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Computational Studies of C-H Bond Activation and Ethylene Polymerization Using Transition Metal Complexes

Description: This work discusses the C-H bond activation by transition metal complexes using various computational methods. First, we performed a DFT study of oxidative addition of methane to Ta(OC2H4)3A (where A may act as an ancillary ligand) to understand how A may affect the propensity of the complex to undergo oxidative addition. Among the A groups studied, they can be a Lewis acid (B or Al), a saturated, electron-precise moiety (CH or SiH), a σ-donor (N), or a σ-donor/π-acid (P). By varying A, we seek… more
Date: May 2019
Creator: Parveen, Riffat
Partner: UNT Libraries

Computational Studies of Catalysis Mediated by Transition Metal Complexes

Description: Computational methods were employed to investigate catalytic processes. First, DFT calculations predicted the important geometry metrics of a copper–nitrene complex. MCSCF calculations supported the open-shell singlet state as the ground state of a monomeric copper nitrene, which was consistent with the diamagnetic character deduced from experimental observations. The calculations predicted an elusive terminal copper nitrene intermediate. Second, DFT methods were carried out to investigate the … more
Date: May 2019
Creator: Jiang, Quan
Partner: UNT Libraries

Construction Management Methods and Techniques in Army Tactical Shelter

Description: This thesis presents a research effort aimed at developing using construction methods and techniques in army tactical shelter. The beginning step focuses on developing and identifying different activities and work breakdown structure applicable in shelter prototype. The next step focuses on identifying resource allocation. This include allocate resources based on the delivered project as per alternative one and for the second alternative as optimization, resource allocation modified and tried t… more
Date: December 2019
Creator: Yeganehtalab, Babak
Partner: UNT Libraries

Decision Making in Alternative Modes of Transportation: Two Essays on Ridesharing and Self-Driving Vehicles

Description: This manuscript includes an investigation of decision making in alternative modes of transportation in order to understand consumers' decision in different contexts. In essay 1 of this study, the motives for participation in situated ridesharing is investigated. The study proposes a theoretical model that includes economic benefits, time benefits, transportation anxiety, trust, and reciprocity either as direct antecedents of ridesharing participation intention, or mediated through attitude towa… more
Date: May 2019
Creator: Amirkiaee, Seyede Yasaman
Partner: UNT Libraries

Deep Learning Approach for Sensing Cognitive Radio Channel Status

Description: Cognitive Radio (CR) technology creates the opportunity for unlicensed users to make use of the spectral band provided it does not interfere with any licensed user. It is a prominent tool with spectrum sensing functionality to identify idle channels and let the unlicensed users avail them. Thus, the CR technology provides the consumers access to a very large spectrum, quality spectral utilization, and energy efficiency due to spectral load balancing. However, the full potential of the CR techno… more
Date: December 2019
Creator: Gottapu, Srinivasa Kiran
Partner: UNT Libraries

Defining Components Linked to Bacterial Nutritional Utilization of Cyanide as a Sole Nitrogen Source

Description: One of the challenges in biology is placing a function on the myriad of gene sequences having become available from rapid advances in genome sequencing. One such example is a gene cluster (Nit1C) found in bacteria that is tied to the unusual ability of certain bacteria to grow when supplied cyanide as the sole nitrogen source. The term cyanotrophs has been applied to such bacteria, for which a genetic linkage between cyanotrophy and Nit1C was demonstrated for 10 separate bacteria. In additio… more
Date: May 2019
Creator: Jones, Lauren Brittany
Partner: UNT Libraries

Depression, Religious Behaviors and Social Support as Predictors of Health-Related Quality of Life among HIV Positive Individuals

Description: The goal of the current study was to evaluate the ways in which religious behaviors and perceived social support are associated with the relationship between depressive symptoms and health-related quality of life for this group. We hypothesized (1) that religious behaviors moderate the relationship between depressive symptoms and health-related quality of life, (2) perceived social support mediates the relationship between depressive symptoms and health-related quality of life and (3) that reli… more
Date: December 2019
Creator: Davis, Cameron W
Partner: UNT Libraries

Design Method of Cold-Formed Steel Framed Shear Wall Sheathed by Structural Concrete Panel

Description: The objective of this research is developing a new method of design for cold-formed steel framed shear wall sheathed by ¾" thick USG structural panel concrete subfloor using a predictive analytical model and comparing the results obtained from the model with those achieved from real testing to verify the analytical model and predicted lateral load-carrying capacity resulted from that. Moreover, investigating the impact of various screw spacings on shear wall design parameter such as ultimate st… more
Date: December 2019
Creator: Ashkanalam, Aida
Partner: UNT Libraries

