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 Decade: 2010-2019
 Collection: UNT Theses and Dissertations
9-Lipoxygenase Oxylipin Pathway in Plant Response to Biotic Stress
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The activity of plant 9-lipoxygenases (LOXs) influences the outcome of Arabidopsis thaliana interaction with pathogen and insects. Evidence provided here indicates that in Arabidopsis, 9-LOXs facilitate infestation by Myzus persicae, commonly known as the green peach aphid (GPA), a sap-sucking insect, and infection by the fungal pathogen Fusarium graminearum. in comparison to the wild-type plant, lox5 mutants, which are deficient in a 9-lipoxygenase, GPA population was smaller and the insect spent less time feeding from sieve elements and xylem, thus resulting in reduced water content and fecundity of GPA. LOX5 expression is induced rapidly in roots of GPA-infested plants. This increase in LOX5 expression is paralleled by an increase in LOX5-synthesized oxylipins in the root and petiole exudates of GPA-infested plants. Micrografting experiments demonstrated that GPA population size was smaller on plants in which the roots were of the lox5 mutant genotype. Exogenous treatment of lox5 mutant roots with 9-hydroxyoctadecanoic acid restored water content and population size of GPA on lox5 mutants. Together, these results suggest that LOX5 genotype in roots is critical for facilitating insect infestation of Arabidopsis. in Arabidopsis, 9-LOX function is also required for facilitating infection by F. graminearum, which is a leading cause of Fusarium head blight (FHB) disease in wheat and other small grain crops. Loss of LOX1 and LOX5 function resulted in enhanced resistance to F. graminearum infection. Similarly in wheat, RNA interference mediated silencing of the 9-LOX homolog TaLpx1, resulted in enhanced resistance to F. graminearum. Experiments in Arabidopsis indicate that 9-LOXs promote susceptibility to this fungus by suppressing the activation of salicylic acid-mediated defense responses that are important for basal resistance to this fungus. the lox1 and lox5 mutants were also compromised for systemic acquired resistance (SAR), an inducible defense mechanism that is systemically activated throughout a plant in response to a localized infection. the lox1 and lox5 mutants exhibited reduced cell death and delayed hypersensitive response when challenged with an avirulent strain of the bacterial pathogen Pseudomonas syringae pv tomato. LOX1 and LOX5 functions were further required for the synthesis as well as perception of a SAR-inducing activity present in petiole exudates collected from wild-type avirulent pathogen-challenged leaves. Taken together, results presented here demonstrate that 9-LOX contribute to host susceptibility as well as defense against different biotic stressors. digital.library.unt.edu/ark:/67531/metadc115127/
American Blitzkrieg: Courtney Hodges and the Advance Toward Aachen (August 1 - September 12, 1944)
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This is an analysis of combat operations of US First Army under the command of Courtney Hodges, between August 1 and September 12, 1944, with an emphasis upon 1st, 4th, 9th, and 30th Divisions. However, other formations are necessarily discussed in order to maintain context. Indeed, many historians have failed to emphasize the complex interdependent nature of these efforts, and the traditional narrative has been distorted by inadequate situational awareness. This study argues that the army's operations were exceedingly difficult, resulting in approximately 40,000 casualties over a six week period. Although historians claim that the Germans were essentially defeated by the end of July, and that the Allied advance was subsequently halted by logistical difficulties, the official combat records clarify that logistical shortages were a tertiary factor, as the enemy remained capable of strong resistance. Consequently, defensive efforts were the primary factor hindering the advance, in conjunction with deteriorating weather conditions, rugged terrain, and surprisingly severe traffic congestion. Although this was mobile warfare, military theorists have overestimated the effectiveness of mechanization and underestimated the potential for antitank defenses. Ultimately, this study asserts that First Army was the primary American combat formation, and historians have exaggerated the importance of George Patton's Third Army. Therefore, in order to understand an American way of war, the combat operations of First Army deserve far more attention than they have previously received. This narrative thus emphasizes forgotten battles, including: Tessy, St. Sever, Tete, Perriers, Mayenne, Ranes, Flers, Mace, Elbeuf, Mantes, Corbeil, Sevran, Mons, Cambrai, Philippeville, Dinant, and Aubel. digital.library.unt.edu/ark:/67531/metadc177245/
Americans Who Would Not Wait: The American Legion of the Canadian Expeditionary Force, 1915-1917
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This dissertation examines the five battalions of the Canadian Expeditionary Force designated as the American Legion. Authorized in Canada between 1915 and 1917, these units were formed to recruit volunteers from the United States to serve in the Canadian Overseas Contingent during the First World War. This work reviews the organization of Canada’s militia and the history of Anglo-American relations before examining the Canadian war effort, the formation of the American Legion, the background of its men, and the diplomatic, political, and constitutional questions that it raised. Much of the research focuses on the internal documents of its individual battalions (the 97th, 211th, 212th, 213th and 237th) and the papers of Reverend Charles Bullock now housed at the Public Archives of Canada. Documentation for the diplomatic furor the American Legion caused comes largely through the published diplomatic documents, British Foreign Office records held at the Public Record Office at Kew, and United States Department of State files at the National Archives at College Park, Maryland. The most useful sources for American Legion correspondence are the Beaverbrook papers held at the House of Lords Record Office, the papers of Canadian Prime Minister Sir Robert Laird Borden, and those of the Governor-General, the Duke of Connaught found in the Public Archives of Canada. During its brief existence the American Legion precipitated diplomatic and political problems in the United States, the United Kingdom, and the Dominion of Canada. Among the issues raised by the controversy surrounding the American Legion were: the relationship between the dominion government in Canada and the British government; the structural problems of imperial communications; the rise of a Canadian national identity and the desire for greater autonomy; and, the nature of citizenship and expatriation. This dissertation is also a long overdue account of the thousands of United States citizens who left their homes and families to join the American Legion in order to fight another country’s war. digital.library.unt.edu/ark:/67531/metadc177171/
Anchor Nodes Placement for Effective Passive Localization
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Wireless sensor networks are composed of sensor nodes, which can monitor an environment and observe events of interest. These networks are applied in various fields including but not limited to environmental, industrial and habitat monitoring. In many applications, the exact location of the sensor nodes is unknown after deployment. Localization is a process used to find sensor node's positional coordinates, which is vital information. The localization is generally assisted by anchor nodes that are also sensor nodes but with known locations. Anchor nodes generally are expensive and need to be optimally placed for effective localization. Passive localization is one of the localization techniques where the sensor nodes silently listen to the global events like thunder sounds, seismic waves, lighting, etc. According to previous studies, the ideal location to place anchor nodes was on the perimeter of the sensor network. This may not be the case in passive localization, since the function of anchor nodes here is different than the anchor nodes used in other localization systems. I do extensive studies on positioning anchor nodes for effective localization. Several simulations are run in dense and sparse networks for proper positioning of anchor nodes. I show that, for effective passive localization, the optimal placement of the anchor nodes is at the center of the network in such a way that no three anchor nodes share linearity. The more the non-linearity, the better the localization. The localization for our network design proves better when I place anchor nodes at right angles. digital.library.unt.edu/ark:/67531/metadc33132/
