The activity of plant 9-lipoxygenases (LOXs) influences the outcome of Arabidopsis thaliana interaction with pathogen and insects. Evidence provided here indicates that in Arabidopsis, 9-LOXs facilitate infestation by Myzus persicae, commonly known as the green peach aphid (GPA), a sap-sucking insect, and infection by the fungal pathogen Fusarium graminearum. in comparison to the wild-type plant, lox5 mutants, which are deficient in a 9-lipoxygenase, GPA population was smaller and the insect spent less time feeding from sieve elements and xylem, thus resulting in reduced water content and fecundity of GPA. LOX5 expression is induced rapidly in roots of GPA-infested plants. This increase in LOX5 expression is paralleled by an increase in LOX5-synthesized oxylipins in the root and petiole exudates of GPA-infested plants. Micrografting experiments demonstrated that GPA population size was smaller on plants in which the roots were of the lox5 mutant genotype. Exogenous treatment of lox5 mutant roots with 9-hydroxyoctadecanoic acid restored water content and population size of GPA on lox5 mutants. Together, these results suggest that LOX5 genotype in roots is critical for facilitating insect infestation of Arabidopsis. in Arabidopsis, 9-LOX function is also required for facilitating infection by F. graminearum, which is a leading cause of Fusarium head blight (FHB) disease in wheat and other small grain crops. Loss of LOX1 and LOX5 function resulted in enhanced resistance to F. graminearum infection. Similarly in wheat, RNA interference mediated silencing of the 9-LOX homolog TaLpx1, resulted in enhanced resistance to F. graminearum. Experiments in Arabidopsis indicate that 9-LOXs promote susceptibility to this fungus by suppressing the activation of salicylic acid-mediated defense responses that are important for basal resistance to this fungus. the lox1 and lox5 mutants were also compromised for systemic acquired resistance (SAR), an inducible defense mechanism that is systemically activated throughout a plant in response to a …
In this research, multi-perspective image registration using LiDAR and visual images was considered. 2D-3D image registration is a difficult task because it requires the extraction of different semantic features from each modality. This problem is solved in three parts. The first step involves detection and extraction of common features from each of the data sets. The second step consists of associating the common features between two different modalities. Traditional methods use lines or orthogonal corners as common features. The third step consists of building the projection matrix. Many existing methods use global positing system (GPS) or inertial navigation system (INS) for an initial estimate of the camera pose. However, the approach discussed herein does not use GPS, INS, or any such devices for initial estimate; hence the model can be used in places like the lunar surface or Mars where GPS or INS are not available. A variation of the method is also described, which does not require strong features from both images but rather uses intensity gradients in the image. This can be useful when one image does not have strong features (such as lines) or there are too many extraneous features.
The field of strategic management addresses challenges that firms encounter in an attempt to remain competitive. The ability to explain variation in firm success through examination of knowledge flows has become a prominent focus of research in the strategic management literature. Specifically, researchers have sought to further examine how firms convert knowledge, a phenomenon conceptualized as absorptive capacity. Absorptive capacity is the firm’s ability to acquire, assimilate, transform, and exploit knowledge. Few studies have captured the richness and multi-dimensionality of absorptive capacity, and it remains to be understood how the dimensions of the phenomenon convert knowledge. Furthermore, how absorptive capacity influences the firm remains to be understood. To address these research gaps, this dissertation seeks to (1) determine how absorptive capacity converts knowledge, and (2) determine how absorptive capacity influences firm capabilities. The research questions are investigated using structural modeling techniques to analyze data collected from software-industry firms. The findings offer contributions to the absorptive capacity and capability literatures. For example, absorptive capacity is hypothesized to consist of complex relationships among its internal dimensions. However, findings of this study suggest the relationships among the dimensions are linear in nature. This finding is in line with the theoretical foundations of and early literature on absorptive capacity but contrary to recent conceptualizations, which suggests relationships among the dimensions are more closely related to the theoretical origins of absorptive capacity. Additionally, to examine how absorptive capacity influences the firm, a capability-based perspective is used to hypothesize the influence of absorptive capacity on firm capabilities. Findings suggest absorptive capacity positively influences each dimension of firm capabilities (e.g., operational, customer, and innovation capabilities); thus, absorptive capacity influences the firm by altering firm capabilities. Given the richness of the findings, numerous fields are likely to benefit from this investigation. Through an examination of absorptive capacity and …
Despite socioeconomic disadvantages, less acculturated Mexican Americans tend to exhibit better mental health than their more acculturated counterparts. However, in the case of older Mexican American adults, research has demonstrated the opposite to be true (Gonzalez, Haan, & Hinton, 2001). A variable of interest potentially responsible for this difference is social support. Thus, the current study proposed to investigate the mediation and moderation effects that social support has on the relationship between acculturation and depression in older Mexican American adults age 60 or older. Data from the Health and Retirement Study (HRS) was analyzed. Results showed that the mediating effect of contact with one’s children (-.109*) and the moderating effect of total social support and contact with one’s children (-.127*; -.103*) were statistically significant in the relationship between acculturation and depression. Although these effects are small they may still hold important implications for better understanding this population.
There are over a million adopted children in the United States, which makes up over 2% of the population. in spite of the fact that the majority of children are adopted into loving and caring homes, early life trauma puts them at higher risk for developing behavioral and emotional problems than non-adopted children. Due to these issues, many adoptive parents encounter post-adoption stress. This stress is often linked to minimal education regarding short- and long-term challenges associated with adoption. the adoption agency is likely the best group for addressing challenges, yet few researchers have studied adoption agency communication and adoptive parent adjustment. in this study I examined pre-adoption communication satisfaction, post-adoption adjustment (life change and parental adjustment), and coping strategies. Hypothesis 1 questioned the relationship between adoptive parents’ pre-adoption communication satisfaction with their social workers and post-adoption family adjustment; this hypothesis was supported only for problems related to home and work life adjustment. Hypothesis 2 predicted coping strategies would mediate the relationship between communication satisfaction and family adjustment. H2 was not supported for both life change and parental adjustment. Research Questions 1a and 1b inquired about the coping strategy that had an impact on life change and parental adjustment; escape-avoidance coping was most common for problems related to parental difficulty adjustment. a second research question was added post hoc; it questioned if special needs adopted children had an impact on family adjustment. Results indicated the special needs designation is related to home and work life adjustment. After discussing the theoretical and practical implications of this study, I offer limitations and directions for future research.