Design, Synthesis and Characterization of Polymer and Protein Coated Hybrid Nanomaterials: Investigation of Prototypes for Antimicrobial and Anticancer Applications

Description: This work involves synthesis and characterization of isotropic and anisotropic noble metal nanoparticles for applications ranging from antimicrobial uses to anticancer applications. These nanomaterials are stabilized in genuinely benign biomaterials ranging from polymers to cross linked proteins for targeted cancer treatments. The nanoparticles are found to have tunable optical properties.
Date: May 2019
Creator: Korir, Daniel Kiplangat
Partner: UNT Libraries

Development and Testing of Gold(I) and Europium(III) Based Sensors for Environmental Applications

Description: This dissertation focuses on the development, characterization, and analysis of luminescent materials and coatings for sensing applications, including CO2, heavy metals, and silver. Chapter 2 involves the use of a gold(I) pyrazolate trimer that is able to detect silver ions with an AgNP medium. Detection of silver is vital, because there is an influx of silver into our environment caused by the increased use of AgNP. Therefore, having a sensor that is able to differentiate between and detect on… more
Date: May 2019
Creator: Benton, Erin Nicole
Partner: UNT Libraries

Disasters, Smart Growth and Economic Resilience: An Empirical Analysis of Florida Cities

Description: This dissertation examines the relationship between economic resilience, disaster experience, and smart growth policies at the local government level. The study is based upon three research questions that examine spatial distribution of economic resilience in Florida cities, and examines the impact of disaster experience, and smart growth policies adopted by local governments on economic resilience. Based upon the bounce-forward approach (Cowell, 2013; Klein et al. 2003), economic resilience is… more
Date: August 2019
Creator: Chatterjee, Vaswati
Partner: UNT Libraries

Diverse Learners in the Classroom: Students with Special Needs Enrolled in Science, Technology, Engineering, and Mathematics (STEM) Texas Public Classrooms

Description: The purpose of this study was to determine if students with special needs participating in an inclusive classroom can learn the skills related to a STEM career as compared to the general student population. The study involved seventh grade students from two rural middle schools in north central Texas and was framed through a constructivist lens using a quasi-experimental design with a convenience sample. The Solenoid Invention Kit Assessment and the STEM Semantics Survey used in this study were… more
Date: August 2019
Creator: Briones, San Juanita G
Partner: UNT Libraries

Dynamic Deformation and Shear Localization in Friction-Stir Processed Al0.3CoCrFeNi and Fe50Mn30Co10Cr10 High-Entropy Alloys

Description: High entropy alloys (HEAs) are a relatively new class of solid solution alloys that contain multiple principal elements to take advantage of their high configurational entropy, sluggish diffusion, lattice distortion, and the cocktail effect. In recent development, work hardening mechanisms known as twinning induced plasticity (TWIP) and transformation induced plasticity (TRIP) have been found active in Al0.3CoCrFeNi (molar fraction) and Fe50Mn30Co10Cr10 (at %) HEA compositions. Friction-stir pr… more
Date: August 2019
Creator: Macdonald, Neil
Partner: UNT Libraries

The Effect of Processing Conditions on the Surface Morphology of Few-Layered WS2 Thin Films

Description: Recent progress in layered transition metal dichalcogenides (TMDs) has led to various promising electronic and optoelectronic applications. However, the structure of materials plays a critical role in electronic and optoelectronic devices, and determines performance. Electronic and optoelectronic devices typically consist of multiple layers that form electrical homojunctions or heterojunctions. Therefore, in a device it can be expected that a WS2 layer may serve as the substrate for a subseque… more
Date: May 2019
Creator: Cai, Bimin
Partner: UNT Libraries

The Effect of Trauma Experiences and PTSD Severity on Positive Memory Recall and Memory Phenomenology

Description: Positive memories play an important role in the etiology and maintenance of posttraumatic stress disorder (PTSD). Additionally, there are potential clinical benefits of recalling positive memories on affect, cognitions, and behaviors. However, most research/clinical work has focused on the role of traumatic memories in PTSD's symptomatology and treatment. The current study examined positive memory recall difficulties and positive memory phenomenology among 185 trauma-exposed individuals with va… more
Date: May 2019
Creator: Dolan, Megan
Partner: UNT Libraries