Aphorismen, Capriccio, and Heptameron for Piano Solo By Jürg Baur: a Performer's Guide
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The purpose of this dissertation is to give instruction regarding the performance of three important piano works by Jürg Baur (1918-2010). Aphorismen, Capriccio, and Heptameron stand out as his most significant piano works both because of their length and because of their pianistic complexity. Since Baur had a successful career as both teacher and composer during his lifetime, his acclaimed works received many honors in Germany. His works can be performed by intermediate to advanced students. Intermediate students can easily offer simpler pieces like Aphorismen in competitions, while pieces like Capriccio and Heptameron better are suited to a more advanced level. Although some of his compositions are difficult to perform compared with other modern German works, Baur's music is more accessible. In the article, "Auf der Spuren der alten Zeit" Baur is quoted to state that Paul Hindemith and Bela Bartok's music influenced his own compositional ideas. However, although Baur is a modern composer, he didn't write in a totally atonal style, but rather attempted to broaden tonality. While Heptameron is atonal, Aphorismen and Capriccio give the impression of tonality, thus they are more accessible to the audience. I was fortunate enough to study Aphorismen with Baur as well as receiving advice for performance of Capriccio and some movements of Heptameron. Therefore, I gained a primary source of instruction, particularly in regards to pedal markings, rhythmic indications, voice balancing, finger suggestions, articulation markings, and tone of musical expression. In this dissertation, I include my own instructions (accepted by the composer) along with the composer's intentions. digital.library.unt.edu/ark:/67531/metadc177239/
An Assessment of Consumers' Willingness to Patronize Foreign-Based Business Format Franchises: An Investigation in the Fast-Food Sector
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This study aimed to address consumers' stereotypical categorizations in the form of essentialist views about foreign cultures and their effect on individual consumers, including their negative or aroused emotions and subsequent retail patronage behaviors. The research mission was to empirically assess the salient dimensions of consumers' states of mind (positive and negative affect, psychological essentialism, epistemic curiosity), states of being (store atmospherics), and states of action (retail patronage behaviors) in a cultural context based on Mehrabian-Russell theory of environmental psychology. Specifically, the retail patronage setting was selected as foreign-based fast-food franchises because it represents both a relevant and timely situational context for consumer behavior. This dissertation makes several contributions to international retail patronage literature. First, it frames curiosity as an aroused emotional state and finds support for the relationship between consumer epistemic curiosity and retail patronage. Second, it provides support for the linkage between consumer affect and retail patronage in an international retail setting. Third, it reveals that affect has a greater impact on retail patronage than epistemic curiosity. The overarching finding of this study is an inability to tie the cultural elements in retail atmospherics, including signs, symbols, and artifacts, to consumer emotions. In addition, we were unable to frame psychological essentialism as a personality trait that would reduce the levels of affect and curiosity in retail store environments characterized by foreign-cultural elements. digital.library.unt.edu/ark:/67531/metadc28417/
Between Comancheros and Comanchería: a History of Fort Bascom, New Mexico
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In 1863, Fort Bascom was built along the Canadian River in the Eroded Plains of Territorial New Mexico. Its unique location placed it between the Comanches of Texas and the Comancheros of the Sangre de Cristo Mountains. This post was situated within Comanchería during the height of the United States Army's war against the Southern Plains Indians, yet it has garnered little attention. This study broadens the scholarly understanding of how the United States Army gained control of the Southwest by examining the role Fort Bascom played in this mission. This includes an exploration of the Canadian River Valley environment, an examination of the economic relationship that existed between the Southern Plains Indians and the mountain people of New Mexico, and an account of the daily life of soldiers posted to Fort Bascom. This dissertation thus provides an environmental and cultural history of the Canadian River Valley in New Mexico, a social history of the men stationed at Fort Bascom, and proof that the post played a key role in the Army's efforts to gain control of the Southern Plains Indians. This study argues that Fort Bascom should be recognized as Texas' northern-most frontier fort. Its men were closer to the Comanche homeland than any Texas post of the period. Its records clearly show that the Army used Fort Bascom as a key forward base of operations against Comanches and Kiowas. An examination of Bascom's post returns, daily patrols, and major expeditions allows its history to provide a useful perspective on the nineteenth-century American Southwest. digital.library.unt.edu/ark:/67531/metadc283832/
Can These Bones Live? A Collection of Stories
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The collection concerns itself with race, gender, masculinity, marginalization, the act of violence as a means of self expression, identity and the performance of identity, love, and loss. The collection also uses historical events-more specifically, events that are central to black culture in Northeast, Ohio- to situate the characters and witness their response to these historical events. I strive to illustrate blackness as both political and fragmented with the characters in my collection. My characters believe that what they are doing-exacting violence, abusing women, disrespecting each other- is somehow the normative; that somehow what it is that they have learned is how they should perform black identity. digital.library.unt.edu/ark:/67531/metadc28431/
Challenge the Silence
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This collection of personal essays about incest, abuse, and depression explores the lasting effects of an invisible childhood. The essays follow the protagonist from the age of five to her early twenties. Her brother, at a young age, becomes sexually abusive of her and her sisters, and her parents fail to protect their daughters. The family is divided as the older girls strive to defend their little sisters, while their parents attempt to excuse their son. When her brother is finally sent away, the protagonist is left to salvage what remains of her relationships with her parents. digital.library.unt.edu/ark:/67531/metadc283840/
Child Rescue As Survival Resistance: Hidden Children in Nazi-occupied Western Europe
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The phenomenon of rescue organizations that devoted themselves specifically to hiding and saving Jewish children appeared throughout Nazi-occupied Western Europe (France, Belgium, and the Netherlands). Jewish and non-Jewish rescuers risked their lives to save thousands of children from extermination. This dissertation adds to the historiographical understanding of Holocaust resistance by analyzing the efforts of these child rescue organizations as a form of “survival resistance.” Researching the key aspects of traditional resistance (conscious intent, extensive organization, and effective turn-out) demonstrates that, while child rescue did not present armed resistance, it still was a form of active resistance against the Nazi Final Solution. By looking at rescuers’ testimonies and archival sources (from Yad Vashem, United States Holocaust Memorial Museum, Centre de documentation juive contemporaine, and Kazerne Dossin), this dissertation first outlines the extensive organization and intent of Jewish rescue groups, such as the Oeuvre de Secours aux Enfants (OSE) and Comité de défense des Juifs (CDJ), in France, Belgium, and the Netherlands. The second part looks at rescue organization and intent by Catholic, Protestant, and humanitarian groups. The dissertation concludes by discussing the effectiveness of organized child rescue. In the end, the rescue groups saved thousands of children and proofs that Child rescue in Nazi-occupied Western Europe was a valid--not to mention heroic--form of survival resistance. digital.library.unt.edu/ark:/67531/metadc149581/
The Chopin Etudes: a Study Guide for Teaching and Learning Opus 10 and Opus 25
