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 Decade: 2010-2019
 Collection: UNT Theses and Dissertations
9-Lipoxygenase Oxylipin Pathway in Plant Response to Biotic Stress

9-Lipoxygenase Oxylipin Pathway in Plant Response to Biotic Stress

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Date: May 2012
Creator: Nalam, Vamsi J.
Description: The activity of plant 9-lipoxygenases (LOXs) influences the outcome of Arabidopsis thaliana interaction with pathogen and insects. Evidence provided here indicates that in Arabidopsis, 9-LOXs facilitate infestation by Myzus persicae, commonly known as the green peach aphid (GPA), a sap-sucking insect, and infection by the fungal pathogen Fusarium graminearum. in comparison to the wild-type plant, lox5 mutants, which are deficient in a 9-lipoxygenase, GPA population was smaller and the insect spent less time feeding from sieve elements and xylem, thus resulting in reduced water content and fecundity of GPA. LOX5 expression is induced rapidly in roots of GPA-infested plants. This increase in LOX5 expression is paralleled by an increase in LOX5-synthesized oxylipins in the root and petiole exudates of GPA-infested plants. Micrografting experiments demonstrated that GPA population size was smaller on plants in which the roots were of the lox5 mutant genotype. Exogenous treatment of lox5 mutant roots with 9-hydroxyoctadecanoic acid restored water content and population size of GPA on lox5 mutants. Together, these results suggest that LOX5 genotype in roots is critical for facilitating insect infestation of Arabidopsis. in Arabidopsis, 9-LOX function is also required for facilitating infection by F. graminearum, which is a leading cause of Fusarium head ...
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Ab Initio and Density Functional Investigation of the Conformer Manifold of Melatonin and a Proposal for a Simple Dft-based Diagnostic for Nondynamical Correlation

Ab Initio and Density Functional Investigation of the Conformer Manifold of Melatonin and a Proposal for a Simple Dft-based Diagnostic for Nondynamical Correlation

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Date: August 2013
Creator: Fogueri, Uma
Description: In this work we address two problems in computational chemistry relevant to biomolecular modeling. In the first project, we consider the conformer space of melatonin as a a representative example of “real-life” flexible biomolecules. Geometries for all 52 unique conformers are optimized using spin-component scaled MP2, and then relative energies are obtained at the CCSD (T) level near the complete basis set limit. These are then used to validate a variety of DFT methods with and without empirical dispersion corrections, as well as some lower-level ab initio methods. Basis set convergence is found to be relatively slow due to internal C-H…O and C-H…N contacts. Absent dispersion corrections, many DFT functionals will transpose the two lowest conformers. Dispersion corrections resolve the problem for most functionals. Double hybrids yield particularly good performance, as does MP2.5. In the second project, we propose a simple DFT-based diagnostic for nondynamical correlation effects. Aλ= (1-TAE [ΧλC]/TAE[XC])/λ where TAE is the total atomization energy, XC the “pure” DFT exchange-correlation functional, and ΧλC the corresponding hybrid with 100λ% HF-type exchange. The diagnostic is a good predictor for sensitivity of energetics to the level of theory, unlike most of the wavefunction-based diagnostics. For GGA functionals, Aλ values approaching unity ...
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The Academic Steroid: Nonmedical Use of Prescription Stimulants at a North Texas University

The Academic Steroid: Nonmedical Use of Prescription Stimulants at a North Texas University

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Date: December 2014
Creator: Pennington, Cody W
Description: The goal of this study was to determine the extent, motivations, and justifications of nonmedical prescription stimulant use among the population at a large public university in the North Texas region. Participants consisted of 526 undergraduate students enrolled at the studied university during the spring and summer 2014 semesters. The findings of the study suggest that the nonmedical use by students was higher than the findings in much of the current literature, but was within the parameters established in the literature. The primary motivation for nonmedical use was academic in nature and was justified by moderation of nonmedical use to strategic academic times.
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Accelerated Corrosion Test with Operation Simulation of All-Aluminum Microchannel Heat Exchangers

Accelerated Corrosion Test with Operation Simulation of All-Aluminum Microchannel Heat Exchangers