Floating describes the act of staff moving from one unit to another based on the needs of the patients in a hospital. Many staff who float to different units express negative feelings, including anxiety and lack in self-efficacy. However, floating is both an economical and efficient method to use staff across the hospital, especially with current staffing shortages in the United States. This study investigated how the use of mobile performance support devices may help reduce anxiety and increase self-efficacy for those staff who float to different units. with access to multiple resources available on the mobile device, Bandura's social learning theory and self-efficacy concept set the framework through modeling, observing, and imitating others in order to reproduce certain behaviors and tasks and believe in one's capability to perform. a quantitative study incorporating the retrospective pretest-posttest design was conducted using the population of float staff, including both nurses and respiratory therapists, from Children's Medical Center of Dallas. Both the State-Trait Anxiety Inventory and General Self-Efficacy Scale, along with a basic demographic tool, were used to explore anxiety and self-efficacy in relation to the usage of mobile performance support devices. Findings can be used to impact the negative feelings of staff towards the idea of floating.
Studies of affective forecasting examine people’s ability to predict (forecast) their emotional (affective) responses to future events. Affective forecasts underlie nearly all decisions people make and the actions they take. However, people engage in systematic cognitive errors when making affective forecasts and most often overestimate the intensity and duration of their emotional responses. Understanding the mechanisms that lead to affective forecasting errors (e.g., immune neglect) and examining the utility of methods for improving affective forecasting errors (e.g., surrogation) can provide highly valuable information for clinicians as they assist clients in determining their goals both for therapy and for life. The first purpose of the current study was to determine if affective forecasting errors due to immune neglect lead to misjudgments about the relative emotional impact of minor versus moderate negative experiences (i.e., trauma severity). The second purpose was to examine the utility of surrogation for improving affective forecasts. Potential interaction effects between these two variables were also examined. The current study utilized a 2 (Trauma Severity: minor, moderate) X 3 (Prediction Information: surrogation information only, simulation information only, both types of information) experimental design. Undergraduates were recruited via the SONA system and randomly assigned to one of the six experimental conditions. A preliminary study was conducted to obtain surrogation information for use in the main study. All participants in the main study predicted how they would feel 10 minutes after receiving negative personality feedback, using a 10-point scale ranging from (1) very unhappy to (10) very happy. These predictions constitute their affective forecasts. All participants then actually received the negative personality feedback (ostensibly from another participant, a peer, in a nearby room) and reported their actual affective states ten minutes later, using the same scale. These ratings constitute their affective reports. Affective forecasting error was calculated as the difference between …
The dissertation consists of a critical preface and a novel. The preface analyzes what it terms “polyvocal” novels, or novels employing multiple points of view, as well as “layered storytelling,” or layers of textuality within novels, such as stories within stories. Specifically, the first part of the preface discusses polyvocality in twenty-first century American novels, while the second part explores layered storytelling in novels responding to World War II or the terrorist attacks of 9/11. The preface analyzes the advantages and difficulties connected to these techniques, as well as their aptitude for reflecting the fractured, disconnected, and subjective nature of the narratives we construct to interpret traumatic experiences. It also acknowledges the necessity—despite its inherent limitations—of using language to engage with this fragmentation and cope with its challenges. The preface uses numerous novels as examples and case studies, and it also explores these concepts and techniques in relation to the process of writing the novel After the Planes. After the Planes depicts multiple generations of a family who utilize storytelling as a means to work through grief, hurt, misunderstanding, and loss—whether from interpersonal conflicts or from war. Against her father’s wishes, a young woman moves in with her nearly-unknown grandfather, struggling to understand the rifts in her family and how they have shaped her own identity. She reads a book sent to her by her father, which turns out to be his story of growing up in the years following World War II. The book was intercepted and emended by her grandfather, who inserts his own commentary throughout, complicating her father’s hopes of reconciliation. The novel moves between two main narratives, one set primarily in 1951 and the other in the days and weeks immediately prior to September 11, 2001.
In this collection of short stories, I abduct experiences from my own life and take them on an imaginative journey. I experiment with elements of structure and point of view, often incorporating the magical or surreal to amplify the narrator’s internal landscape. As demonstrated in the title story, “Almost Astronauts,” these stories all deal with a sudden and sometimes destructive shift in the narrator’s perspective.
N-Acylethanolamines (NAEs) are a class of bioactive lipids, and FAAH is one of the enzymes responsible for degrading NAEs in both plants and animals. in plants, FAAH appears to be closely associated with ABA, a phytohormone which has long been associated with plant stress responses, since the overexpression of FAAH in Arabidopsis results in ABA hypersensitivity. Therefore, it is reasonable to speculate that alterations in FAAH transcript levels will result in altered stress responses in plants. to investigate this hypothesis experiments were carried out in which wild type (WT), FAAH-overexpressing (OE), and T-DNA insertional FAAH knockouts of Arabidopsis (faah) were grown in MS media under stress conditions. the stress conditions tested included chilling stress, heavy metal stress induced by cadmium or copper, nutrient limitations induced by low phosphorus or low nitrogen, salt stress induced with NaCl, and osmotic stress induced with mannitol. the OE plants were consistently hypersensitive to all stress conditions in relation to wild type plants. Inactive FAAH overexpressors did not have the hypersensitivity to the salt and osmotic stress of the active OE plants and were instead tolerant to these stresses. FAAH2 (faah2) knockouts and FAAH 1 and 2 double knockouts (faah 1+2) were based on some root development parameters somewhat more tolerant than WT plants, but more sensitive in terms of shoot growth. Collectively the data suggests that FAAH activity may interact with stress-responsive pathways in plants, perhaps including pathways involving ABA.
This paper examines two English polyverbal constructions, COME to V2 and GET to V2, as exemplified in Examples 1 and 2, respectively. (1) the senator came to know thousands of his constituents (2) Little Johnny got to eat ice cream after every little league game. Previous studies considered these types of constructions (though come and get as used here have not been sufficiently studied) as belonging to a special class of complement constructions, in which the infinitive is regarded as instantiating a separate, subordinate predication from that of the “matrix” or leftward finite verb. These constructions, however, exhibit systematic deviation from the various criteria proposed in previous research. This study uses the American National Corpus to investigate the statistical propensities of the target phenomena via lexico-syntactic (collostructional analysis) and morpho-syntactic (binary logistic regression) features, as captured through the lens of construction grammar.
