A T-Shaped Three-Coordinate Nickel(l) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes

Description:

This article discusses a T-shaped three-coordinate nickel(l) carbonyl complex and the geometric preferences of three-coordinate d9 complexes.

Creator(s):
Creation Date: October 5, 2005
Partner(s):
UNT College of Arts and Sciences
Collection(s):
UNT Scholarly Works
Usage:
Total Uses: 282
Past 30 days: 14
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Creator (Author):
Eckert, Nathan A.

University of Rochester

Creator (Author):
Dinescu, Adriana

University of North Texas

Creator (Author):
Cundari, Thomas R., 1964-

University of North Texas

Creator (Author):
Holland, Patrick L.

University of Rochester

Publisher Info:
Publisher Name: American Chemical Society
Place of Publication: [Washington, D.C.]
Date(s):
  • Creation: October 5, 2005
Description:

This article discusses a T-shaped three-coordinate nickel(l) carbonyl complex and the geometric preferences of three-coordinate d9 complexes.

Degree:
Department: Chemistry
Note:

Reprinted with permission from Inorganic Chemistry. Copyright 2005 American Chemical Society.

Note:

Abstract: A three-coordinate diketiminate-nickel(l) complex with a carbonyl ligand has been characterized using EPR and IR spectroscopies and X-ray crystallography. The T geometry (bending from the sterically favored C2v structure) contrasts with that of isosteric d9 copper(ll) complexes. DFT calculations on a truncated model reproduce experimental geometries, implying that the geometric differences are electronic in nature. Analysis of the charge distribution in the complexes shows that the geometry of the three-coordinate d9 complexes is affected by differential charge donation of the ligands to the metal center.

Physical Description:

3 p.

Language(s):
Subject(s):
Keyword(s): three-coordinate complexes | transition metals
Source: Inorganic Chemistry, 2005, Washington DC: American Chemical Society, pp. 7702-7704
Partner:
UNT College of Arts and Sciences
Collection:
UNT Scholarly Works
Identifier:
  • DOI: 10.1021/ic0510213 |
  • ARK: ark:/67531/metadc77127
Resource Type: Article
Format: Text
Rights:
Access: Public
Citation:
Publication Title: Inorganic Chemistry
Volume: 44
Issue: 22
Page Start: 7702
Page End: 7704
Pages: 3
Peer Reviewed: Yes