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Date: May 2016
Creator: Vaughan, Haydn
Description: The HVAC&R industry is looking to transition from copper-aluminum heat exchangers to all-aluminum microchannel technology. The want for the transition stemmed from seeing the performance improvement of all-aluminum microchannel radiators in the automotive industry. Applications differ between the two industries; therefore, applying this technology for HVAC&R use must be validated. Research towards operating modes of an all-aluminum heat exchanger in a defined corrosive environment will provide the industry with a better understanding of heat exchanger design and heat exchanger material selection. The worth in this is preventing overdesign and producing more efficient heat exchangers. Furthermore, ASHRAE members and the corrosion community will find value in a defined corrosion system and corrosion test procedure. The information gained through past research has progressed assessment of material performance; however, the methods improperly simulate and expedite natural weathering. The most common method being used is the ASTM (American Society of Testing Materials) Sea Water Acetic Acid Test. The research discussed in this paper was focused on improving a standard corrosion system by implementing system modifications to simulate heat exchanger operation while performing a modified wet-dry cyclic test (e.g. ASTM G85 Annex 5). The goal is to produce results that are more representative of natural ...
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Acute Effects of the Antibiotic Streptomycin on Neural Network Activity and Pharmacological Responses

Acute Effects of the Antibiotic Streptomycin on Neural Network Activity and Pharmacological Responses

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Date: December 2014
Creator: Zeng, Wei Rong
Description: The purpose of this study is to find out that if antibiotic streptomycin decreases neuronal network activity or affects the pharmacological responses. The experiments in this study were conducted via MEA (multi-electrode array) technology which records neuronal activity from devices that have multiple small electrodes, serve as neural interfaces connecting neurons to electronic circuitry. The result of this study shows that streptomycin lowered the spike production of neuronal network, and also, sensitization was seen when neuronal network pre-exposed to streptomycin.
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Adhesion and Surface Energy Profiles of Large-area Atomic Layers of Two-dimensional MoS2 on Rigid Substrates by Facile Methods

Adhesion and Surface Energy Profiles of Large-area Atomic Layers of Two-dimensional MoS2 on Rigid Substrates by Facile Methods

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Date: May 2016
Creator: Wu, Min
Description: Two-dimensional (2D) transition metal dichalcogenides (TMDs) show great potential for the future electronics, optoelectronics and energy applications. But, the studies unveiling their interactions with the host substrates are sparse and limits their practical use for real device applications. We report the facile nano-scratch method to determine the adhesion energy of the wafer scale MoS2 atomic layers attached to the SiO2/Si and sapphire substrates. The practical adhesion energy of monolayer MoS2 on the SiO2/Si substrate is 7.78 J/m2. The practical adhesion energy was found to be an increasing function of the MoS2 thickness. Unlike SiO2/Si substrates, MoS2 films grown on the sapphire possess higher bonding energy, which is attributed to the defect-free growth and less number of grain boundaries, as well as less stress and strain stored at the interface owing to the similarity of Thermal Expansion Coefficient (TEC) between MoS2 films and sapphire substrate. Furthermore, we calculated the surface free energy of 2D MoS2 by the facile contact angle measurements and Neumann model fitting. A surface free energy ~85.3 mJ/m2 in few layers thick MoS2 manifests the hydrophilic nature of 2D MoS2. The high surface energy of MoS2 helps explain the good bonding strength at MoS2/substrate interface. This simple adhesion ...
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American Blitzkrieg: Courtney Hodges and the Advance Toward Aachen (August 1 - September 12, 1944)

American Blitzkrieg: Courtney Hodges and the Advance Toward Aachen (August 1 - September 12, 1944)