This is an analysis of combat operations of US First Army under the command of Courtney Hodges, between August 1 and September 12, 1944, with an emphasis upon 1st, 4th, 9th, and 30th Divisions. However, other formations are necessarily discussed in order to maintain context. Indeed, many historians have failed to emphasize the complex interdependent nature of these efforts, and the traditional narrative has been distorted by inadequate situational awareness. This study argues that the army's operations were exceedingly difficult, resulting in approximately 40,000 casualties over a six week period. Although historians claim that the Germans were essentially defeated by the end of July, and that the Allied advance was subsequently halted by logistical difficulties, the official combat records clarify that logistical shortages were a tertiary factor, as the enemy remained capable of strong resistance. Consequently, defensive efforts were the primary factor hindering the advance, in conjunction with deteriorating weather conditions, rugged terrain, and surprisingly severe traffic congestion. Although this was mobile warfare, military theorists have overestimated the effectiveness of mechanization and underestimated the potential for antitank defenses. Ultimately, this study asserts that First Army was the primary American combat formation, and historians have exaggerated the importance of George Patton's Third Army. Therefore, in order to understand an American way of war, the combat operations of First Army deserve far more attention than they have previously received. This narrative thus emphasizes forgotten battles, including: Tessy, St. Sever, Tete, Perriers, Mayenne, Ranes, Flers, Mace, Elbeuf, Mantes, Corbeil, Sevran, Mons, Cambrai, Philippeville, Dinant, and Aubel.
Pastorale pour Orgue (1909) is Jean Jules Aimable Roger-Ducasse’s only solo organ composition, which demonstrates skillful use of organ colors and demands a virtuoso technique for performance. Writing Pastorale in 1909, Roger-Ducasse synthesized compositional styles and techniques of two very different compositional approaches – impressionism and classicism. This study examines the stylistic characteristics of Pastorale by Roger-Ducasse as examples of both of these influences. the synthesis in Pastorale is primarily evident in the combination of classical forms and generic references with impressionist harmony and color. Thus, examining these musical elements provides hitherto unexplored insights into Pastorale as a master solo organ work of the early twentieth century. the dissertation is divided into four chapters. the first chapter presents the purpose, the significance, and the state of research of the piece. in the second chapter, I examine the traits of classicism through genre, form, thematic variation and other classicist elements of the composition. the third chapter presents the traits of impressionism including harmonic parallelism, extended chords, pedal points, ostinatos, and whole-tone scales. in the fourth chapter, I summarize the study and make a suggestion for further research of the piece.
Texas is the second largest state in U.S.A. based on geographical area, population and the economy. It is home to several large coastal urban areas with major industries and infrastructure supporting the fossil-fuel based energy sector. Most of the major cities on the state have been impacted by significant air pollution events over the past decade. Studies conducted in the southern coastal region of TX have identified long range transport as a major contributor of particulate matter (PM) pollution along with local emissions. Biomass burns, secondary sulfates and diesel emissions sources are comprise as the dominant mass of PM2.5 have been noted to be formed by the long range transport biomass from Central America. Thus, the primary objective of this study was to identify and quantify local as well as regional sources contributing to the PM pollution in the coastal area of Brownsville located along the Gulf of Mexico. Source apportionment techniques such as principal component analysis (PCA) and positive matrix factorization (PMF) were employed on the air quality monitoring data to identify and quantify local and regional sources affecting this coastal region. As a supplement to the PMF and PCA, conditional probability function (CPF) analysis and potential source contribution function (PSCF) analysis were employed to characterize the meteorological influences for PM events. PCA identified an optimal solution of 6 sources affecting the coastal area of Brownsville, while PMF resolved 8 sources for the same area. Biomass comingled with sea salt was identified to be the dominant contributor from the PCA analysis with 30.2% of the apportioned PM mass in Brownsville, meanwhile PMF account secondary sulfates I & II with 27.6%. the other common sources identified included, biomass burning, crustal dust, secondary sulfate, oil combustion, mobile sources and miscellaneous traffic sources.
This study was a program evaluation for an autism treatment center for the period of April 2008 through August 2011. the study extended previous evaluations of the autism treatment center. the purpose of this evaluation was to determine the degree to which the center’s measures corresponded with its stated mission goals. a number of data sources were reviewed including client records of demographic and outcome information. Findings suggest the center maintained records that allow for the evaluation of most of its mission’s goals. There were, however, difficulties with data collection, storage, and retrieval. the present program evaluation found that missing information and lack of follow-up information hindered efforts toward mission evaluation.
The main purpose of this mixed methods research was to explore and analyze visitors’ overall experience while they attended a museum exhibition, and examine how this experience was affected by previously using a virtual 3dimensional representation of the museum itself. The research measured knowledge acquisition in a virtual museum, and compared this knowledge acquired between a virtual museum versus a real one, employing a series of questionnaires, unobtrusive observations, surveys, personal and group interviews related to the exhibition and the artist. A group of twenty-seven undergraduate students in their first semester at the College of Architecture and Design of the Autonomous University of the State of Mexico participated in the research, and were divided in two groups, one of which used a 3D virtual representation previous to the museum visit. Results show that participants who experienced the virtual museum concurred that using it was a positive experience that prepared them to go to the real museum because they knew already what they were going to find. Most of the participants who experienced the virtual museum exhibited an increased activity during their museum visit, either agreeing, being more participative, concurring and showing acceptance, asking questions, or even giving their opinion and analysis, disagreeing with the guide and showing passive rejection. Also participants from this group showed an increase on their correct answers to the knowledge acquisition questionnaires, going from 27% answers responded correctly in the pre-test, to 67% of correct answers after the virtual museum usage. The research attempted to show that experiencing a virtual museum can be similar to the experience in physical museum visits, not only engaging participants to go to the museum, but sometimes even offering a more functional way to deliver content. Results of this research evidence that using a virtual museum creates a positive impact in …
This dissertation contains two parts: Part I, which discusses the elegy of possessive intent, a subgenre of the contemporary American elegy; and Part II, Antigravity, a collection of poems. English elegies have been closely rooted to a specific grief, making the poems closer to occasional poems. The poet—or at least the poet’s speaker—seeks some kind of public consolation for (often) a private loss. The Americanized form does stray from the traditional elegy yet retains some of its characteristics. Some American elegies memorialize failed romantic relationships rather than the dead. In their memorials, these speakers seek a completion for the lack the broken relationship has created in the speakers’ lives. What they can’t replace, they substitute with something personal. As the contemporary poem becomes further removed from tradition, it’s no surprise that the elegy has evolved as well. Discussions of elegies have never ventured into the type of elegy that concerns itself with the sort of unacknowledged loss found in some contemporary American poems of unrequited love. These poems all have speakers who willfully refuse to acknowledge the loss of their love-objects and strive to maintain control/ownership of their beloveds even in the face of rejection.