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The etudes of Chopin are masterworks of the piano literature and are designed to go beyond mere technical exercises; moreover, each etude represents not only a technical study but also has a distinct musical character. Alarmingly, the current trend seems to be to assign the Chopin etudes at an increasingly young age to students who are not yet equipped either technically or musically to handle them. As Chopin’s pupil, Carl Mikuli, commented in the preface to his Chopin edition, the etudes were meant for “more advanced students.” If Chopin had intended his etudes for students at an intermediate level, he would have assigned them to most of his students; however, only a limited number of students had his permission to work on their master’s etudes. As a teacher, I have always felt the need to devise a systematic teaching plan to guide students to handle the challenges of these pieces both physically and musically. This study examines the repertoire which might help prepare a student to learn the etudes without overstraining his/her muscular and mental ability. Rooted in Chopin’s teaching and his recommendation of the pieces to learn before tackling the etudes themselves, this pedagogical study guide intends to help students and teachers to work progressively towards the study of these works. While pinpointing some exercises and simple pieces to assign to a student in preparation for studying the individual etudes, helpful works of later composers are also liberally incorporated, as well as some suggestions for practicing the etudes themselves. Finally, I shall provide my own “re-ordering” of the etudes, with a progressive degree of difficulty, as an additional aid to a young pianist who may eventually want to learn the entire opus 10 and opus 25. digital.library.unt.edu/ark:/67531/metadc115039/
A Chorus of Trees
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This two-part thesis includes a critical preface and a collection of my poems. Using three poems-Louise Glück's "Lullaby," Bob Hicok's "Poem for My Mother's Hysterectomy," and Nick Flynn's "Memento Mori"-the critical preface examines how, in poetry, the transformation of a body negotiates trauma and triggers a conceptual shift, the creation and revision of identity, and the release of the duende's inspirational force. The collection of poetry that follows seeks to transfigure the body as a way to explore the nuanced traumas of human experience. digital.library.unt.edu/ark:/67531/metadc30485/
The Correlates of Number of Minority Faculty, Minority Student Organizations, Diversity Course Offerings, and Geographic Location to Minority Student Enrollment in Texas Colleges
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This study examined the correlates between the dependent variables African-American and Hispanic student enrollment in Texas public higher education to the independent variables institution type, education region, faculty demographics, curricular offerings and student organizations. Data for African-American (n = 124,000) and Hispanic enrollment (n = 314,000) in all Texas public higher education institutions (n = 109) for the 2008 academic year were examined. Significant results, using a statistical significance of p = .005, were reported for two of the variables. A correlation of Pearson's r = .946 and statistical significance of p = .000 was observed between African-American student enrollment and the percentage representation of African-American faculty in the same institution. A correlation of Pearson's r = .982 and statistical significance of p = .000 was observed between Hispanic student enrollment and the percentage representation of Hispanic faculty in the same institution. The results of this study found significant relationships between the presence of African-American and Hispanic faculty and enrollment of African-American and Hispanic students. Recommendations are made for exploring these findings in further detail. digital.library.unt.edu/ark:/67531/metadc33131/
Cosmology, Extraterrestrial Life, and the Development and Character of Western European Thought in the Seventeenth and Eighteenth Centuries
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Cosmology, as an all-encompassing theoretical construction of universal reality, serves as one of the best indicators for a variety of philosophical, scientific, and cultural values. Within any cosmological system, the question of extraterrestrial life is an important element. Mere existence or nonexistence, however, only exposes a small portion of the ideological significance behind the contemplation of life outside of earth. The manners by which both believers and disbelievers justify their opinions and the ways they characterize other worlds and their inhabitants show much more about the particular ideas behind such decisions and the general climate of thought surrounding those who consider the topic. By exploring both physical and abstract structures of the universe, and specifically concepts on the plurality of worlds and extraterrestrial life, Western European thought in the seventeenth and eighteenth centuries reveals not an era of pure advancement and modernization, but as a time of both tradition and change. digital.library.unt.edu/ark:/67531/metadc84276/
The Counterinsurgency Dilemma: The Causes and Consequences of State Repression of Human Rights in Civil Wars
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In this project a theory of adaptive differential insurgency growth by the mechanism of repression driven contagion is put forth to explain variation in the membership and spatial expansion of insurgencies from 1981 to 1999. As an alternative to the dominant structural approaches in the civil war literature, Part 1 of the study proposes an interactive model of insurgency growth based on Most and Starr's opportunity and willingness framework. The findings suggest that state capacity, via its impact on state repressive behavior, plays an important gatekeeping function in selecting which minor insurgencies can grow into civil war, but contributes little to insurgency growth directly. In Part 2 of the study, I directly examine variation in insurgency membership and geographical expansion as a function of repression driven contagion. I find that repression increases the overall magnitude of insurgency activity within states, while at the same time reducing the density of insurgency activity in any one place. Despite an abundance of low intensity armed struggles against a highly diverse group of regimes around the world, I find an extremely strong and robust regularity: where repression is low - insurgencies don't grow. digital.library.unt.edu/ark:/67531/metadc28464/
Cuff-less Blood Pressure Measurement Using a Smart Phone
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Blood pressure is vital sign information that physicians often need as preliminary data for immediate intervention during emergency situations or for regular monitoring of people with cardiovascular diseases. Despite the availability of portable blood pressure meters in the market, they are not regularly carried by people, creating a need for an ultra-portable measurement platform or device that can be easily carried and used at all times. One such device is the smartphone which, according to comScore survey is used by 26.2% of the US adult population. the mass production of these phones with built-in sensors and high computation power has created numerous possibilities for application development in different domains including biomedical. Motivated by this capability and their extensive usage, this thesis focuses on developing a blood pressure measurement platform on smartphones. Specifically, I developed a blood pressure measurement system on a smart phone using the built-in camera and a customized external microphone. the system consists of first obtaining heart beats using the microphone and finger pulse with the camera, and finally calculating the blood pressure using the recorded data. I developed techniques for finding the best location for obtaining the data, making the system usable by all categories of people. the proposed system resulted in accuracies between 90-100%, when compared to traditional blood pressure meters. the second part of this thesis presents a new system for remote heart beat monitoring using the smart phone. with the proposed system, heart beats can be transferred live by patients and monitored by physicians remotely for diagnosis. the proposed blood pressure measurement and remote monitoring systems will be able to facilitate information acquisition and decision making by the 9-1-1 operators. digital.library.unt.edu/ark:/67531/metadc115102/
Culture and self-representation in the Este court: Ercole Strozzi's funeral Elegy of Eleonora of Aragon, a Text, Translation, and Commentary.