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Date: December 2012
Creator: Rinkleff, Adam J.
Description: This is an analysis of combat operations of US First Army under the command of Courtney Hodges, between August 1 and September 12, 1944, with an emphasis upon 1st, 4th, 9th, and 30th Divisions. However, other formations are necessarily discussed in order to maintain context. Indeed, many historians have failed to emphasize the complex interdependent nature of these efforts, and the traditional narrative has been distorted by inadequate situational awareness. This study argues that the army's operations were exceedingly difficult, resulting in approximately 40,000 casualties over a six week period. Although historians claim that the Germans were essentially defeated by the end of July, and that the Allied advance was subsequently halted by logistical difficulties, the official combat records clarify that logistical shortages were a tertiary factor, as the enemy remained capable of strong resistance. Consequently, defensive efforts were the primary factor hindering the advance, in conjunction with deteriorating weather conditions, rugged terrain, and surprisingly severe traffic congestion. Although this was mobile warfare, military theorists have overestimated the effectiveness of mechanization and underestimated the potential for antitank defenses. Ultimately, this study asserts that First Army was the primary American combat formation, and historians have exaggerated the importance of George Patton's ...
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American Indian Worldviews, Risk Perceptions and Disaster Planning: an Exploratory Study

American Indian Worldviews, Risk Perceptions and Disaster Planning: an Exploratory Study

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Date: December 2013
Creator: Bales, Rodney A.
Description: It is commonly assumed that when confronted with an imminent hazard that people will react rationally, and prepare for, or at least attempt to avoid, danger from pending disasters. However, this conventional wisdom is not as evident as it appears. People prepare for, react to, or take social action to avoid hazards when they perceive the risk of danger to be threatening enough to warrant action, providing one has the will, insight and resources to do so. However, not all people perceive risks similarly. Risk is perceived differently by different people which affects risk perception and responses to hazards. This dissertation explores the relationships between American Indian worldviews, risk perceptions and disaster planning. To carry out this research 28 American Indians were interviewed. The sample consists of 14 American Indians residing in a rural are on the northern plains and 14 urban American Indians. The results only partially support that worldview is linked to risk perception and subsequent disaster planning. Other factors found to relate to risk perception and disaster planning for this non-representative sample of American Indians include various forms of social vulnerability.
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Americans Who Would Not Wait:  The American Legion of the Canadian Expeditionary Force, 1915-1917

Americans Who Would Not Wait: The American Legion of the Canadian Expeditionary Force, 1915-1917

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Date: August 2012
Creator: Smylie, Eric Paul
Description: This dissertation examines the five battalions of the Canadian Expeditionary Force designated as the American Legion. Authorized in Canada between 1915 and 1917, these units were formed to recruit volunteers from the United States to serve in the Canadian Overseas Contingent during the First World War. This work reviews the organization of Canada’s militia and the history of Anglo-American relations before examining the Canadian war effort, the formation of the American Legion, the background of its men, and the diplomatic, political, and constitutional questions that it raised. Much of the research focuses on the internal documents of its individual battalions (the 97th, 211th, 212th, 213th and 237th) and the papers of Reverend Charles Bullock now housed at the Public Archives of Canada. Documentation for the diplomatic furor the American Legion caused comes largely through the published diplomatic documents, British Foreign Office records held at the Public Record Office at Kew, and United States Department of State files at the National Archives at College Park, Maryland. The most useful sources for American Legion correspondence are the Beaverbrook papers held at the House of Lords Record Office, the papers of Canadian Prime Minister Sir Robert Laird Borden, and those of the Governor-General, ...
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Analysis and Optimization of Graphene FET based Nanoelectronic Integrated Circuits

Analysis and Optimization of Graphene FET based Nanoelectronic Integrated Circuits

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Date: May 2016
Creator: Joshi, Shital
Description: Like cell to the human body, transistors are the basic building blocks of any electronics circuits. Silicon has been the industries obvious choice for making transistors. Transistors with large size occupy large chip area, consume lots of power and the number of functionalities will be limited due to area constraints. Thus to make the devices smaller, smarter and faster, the transistors are aggressively scaled down in each generation. Moore's law states that the transistors count in any electronic circuits doubles every 18 months. Following this Moore's law, the transistor has already been scaled down to 14 nm. However there are limitations to how much further these transistors can be scaled down. Particularly below 10 nm, these silicon based transistors hit the fundamental limits like loss of gate control, high leakage and various other short channel effects. Thus it is not possible to favor the silicon transistors for future electronics applications. As a result, the research has shifted to new device concepts and device materials alternative to silicon. Carbon is the next abundant element found in the Earth and one of such carbon based nanomaterial is graphene. Graphene when extracted from Graphite, the same material used as the lid in pencil, ...
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Anchor Nodes Placement for Effective Passive Localization