The purpose of this dissertation is to give instruction regarding the performance of three important piano works by Jürg Baur (1918-2010). Aphorismen, Capriccio, and Heptameron stand out as his most significant piano works both because of their length and because of their pianistic complexity. Since Baur had a successful career as both teacher and composer during his lifetime, his acclaimed works received many honors in Germany. His works can be performed by intermediate to advanced students. Intermediate students can easily offer simpler pieces like Aphorismen in competitions, while pieces like Capriccio and Heptameron better are suited to a more advanced level. Although some of his compositions are difficult to perform compared with other modern German works, Baur's music is more accessible. In the article, "Auf der Spuren der alten Zeit" Baur is quoted to state that Paul Hindemith and Bela Bartok's music influenced his own compositional ideas. However, although Baur is a modern composer, he didn't write in a totally atonal style, but rather attempted to broaden tonality. While Heptameron is atonal, Aphorismen and Capriccio give the impression of tonality, thus they are more accessible to the audience. I was fortunate enough to study Aphorismen with Baur as well as receiving advice for performance of Capriccio and some movements of Heptameron. Therefore, I gained a primary source of instruction, particularly in regards to pedal markings, rhythmic indications, voice balancing, finger suggestions, articulation markings, and tone of musical expression. In this dissertation, I include my own instructions (accepted by the composer) along with the composer's intentions.
The 21st century is now in the second decade and the need for 21st century skills is discussed at all levels of education as necessary for student success in the future. Federal, state, and districts are addressing this need and have written technology plans to address 21st century skills needed. the purpose of this dissertation is to contribute to the knowledge of 21st century educational technology. the data includes seven recorded interviews from two separate research projects covering two models of education as teachers discuss teaching, learning, and technology. the data studied determines how educational technology perceived in the school environments has been integrated into the classrooms. the initial scripting of video interviews from two research projects began the analysis of data. Particular themes emerged in response to questions established by the two separate research projects focused on classroom, school, and district environmental arrangements that examined; teaching responsibilities and practices; student learning opportunities; and how technology is woven throughout instruction. Further exploration of themes stemmed from analysis conducted with the qualitative software program, NVivo 9. the themes discussed in this paper relate to instructor perceptions of teaching, learning, classroom procedures, and the role technology plays in each. Also noted are the factors beyond the teacher’s responsibility and set rules that include the school environment, district expectations, and supported teaching strategies for the schools. the teachers expressed their view that technology is an important support for learning and that they used technology to accomplish many of the tasks related to supporting teaching and learning. As perceived by the teachers, a major component that surfaced as a result of the analysis was children’s technology use was most drastically influenced by the expectations of the instructional leader to develop and the need to foster 21st century learning strategies such as critical thinking skills, …
The purpose of the Roman Argei ceremony, during which the Vestal Virgins harvested made and paraded rush puppets only to throw them into the Tiber, is widely debated. Modern historians supply three main reasons for the purpose of the Argei: an agrarian act, a scapegoat, and finally as an offering averting deceased spirits or Lares. I suggest that the ceremony also related to war and the spectacle of displaying war casualties. I compare the ancient Near East and Rome and connect the element of war and husbandry and claim that the Argei paralleled the sacred marriage. in addition to an agricultural and purification rite, these rituals may have served as sympathetic magic for pre- and inter-war periods. As of yet, no author has proposed the Argei as a ceremony related to war. By looking at the Argei holistically I open the door for a new direction of inquiry on the Argei ceremony, fertility cults in the Near East and in Rome, and on the execution of war criminals.The Argei and new year’s sacred marriage both occurred during the initiation of campaign and spring planting and harvest season. Both in the ancient Near East and in Rome, animal victims were sacrificed and displayed through impaling, crucifixion, and hanging for fertility and in war. for both Rome and the Near East war casualties were displayed on sacred trees. Through the Near East cultures a strong correlation existed between impaling, hanging, and crucifixion in war and Sacred Tree fertility worship. By examining Roman tree worship, military rituals, and agricultural ceremonies a similar correlation becomes apparent. on the same day of the Argei, Mars was married to the anthropomorphized new year and within the month became a scapegoat expelled from the city. Additionally, on the first day of the Argei boys became soldiers.
This auto-ethnographic study focuses on Houston’s art car community and the grassroots movement’s 25 year relationship with the city through an art form that has created a sense of community. Art cars transform ordinary vehicles into personally conceived visions through spectacle, disrupting status quo messages of dominant culture regarding automobiles and norms of ownership and operation. An annual parade is an egalitarian space for display and performance, including art cars created by individuals who drive their personally modified vehicles every day, occasional entries by internationally renowned artists, and entries created by youth groups. A locally proactive public has created a movement has co-opted the cultural spectacle, creating a community of practice. I studied the events of the Orange Show Center for Visionary Art’s Art Car Weekend to give me insight into art and its value for people in this community. Sources of data included the creation of a participatory art car, journaling, field observation, and semi-structured interviews. The first part is my academic grounding, informed by critical pedagogy and socially reconstructive art practices. The second part narrates my experiences and understandings of the community along with the voices of others. Dominant themes of exploration include empowerment, community, and art. I examine the purposes for participation by artists, as well in the practices of audiences and organizations that provide support for this art form. My findings have significant implications community-based art education and k-12 classroom educators. Relational and dialogic approaches to making art, teaching, and researching are tied to problem-posing education as a recommendation for art education.
Childhood obesity in America is reaching epidemic proportions. This study explored whether daily online lunch menu information was sufficient to enable parents to advise their children about healthy and unhealthy menu choices in 350 Texas middle schools and whether online menu information strongly correlated with the descriptions of the offerings given by 52 school cafeteria managers in telephone interviews. Although schools are making efforts to describe their offerings, they are not vigorously taking advantage of the opportunity to aggressively inform or educate. They are not coding their descriptions in such a way as to explicitly brand food as healthy or unhealthy. They are also not labeling food as generally required by law for consumer services that provide food (except for the fresh produce that lines supermarket shelves). Instead, they only briefly describe what they are serving in the way of fruit in one or two word snippets. Finally, cafeteria managers’ online descriptions were inconsistent with what they described in interviews. Online and verbal descriptions were sometimes contradictory, raising questions about the accuracy of either type of description.