The Effects of Benefit Types on Customer Loyalty in Integrated Resorts

Description: This study examined the relationships between the six benefit types and customer loyalty through trust and satisfaction in integrated resorts. A self-administered survey was developed based on previous studies in customer loyalty and was distributed through e-Reward online survey panel. The findings showed that only financial gaming benefits, functional gaming benefits, and psychological non-gaming benefits had impacts on customer attitudinal loyalty and customer behavioral loyalty through trus… more
Date: August 2019
Creator: Su, Hsiang Wen
Partner: UNT Libraries

Effects of Telepractice for Training Autism Teachers to Contrive Motivating Operations

Description: The rising rate of the autism spectrum disorders (ASD) has resulted in challenges for teachers in public schools, concerning the delivery of evidence-based practices for superior outcomes. Thus, school districts are in need of professional learning options that can be efficiently and effectively delivered to improve the procedural fidelity of interventions. The purpose of this study is to demonstrate the effectiveness of using telepractice to teach autism teachers how to contrive motivating o… more
Date: May 2019
Creator: Shearer, Carin R
Partner: UNT Libraries

The Effects of the IAM Workshop on Preservice Teachers' Perceptions and Attitudes on Integrating Art and Mathematics In Saudi Arabia

Description: This mixed-methods dissertation used an explanatory sequential design to examine art and mathematics preservice teachers' perceptions and attitudes towards integrating art and mathematics (IAM) after an IAM workshop. The conceptual framework of this study has its basis in three theoretical sources: constructivism, multiple intelligence theory, and semiotics. Each of these sources provides a conceptual lens to examine art integration in the curriculum and the teacher's role in facilitating this … more
Date: August 2019
Creator: Mereie, Iman Ali
Partner: UNT Libraries

Electrochemical Deposition of Metal Organic-Modified-Ceramic Nanoparticles to Improve Corrosion and Mechanical Properties

Description: Corrosion is an unstoppable process that occurs spontaneously in many areas of industry, specially, oil and gas industries. Therefore, the need of developing protective coating to lower the cost of corrosion is very consistent. Among different methods, electrodeposition has been a popular method since it offer many advantages such as low cost, ability to control the surface and thickness of the coating, ability to perform at low temperature and pressure, and very convenience. Ceramic nanopartic… more
Date: August 2019
Creator: Ngo, Ngan Kim
Partner: UNT Libraries

Enhanced Approach for the Classification of Ulcerative Colitis Severity in Colonoscopy Videos Using CNN

Description: Ulcerative colitis (UC) is a chronic inflammatory disease characterized by periods of relapses and remissions affecting more than 500,000 people in the United States. To achieve the therapeutic goals of UC, which are to first induce and then maintain disease remission, doctors need to evaluate the severity of UC of a patient. However, it is very difficult to evaluate the severity of UC objectively because of non-uniform nature of symptoms and large variations in their patterns. To address this,… more
Date: August 2019
Creator: Sure, Venkata Leela
Partner: UNT Libraries

Enhancing Storage Dependability and Computing Energy Efficiency for Large-Scale High Performance Computing Systems

Description: With the advent of information explosion age, larger capacity disk drives are used to store data and powerful devices are used to process big data. As the scale and complexity of computer systems increase, we expect these systems to provide dependable and energy-efficient services and computation. Although hard drives are reliable in general, they are the most commonly replaced hardware components. Disk failures cause data corruption and even data loss, which can significantly affect system per… more
Date: May 2019
Creator: Huang, Song
Partner: UNT Libraries

Ensemble Singing in the Bel Canto Salon Repertory: A Pedagogical Reconsideration

Description: Vocal duets have had a long history in the Western classical music tradition. Their use as a teaching resource can be traced back to the Renaissance, where duets were used for the development of singing, performance, and musicianship. In the late 19th and all of the 20th centuries, this pathway of vocal pedagogy has markedly declined. This study proposes a reintroduction of this methodology of teaching, asserting that it provides the collegiate vocal student with maximum opportunity for growth … more
Date: December 2019
Creator: Brown, Shaun (Shaun Joseph)
Partner: UNT Libraries

An Exploration of Professional Training and Professional Practice: Title IX Administrators and Meaning Making

Description: Federal law requires institutions to designate campus-based administrators to oversee Title IX processes and investigations, but little is known about how these have been professionally prepared for their roles. The purpose of this study was to understand the professional preparation, educational experiences, and professional training of Title IX administrators and to understand their independence in decision-making in those roles. This study utilized qualitative content analysis and a social c… more
Date: December 2019
Creator: Razo, Demesia
Partner: UNT Libraries
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