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This dissertation presents a previously unedited text by one of the most distinguished- yet neglected-Latin writers of the Italian Renaissance, Ercole Strozzi (1471-1508), a poet and administrator in the court of Ferrara. Under the Este Dukes, Ferrara became a major center of literary and artistic patronage. The Latin literary output of the court, however, has received insufficient scholarly scrutiny. The text is a verse funeral elegy of Eleonora of Aragon (1450-1493), the first Duchess of Ferrara. Eleonora was a remarkable woman whose talents and indefatigable efforts on behalf of her husband, her children, and her state, won her accolades both at home and abroad. She also served as a prototype for the remarkable careers of her two daughters, Isabella d'Este, and Beatrice d'Este, who are celebrated for their erudition and patronage of arts and letters. The text is a mirror of the Estense court and reveals to us how its members no doubt saw themselves, at the very peak of its temporal power and the height of its prestige as a center of cultural creativity. It is also important for the striking portrait it presents of Eleonora. Ercole Strozzi chose to call his poem an epicedium, an ancient minor literary genre that had received attention in the two decades prior to its composition, due to the discovery and printing of the silver age Roman poet Statius, whose text includes several epicedia. Strozzi deftly adapts and transcends both his ancient and contemporary models (especially Poliziano), and in the process, creates a new Latin literary genre, the Renaissance epicedium. It is a fine poem, full of both erudition and creativity, and as such is the first fruits of what would be Ercole Strozzi's illustrious poetic career. The work is genuinely worthy of study on both esthetic and historical grounds. digital.library.unt.edu/ark:/67531/metadc33223/
Data Compression Using a Multi-residue System (Mrs)
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This work presents a novel technique for data compression based on multi-residue number systems. The basic theorem is that an under-determined system of congruences could be solved to accomplish data compression for a signal satisfying continuity of its information content and bounded in peak-to -peak amplitude by the product of relatively prime moduli,. This thesis investigates this property and presents quantitative results along with MATLAB codes. Chapter 1 is introductory in nature and Chapter 2 deals in more detail with the basic theorem. Chapter 3 explicitly mentions the assumptions made and chapter 4 shows alternative solutions to the Chinese remainder theorem. Chapter 5 explains the experiments in detail whose results are mentioned in chapter 6. Chapter 7 concludes with a summary and suggestions for future work. digital.library.unt.edu/ark:/67531/metadc149639/
Dead Fox Run: A Collection of Stories
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This collection consists of a critical preface and five linked short stories. The preface analyzes the usage of violence in literate and other forms of media, and specifically the ways in which literature can address violence without aggrandizing or stylizing it. The stories explore this idea through the lens of the lives of two young men, following them from boyhood marked by violence to adulthood crushed by the trauma of the American Civil War. Collection includes the stories "Dead Foxes," "Cow Pen," "Fatherless," "Woodsmoke," and "Brotherhood." digital.library.unt.edu/ark:/67531/metadc68046/
Design, Synthesis and Screening of Homoleptic and Heteroleptic Platinum(ii) Pyridylazolate Complexes for N-type Semiconducting and Light-emitting Devices
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A series of heteroleptic and homoleptic platinum(II) complexes has been synthesized and characterized towards their use in thin film devices such as organic light-emitting diodes (OLEDs) and organic thin film transistors (OTFTs). Pyridylpyrazolate- and pyridyltetrazolate-containing ligands were selected due to their structural rigidity and ease of functionalization. Single-crystal x-ray diffraction studies of two selected heteroleptic complexes show strong aggregation with preferential stacking into vertical columns with a varying degree of overlap of the neighboring square planar molecular units. It is shown that the close proximity of the molecules to one another in the stack increases semiconducting character, phosphorescence quantum yields, and shorter radiative lifetimes. The potential for these materials towards incorporation into high-efficiency doping free white OLEDs (DFW-OLEDs) for solid-state lighting and display applications has been realized and will be expanded upon by present and future embodiments of materials in this thesis. digital.library.unt.edu/ark:/67531/metadc283853/
Determinants of Mental Health Problems Among College Students
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Many college students have reported struggling with mental health problems while dealing with challenging demands of college. The initial theoretical framework for this research was Pearlin's stress process model (SPM). Building on the SPM, the three additional mediating variables of perceived control, meaninglessness, and financial worries were added to create a composite model for the research. Mental health outcomes in the model were measured by a comprehensive range of factors, which included: psychological distress, suicide, substance abuse, and anger. Data were collected from a non-probability convenience sample of 463 undergraduate students attending a large state supported university in the southwestern region of the United States. Among the social status variables measured, being married, female, and white were significant predictors of poor mental health in the sampled college students. Poor self-image, feeling of meaninglessness, and worrying about current and future finances were significant mediating variables. Poor mental health could make individuals overwhelmed and discouraged. This is a formula for failure in college. The results of this study contribute to a better understanding of the correlates of mental health problems among college students. A greater understanding means that families and college administrations will have better ideas about how to intervene to reduce the stress of students and to focus the available and often limited resources to help young adults in their college experience. digital.library.unt.edu/ark:/67531/metadc33227/
Development of Indium Oxide Nanowires as Efficient Gas Sensors
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Crystalline indium oxide nanowires were synthesized following optimization of growth parameters. Oxygen vacancies were found to impact the optical and electronic properties of the as-grown nanowires. Photoluminescence measurements showed a strong U.V emission peak at 3.18 eV and defect peaks in the visible region at 2.85 eV, 2.66 eV and 2.5 eV. The defect peaks are attributed to neutral and charged states of oxygen vacancies. Post-growth annealing in oxygen environment and passivation with sulphur are shown to be effective in reducing the intensity of the defect induced emission. The as-grown nanowires connected in an FET type of configuration shows n-type conductivity. A single indium oxide nanowire with ohmic contacts was found to be sensitive to gas molecules adsorbed on its surface. digital.library.unt.edu/ark:/67531/metadc103318/
Development of Silicon Nanowire Field Effect Transistors
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An economically reliable technique for the synthesis of silicon nanowire was developed using silicon chloride as source material. The 30-40 micron long nanowires were found to have diameters ranging from 40 – 100 nm. An amorphous oxide shell covered the nanowires, post-growth. Raman spectroscopy confirmed the composition of the shell to be silicon-dioxide. Photoluminescence measurements of the as-grown nanowires showed green emission, attributed to the presence of the oxide shell. Etching of the oxide shell was found to decrease the intensity of green emission. n-type doping of the silicon nanowires was achieved using antimony as the dopant. The maximum dopant concentration was achieved by post-growth diffusion. Intrinsic nanowire parameters were determined by implementation of the as-grown and antimony doped silicon nanowires in field effect transistor configuration. digital.library.unt.edu/ark:/67531/metadc103364/
Device Engineering for Enhanced Efficiency from Platinum(II) Phosphorescent OLEDs
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Phosphorescent organic light emitting diodes (PHOLEDs) based on efficient electrophosphorescent dopant, platinum(II)-pyridyltriazolate complex, bis[3,5-bis(2-pyridyl)-1,2,4-triazolato]platinum(II) (Pt(ptp)2) have been studied and improved with respect to power efficiency, external efficiency, chromacity and efficiency roll-off. By studying the electrical and optical behavior of the doped devices and functionality of the various constituent layers, devices with a maximum EQE of 20.8±0.2 % and power efficiency of 45.1±0.9 lm/W (77lm/W with luminaries) have been engineered. This improvement compares to devices whose emission initially could only be detected by a photomultiplier tube in a darkened environment. These devices consisted of a 65 % bis[3,5-bis(2-pyridyl)-1,2,4-triazolato]platinum(II) (Pt(ptp)2) doped into 4,4'-bis(carbazol-9-yl)triphenylamine (CBP) an EML layer, a hole transporting layer/electron blocker of 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC), an electron transport layer of 1,3,5-tris(phenyl-2-benzimidazolyl)-benzene (TPBI), and a LiF/Al cathode. These devices show the acceptable range for warm white light quadrants and qualify to be called "warm white" even w/o adding another emissive layer. Dual EML devices composed of neat Pt(ptp)2 films emitting orange and CBP: Pt(ptp)2 film emitting blue-green produced a color rendering index (CRI) of 59 and color coordinates (CIE) of (0.47,0.49) at 1000Cd/m² with power efficiency of 12.6±0.2 lm/W and EQE of 10.8±0.2 %. Devices with two blue fluorescent emission layers as singlet filters and one broad yellow emission layer from CBP: Pt(ptp)2 displayed a CRI of 78 and CIE of (0.28,0.31) at 100Cd/m² with maximum power efficiency of 6.7±0.3 lm/W and EQE of 5.7±0.2 %. digital.library.unt.edu/ark:/67531/metadc30482/