Anchor Nodes Placement for Effective Passive Localization

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Date: August 2010
Creator: Pasupathy, Karthikeyan
Description: Wireless sensor networks are composed of sensor nodes, which can monitor an environment and observe events of interest. These networks are applied in various fields including but not limited to environmental, industrial and habitat monitoring. In many applications, the exact location of the sensor nodes is unknown after deployment. Localization is a process used to find sensor node's positional coordinates, which is vital information. The localization is generally assisted by anchor nodes that are also sensor nodes but with known locations. Anchor nodes generally are expensive and need to be optimally placed for effective localization. Passive localization is one of the localization techniques where the sensor nodes silently listen to the global events like thunder sounds, seismic waves, lighting, etc. According to previous studies, the ideal location to place anchor nodes was on the perimeter of the sensor network. This may not be the case in passive localization, since the function of anchor nodes here is different than the anchor nodes used in other localization systems. I do extensive studies on positioning anchor nodes for effective localization. Several simulations are run in dense and sparse networks for proper positioning of anchor nodes. I show that, for effective passive localization, the ...
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“The Angular Degrees of Freedom” and Other Stories

“The Angular Degrees of Freedom” and Other Stories

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Date: December 2014
Creator: Feagin, Aprell McQueeney
Description: The preface, " Performing Brain Surgery: The Problematic Nature of Endings in Short Fiction," deals with the many and varied difficulties short story writers encounter when attempting to craft endings. Beginning with Raymond Carver and Flannery O’Connor and moving to my own work, I discuss some of the obscure criteria used to designate a successful ending, as well as the more concrete idea of the ending as a unifying element. Five short stories make up the remainder of this thesis: "In-between Girls," "Crocodile Man," "Surprising Things, Sometimes Amusing," "Good Jewelry," and "The Angular Degrees of Freedom."
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Aphorismen, Capriccio, and Heptameron for Piano Solo By Jürg Baur: a Performer's Guide

Aphorismen, Capriccio, and Heptameron for Piano Solo By Jürg Baur: a Performer's Guide

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Date: December 2012
Creator: Park, Esther
Description: The purpose of this dissertation is to give instruction regarding the performance of three important piano works by Jürg Baur (1918-2010). Aphorismen, Capriccio, and Heptameron stand out as his most significant piano works both because of their length and because of their pianistic complexity. Since Baur had a successful career as both teacher and composer during his lifetime, his acclaimed works received many honors in Germany. His works can be performed by intermediate to advanced students. Intermediate students can easily offer simpler pieces like Aphorismen in competitions, while pieces like Capriccio and Heptameron better are suited to a more advanced level. Although some of his compositions are difficult to perform compared with other modern German works, Baur's music is more accessible. In the article, "Auf der Spuren der alten Zeit" Baur is quoted to state that Paul Hindemith and Bela Bartok's music influenced his own compositional ideas. However, although Baur is a modern composer, he didn't write in a totally atonal style, but rather attempted to broaden tonality. While Heptameron is atonal, Aphorismen and Capriccio give the impression of tonality, thus they are more accessible to the audience. I was fortunate enough to study Aphorismen with Baur as well as ...
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Application of Cyclic Polarization of Aluminum 3003 Used in All-aluminum Microchannel Heat Exchangers

Application of Cyclic Polarization of Aluminum 3003 Used in All-aluminum Microchannel Heat Exchangers

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Date: May 2015
Creator: Barnes, Javier
Description: All-aluminum microchannel heat exchangers are designed to significantly reduce refrigerant charge requirements, weight, reduced brazed joints, and decreased potential for leakage by increasing reliability. Al 3003 alloy is corrosion resistant and can be formed, welded, and brazed but the issue with all-aluminum heat exchangers is localized corrosion (pitting) in corrosive environments. Currently, there is no universally accepted corrosion test that all coil manufacturers use to characterize their products. Electrochemical testing method of cyclic polarization was employed in this investigation and relevant parameters including electrolyte corrosive agent and its concentration, electrolyte pH, and applied potential scan rate was varied to find an optimal set of parameters. Results of cyclic polarization of Al 3003 in electrolytes containing various concentrations of NaCl were compared with those of the tests in Sea Water Acidified Accelerated Test (SWAAT) electrolyte and it is shown the SWAAT electrolyte (4.2% sea salt acidified to pH of 2.9) is by far stronger (in terms of corrosivity) than typical 3.5% NaCl solution used in most corrosion testing. Corrosion rates (g/m2yr) of Al 3003 measured in this investigation were comparable to those provided by ISO 9223 standard corresponding to C1 through CX categories. Duration of cyclic polarization test is much shorter ...
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Assessing Social Determinants of Severe Mental Illness in High-Risk Groups

