into play in the analysis of this work.
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A Driver, Vehicle and Road Safety System Using Smartphones

A Driver, Vehicle and Road Safety System Using Smartphones

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Date: May 2012
Creator: Gozick, Brandon
Description: As vehicle manufacturers continue to increase their emphasis on safety with advanced driver assistance systems (ADAS), I propose a ubiquitous device that is able to analyze and advise on safety conditions. Mobile smartphones are increasing in popularity among younger generations with an estimated 64% of 25-34 year olds already using one in their daily lives. with over 10 million car accidents reported in the United States each year, car manufacturers have shifted their focus of a passive approach (airbags) to more active by adding features associated with ADAS (lane departure warnings). However, vehicles manufactured with these sensors are not economically priced while older vehicles might only have passive safety features. Given its accessibility and portability, I target a mobile smartphone as a device to compliment ADAS that can bring a driver assist to any vehicle without regards for any on-vehicle communication system requirements. I use the 3-axis accelerometer of multiple Android based smartphone to record and analyze various safety factors which can influence a driver while operating a vehicle. These influences with respect to the driver, vehicle and road are lane change maneuvers, vehicular comfort and road conditions. Each factor could potentially be hazardous to the health of the driver, ...
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Dynamic Behaviors of Historical Wrought Iron Truss Bridges – a Field Testing Case Study

Dynamic Behaviors of Historical Wrought Iron Truss Bridges – a Field Testing Case Study

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Date: December 2015
Creator: Hedric, Andrew C.
Description: Civil infrastructure throughout the world serves as main arteries for commerce and transportation, commonly forming the backbone of many societies. Bridges have been and remain a crucial part of the success of these civil networks. However, the crucial elements have been built over centuries and have been subject to generations of use. Many current bridges have outlived their intended service life or have been retrofitted to carry additional loads over their original design. A large number of these historic bridges are still in everyday use and their condition needs to be monitored for public safety. Transportation infrastructure authorities have implemented various inspection and management programs throughout the world, mainly visual inspections. However, careful visual inspections can provide valuable information but it has limitations in that it provides no actual stress-strain information to determine structural soundness. Structural Health Monitoring (SHM) has been a growing area of research as officials need to asses and triage the aging infrastructure with methods that provide measurable response information to determine the health of the structure. A rapid improvement in technology has allowed researchers to start using new sensors and algorithms to understand the structural parameters of tested structures due to known and unknown loading scenarios. ...
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Eaten: A Novel

Eaten: A Novel

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Date: May 2016
Creator: Foster, Natalie
Description: This novel operates on two levels. First, it is a story concerning the fate of a young woman named Raven Adams, who is prompted into journeying westward after witnessing what she believes to be an omen. On another level, however, the novel is intended to be a philosophical questioning of western modes of “science-based” singular conceptualizations of reality, which argue that there is only one “real world” and anyone who deviates from this is “crazy,” “stupid,” or “wrong.” Raven as a character sees the world in terms of what might be called “magical thinking” in modern psychology; her closest relationship is with a living embodiment of a story, the ancient philosopher Diogenes, which she believes is capable of possessing others and directing her journey. As the story continues the reader comes to understand Raven’s perceptions of her reality, leading to a conceptualization of reality as being “multi-layered.” Eventually these layers are collapsed and unified in the final chapters. The novel makes use of many reference points including philosophy, classical mythology, folklore, religion, and internet social media in order to guide the reader along Raven’s story.
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Economic Mobility into the Planter Class in Texas, 1846-1860

Economic Mobility into the Planter Class in Texas, 1846-1860

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Date: December 2011
Creator: Nelson, Robert Nicholas
Description: This study examines upward economic mobility into the planter class in Texas during the antebellum statehood period, 1846-1860. Using quantitative methods to analyze data from census and tax records, this study addresses several questions regarding the property owning experience of Texas planters. Did any of the 1860 planters, men or women, rise to that status from another class? If so, how many rose from small slaveholder or small planter origins, and how many advanced from plain folk origins? In what ways did the amount and nature of wealth of these individuals change in the period studied? In what ways do these findings provide insights into the debate over planter dominance versus ‘plain folk’ inclusive herrenvolk democracy and the relationship between the planters and the other classes? Did the experiences of female planters differ from that of male planters? Did female planter experiences in Texas differ from female planters in other parts of the Old South? The results of these questions demonstrate that economic class mobility into the richest class was significant but limited and that women’s experiences were closely tied to those of male kin.
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Effect of Acute Alcohol Ingestion on Resistance Exercise Induced Mtorc1 Signaling in Human Muscle