Dolores Dyer: Women's Basketball and the American Dream
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Dolores Dyer played from 1952-1953 for the Texas Cowgirls, a barnstorming women's basketball team that provided a form of entertainment popular throughout the United States in that era. The story of Dyer's life demonstrates how a woman could attempt to achieve the American dream—a major theme in American history—through success in athletic competition. Dyer's participation with the Texas Cowgirls also provides a look into the circumstances that limited women's participation in professional sport during the mid-twentieth century. Women's sports studies, although some are very thorough, have gaps in the research, and women's barnstorming basketball is one of the areas often overlooked. In light of this gap, this thesis relies on a variety of sources, including primary documents from unpublished collections, archived materials, and original oral histories from several members of the Texas Cowgirls team. This thesis contains analysis of the socioeconomic factors that influenced Dolores Dyer's maturation into a professional basketball player, examines what the American dream meant to her, and evaluates the extent to which she achieved it. Overall, it constructs a social history that can serve as a foundational source for further study of women in sports during the twentieth century. digital.library.unt.edu/ark:/67531/metadc177246/
Dream of a Thousand Keys: A Concerto for Piano and Orchestra
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Dream of a Thousand Keys is a concerto for piano and orchestra, which consists of four movements presenting multiple dimensional meanings as suggested by the word "key." I trace the derivation of Korean traditional rhythmic cycles and numerical sequences, such as the Fibonacci series, that are used throughout the work, and explore the significant role of space between the soloist and piano that are emphasized in a theatrical aspect of the composition. The essay addresses the question of musical contrasts, similarities, and metamorphosis. Lastly, I cover terms and concepts of significant 21st-century compositional techniques that come into play in the analysis of this work. digital.library.unt.edu/ark:/67531/metadc67968/
A Driver, Vehicle and Road Safety System Using Smartphones
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As vehicle manufacturers continue to increase their emphasis on safety with advanced driver assistance systems (ADAS), I propose a ubiquitous device that is able to analyze and advise on safety conditions. Mobile smartphones are increasing in popularity among younger generations with an estimated 64% of 25-34 year olds already using one in their daily lives. with over 10 million car accidents reported in the United States each year, car manufacturers have shifted their focus of a passive approach (airbags) to more active by adding features associated with ADAS (lane departure warnings). However, vehicles manufactured with these sensors are not economically priced while older vehicles might only have passive safety features. Given its accessibility and portability, I target a mobile smartphone as a device to compliment ADAS that can bring a driver assist to any vehicle without regards for any on-vehicle communication system requirements. I use the 3-axis accelerometer of multiple Android based smartphone to record and analyze various safety factors which can influence a driver while operating a vehicle. These influences with respect to the driver, vehicle and road are lane change maneuvers, vehicular comfort and road conditions. Each factor could potentially be hazardous to the health of the driver, neighboring public, and automobile and is therefore analyzed thoroughly achieving 85.60% and 89.89% classification accuracy for identifying road anomalies and lane changes, respectively. Effective use of this data can educate a potentially dangerous driver on how to operate a vehicle safely and efficiently. with real time analysis and auditory alerts of these factors, I hope to increase a driver's overall awareness to maximize safety. digital.library.unt.edu/ark:/67531/metadc115086/
Economic Mobility into the Planter Class in Texas, 1846-1860
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This study examines upward economic mobility into the planter class in Texas during the antebellum statehood period, 1846-1860. Using quantitative methods to analyze data from census and tax records, this study addresses several questions regarding the property owning experience of Texas planters. Did any of the 1860 planters, men or women, rise to that status from another class? If so, how many rose from small slaveholder or small planter origins, and how many advanced from plain folk origins? In what ways did the amount and nature of wealth of these individuals change in the period studied? In what ways do these findings provide insights into the debate over planter dominance versus ‘plain folk’ inclusive herrenvolk democracy and the relationship between the planters and the other classes? Did the experiences of female planters differ from that of male planters? Did female planter experiences in Texas differ from female planters in other parts of the Old South? The results of these questions demonstrate that economic class mobility into the richest class was significant but limited and that women’s experiences were closely tied to those of male kin. digital.library.unt.edu/ark:/67531/metadc103363/
Effect of Retting on Surface Chemistry and Mechanical Performance Interactions in Natural Fibers for High Performance Polymer Composites
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Sustainability through replacement of non-renewable fibers with renewable fibers is an ecological need. Impact of transportation costs from South-east Asia on the life cycle analysis of the composite is detrimental. Kenaf is an easily grown crop in America. Farm based processing involves placing the harvested crop in rivers and ponds, where retting of the fibers from the plant (separation into fibers) can take 2 weeks or more. The objective of this thesis is to analyze industrially viable processes for generating fibers and examine their synergistic impact on mechanical performance, surface topography and chemistry for functional composites. Comparison has been made with commercial and conventional retting process, including alkali retting, enzymatic retting, retting in river and pond water (retting occurs by natural microbial population) with controlled microbial retting. The resulting kenaf fibers were characterized by dynamic mechanical analysis (DMA), Raman spectroscopy (FT-Raman), Fourier transform infrared spectroscopy (FT-IR), polarized optical microscopy (POM), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM) optical fluorescence microscopy, atomic force microscopy (AFM) and carbohydrate analysis. DMA results showed that pectinase and microbe treated fibers have superior viscoelastic properties compared to alkali retting. XPS, Raman, FT-IR and biochemical analysis indicated that the controlled microbial and pectinase retting was effective in removing pectin, hemicellulose and lignin. SEM, optical microscopy and AFM analysis showed the surface morphology and cross sectional architecture were preserved in pectinase retting. Experimental results showed that enzymatic retting at 48 hours and controlled microbial retting at 72 hours yield uniform and superior quality fibers compared to alkali and natural retting process. Controlled microbial retting is an inexpensive way to produce quality fibers for polymer composite reinforcement. digital.library.unt.edu/ark:/67531/metadc271883/
Electrochemically Deposited Metal Alloy-silicate Nanocomposite Corrosion Resistant Materials
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Zinc-nickel ?-phase silicate and copper-nickel silicate corrosion resistant coatings have been prepared via electrochemical methods to improve currently available corrosion resistant materials in the oil and gas industry. A layered silicate, montmorillonite, has been incorporated into the coatings for increased corrosion protection. For the zinc nickel silicate coatings, optimal plating conditions were determined to be a working pH range of 9.3 -9.5 with a borate based electrolyte solution, resulting in more uniform deposits and better corrosion protection of the basis metal as compared to acidic conditions. Quality, strongly adhering deposits were obtained quickly with strong, even overall coverage of the metal substrate. The corrosion current of the zinc-nickel-silicate coating is Icorr = 3.33E-6 for a borate based bath as compared to a zinc-nickel bath without silicate incorporation (Icorr = 3.52E-5). Step potential and direct potential methods were examined, showing a morphological advantage to step potential deposition. The effect of borate addition was examined in relation to zinc, nickel and zinc-nickel alloy deposition. Borate was found to affect the onset of hydrogen evolution and was examined for absorption onto the electrode surface. For copper-nickel silicate coatings, optimal conditions were determined to be a citrate based electrolytic bath, with pH = 6. The solutions were stable over time and strong adhering, compact particle deposits were obtained. The corrosion current of the copper-nickel-silicate coatings is Icorr = 3.86E-6 (copper-nickel coatings without silicate, Icorr = 1.78E-4). The large decrease in the corrosion current as the silicate is incorporated into the coating demonstrates the increase in corrosion resistance of the coatings with the incorporation of silicates. digital.library.unt.edu/ark:/67531/metadc271794/