Assessing Social Determinants of Severe Mental Illness in High-Risk Groups

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Date: May 2014
Creator: Sun, Qi
Description: The primary objective of this research was to explore the impact of possible social factors on non-institutionalized adults 18 years of age or older residing in the United States who exhibited severe mental illness (SMI). A holistic sociological model was developed to explain SMI by incorporating elements of social learning theory, social disorganization theory, and gender socialization theory with social demographic factors. Based on the holistic sociological model, the following factors were investigated: demographic aspects of age, education, income and gender; gender socialization; influence of neighborhood area; social network influence based on communication and interaction among peers and family members; and socially deviant behaviors such as frequently smoking cigarettes, drinking alcohol and using drugs specifically marijuana. The impact of these factors on SMI was examined. A sample of 206 respondents drawn from National Survey on Drug Use and Health, 2003 was assessed. These respondents had answered all the questions related to SMI; social deviant behaviors; neighborhood environment; and communications among peers, family members and friends; and the other studied factors. Ordinary linear regression with interaction terms was employed as a statistical tool to assess the impact of social determinants on SMI. Being female, living a disorganized neighborhood, and frequent and ...
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Assessing Terrorist Cyber Threats: Engineering a Functional Construct

Assessing Terrorist Cyber Threats: Engineering a Functional Construct

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Date: December 2014
Creator: Morgan, Deanne
Description: Terrorist organizations and individuals make use of the Internet for supportive activities such as communication, recruiting, financing, training, and planning operations. However, little is known about the level of computer-based (“cyber”) threat such terrorist organizations and individuals pose. One step in facilitating the examination and assessment of the level of cyber threat posed by terrorist organizations and individuals is development of an assessment tool or methodology. This tool would guide intelligence collection efforts and would support and facilitate comparative assessment of the cyber threat posed by terrorist organizations and individuals through the provision of a consistent method of assessment across time, amongst organizations and individuals, and between analysts. This study leveraged the professional experience of experts to engineer a new functional construct – a structured analytical technique designed to assess the cyber threat posed by terrorist entities and individuals. The resultant instrument was a novel structured analytical construct that uses defined indicators of a terrorist organization/individual’s intent to carry out cyber attacks, and their capability to actually do so as measures of an organization/individual’s overall level of cyber threat.
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An Assessment of Consumers' Willingness to Patronize Foreign-Based Business Format Franchises: An Investigation in the Fast-Food Sector

An Assessment of Consumers' Willingness to Patronize Foreign-Based Business Format Franchises: An Investigation in the Fast-Food Sector

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Date: May 2010
Creator: Ertekin, Selcuk
Description: This study aimed to address consumers' stereotypical categorizations in the form of essentialist views about foreign cultures and their effect on individual consumers, including their negative or aroused emotions and subsequent retail patronage behaviors. The research mission was to empirically assess the salient dimensions of consumers' states of mind (positive and negative affect, psychological essentialism, epistemic curiosity), states of being (store atmospherics), and states of action (retail patronage behaviors) in a cultural context based on Mehrabian-Russell theory of environmental psychology. Specifically, the retail patronage setting was selected as foreign-based fast-food franchises because it represents both a relevant and timely situational context for consumer behavior. This dissertation makes several contributions to international retail patronage literature. First, it frames curiosity as an aroused emotional state and finds support for the relationship between consumer epistemic curiosity and retail patronage. Second, it provides support for the linkage between consumer affect and retail patronage in an international retail setting. Third, it reveals that affect has a greater impact on retail patronage than epistemic curiosity. The overarching finding of this study is an inability to tie the cultural elements in retail atmospherics, including signs, symbols, and artifacts, to consumer emotions. In addition, we were unable to ...
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Bank Capital, Efficient Market Hypothesis, and Bank Borrowing During the Financial Crisis of 2007 and 2008

