Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands Metadata

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Title

  • Main Title Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands

Creator

  • Author: Boyer, Julie L.
    Creator Type: Personal
    Creator Info: University of Illinois at Urbana-Champaign
  • Author: Cundari, Thomas R., 1964-
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: DeYonker, Nathan J.
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Rauchfuss, Thomas B.
    Creator Type: Personal
    Creator Info: University of Illinois at Urbana-Champaign
  • Author: Wilson, Scott R.
    Creator Type: Personal
    Creator Info: University of Illinois at Urbana-Champaign

Publisher

  • Name: American Chemical Society
    Place of Publication: [Washington, D.C.]

Date

  • Creation: 2009-12-19

Language

  • English

Description

  • Content Description: Article discussing the redox activation of alkene ligands in platinum complexes with non-innocent ligands.
  • Physical Description: 8 p.

Subject

  • Keyword: alkene ligands
  • Keyword: platinum complexes
  • Keyword: non-innocent ligands

Source

  • Journal: Inorganic Chemistry, 48(2), American Chemical Society, December 19, 2009, pp. 1-8

Citation

  • Publication Title: Inorganic Chemistry
  • Volume: 48
  • Issue: 2
  • Page Start: 638
  • Page End: 645
  • Peer Reviewed: True

Collection

  • Name: UNT Scholarly Works
    Code: UNTSW

Institution

  • Name: UNT College of Arts and Sciences
    Code: UNTCAS

Rights

  • Rights Access: public

Resource Type

  • Article

Format

  • Text

Identifier

  • DOI: 10.1021/ic8017248
  • Archival Resource Key: ark:/67531/metadc77133

Degree

  • Academic Department: Chemistry
  • Academic Department: Center for Advanced Scientific Computing and Modeling

Note

  • Display Note: Reprinted with permission from Inorganic Chemistry. Copyright 2009 American Chemical Society.
  • Display Note: Abstract: The reactivity of metal olefin complexes with non-innocent ligands (NILs) was examined. Treatment of PtCl2(diene) with the deprotonated catechol or aminophenol ligands afforded the corresponding Pt(NIL)(diene) complexes. The Pt(ͭBAfPh)(COD), Pt(tBAfPh)(nbd), and Pt(O2C6H2tBu2)(COD) (H2tBAfPh = 2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol, H2O2C6H2tBu2 = 3,5-di-tert-butylcatechol) complexes were examined by cyclic voltammetry. Treatment of Pt(tBAfPh)(COD) or Pt(tBAfPh)(ndb) with AgPF6 afforded the imino-semiquinones [Pt(tBAfPh)(COD)] PF6 or [Pt(tBAfPh)(nbd)]PF6 respectively. The [Pt(tBAfPh)(COD)] complex was unreactive toward nucleophiles, whereas the oxidized derivative, [Pt(tBAfPh)(COD)]PF6, rapidly and stereospecifically added alkoxides at the carbon trans to the phenolate. The Pt(tBAfPh)(COD), [Pt(tBAfPh)(COD)]PF6, Pt(tBAfPh)(C8H12OMe), and [Cp2Co][Pt-(tBAfPh)(C8H12OMe)] complexes were characterized crystallographically.
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