Electronic Sound Analysis with Hardware System and Remote Internet Display
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Currently, standards from government agencies such as the National Institute for Occupation Safety and Health exist to aid in safeguarding individuals’ capacity for hearing, but only in factory settings in which large machines often produce loud levels of sound. Neglecting the fact that these preventative measures are only in place in the most limited of settings, no system currently exists to observe and report sound exposure levels in a manner timely or easily recognizable enough to adequately serve its purpose of hearing conservation. Musicians may also incur significant levels of risk for hearing loss in their day-to-day rehearsals and concerts, from high school marching bands to university wind bands. As a result, music school accrediting organizations such as the National Association of Schools of Music and even the European Union have begun taking steps meant to determine the risks associated with music. To meet these goals and improve upon current technologies, a system has been developed that electronically records sound levels utilizing modern hardware, increases the speed of reporting by transmitting data over computer networks and the Internet, and displays measures calculated from these data in a web browser for a highly viewable, user-friendly interface. digital.library.unt.edu/ark:/67531/metadc103358/
Electrostatic Effects in III-V Semiconductor Based Metal-optical Nanostructures
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The modification of the band edge or emission energy of semiconductor quantum well light emitters due to image charge induced phenomenon is an emerging field of study. This effect observed in quantum well light emitters is critical for all metal-optics based light emitters including plasmonics, or nanometallic electrode based light emitters. This dissertation presents, for the first time, a systematic study of the image charge effect on semiconductor–metal systems. the necessity of introducing the image charge interactions is demonstrated by experiments and mathematical methods for semiconductor-metal image charge interactions are introduced and developed. digital.library.unt.edu/ark:/67531/metadc115090/
The Enameling Arts in Kuwaiti Pre-service Art Teacher Education
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The purpose of this study was twofold: (1) to examine the knowledge, skills, and experiences in the enameling arts and the attitudes and perceptions of in-service (n = 12) and pre-service Kuwaiti art teachers (n = 170), art supervisors at the Ministry of Education (MOE) (n = 3) and art education faculty members at the College of Basic Education (CBE) and Kuwait University (KU) (n = 8) about what they believed pre-service art teachers should know and be able to do in order to teach the enameling arts, and (2) to use this information to inform and guide the development of a content outline for an enameling course for pre-service Kuwaiti art teachers that is educationally (how to perform enameling arts skills and how to teach what they know), practically (safety issues, workshop management, etc), and culturally (its relation to Islamic culture) suitable. Both quantitative and qualitative approaches were used. Most of the respondents revealed limited knowledge and skills and modest experiences in the enameling arts. All interviewees in the study expressed positive perceptions and attitudes about the enameling arts. Most agreed that a revision to the current art education curriculum at the CBE was needed and made suggestions about how the curriculum should be revised. It was clear that there is a disconnection and miscommunication between the MOE and the CBE with regards to the information about enameling that should be covered and taught in the art education classes. All respondents expressed support for the inclusion of a course in enameling in the art education curriculum at the CBE. Because of the limited knowledge of the participants in the study, they were not able to provide guidance in shaping the content for a course in the enameling arts. The researcher had to rely on the literature review and his expertise as an enameling artist to develop a content outline that was educationally, practically, and culturally suitable for the pre-service Kuwaiti art teachers. Further study was recommended in regard to curriculum issues, especially those related to the inclusion of Islamic culture, and methods of delivering instruction in the enameling arts. digital.library.unt.edu/ark:/67531/metadc28410/
The Enemy of My Enemy Is What, Exactly? the British Flanders Expedition of 1793 and Coalition Diplomacy
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The British entered the War of the First Coalition against Revolutionary France in 1793 diplomatically isolated and militarily unprepared for a major war. Nonetheless, a French attack on the Dutch Republic in February 1793 forced the British to dispatch a small expeditionary force to defend their ally. Throughout the Flanders campaign of 1793, the British expeditionary force served London as a tool to end British isolation and enlist Austrian commitment to securing British war objectives. The 1793 Flanders campaign and the Allied war effort in general have received little attention from historians, and they generally receive dismissive condemnation in general histories of the French Revolutionary Wars. This thesis examines the British participation in the 1793 Flanders campaign a broader diplomatic context through the published correspondence of relevant Allied military and political leaders. Traditional accounts of this campaign present a narrative of defeat and condemn the Allies for their failure to achieve in 1793 the accomplishments of the sixth coalition twenty years later. Such a perspective obscures a clear understanding of the reasons for Allied actions. This thesis seeks to correct this distortion by critically analyzing the relationship between British diplomacy within the Coalition and operations in Flanders. Unable to achieve victory on their own strength, the British used their expeditionary force in Flanders as diplomatic leverage to impose their objectives on the other powers at war with France. digital.library.unt.edu/ark:/67531/metadc283820/
Excerpts From the Eva Crane Field Diary: Stories
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Male or female, young or old, the characters of this collection inhabit a liminal space of trauma and social dislocation in which elements of the real and fabulous coexist in equal measure. The ghosts that populate the stories are as much the ghosts of the living, as they are the ghosts of the dead. They represent individual conscience and an inescapable connection to the past. digital.library.unt.edu/ark:/67531/metadc28436/
Exploring Sustainability VALS: Sustainability Value, Lifestyle Practices and Stewardship
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Living sustainability is a set of behaviors for the long-term functioning of society. Sustainability VALS provides the clothing and textiles industry distinctive insight into comprehending the phenomenon through the application of the appropriate theoretical platform. The objectives are to identify the dimensionality of sustainability value, sustainability practices and sustainability stewardship in consumers’ perceptive, and to examine the impacts of sustainability value and stewardship on sustainability practices. Analyzing data (n = 239) from a southwestern university reveals the critical dimensions of sustainability lifestyle practices, sustainability value and sustainability stewardship. 62 out of 64 hypotheses were confirmed the significant impacts of sustainability values and stewardship on sustainability lifestyle practices. The findings revealed that the altruistic, openness to change, anthropocentrism, and ecocentrism values are influential sustainability values affecting on sustainability lifestyle practices. Given the theoretical perspective of sustainability VALS, sustainability stewardships can facilitate the holistic idea to incur consumer’s sustainability lifestyle practices. digital.library.unt.edu/ark:/67531/metadc103352/
Expression of G-protein Coupled Receptors in Young and Mature Thrombocytes and Knockdown of Gpr18 in Zebrafish
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In this study, a novel method based on biotinylated antibodies and streptavidin coated magnetic beads was used to separate the thrombocyte subpopulations from zebrafish whole blood. DiI-C18, a lipophilic dye, labels only young thrombocytes when used at low concentrations. Commercially available biotinylated anti-Cy3 antibody was used to label the chromophore of DiI-C18 on the young thrombocytes and streptavidin coated magnetic beads were added subsequently, to separate young thrombocytes. The remaining blood cells were probed with custom-made biotinylated anti-GPIIb antibody and streptavidin magnetic beads to separate them from other cells. Further, thrombocytes are equivalents of mammalian platelets. Platelets play a crucial role in thrombus formation. The G-protein coupled receptors (GPCRs) present on the platelet surface are involved during platelet activation and aggregation processes. So, thrombocytes were studied for the presence of GPCRs. The GPCR mRNA transcripts expressed in the young and mature thrombocytes were subjected to densitometry analysis and pixel intensities of the bands were compared using one way ANOVA. This analysis did not show significant differences between the young and mature GPCR mRNA transcripts but identified a novel GPCR, GPR18 that was not reported in platelets earlier. To study the function of this GPCR, it was knocked down using GPR18 specific antisense morpholino and vivo morpholino. The immunofluorescence experiment indicated the presence of GPR18 on thrombocytes. The results of the assays, such as, time to occlusion (TTO) and time to aggregation (TTA) in response to N-arachidonyl glycine (NAG) as an agonist, showed prolongation of time in GPR18 larval and adult morphants respectively, suggesting that GPR18 plays a role in thrombus formation in zebrafish. In conclusion, our results indicate that GPR18 may be present in zebrafish thrombocytes, it may be involved in thrombus formation and that NAG may be an agonist at GPR18 on thrombocytes. digital.library.unt.edu/ark:/67531/metadc271881/