Auditors regularly make judgments regarding whether a client’s chosen accounting policy is appropriate and in accordance with generally accepted accounting Principles (GAAP). However, to form this judgment, auditors must either possess adequate topic-specific knowledge or must gain such knowledge through information search. This search is subject to numerous biases, including a bias toward confirmation of a client’s preference. It is important to further our understanding of bias in auditors’ information search to identify its causes and effects. Furthering our understanding is necessary to provide a basis for recommending and evaluating a potential debiaser, such as accountability. the Public Company Accounting Oversight Board (PCAOB) annually inspects the audit files of selected engagements, which introduces a new form of accountability within the auditing profession. This new form of accountability has come at great cost, however, there is little empirical evidence regarding its effects on auditors’ processes. As such, it is important to understand whether the presence of accountability from the PCAOB is effective in modifying auditors’ search behaviors to diminish confirmation bias. Using an online experiment, I manipulate client preference (unknown vs. known) and PCAOB accountability pressure (low vs. high) and measure search type (information –focus or decision-focus), search depth (shallow or deep) and documentation quality. I investigate whether auditors’ information search behaviors differ based on knowledge of client’s preference and in the presence of accountability from an expected PCAOB inspection. I also investigate whether differences in auditors’ information search behaviors influence documentation quality, which is the outcome of greatest concern to the PCAOB. I hypothesize and find a client preference effect on information search type such that auditors with knowledge of the client preference consider guidance associated with the client’s preference longer than those without knowledge of the client’s preference. Contrary to expectations, PCAOB accountability pressure does not influence information search …
This thesis explores the classification of emotions in song lyrics, using automatic approaches applied to a novel corpus of 100 popular songs. I use crowd sourcing via Amazon Mechanical Turk to collect line-level emotions annotations for this collection of song lyrics. I then build classifiers that rely on textual features to automatically identify the presence of one or more of the following six Ekman emotions: anger, disgust, fear, joy, sadness and surprise. I compare different classification systems and evaluate the performance of the automatic systems against the manual annotations. I also introduce a system that uses data collected from the social network Twitter. I use the Twitter API to collect a large corpus of tweets manually labeled by their authors for one of the six emotions of interest. I then compare the classification of emotions obtained when training on data automatically collected from Twitter versus data obtained through crowd sourced annotations.
Globally distributed software teams are widespread throughout industry. But finding reliable methods that can properly assess a team's activities is a real challenge. Methods such as surveys and manual coding of activities are too time consuming and are often unreliable. Recent advances in information retrieval and linguistics, however, suggest that automated and/or semi-automated text classification algorithms could be an effective way of finding differences in the communication patterns among individuals and groups. Communication among group members is frequent and generates a significant amount of data. Thus having a web-based tool that can automatically analyze the communication patterns among global software teams could lead to a better understanding of group performance. The goal of this thesis, therefore, is to compare automatic and semi-automatic measures of communication and evaluate their effectiveness in classifying different types of group activities that occur within a global software development project. In order to achieve this goal, we developed a web-based component that can be used to help clean and classify communication activities. The component was then used to compare different automated text classification techniques on various group activities to determine their effectiveness in correctly classifying data from a global software development team project.
While advancements in treatment have made HIV a more manageable disease, only recently have psychosocial variables associated with the health of persons living with HIV (PLH) began to receive increased scrutiny. HIV-related stigma, considered by some researchers to be a “second epidemic,” is one such psychosocial variable and is associated with negative physiological and psychological health outcomes. In an effort to alleviate the effects of stress, increased research attention has focused on forgiveness as a teachable coping strategy. Current forgiveness interventions demonstrate encouraging results in decreasing anger and neutralizing stress but have not been applied to HIV-positive populations. In this study, Lazarus and Folkman’s transactional model of stress and coping (1984) and Prochaska and Velicer’s transtheoretical model of health behavior (1997) were utilized as theoretical frameworks to inform a randomized clinical trial that examines coping skills, particularly forgiveness, in PLH and perceived HIV-related stigma. An ethnically diverse sample of HIV-positive adults (n = 57) was randomized into a treatment or control group. The treatment group participated in six weeks of cognitive-behavioral group therapy that focused on the teaching of forgiveness as an effective coping tool while the control group was psychoeducational in nature and did not involve mention of forgiveness. Data was obtained on a variety of medical and psychosocial variables, including types of forgiveness (dispositional forgiveness, forgiveness of self, forgiveness of others, and forgiveness of situations) and perceived HIV-related stigma. Data were collected at three time points: at baseline (Time 1) prior to randomization of participants to the treatment or control group, immediately post intervention (Time 2), and at six-month follow-up (Time 3). Importantly, forgiveness was shown to be a teachable skill that PLH can use to potentially improve mental health. Men in the treatment group reported significantly higher levels of dispositional forgiveness and self-forgiveness than men in the …
As the technology is advances the reduced size of hardware gives rise to an additive 1/f baseband noise. This additive 1/f noise is a system noise generated due to miniaturization of hardware and affects the lower frequencies. Though 1/f noise does not show much effect in wide band channels because of its nature to affect only certain frequencies, 1/f noise becomes a prominent in OFDM communication systems where narrow band channels are used. in this thesis, I study the effects of 1/f noise on the OFDM systems and implement algorithms for estimation and suppression of the noise using Kalman filter. Suppression of the noise is achieved by subtracting the estimated noise from the received noise. I show that the performance of the system is considerably improved by applying the 1/f noise suppression.
The existing design provision in North American Specification for Cold- Formed Steel Structural Member (AISI S100) for the bearing strength of bolted connections were developed from tests on bolted connected sheets which were restrained by bolt nut and head with or without washers. However, in the cold-formed assemblies, particularly in trusses, the single bolt goes through both sides of the connected sections, making the connected sheets on each side unrestrained. the warping of the unrestrained sheet may reduce the bearing strength of the bolted connection. This research investigates the behavior and strength of bearing failure in bolted connections in cold-formed steel trusses. Tensile tests were conducted on trusses connections with various material thicknesses. It was found that the AISI S100 works well for thick connections but provides unconservative predictions for thin materials. Based on the experimental results, a modified bearing strength method is proposed for calculating the bearing strength of bolted truss connections. the proposed method can be used for any cold-formed steel connections with unrestrained sheet.
