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Chapter 48: Analytical Chemistry of Cobalt

Description: This report provides a detailed discussion of the analytical chemistry of cobalt, including an introduction, the properties of cobalt, the sampling of cobalt-bearing materials, the separation and isolation of cobalt, the detection and identification of cobalt, the determination of cobalt, and the specific methods for determining cobalt.
Date: 1961
Creator: Dale, John M. & Banks, Charles V.
Partner: UNT Libraries Government Documents Department
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Chemical Reactions In Crossed Molecular Beams

Description: Even in its present primitive stage the molecular beam method promises to open up many opportunities for detailed studies of reactive collisions. The early results described here have revealed several features inaccessible to the traditional methods of kinetics. We hope this program of beam studies will ultimately provide the basis for constructing a theory of the molecular mechanics of reactions. By borrowing what are now everyday techniques in nuclear physics (modulation of the beams; mass an… more
Date: July 1961
Creator: Herschbach, Dudley R.
Partner: UNT Libraries Government Documents Department
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The Chemical Thermodynamic Properties of Hydrocarbons and Related Substances: Properties of 100 Linear Alkane Thiols, Sulfides, and Symmetrical Disulfides in the Ideal Gas State from 0° to 1,000° K

Description: Report describing the chemical thermodynamic properties of 100 linear alkane thiols, sulfides, and symmetrical disulfides in their ideal gas state. Comprehensive tables of basic data are provided.
Date: 1961
Creator: Scott, Donald W. & McCullough, John P.
Partner: UNT Libraries Government Documents Department
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The Chemical Thermodynamic Properties of Hydrocarbons and Related Substances: The Use of n-Heptane as a Reference Substance for Low-Temperature Calorimetry

Description: From Introduction and Summary: "This bulletin presents the results obtained n-heptane by the petroleum thermodynamics laboratory of the Bartlesville, Okla., facility. Detailed results of five investigations are given; selected values if the low-temperature thermal properties are tabulated; and comparisons with results that were obtained in other laboratories are made. The findings of this extensive study will serve to characterize the low-temperature thermal data for over 100 compounds that wil… more
Date: 1961
Creator: Griffith, F. E.; Magnuson, M. O. & Toothman, G. J. R.
Partner: UNT Libraries Government Documents Department
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Chemistry of Anhydrous Systems Containing Hydrogen Fluoride and Nitrogen Oxides

Description: Nitrosyl and fluoride ions are formed in liquid anhydrous hydrogen fluoride when nitric oxide, nitrogen sesquioxide, nitrogen tetroxide, or nitrosyl fluoride, are dissolved. Vapor infrared analysis was used to study the solution composition and gaseous reaction products. These solutions react with metallic uranium, plutonium, zirconium, iron, and aluminum, as well as ceramic uranium oxide and uranium carbide, forming soluble nitrosyl metal fluoride complexes and liberating nitric oxide. The ura… more
Date: 1961
Creator: Horn, Frederick, L.; Bartlett, Charles, B. & Tivers, Richard, J.
Partner: UNT Libraries Government Documents Department
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Chlorotriammineplatinum(II) Ion : Acid Hydrolysis and Isotopic Exchange of Chloride Ligand

Description: Abstract: The acid hydrolysis of [Pt(NH3)3Cl] has been shown to occur to a measurable extent. for this reaction: [APt(NH3)cCl]+ + H2O [chemical equilibrium symbol with rate constant k-1 above and k1 below] [Pt(NH3)c(H2O)]++ + Cl-, the equilibrium quotient was measured at 25 degree C and 35 degree C. At 25 degree C this quotient was 8.4 x 10-5 at [Mu] (ionic strength) = 0 and 25 x 10-5 at [mu] = .318 M. This variation is consistent with the expected changes in activity coefficients. [Delta]H … more
Date: May 15, 1961
Creator: Aprile, Ferruccio. & Martin, Don S., Jr.
Partner: UNT Libraries Government Documents Department
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Close-Capture Adsorption System For Remote Radioisotope Chemistry

Description: Molecular sieves are synthetic zeolites which, when dehydrated, contain a network of empty pores and cavities that constitute almost 50% of the total volume of the crystals. They have the unique property of adsorbing within these cavities only those molecules that are small enough to pass through the pores of the crystals, Molecular sieves have a very strong affinity for water and other polar molecules. It is this selective property plus their stability and reasonable cost that make them of int… more
Date: August 17, 1961
Creator: Spencer, Neil C.; Parsons, Thomas C. & Howe, Patrick W.
Partner: UNT Libraries Government Documents Department
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The Closest Packing of Spheres (A Unifying Basis for Crystal Structures)

Description: "An intuitive approach to the understanding of crystal structures is presented in terms of the concept of the closest packing of spheres. The qualitative features of the concept are sorted out and correlated by successively treating single, double, triple, and multiple layered arrays of closest packed spheres" (p. ix).
Date: July 30, 1961
Creator: Gehman, William G.
Partner: UNT Libraries Government Documents Department
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The Cold Pressing of Sinterable UOâ‚‚

Description: The intent of this work was to explore more fully the pressing of sinterable UO2 powders into cylindrical compacts in the hope that a more precise prediction of green density in terms of powder properties, pressure, and geometry could be evolved.
Date: March 27, 1961
Creator: Levey, R. P., Jr.
Partner: UNT Libraries Government Documents Department
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A Comparative Study of Two Grades of BeO