Effect of Acute Alcohol Ingestion on Resistance Exercise Induced Mtorc1 Signaling in Human Muscle

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Date: August 2015
Creator: Anthony A. Duplanty
Description: The purpose of this project was to further elucidate the effects post-exercise alcohol ingestion. This project had many novel aspects including using a resistance exercise (RE) only exercise design and the inclusion of women. To our knowledge, we are the first to investigate the effect of post-RE alcohol ingestion in women. In the first chapter of this project, information on the prevalence of alcohol use and the importance of skeletal muscle as a dynamic and metabolic tissue was provided. In chapter two, the effects of post-RE alcohol ingestion in men and women are detailed. The major findings of this study was that although RE elicited similar mTORC1 signaling both in men and in women, alcohol ingestion appeared to only attenuate RE-induced phosphorylation of the mTORC1 signaling pathway in men. The third chapter focused on examining the effects of post-RE alcohol ingestion on acute testosterone bioavailability. The primary findings of this study was that alcohol substantially elevated serum total and free testosterone concentrations during recovery from a bout of resistance exercise. The fourth chapter detailed factors that contribute to bone density in men. The major findings of this study was that young adult male long-distance runners who participated in resistance training ...
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The Effect of Curcumin Supplementation on Physical and Biological Indices of Delayed Onset Muscle Soreness and Inflammation Following Muscle Injury

The Effect of Curcumin Supplementation on Physical and Biological Indices of Delayed Onset Muscle Soreness and Inflammation Following Muscle Injury

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Date: May 2015
Creator: Venable, Adam Steven
Description: In this project, the effects of dietary polyphenols on exercise-induced muscle damage and vascular health are examined. Dietary polyphenols exert well-known anti-inflammatory effects; however, how these effects are realized with respect to vascular health and EIMD is relatively unknown. I begin by reviewing the available literature surrounding the impact of three dietary polyphenols (curcumin, catechins, and quercetin) on inflammation associated with EIMD. It is well established that their primary means of anti-inflammation is through alterations of NF-κB and AP-1 transcription activities. Given this, their inclusion into training strategies seems reasonable. Consistent evidence is presented making a case for the anti-inflammatory effects of dietary polyphenols following EIMD. I follow this review up by completing an in-depth study on the consumption of curcumin prior to EIMD. I found curcumin (1000 mg/day) can reduce subjective soreness and decrease inflammation compared to placebo controls. To further understand the effects of dietary polyphenols on health, I investigate the effects of a four-week supplementation period of cocoa (catechins) on vascular. I concluded that atherogenic risk in obese women is reduced after consumption of cocoa. In addition to these experimental projects, I developed two novel methods that can be used to investigate vascular health (EMP concentration) and ...
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The Effect of Natural Gas Well Setback Distance on Drillable Land in the City of Denton, Texas

The Effect of Natural Gas Well Setback Distance on Drillable Land in the City of Denton, Texas

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Date: May 2014
Creator: Daniel, Michael
Description: Municipalities protect human health and environmental resources from impacts of urban natural gas drilling through setback distances; the regulation of distances between well sites and residences, freshwater wells, and other protected uses. Setback distances have increased over time, having the potential to alter the amount and geographical distribution of drillable land within a municipality, thereby having implications for future land use planning and increasing the potential for future incompatible land uses. This study geographically applies a range of setback distances to protected uses and freshwater wells in the city limits of Denton, Texas to investigate the effect on the amount of land remaining for future gas well development and production. Denton lies on the edge of a productive region of the Barnett Shale geological formation, coinciding with a large concentration of drillable land in the southwestern region of the study area. This region will have the greatest potential for impacts to future municipal development and land use planning as a result of future gas well development and higher setback standards. Given the relatively high acreage of drillable land in industrially zoned subcategory IC-G and the concern regarding gas well drilling in more populated areas, future drilling in IC-G, specifically in ...
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Effect of Retting on Surface Chemistry and Mechanical Performance Interactions in Natural Fibers for High Performance Polymer Composites