Bank Capital, Efficient Market Hypothesis, and Bank Borrowing During the Financial Crisis of 2007 and 2008

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Date: December 2014
Creator: Zia, Mujtaba
Description: During the Great Recession of 2007 and 2008, liquidity and credit dried up, threatening the stability of financial institutions, particularly the banking firms. Traditional source of funds from the last resort, the Discount Window of the Federal Reserve System, failed to remedy the liquidity problem. To assuage the liquidity and credit problem, the Federal Reserve System established several emergency lending facilities and provided unprecedented amount of loans to the banking industry. Using a dataset published by Bloomberg LLP in the aftermaths of the financial crisis, which contains daily loan balances from the Fed, I conduct an event study to test whether financial markets are efficient in reflecting all public, anticipated and classified information in security prices. The most important contribution of this dissertation to the finance discipline and literature is the investigation and analysis of the Fed’s unprecedented loans to the banking industry during the Great Recession and the market reaction to it. The second major contribution of this study is the empirical test of strong form efficient market hypothesis, which has not been feasible due to legal data challenges. This dissertation has other contributions to the finance discipline and banking research. First, I develop an algorithm for measuring the ...
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Bass Reeves: a History • a Novel • a Crusade, Volume 1: the Rise

Bass Reeves: a History • a Novel • a Crusade, Volume 1: the Rise

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Date: August 2015
Creator: Thompson, Sidney
Description: This literary/historical novel details the life of African-American Deputy US Marshal Bass Reeves between the years 1838-1862 and 1883-1884. One plotline depicts Reeves’s youth as a slave, including his service as a body servant to a Confederate cavalry officer during the Civil War. Another plotline depicts him years later, after Emancipation, at the height of his deputy career, when he has become the most feared, most successful lawman in Indian Territory, the largest federal jurisdiction in American history and the most dangerous part of the Old West. A preface explores the uniqueness of this project’s historical relevance and literary positioning as a neo-slave narrative, and addresses a few liberties that I take with the historical record.
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Belief Transfers in Co-branding and Brand Extension and the Roles of Perceptual Fit

Belief Transfers in Co-branding and Brand Extension and the Roles of Perceptual Fit

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Date: May 2015
Creator: Roswinanto, Widyarso
Description: Existing co-branding and brand extension research generally coalesces around two important constructs: perceptual fit and attitude toward the brand. Studies in co-branding and brand extension to date have generally emphasized the transference of affective elements of attitude from parent brand to the extension. Researchers and practitioners clearly need to learn more about the transfer of belief, the cognitive elements of attitude. Too little is currently known about whether and how beliefs are actually transferred in co-branding and brand extension applications, particularly in terms of perceptual fit. This dissertation investigates belief transfer and the effect of perceptual fit on belief transfer in co-branding and brand extension scenarios and develops answers to the following research questions: 1.Are different categories of beliefs transferable from parent brand to theextension? 2.How do various sub-dimensions of perceptual fit affect belief transfers fromparent brands to the extension? 3.How do different categories of beliefs affect consumers’ intentions to purchasethe extension products? Categorization Theory was used as the fundamental theory to build the hypotheses. This dissertation involved qualitative studies, belief scale development, and experimental design studies. The results revealed that aesthetic and functional beliefs are positively transferred from parent brand to the extension. The transfer of aesthetic beliefs is ...
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Between Comancheros and Comanchería: a History of Fort Bascom, New Mexico