My dissertation aims at constructing an environmental ethics theory based on environmental aesthetics in order to advocate and promote environmentally sustainable practices, policies, and lifestyles. I attempt to construct an integrated environmental aesthetics in order to inspire people’s feelings of love towards nature and motivate them to protect it. In order to achieve this goal, I first examine the philosophical understanding and aesthetic appreciation of nature from philosophical traditions of China, which have an impact on the general public’s attitude towards nature. in chapter one of my dissertation, I point out that nature is viewed as an organic system which is always in a self-generating process of production and reproduction of life. the metaphysical foundation for this perspective of nature is ch’i. Therefore the aesthetic appreciation of nature in China is also the aesthetic appreciation of ch’i. with regard to the concept of ch’i, I focus on the following three questions: (1) what are the objective and aesthetic features of ch’i? (2) How do the Chinese appreciate aesthetic features of ch’i? (3) Why the objective features of ch’i are regarded as the objects of aesthetic appreciation? I argue that the Chinese appreciate the aesthetic features of ch’i by using intellectual intuition and that empathy is the reason why the objective features of ch’i are considered to be aesthetic features. in Chapter 2, I explain in detail the two aesthetic categories for aesthetic appreciation of nature in two major philosophical schools in China: emptiness and creativity. in Chapter 3, I examine the philosophical foundations for aesthetic appreciation of nature in the West. I first investigate the influence of traditional Western philosophy on the perceptions of nature. I argue that traditional Western philosophical thinking doesn’t support aesthetic appreciation of nature. I point out that aesthetic appreciation of nature started from eighteenth century …
The existing research on Latino familialism draws a distinction between the attitudes associated with familialism and familialism-based action. Because attitudes tend to be more stable when considering variables such as immigration generation status, etc., social science researchers tend to employ measures based on attitudinal aspects of familialism, rather than action or behavior. Because of this preference, there is a lack of studies that examine familialism-based action and behaviors. This dissertation consists of three unique studies that examine actions and behaviors associated with familialism, while taking into account the methodological concerns expressed by previous researchers. The first study uses nationally representative U.S. data to compare the differences in the frequency of contact with various family members, among black non-Hispanics, Hispanics, and white non-Hispanics. The central finding of this study is that Hispanics maintain more frequent contact with family than white non-Hispanics, but there is no difference between Hispanics and black non-Hispanics, with the exception of contact with fathers. The second study, which employs qualitative data collected from a metropolitan area in the Southwest U.S., examines the locus of educational aspirations and expectations among a sample of Hispanics and white non-Hispanics. Among other things, this study finds that Hispanic females were more likely than other participants to make statements that suggest the aspirations or expectations of significant others were a strong influence in the decision to attend college. This study further argues that this tendency is related to the acquiescent nature of traditional Hispanic gender norms associated with the familial concept of marianismo. Using nationally representative U.S. data, the final study finds that, other things being equal, Hispanic college students are more likely than non-Hispanic students to attend a college or university that is within fifty miles of their permanent residence. The study further finds that this tendency mediates the gap between …
Chicken embryos were chronically exposed to the ?1- blocker atenolol during one of three stages: mesonephros (E7-E9), mesonephros-metanephros (E11-E13), or metanephros (E15-E17). Mesonephros group hearts were larger than all other groups (P < 0.01). Mesonephros and metanephros group kidneys were larger than all remaining groups (P < 0.0001). The mesonephros group nephron number was ~40% lower than control values (P = 0.002). Glomerular areas were 26% and 18% larger than the control group in the mesonephros and metanephros groups, respectively (P < 0.001). These data suggest an E7-E9 critical window of cardiovascular and renal development for atenolol. Acute atenolol exposure in E15 embryos showed an increase in mean arterial pressure with all but the highest dose. All doses significantly decreased heart rate.
In 1863, Fort Bascom was built along the Canadian River in the Eroded Plains of Territorial New Mexico. Its unique location placed it between the Comanches of Texas and the Comancheros of the Sangre de Cristo Mountains. This post was situated within Comanchería during the height of the United States Army's war against the Southern Plains Indians, yet it has garnered little attention. This study broadens the scholarly understanding of how the United States Army gained control of the Southwest by examining the role Fort Bascom played in this mission. This includes an exploration of the Canadian River Valley environment, an examination of the economic relationship that existed between the Southern Plains Indians and the mountain people of New Mexico, and an account of the daily life of soldiers posted to Fort Bascom. This dissertation thus provides an environmental and cultural history of the Canadian River Valley in New Mexico, a social history of the men stationed at Fort Bascom, and proof that the post played a key role in the Army's efforts to gain control of the Southern Plains Indians. This study argues that Fort Bascom should be recognized as Texas' northern-most frontier fort. Its men were closer to the Comanche homeland than any Texas post of the period. Its records clearly show that the Army used Fort Bascom as a key forward base of operations against Comanches and Kiowas. An examination of Bascom's post returns, daily patrols, and major expeditions allows its history to provide a useful perspective on the nineteenth-century American Southwest.
The ethnographic study utilized the research techniques of observations, content analysis, and semi-structured interviews with tween participants (i.e., 9 through 13 year-old youth) during an 8-week literary blog project. Twenty-six participants created individual blog pages within a member-only classroom blog site that allowed for online communication between members. the blog project incorporated social networking applications with which youth frequently engage. the research questions ensured data regarding what facets participants found appealing and motivating during the project was collected. the questions allowed for determining if participants utilized peer blogs for reading material selection or repurposed the blogs to discuss other topics. Components of self-determination theory and engagement theory underlay the project design and aided in identifying motivational aspects of the data. Frequency tables outlined the identified patterns and structures of participants’ online activity. Participants found the ability to change the colors of their blog backgrounds and to design their individual blogs and the giving and receiving of feedback to be the two most appealing features of the project. Participants chose books from peer suggestions in the online world but also selected materials from recommendations they received in face-to-face interactions with their peers, their teacher, and the school librarian. Little evidence of repurposing the blog for social topics was observed. Participants engaged in discussions predominantly based around the books they were currently reading or had read. Implications for incorporating social networking applications within the classroom environment are discussed.
Blood Brothers as a media project works as a diptych. There are two – seemingly identical – pieces of the project that must both be experienced to understand the project as a whole. The first piece of the project is the linear documentary. This part captures the experience as it exists in the past. It exists as a master copy of the original story of mine and my foster brother’s relationship. This version of the story will always exist in the past. The second part is the live-cinema documentary performance. In this version of the story, my foster brother and I are no longer only images on a screen; we are living, breathing, and emotional subjects in the present. Our presence alters how the audience consumes the material.
The chakra system consists of seven energetic vortexes ascending up the spine that connect to every aspect of human existence. These vortexes become blocked and unblocked through the course of a life, these openings and closings have physiological and mental repercussions. Knowledge of these physical and mental manifestations, indicate where the chakra practitioner is in need, the practitioner can then manipulate their mind and body to create a desired outcome. These manipulations are based upon physical exercises and associative meditations for the purpose of expanding the human experience. As a poem can be thought of as the articulation of the human experience, and the chakra system can be thought of as a means to understand and enhance that experience, it is interesting and worthwhile leap to explore the how the chakras can develop and refresh the way we read and write poetry. This critical preface closely reads seven poems, one through each chakra, finding what the chakras unveil. Here, each chakra is considered for its dynamic creative capabilities and for its beneficial potentiality in the reading and writing process, finding each chakra provides tools: idea generators with the potential to free the poet from usual patterns of creativity while broadening vision and expressivity. In this collection of poetry poems are experiences chopped into consumable units that show and tell the constant negotiation between what is actually happening and the stories we tell ourselves about what is happening.
The purpose of the current study was to further our understanding of the subjective experience of middle-age African American women who are HIV+ and on highly active antiretroviral therapy, particularly how self-reported lipodystrophy (LD), levels of body dissatisfaction, body image quality of life, and engagement in disordered eating behaviors are related. Multiple regression, MANOVA, MANCOVA, ANOVA, and chi-square were utilized to test hypotheses. Results revealed that HIV+ and HIV- women did not differ significantly on their levels of body dissatisfaction or drive for thinness. When HIV+ women were examined in more detail a pattern emerged: women who self-reported fat hypertrophy had significantly higher levels of body dissatisfaction, bingeing, but not purging, and dietary restriction and fear of weight gain compared to women who did not self-report LD. About 75% of the sample was overweight or obese, and when BMI was controlled for, these differences persisted for body dissatisfaction and disordered eating behaviors for fat hypertrophy, but not fat atrophy. Overall, the findings indicate that the type of LD, specifically hypertrophy, is more related to body dissatisfaction and disordered eating behaviors, than LD in general. Clinical implications and limitations of these findings are discussed.