Description: Pechiney and Brush UOX BeO differ markedly in fabrication behaviour, only Brush UOX being readily sinterable. A comparative study of the two powders has shown few outstanding differences in powder properties. Both are of high purity but contain free and combined moisture to the extent of about 1.5 per cent. Pechiney BeO has a larger mean crystallite size (0.2 — 0.3μ) than Brush UOX (0.1 — 0.15μ) and a larger range of crystallite size, and both contain a small proportion of crystallites of size … more
Date: November 1961
Creator: Reeve, Keith Desmond, 1928- & Ramm, E. J.
Partner: UNT Libraries Government Documents Department
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Comparison of Radiation-Induced Graft Copolymerization Untilizing Electron Accelerators and Isotope Sources as Radiation Initiators

Description: "A comparison of the grafting of a 2:1 molar mixture of methacrylic acid and styrene to both polypropylene film and fabric using CO60 source and electron accelerator as sources of ionizing radiation is made on the basis of mutual or simultaneous grafting and post-irradiation grafting.
Date: January 31, 1961
Partner: UNT Libraries Government Documents Department
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Comparison of Radiation-Induced Graft Copolymerization Untilizing Electron Accelerators and Isotope Sources as Radiation Initiators

Description: "A comparison of grafting to two thicknesses of polypropylene film is made using isotope and electron accelerator initiation. The results indicate that the grafting of methacrylic acid: styrene to polypropylene is mainly a surface reaction."
Date: September 12, 1961
Creator: Odian, George; Oliver, William F. & Pierre, Karl
Partner: UNT Libraries Government Documents Department
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Comparison of Radiation-Induced Graft Copolymerization Untilizing Electron Accelerators and Isotope Sources as Radiation Initiators

Description: "Graft polymers were made by Co60 mutual irradiation of mixtures of styrene and methyl acrylate in contact Teflon. These graft copolymers were analyzed by infra-red absorption and their composition determined. The composition of the graft copolymer formed from styrene and methyl acrylate was different from that which is predicted by the copolymer composition equation."
Date: May 8, 1961
Partner: UNT Libraries Government Documents Department
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Comparison of Radiation-Induced Graft Copolymerization Untilizing Electron Accelerators and Isotope Sources as Radiation Initiators

Description: "A brief examination of the post irradiation grafting of machine irradiated polyethylene film with acrylic acid monomer was made. Evidence of postgrafting was detected in samples that had been irradiated to a total dose of 10 Mrads at a dose rate of 0.01 Mrad/sec. and then exposed to a 25% purified acrylic acid solution in benzene for periods of 1 to 4 days."
Date: October 17, 1961
Partner: UNT Libraries Government Documents Department
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Compilation of Techniques Used By Vallecitos Radioactive Materials Laboratory

Description: Equipment and techniques for remote examination of irradiated fuel assemblies applicable to the Maritime Program are described. The following subjects are covered: visual and photographic examination, dimensional measurements, gamma activity scanning, fission gas release and fuel rod void volume determinations, density measurements, metallographic examination, and radiochemical burnup analysis.
Date: February 1961
Creator: Brandt, F. A.; Mathay, P. W. & Zimmerman, D. L.
Partner: UNT Libraries Government Documents Department
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Composition of Shale-Oil Naphtha

Description: From Summary: "This report describes the analysis if shale-oil naphthas and discusses their composition, based on investigation by the Federal Bureau of Mines. Individual compounds identified in this investigation. are listed, together with those reported previously in the literature. Also, quantitative data are given on the occurrence of individual compounds and groups of related compounds."
Date: 1961
Creator: Dinneen, G. U.; Van Meter, R. A.; Smith, J. R.; Bailey, C. W.; Cook, G. L.; Allbright, C. S. et al.
Partner: UNT Libraries Government Documents Department
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Computations for AGS Experimental Beams: Description of Computer Program

Description: Description of a computer program which optimizes the locations and strengths of magnets for experimental beams at the Brookhaven AGS written for the IBM 7090 computer. Layout, method, and routines are given particular attention, and representative data cards are shown.
Date: December 15, 1961
Creator: Baker, Winslow F.
Partner: UNT Libraries Government Documents Department
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Conceptual Design of an In-Pile Package Loop for Fast Reactor Fuel Testing

Description: Report issued by the APDA over a design study conducted on an "in-pile package loop for use as a reactor fuel test facility" (p. 5). The results are presented and discussed. This report includes tables, and illustrations.
Date: July 28, 1961
Creator: Blessing, W. G.; Balsbaugh, R. R.; Bloomfield, D. E.; Busch, J. S.; Hennig, R. J.; Jens, W. H. et al.
Partner: UNT Libraries Government Documents Department
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Conceptual design of an in-pile package loop for sodium-cooled thermal reactor fuel testing

Description: Report issued by the APDA over a design study "of a facility for testing sodium-cooled thermal reactor fuel assemblies in the Advanced Test Reactor" (p. 5). The results are presented and discussed. This report includes tables, and illustrations.
Date: September 15, 1961
Creator: Blessing, W. G.
Partner: UNT Libraries Government Documents Department
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