Between Comancheros and Comanchería: a History of Fort Bascom, New Mexico

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Date: August 2012
Creator: Blackshear, James Bailey
Description: In 1863, Fort Bascom was built along the Canadian River in the Eroded Plains of Territorial New Mexico. Its unique location placed it between the Comanches of Texas and the Comancheros of the Sangre de Cristo Mountains. This post was situated within Comanchería during the height of the United States Army's war against the Southern Plains Indians, yet it has garnered little attention. This study broadens the scholarly understanding of how the United States Army gained control of the Southwest by examining the role Fort Bascom played in this mission. This includes an exploration of the Canadian River Valley environment, an examination of the economic relationship that existed between the Southern Plains Indians and the mountain people of New Mexico, and an account of the daily life of soldiers posted to Fort Bascom. This dissertation thus provides an environmental and cultural history of the Canadian River Valley in New Mexico, a social history of the men stationed at Fort Bascom, and proof that the post played a key role in the Army's efforts to gain control of the Southern Plains Indians. This study argues that Fort Bascom should be recognized as Texas' northern-most frontier fort. Its men were closer to ...
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Bioinspired and biocompatible coatings of poly(butylene adipate-co-terephthalate) and layer double hydroxide composites for corrosion resistance

Bioinspired and biocompatible coatings of poly(butylene adipate-co-terephthalate) and layer double hydroxide composites for corrosion resistance

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Date: May 2016
Creator: Rizvi, Syed Hussain
Description: Hierarchical arrangement of biological composites such as nacre and bone containing high filler (ceramic) content results in high strength and toughness of the natural material. In this study we mimic the design of layered bone microstructure and fabricate an optimal multifunctional bio-nanocomposite having strength, toughness and corrosion resistance. Poly (butylene adipate-co-terephthalate) (PBAT), a biodegradable polymer was used as a substrate material with the reinforcement of LDH (Layered double hydroxide) as a nanofiller in different concentrations to achieve enhancement in mechanical properties as well as processing related thermostability. Corrosion resistance was increased by mimicking a layered structured which incorporated a tortuous diffusion path.
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Biomass-Derived Activated Carbon through Self-Activation Process

Biomass-Derived Activated Carbon through Self-Activation Process

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Date: May 2016
Creator: Xia, Changlei
Description: Self-activation is a process that takes advantage of the gases emitted from the pyrolysis process of biomass to activate the converted carbon. The pyrolytic gases from the biomass contain CO2 and H2O, which can be used as activating agents. As two common methods, both of physical activation using CO2 and chemical activation using ZnCl2 introduce additional gas (CO2) or chemical (ZnCl2), in which the CO2 emission from the activation process or the zinc compound removal by acid from the follow-up process will cause environmental concerns. In comparison with these conventional activation processes, the self-activation process could avoid the cost of activating agents and is more environmentally friendly, since the exhaust gases (CO and H2) can be used as fuel or feedstock for the further synthesis in methanol production. In this research, many types of biomass were successfully converted into activated carbon through the self-activation process. An activation model was developed to describe the changes of specific surface area and pore volume during the activation. The relationships between the activating temperature, dwelling time, yield, specific surface area, and specific pore volume were detailed investigated. The highest specific surface area and pore volume of the biomass-derived activated carbon through the self-activation process ...
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Boosting for Learning From Imbalanced, Multiclass Data Sets

Boosting for Learning From Imbalanced, Multiclass Data Sets

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Date: December 2013
Creator: Abouelenien, Mohamed
Description: In many real-world applications, it is common to have uneven number of examples among multiple classes. The data imbalance, however, usually complicates the learning process, especially for the minority classes, and results in deteriorated performance. Boosting methods were proposed to handle the imbalance problem. These methods need elongated training time and require diversity among the classifiers of the ensemble to achieve improved performance. Additionally, extending the boosting method to handle multi-class data sets is not straightforward. Examples of applications that suffer from imbalanced multi-class data can be found in face recognition, where tens of classes exist, and in capsule endoscopy, which suffers massive imbalance between the classes. This dissertation introduces RegBoost, a new boosting framework to address the imbalanced, multi-class problems. This method applies a weighted stratified sampling technique and incorporates a regularization term that accommodates multi-class data sets and automatically determines the error bound of each base classifier. The regularization parameter penalizes the classifier when it misclassifies instances that were correctly classified in the previous iteration. The parameter additionally reduces the bias towards majority classes. Experiments are conducted using 12 diverse data sets with moderate to high imbalance ratios. The results demonstrate superior performance of the proposed method compared ...
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