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Abstract: Our combined experimental and theoretical analysis of the shifts, with particle size, of core-level binding energies (BE's) of metal nanoparticles on insulating supports, shows that these shifts have an important initial state contribution arising, in large part, because of lattice strain. This contribution of BE shifts has not been recognized previously. Lattice strain changes the chemical bonding between the metal atoms and this change induces BE shifts.
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Richter, B.; Kuhlenbeck, H.; Freund, H. J. & Bagus, Paul S.Cluster Core-Level Binding-Energy Shifts: The Role of Lattice Strain,
article,
July 2004;
[College Park, Maryland].
(https://digital.library.unt.edu/ark:/67531/metadc78320/:
accessed April 25, 2024),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT College of Arts and Sciences.