Fathom's Edge
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Investigating elements of the creative process in the work of three poets: James Wright, Gjertrud Schnackenberg, and Pegeen Kelly. Each poet deploys a different method for access to those experiences that lie at the edge of accessible language. Each method is discussed and its deployment illustrated. Wright leads us from the sensory world to the supersensual. Schnackenberg makes use of the formal device of the fairy tale. Kelly immerses in the logic of dreams. Drawing on Elaine Scarry's theory of the imagination, the case is made that the poetic act is a dialectic between the poet and the sensory world, in which perception and imagination are equally important. digital.library.unt.edu/ark:/67531/metadc28483/
The Function of Social Structure in Controlling Violent Crime in Turkey
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This dissertation examines the relationship between social structural factors and violent crime rates in Turkey. The relationship between social structural characteristics and violent crime is worth exploring in areas that have attracted little academic attention, such as violent crime in Turkey. In order to understand and prevent the occurrence of crime, researchers have long investigated possible factors related to crime. Examining how crime varies across different regions can help us to understand underlying reasons for violent crime, which is considered one of the enduring problems in society. The findings of this research, to some extent, support the assumptions of social disorganization theory regarding the distribution of violent crime. Both the findings of multivariate and bivariate analysis indicated that poverty, unemployment, and family disruptions may have a positive effect on the distribution of violent crime in the cities of Turkey. The analysis of the effects of the social structure variables through the mediating variables, such as religious institutions, libraries and voluntary associations on the number of violent crimes and violent criminals, to some extent, support the tenets of social disorganization theory. However, all mediating variables cannot mediate all the indirect effects of social structural covariates. In brief, none of their indirect impacts on the social structural variables on the outcome variable was significant via mediating variables. digital.library.unt.edu/ark:/67531/metadc33225/
Gentrification in Oklahoma City: Examining Urban Revitalization in Middle America
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Gentrification applies not only to the largest and oldest cities; it is a multi-scalar phenomenon playing out in smaller and less prominent settings as well. This study examines temporal changes in property values, demographic characteristics, and types of businesses in the central Oklahoma City area. A major urban revitalization project which began in 1993 created strong gentrification characteristics near the renewal's epicenter, the Bricktown entertainment district. Data suggest that several specific neighborhoods in the surrounding area exhibited rising property values, improving educational attainment rates, decreasing household sizes, and a shift toward cosmopolitan retail activity. While it is evident that Bricktown has been transformed, the socio-economic traits of surrounding neighborhoods have been altered by the ripple effects of urban renewal. digital.library.unt.edu/ark:/67531/metadc84266/
The Girl Disappeared: the Prostitute of La Isla De Santa Flora
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The novella, The Girl Disappeared, focuses on the life of Emalia, a street kid from Mexico. She is taken from the streets of Veracruz and forced into a life of prostitution on the fictitious island of La Isla de Santa Flora. The primary conflict that drives the action of the story is her pending choice between escaping her life of slavery and saving another young woman who is on the verge of being forced into a life of prostitution as well. The novella, as a literary piece, dwells on the question of character agency and explores the multilayered nature of code switching. Language for these women becomes a tool in their struggle against their captives and a means of self-preservation, or sanctuary, as they use their growing bilingualism to foment a limited agency, to act in their own defense. digital.library.unt.edu/ark:/67531/metadc271917/
Hand Amputees have an Altered Perception of Images at Arm's Length
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The preface to this collection "Dust Clouding: Ambiguity and the Poetic Image," highlights the ways in which poets such as W.S Merwin and Donald Revell use ambiguity and the poetic image to strengthen their poems and encourage equality between reader and writer. Hand Amputees have an Altered Perception of Images at Arm's Length is a collection of poems and poem like adventures. digital.library.unt.edu/ark:/67531/metadc28435/
Henderson Street Bazaar and Other Stories
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The preface, "Against Buses: Charles Baxter and the Contemporary Epiphany" deals with the epiphany as a potential ending to short stories. Baxter holds that epiphanies are trite and without purpose in today's fiction. I argue that Baxter's view, while not without merit, is limiting. Beginning with James Joyce and Katherine Anne Porter and moving to my own work, I discuss how some epiphanies, particularly false ones, can enhance rather than detract from excellent fiction. Five short stories make up the remainder of this thesis: "Dedication," "Taking it with You," "Transition to Flowers," "Profile in Courage," and "Henderson Street Bazaar." digital.library.unt.edu/ark:/67531/metadc33222/
Identification of highly gifted 5- and 6-year-old children: Measures to predict academic achievement.
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Studies indicate the educational needs of highly gifted students are best met through accelerated learning. It is difficult to recognize very young children that are suited for an accelerated curriculum because younger students frequently lack school records or portfolios used to identify gifted students. This study examined the accuracy of cognitive ability and achievement tests in predicting academic achievement by the end of second grade, correlating test results and final grade averages collected from sixteen children ages five to six who entered a public school program for high-ability learners in kindergarten. A multiple regression analysis indicated the Wechsler Preschool and Primary Scale of Intelligence produced the highest mean IQ score and a strong correlation with reading achievement. The Wechsler Individual Achievement Test contributed in small part to the prediction of academic achievement. The Naglieri Nonverbal Ability Test and the Kaufman Brief Intelligence Test-Second Edition had negative correlations with final grade averages, indicating they are not predictors of academic achievement for these students. digital.library.unt.edu/ark:/67531/metadc28471/
Identification of Three Symbiosome Targeting Domains in the MtENOD8 Protein and Cell-to-cell MtENOD8 mRNA Movement in Nodules
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The model legume, Medicago truncatula, is able to enter into a symbiotic relationship with soil bacteria, known as rhizobia. This relationship involves a carbon for nitrogen exchange in which the plant provides reduced carbon from photosynthesis in exchange for reduced, or “fixed” atmospheric nitrogen, which allows the plant to thrive in nitrogen depleted soils. Rhizobia infect and enter plant root organs, known as nodules, where they reside inside the plant cell in a novel organelle, known as the symbiosome where nitrogen fixation occurs. the symbiosome is enriched in plant proteins, however, little is known about the mechanisms that direct plant proteins to the symbiosome. Using the M. truncatula ENOD8 (MtENOD8) protein as a model to explore symbiosome protein targeting, 3-cis domains were identified within MtENOD8 capable of directing green fluorescent protein (GFP) to the symbiosome, including its N-terminal signal peptide (SP). the SP delivered GFP to the vacuole in the absence of nodules suggesting that symbiosome proteins share a common targeting pathway with vacuolar proteins. a time course analysis during nodulation indicated that there is a nodule specific redirection of MtENOD8-SP from the vacuole to the symbiosome in a MtNIP/LATD dependent manner. GFP expression by the MtENOD8 promoter revealed spatial discrepancy between promoter activity and protein localization. in situ localization of MtENOD8 mRNA showed localization to infected cells, where the protein is found, suggesting mRNA cell-to-cell movement. Expression of MtENOD8 in Arabidopsis showed that the SP did not direct GFP to the vacuole indicating that vacuolar targeting of MtENOD8’s SP may be legume specific. Taken together, the research presented here indicates that the MtENOD8 symbiosome protein has evolved redundant domains for targeting, which has part of a common pathway with vacuolar proteins. Observed spatial discrepancy between the MtENOD8 promoter and protein shows additional mechanisms of gene regulation through cell-to-cell mRNA movement, previously unknown in nodules. digital.library.unt.edu/ark:/67531/metadc115118/