Branded content as an advertising tactic is a growing phenomenon that is not widely researched and is generally ambiguous in nature. This study uses qualitative methods to explain how branded content is defined, how it functions, and how it can influence a brand. Case studies of IKEA and Chevrolet were compared alongside four interviews with branded content professionals. the data collected suggests that branded content in structure and substance is varied, however it comprises engagement, the brand, and financial transaction. the data collected also suggested that brands take a variety of stances when controlling content to support their brand, and that branded content generally supports the intangible aspects of a brand, as opposed to product features.
In response to the increasing cost of college, colleges and universities are leveraging financial aid and academic support services to implement access and success programs intended to help financially disadvantaged students afford and persist through a baccalaureate degree program. This research is a study of the efficacy of one such program at a large research university in the southwestern region of the United States. The study sample included low-income program participants in four cohorts of freshmen enrolling for the first time in college from fall 2007 (Cohort 1) to fall 2010 (Cohort 4) and a comparison group of almost 400 low-income freshmen who enrolled for the first time in college in fall 2006 (the year prior to program implementation) for a sample total of over 2150 students. Approximately 64% were female, 36 % were males, over 60% were African American and Hispanic, and over 75% were first generation college students. Logistic regression was used to measure probability and odds of their academic success and retention in the first year of college utilizing gender, ethnicity, parental degree attainment, and program participation as the independent variables. The logistic regression models illustrated that participation in the program netted a consistently positive and significant impact on academic success across all cohorts, increasing the odds ratio for academic success no less than three times in favor of program participants vis-à-vis the comparison group. The statistical models illustrated that the program netted a slight positive impact on the odds of retention, particularly for African American students. Therefore, the principle implication that might be drawn from this study is that by strategically leveraging financial aid and academic support services, access and success programs can facilitate higher rates of academic success and retention for financially disadvantaged college students.
Britain during the Labour government's administration took a major step toward developing Iraq primarily due to the decision of Ernest Bevin, the Foreign Minister, to start a new British policy toward the Iraqi regimes that would increase the British influence in the area. This led to Bevin's strategy of depending on guiding the Iraqi regime to make economic and political reforms that would lead to social justice.
Broad band light emission ranging from the ultraviolet (UV) to the near infrared (NIR) has been observed from silicon nanoparticles fabricated using low energy (30-45 keV) metal and non-metal ion implantation with a fluence of 5*1015 ions/cm2 in crystalline Si(100). It is found from a systematic study of the annealing carried out at certain temperatures that the spectral characteristics remains unchanged except for the enhancement of light emission intensity due to annealing. The annealing results in nucleation of metal nanoclusters in the vicinity of Si nanoparticles which enhances the emission intensity. Structural and optical characterization demonstrate that the emission originates from both highly localized defect bound excitons at the Si/Sio2 interface, as well as surface and interface traps associated with the increased surface area of the Si nanocrystals. The emission in the UV is due to interband transitions from localized excitonic states at the interface of Si/SiO2 or from the surface of Si nanocrystals. The radiative efficiency of the UV emission from the Si nanoparticles can be modified by the localized surface plasmon (LSP) interaction induced by the nucleation of silver nanoparticles with controlled annealing of the samples. The UV emission from Si nanoclusters are coupled resonantly to the LSP modes. The non-resonant emission can be enhanced by electrostatic-image charge effects. The emission in the UV (~3.3 eV) region can also be significantly enhanced by electrostatic image charge effects induced by Au nanoparticles. The UV emission from Si nanoclusters, in this case, can be coupled without LSP resonance. The recombination of carriers in Si bound excitons is mediated by transverse optical phonons due to the polarization of the surface bound exciton complex. The low energy side of emission spectrum at low temperature is dominated by 1st and 2nd order phonon replicas. Broad band emission ranging from the UV to the …
This thesis was written to explore the structural case patterns of the Burushaski sentence and to examine the different participant coding systems which appear between noun marking and verb agreement. Verb suffixes follow nominative alignment patterns of agreement, while the verb prefix agrees with the affected argument as determined by semantic relations, as opposed to syntactic ones. The agent noun phrase is directly marked when highly active or volitional, suggesting a system of agent marking on the noun phrase and nominative alignment on the verb suffix. Nominative alignment also allows for a less marked presence of passive voice. Burushaski's agent marking is not entirely consistent; however, its nominative alignment is consistent. The conclusion is that Burushaski is not an ergative language at all.
This dissertation examines the role of Cardinal Giovanni Battista de Luca in the reform of nepotism in the seventeenth-century Catholic Church. Popes gave very large amounts of money to their relatives and the burden of nepotism on the Catholic Church was very onerous. The Catholic Church was crippled by nepotism and unable to carry out its traditional functions. Although Cardinal de Luca and Pope Innocent XI worked tirelessly to end nepotism, they were thwarted in their attempts by apprehension among the Cardinals concerning conciliarism and concerning the use of reform measures from the Council of Trent; by Gallicanism and the attempts of the French King to exercise power over the French Church; and by the entrenchment of nepotism and its long acceptance within the Church. Cardinal de Luca and Innocent XI were not able to push through reforms during their lifetimes but Pope Innocent XII was able to complete this reform and pass a reform Bull. This dissertation has two complementary themes. First, a confluence of circumstances allowed for the unfettered growth of nepotism in the seventeenth-century Church to the point of threatening the well-being of the Catholic Church. Reform was not undertaken until the threat to Church finances was severe. Secondly, two upstanding and honest reformers arose in the Catholic Church to correct the problem, de Luca and Innocent XI. The achievements of Cardinal de Luca, also an important reformer of the Canon Law, are almost unknown to an English-speaking audience.