Effect of Retting on Surface Chemistry and Mechanical Performance Interactions in Natural Fibers for High Performance Polymer Composites

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Date: May 2013
Creator: Ramesh, Dinesh
Description: Sustainability through replacement of non-renewable fibers with renewable fibers is an ecological need. Impact of transportation costs from South-east Asia on the life cycle analysis of the composite is detrimental. Kenaf is an easily grown crop in America. Farm based processing involves placing the harvested crop in rivers and ponds, where retting of the fibers from the plant (separation into fibers) can take 2 weeks or more. The objective of this thesis is to analyze industrially viable processes for generating fibers and examine their synergistic impact on mechanical performance, surface topography and chemistry for functional composites. Comparison has been made with commercial and conventional retting process, including alkali retting, enzymatic retting, retting in river and pond water (retting occurs by natural microbial population) with controlled microbial retting. The resulting kenaf fibers were characterized by dynamic mechanical analysis (DMA), Raman spectroscopy (FT-Raman), Fourier transform infrared spectroscopy (FT-IR), polarized optical microscopy (POM), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM) optical fluorescence microscopy, atomic force microscopy (AFM) and carbohydrate analysis. DMA results showed that pectinase and microbe treated fibers have superior viscoelastic properties compared to alkali retting. XPS, Raman, FT-IR and biochemical analysis indicated that the controlled microbial and pectinase retting was ...
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The Effectiveness of a Professional Learning Community on Student Achievement in Elementary Reading and Mathematics in a Large Urban School District

The Effectiveness of a Professional Learning Community on Student Achievement in Elementary Reading and Mathematics in a Large Urban School District

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Date: May 2016
Creator: Landry, Jacqueline Hayles
Description: The study was to determine the impact of a Professional Learning Community on student achievement as measured by the state's criterion referenced reading and mathematics achievement tests. Data for this study were extracted from the school district's student database. Two cohorts of 90 students each were randomly selected from a population of approximately 600 students in 3 schools that participated in a Professional Learning Community (treatment) and 3 schools that did not (control). Professional Learning Communities known as PLCs, can serve as a major theoretical framework to promote the improvement of classroom teachers' instructional practice, teacher effectiveness and student achievement. Reading and mathemtics mean scale scores were extracted at three time points (year 1, year 2, and year 3) across three grades (grade 3, grade 4 and grade 5). Test for equality of variance found that no statistically significant difference existed between the mean scale scores of the two cohorts at the beginning of the study. The findings revealed that both cohorts trend toward increased academic achievement from year to year individually; however, when compared to each other, no statistically significant difference existed. Further research is indicated to examine each PLC for implementation, support and leadership as they relate to ...
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Effects of Auditor-provided Tax Services on Book-tax Differences and Investors’ Mispricing of Book-tax Differences

Effects of Auditor-provided Tax Services on Book-tax Differences and Investors’ Mispricing of Book-tax Differences

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Date: May 2015
Creator: Luo, Bing
Description: In this study, I investigate the effect of auditor-provided tax services (ATS) on firms’ levels of book-tax differences and investors’ mispricing of book-tax differences. The joint provision of audit and tax services has been a controversial issue among regulators and academic researchers. Evidence on whether ATS improve or impair the overall accounting quality is inconclusive as a result of the specific testing circumstances involved in different studies. Book-tax differences capture managers’ earnings management and/or tax avoidance intended to maximize reported financial income and to minimize tax expense. Therefore, my first research question investigates whether ATS improve or impair audit quality by examining the relation between ATS and firms’ levels of book-tax differences. My results show that ATS are negatively related to book-tax differences, suggesting that ATS improve the overall audit quality and reduce aggressive financial and/or tax reporting. My second research question examines whether the improved earnings quality for firms acquiring ATS leads to reduced mispricing of book-tax differences among investors. Recent studies document that despite the rich information about firms’ future earnings contained in book-tax differences, investors process such information inefficiently, leading to systematic pricing errors among firms with large book-tax differences. My empirical evidence indicates that ATS mitigate ...
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Effects of Quantum Coherence and Interference