Incorporating Electrochemistry and X-ray Diffraction Experiments Into an Undergraduate Instrumental Analysis Course
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Experiments were designed for an undergraduate instrumental analysis laboratory course, two in X-ray diffraction and two in electrochemistry. Those techniques were chosen due their underrepresentation in the Journal of Chemical Education. Paint samples (experiment 1) and pennies (experiment 2) were characterized using x-ray diffraction to teach students how to identify different metals and compounds in a sample. in the third experiment, copper from a penny was used to perform stripping analyses at different deposition times. As the deposition time increases, the current of the stripping peak also increases. the area under the stripping peak gives the number of coulombs passed, which allows students to calculate the mass of copper deposited on the electrode surface. the fourth experiment was on the effects of variable scan rates on a chemical system. This type of experiment gives valuable mechanistic information about the chemical system being studied. digital.library.unt.edu/ark:/67531/metadc115123/
Interspecimen Study of Bone to Relate Macromechanical, Nanomechanical and Compositional Changes Across the Femoral Cortex of Bone
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Mechanics of bone is widely studied and researched, mainly for the study of fracture. This has been done mostly on a macro scale. In this work hierarchical nature of bone has been explored to investigate bone mechanics in more detail. Flexural test were done to classify the bones according to their strength and deflection. Raman spectroscopy analysis was done to map the mineralization, collagen crosslinking changes across the thickness of the bone. Nanoindentation was done to map indentation hardness and indentation modulus across femoral cortex of the bone. The results indicate that the composition of the bone changes across the thickness of the femoral cortex. The hypothesis is confirmed as increase in mineralization, carbonate to phosphate ratio and collagen crosslinking shows the effect as increased indentation hardness and modulus and decreased deflection. digital.library.unt.edu/ark:/67531/metadc271868/
Investigating Postpartum Depression in Southern Rural Egypt and Effects of Sertraline on Fsh and Lh Gene Expression on Fathead Minnows Using Rt-pcr
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Postpartum depression (PPD) is a major health problem that affects many women worldwide. In Egypt, PPD is neglected despite the expected high prevalence rate among women during the transition period after the Egyptian revolution. This research investigated the prevalence, risk factors, and interventions of postpartum depression in southern rural Egypt. Interviews were conducted with 57 participants recruited from public and private hospitals. Questionnaires and the Arabic version of the Edinburgh Postnatal Depression Scale were administered. The prevalence of PPD is 73.7%. PPD is associated with low income and age at childbirth. Most participants regarded screening mothers after childbirth for PPD as effective; in comparison to, antidepressants that were regarded by most participants as ineffective. Women in southern rural Egypt prefer high number of pregnancies, so investigating the influence of sertraline, an antidepressant medication, on female hormones becomes important. In this research, fathead minnows were exposed to 3 and 10 ppb sertraline for 7 days. Real-time Polymerase Chain Reaction was used to detect the change in gene expression of the Follicle-stimulating hormone (FSH) and luteinizing hormone (LH). Results showed that a down regulation at the 10 ppb was evident on the LH and to a lesser extent on FSH. Our results increased levels of sertraline inhibited GnRH which influenced expression of LH and FSH. digital.library.unt.edu/ark:/67531/metadc271865/
Investigation of Novel Electrochemical Synthesis of Bioapatites and Use in Elemental Bone Analysis
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In this research, electrochemical methods are used to synthesize the inorganic fraction of bone, hydroxyapatite, for application in biological implants and as a calibration material for elemental analysis in human bone. Optimal conditions of electrochemically deposited uniform apatite coatings on stainless steel were investigated. Apatite is a ceramic with many different phases and compositions that have beneficial characteristics for biomedical applications. Of those phases hydroxyapatite (HA) is the most biocompatible and is the primary constituent of the inorganic material in bones. HA coatings on metals and metal alloys have the ability to bridge the growth between human tissues and implant interface, where the metal provides the strength and HA provides the needed bioactivity. The calcium apatites were electrochemically deposited using a modified simulated body fluid adjusted to pH 4-10, for 1-3 hours at varying temperature of 25-65°C while maintaining cathodic potentials of -1.0 to -1.5V. It was observed that the composition and morphology of HA coatings change during deposition by the concentration of counter ions in solution, pH, temperature, applied potential, and post-sintering. The coatings were characterized by powder x-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. The precipitated powders from the experiment were also characterized, with results showing similarities to biological apatite. There is a need for quantitative elemental analysis of calcified biological matrices such as bone and teeth; however there are no suitable calibration materials commercially available for quantitative analysis. Matrix-matched standards are electrochemically synthesized for LA-ICP-MS analysis of human bone. The synthetic bioapatite is produced via a hydrothermal electrochemical process using a simulated body fluid solution to form hydroxyapatite. Additional bioapatite standards are synthesized containing trace amounts of metals. The x-ray diffraction of the synthesized standards shows an increase in cell volume for the crystal structure from 0.534 to 0.542 nm3 with the substitution of metals into the crystal structure. The analyte concentration and recoveries for the synthesized standards and reference materials were determined by ICP-MS with % RSD below 6.3% and limits of detection below 1.2 ng/mL for trace metals. The electrochemically synthesized bioapatite was also compared to standard reference materials with X-ray diffraction, FTIR, and Raman spectroscopy. Optimum laser ablation parameters were determined for the standards and human bone. The synthesized standards were homogeneous and the reproducibility for the isotope concentrations determined by LA-ICP-MS was between 3-10 % compared to 10-35% for SRM 1486 Bone Meal and SRM 1486 Bone Ash. A quantitative method has been developed for 2D mapping using LA-ICP-MS and the matrix-matched standards of metal-doped biopaptite to characterize metal concentrations in human bone. Laser ablation parameters for the method are refined resulting in concentration (ug/g) contour map measurements for each isotope measured in the human bone. Essential and non-essential metals, Al, Ca, Cu, Fe, Pb, and Zn are quantitatively mapped using these parameters. Limit of detection for the metals in the bone range from 0.001 to 0.08 ug/g. The LA-ICP-MS analysis method developed proves to be a straightforward and simple method for quantitative analysis of human bone. digital.library.unt.edu/ark:/67531/metadc177191/
Irony, Humor, and Ontological Relationality in Literature
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The purpose of this dissertation is to investigate ontological relationality in literary theory and criticism by critically reflecting on modern theories of literature and by practically examining the literary texts of Geoffrey Chaucer, William Shakespeare, and Oscar Wilde. Traditional studies of literary texts have been oriented toward interpretative or hermeneutic methodologies, focusing on an independent and individual subject in literature. Instead, I explore how relational ontology uncovers the interactive structures interposed between the author, the text, and the audience by examining the system of how the author's creative positioning provokes the reader's reaction through the text. In Chapter I, I critically inquire into modern literary theories of "irony" in Romanticism, New Criticism, and Deconstructionism to show how they tend to disregard the dynamic dimension of interactive relationships between different literary subjects. Chapter II scrutinizes Wilde's humor in An Ideal Husband (1895) and The Importance of Being Earnest (1895) in order to reveal the ontological relationships triggered by a creative positioning. In chapter III, I examine Chaucer's The Canterbury Tales (c. 1400) and the laughter in "The Miller's Tale" in particular, to examine the ethical and aesthetic dimensions of its interactive relationships. In Chapter IV, I explore Much Ado About Nothing (1598-99), Othello (1603-4), and The Winter's Tale (1609-11) so as to show how artistic positioning creatively constructs a relational system of dynamic interactions to circulate social ideals and values. In so doing, this dissertation is aimed at revealing the aesthetic values of literature and the objective scope of literary discourse rather than providing yet another analytical paradigm dependent primarily on a single literary subject. Thus, the ontological study is proposed as an alternative, yet primary, dimension of literary criticism and theoretical practice. digital.library.unt.edu/ark:/67531/metadc149621/
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