The dissertation examined family caregivers’ perceptions of wandering behavior after their loved one has been diagnosed with ADRD (Alzheimer’s disease and related dementias). Semi-structured in-depth face-to-face interviews of a convenience sample of 22 caregivers in the Dallas metropolitan area were conducted. Responses were analyzed using a grounded theory approach. The use of qualitative methods facilitated the study of how caregivers of a loved one with ADRD understood and explained in their own voice the wandering behavior associated with the disease and how their views of the behavior informed the caregiving process. In particular, this research examined why some caregivers tend to recognize wandering behavior as significant early on while the ADRD patient is still living in the home (and community) and modifications can be made to keep him or her there despite the behavior, and why some caregivers do not. Findings indicated that caregivers were concerned about the general safety of their loved one. Precautions were taken within the home for conditions related to frailty, but were much less likely to be taken to address wandering behavior and its negative consequences. Three groups of caregivers emerged: (a) those who primarily reacted to their loved one’s problem behaviors including wandering, and intervened minimally; (b) those who were proactive, making modifications in their routines and environment to protect their loved one after a trigger event; and (c) those who had a mixed response, who did the best that they could with what they had. This last group of caregivers took on additional roles, modified their homes for safety, but environmental stressors and inadequate supports limited their interventions. Implications of the findings for aging in place and community, further research, policy-making, and practitioners are discussed.
This collection of personal essays about incest, abuse, and depression explores the lasting effects of an invisible childhood. The essays follow the protagonist from the age of five to her early twenties. Her brother, at a young age, becomes sexually abusive of her and her sisters, and her parents fail to protect their daughters. The family is divided as the older girls strive to defend their little sisters, while their parents attempt to excuse their son. When her brother is finally sent away, the protagonist is left to salvage what remains of her relationships with her parents.
Brucella ovis is a sexually transmitted, facultatively anaerobic, intracellular bacterial pathogen of sheep (Ovis aries) and red deer (Cervus elaphus). Brucella spp. infect primarily by penetrating the mucosa and are phagocytized by host macrophages, where survival and replication occurs. At least in some species, it has been shown that entry into stationary phase is necessary for successful infection. Brucella, like other alphaproteobacteria, lack the canonical stationary phase sigma factor ?s. Research on diverse members of this large phylogenetic group indicate the widespread presence of a conserved four-gene set including an alternative ECF sigma factor, an anti-sigma factor, a response regulator (RR), and a histidine kinase (HK). The first description of the system was made in Methylobacterium extorquens where the RR, named PhyR, was found to regulate the sigma factor activity by sequestering the anti-sigma factor in a process termed "sigma factor mimicry." These systems have been associated with various types of extracellular stress responses in a number of environmental bacteria. I hypothesized that homologous genetic sequences (Bov_1604-1607), which are similarly found among all Brucella species, may regulate survival functions during pathogenesis. To further explore the involvement of this system to conditions analogous to those occurring during infection, pure cultures of B. ovis cells were subjected to environments of pH (5 and 7) for 15, 30, and 45 minutes and oxidative (50mM H2O2) stress, or Spermine NONOate for 60 minutes. RNA was extracted and converted to cDNA andchanges in transcript levels of the sigma factor Bov1605 were measured using qPCR. Preliminary results indicate that under the exposure to Spermine NONOate there was little change in expression, but under oxidative stress expression of the sigma factor Bov1605 was 4.68-fold higher than that expressed under normal conditions. These results suggest that the sigma factor Bov1605 may be involved in oxidative stress defense during …
This thesis consists of one major section with two subsections. The first subsection investigates the activity of Arthrobacter globiformis aspartate transcarbamylase's specific activity with increasing concentrations of the enzyme's substrate. Dihydroorotase (DHOase) activity was also measured with increasing concentrations of the substrate dihydroorotate. The second subsection collected data in order to classify the enzyme, resulting in a classification into the category of class A ATCases with bifunctional ATCase-DHOase complexes. The thesis provides evidence to broaden understanding of the ATCase and DHOase enzymes for members of the family that Arthrobacter belongs to.
Electrocardiography (ECG) monitor is a medical device for recording the electrical activities of the heart using electrodes placed on the body. There are many ECG monitors in the market but it is essential to find the accuracy with which they generate results. Accuracy depends on the processing of the ECG signal which contains several noises and the algorithms used for detecting peaks. Based on these peaks the abnormality in the functioning of the heart can be estimated. Hence this thesis characterizes the ECG signal which helps to detect the abnormalities and determine the accuracy of the system.
A novel application of ionic liquid as a charge carrier for the analysis and detection of neutral organometallic complexes using a mass spectrometer has been presented. The mass spectrometer detects only charged compounds which raise a difficulty in analyzing a neutral molecule that lacks a basic site to associate with charge. Therefore, an effective way of providing charge has always been an area of keen interest in the field of mass spectrometry. Ionic liquids have a very fascinating property of forming a cation-? interaction with other molecules to give a charged complex. In order to take advantage of this, it is important to know the geometric structure of the complex. Advanced methodologies like hydrogen-deuterium exchange and computational calculations have been used assisting in better understanding of the structure of the ionic liquid complexes.
This study explores Charlotte Perkins Gilman’s use of the dramatic form to challenge Herbert Spencer’s social Darwinism by offering feminist adaptations of Darwin’s theories of natural and sexual selection. As she does in her career-defining manifesto, Women & Economics (1898), Gilman in her lesser-known plays deploys her own brand of reform Darwinism to serve the feminist cause. Despite her absence in histories of modern drama, Gilman actively participated in the establishment and development of this literary, historical, and cultural movement. After situating Gilman in the context of nineteenth-century naturalist theater, this thesis examines two short dramatic dialogues she published in 1890, “The Quarrel,” and “Dame Nature Interviewed,” as well as two full-length plays, Interrupted (1909) and the Balsam Fir (1910). These plays demonstrate Gilman’s efforts to use the dramatic form in her early plays to “rehearse” for Women & Economics, and in her later drama, to “stage” the theories she presents in that book.
The phenomenon of rescue organizations that devoted themselves specifically to hiding and saving Jewish children appeared throughout Nazi-occupied Western Europe (France, Belgium, and the Netherlands). Jewish and non-Jewish rescuers risked their lives to save thousands of children from extermination. This dissertation adds to the historiographical understanding of Holocaust resistance by analyzing the efforts of these child rescue organizations as a form of “survival resistance.” Researching the key aspects of traditional resistance (conscious intent, extensive organization, and effective turn-out) demonstrates that, while child rescue did not present armed resistance, it still was a form of active resistance against the Nazi Final Solution. By looking at rescuers’ testimonies and archival sources (from Yad Vashem, United States Holocaust Memorial Museum, Centre de documentation juive contemporaine, and Kazerne Dossin), this dissertation first outlines the extensive organization and intent of Jewish rescue groups, such as the Oeuvre de Secours aux Enfants (OSE) and Comité de défense des Juifs (CDJ), in France, Belgium, and the Netherlands. The second part looks at rescue organization and intent by Catholic, Protestant, and humanitarian groups. The dissertation concludes by discussing the effectiveness of organized child rescue. In the end, the rescue groups saved thousands of children and proofs that Child rescue in Nazi-occupied Western Europe was a valid--not to mention heroic--form of survival resistance.
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