Effects of Quantum Coherence and Interference

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Date: August 2013
Creator: Davuluri, Subrahmanya Bhima Sankar
Description: Quantum coherence and interference (QCI) is a phenomenon that takes place in all multi-level atomic systems interacting with multiple lasers. In this work QCI is used to create several interesting effects like lasing without inversion (LWI), controlling group velocity of light to extreme values, controlling the direction of propagation through non-linear phase matching condition and for controlling the correlations in field fluctuations. Controlling group velocity of light is very interesting because of many novel applications it can offer. One of the unsolved problems in this area is to achieve a slow and fast light which can be tuned continuously as a function of frequency. We describe a method for creation of tunable slow and fast light by controlling intensity of incident laser fields using QCI effects. Lasers are not new to the modern world but an extreme ultra-violet laser or a x-ray laser is definitely one of the most desirable technologies today. Using QCI, we describe a method to realize lasing at high frequencies by creating lasing without inversion. Role of QCI in creating correlations and anti-correlations, which are generated by vacuum fluctuations, in a three level lambda system coupled to two strong fields is discussed.
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Electrochemical Synthesis and Applications of Layered Double Hydroxides and Derivatives

Electrochemical Synthesis and Applications of Layered Double Hydroxides and Derivatives

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Date: August 2015
Creator: Kahl, Michael S.
Description: Layered double hydroxides (LDH) are a class of anionic clay with alternating layers of positive and negative charge. A metal hydroxide layer with divalent and trivalent metals with a positive charge is complemented by an interlayer region containing anions and water with a negative charge. The anions can be exchanged under favorable conditions. Hydrotalcite (Mg6Al2(OH)16[CO3]·4H2O) and other variations are naturally occurring minerals. Synthetic LDH can be prepared as a powder or film by numerous methods. Synthetic LDH is used in electrode materials, adsorbents, nuclear waste treatment, drug delivery systems, water treatment, corrosion protection coatings, and catalysis. In this dissertation Zn-Al-NO3 derivatives of zaccagnaite (Zn4Al2(OH)12[CO3]·3H2O) are electrochemically synthesized as films and applied to sensing and corrosion resistance applications. First, Zn-Al-NO3 LDH was potentiostatically electrosynthesized on glassy carbon substrates and applied to the electrochemical detection of gallic acid and caffeic acid in aqueous solutions. The modified electrode was then applied to the detection of gallic acid in green tea samples. The focus of the work shifts to corrosion protection of stainless steel. Modified zaccagnaite films were electrodeposited onto stainless steel in multiples layers to reduce defects caused by drying of the films. The films were deposited using a step potential method. The ...
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Electrochemically Deposited Metal Alloy-silicate Nanocomposite Corrosion Resistant Materials

Electrochemically Deposited Metal Alloy-silicate Nanocomposite Corrosion Resistant Materials

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Date: May 2013
Creator: Conrad, Heidi Ann
Description: Zinc-nickel ?-phase silicate and copper-nickel silicate corrosion resistant coatings have been prepared via electrochemical methods to improve currently available corrosion resistant materials in the oil and gas industry. A layered silicate, montmorillonite, has been incorporated into the coatings for increased corrosion protection. For the zinc nickel silicate coatings, optimal plating conditions were determined to be a working pH range of 9.3 -9.5 with a borate based electrolyte solution, resulting in more uniform deposits and better corrosion protection of the basis metal as compared to acidic conditions. Quality, strongly adhering deposits were obtained quickly with strong, even overall coverage of the metal substrate. The corrosion current of the zinc-nickel-silicate coating is Icorr = 3.33E-6 for a borate based bath as compared to a zinc-nickel bath without silicate incorporation (Icorr = 3.52E-5). Step potential and direct potential methods were examined, showing a morphological advantage to step potential deposition. The effect of borate addition was examined in relation to zinc, nickel and zinc-nickel alloy deposition. Borate was found to affect the onset of hydrogen evolution and was examined for absorption onto the electrode surface. For copper-nickel silicate coatings, optimal conditions were determined to be a citrate based electrolytic bath, with pH = 6. ...
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