Activity Coefficients at Infinite Dilution for Organic Solutes Dissolved in Three 1-Alkyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide Ionic Liquids Bearing Short Linear Alkyl Side Chains of Three to Five Carbons

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Article discussing activity coefficients at infinite dilution for organic solutes dissolved in three 1-alkyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquids bearing short linear alkyl side chains of three to five carbons.

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Mutelet, Fabrice; Hassan, El-Sayed R. E.; Stephens, Timothy W.; Acree, William E. (William Eugene) & Baker, Gary A. July 30, 2013.

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Article discussing activity coefficients at infinite dilution for organic solutes dissolved in three 1-alkyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquids bearing short linear alkyl side chains of three to five carbons.

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9 p.

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Reprinted with permission from the Journal of Chemical and Engineering Data. Copyright 2013 American Chemical Society.

Abstract: In this work, we report the infinite dilution activity coefficients (γ∞₁,₂) of 39 to 43 diverse organic solutes dissolved in three 1-alkyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide ionic liquids (IL) homologues bearing propyl, butyl, and pentyl n-alkyl side chains, respectively, as determined by inverse gas chromatography at temperatures from 323 K to 343 K. The organic solutes include various (cyclo)alkanes, alkenes, alkynes, aromatic hyrdocarbons, alcohols, thiophene, ethers, nitroalkenes, and ketones. The measured retention data were further transformed to gas-to-IL and water-to-IL partition coefficients using established thermodynamic approaches based upon the corresponding gas-to-water partition coefficients of the test solutes. Both sets of partition coefficients were interpreted with a modified form of the basic Abraham general solvation parameter model. The mathematical correlations obtained by regression analysis back-calculated the observed gas-to-IL and water-to-IL partition coefficient data to within average standard deviations of 0.104 and 0.136 log units, respectively.

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  • Journal of Chemical and Engineering Data, 58(8), American Chemical Society, July 30, 2013, pp. 1-9

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  • Publication Title: Journal of Chemical and Engineering Data
  • Volume: 58
  • Issue: 8
  • Page Start: 2210
  • Page End: 2218
  • Peer Reviewed: Yes

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  • July 30, 2013

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  • Aug. 30, 2013, 3:35 p.m.

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  • Feb. 7, 2024, 1:55 p.m.

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Mutelet, Fabrice; Hassan, El-Sayed R. E.; Stephens, Timothy W.; Acree, William E. (William Eugene) & Baker, Gary A. Activity Coefficients at Infinite Dilution for Organic Solutes Dissolved in Three 1-Alkyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide Ionic Liquids Bearing Short Linear Alkyl Side Chains of Three to Five Carbons, article, July 30, 2013; [Washington, DC]. (https://digital.library.unt.edu/ark:/67531/metadc179669/: accessed April 23, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT College of Arts and Sciences.

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