Determination of the Solubilizing Character of 1-Methoxyethyl-1-Methylpiperidinium Tris(Pentafluoroethyl)Trifluorophosphate Based on the Abraham Solvation Parameter Model

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Article on determination of solubilizing character of 1-methoxyethyl-1-methylpiperidinium tris(pentafluoroethyl) trifluorophosphate based on the Abraham solvation parameter model.

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11 p.

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Twu, Pamela; Anderson, Jared L.; Stephens, Timothy W.; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.) January 2012.

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Article on determination of solubilizing character of 1-methoxyethyl-1-methylpiperidinium tris(pentafluoroethyl) trifluorophosphate based on the Abraham solvation parameter model.

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11 p.

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Copyright © 2012, European Chemical Bulletin. All rights reserved.

Abstract: Chromatographic retention data were measured for a chemically diverse set of organic solutes on an anhydrous 1-methoxy-ethyl-1-methylpiperidinium tris(pentafluoroethyl)trifluoro-phosphate, ([MeoeMPip]+[FAP]-), stationary phase at both 323 K and 353 K. The experimental retention factors were combined with previously published thermodynamic data and gas-to-water partition coefficient data to yield gas-to-anhydrous ionic liquid (IL) and water-to-anhydrous IL partition coefficients. The three sets of partition coefficient data were analyzed in accordance with the Abraham model. The Abraham model correlations that were determined in the present study describe the observed gas-to-([MeoeMPip]+[FAP]-) (log K) and water-to-([MeoeMPip]+[FAP]-) (log P) partition coefficient data to within average standard deviations of approximately 0.13 and 0.16 log units, respectively.

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  • European Chemical Bulletin, 1(6), Deuton-X Ltd., January 2012, pp. 1-11

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  • Publication Title: European Chemical Bulletin
  • Volume: 1
  • Issue: 6
  • Page Start: 212
  • Page End: 222
  • Peer Reviewed: Yes

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  • January 2012

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  • June 28, 2013, 2:11 p.m.

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  • Nov. 30, 2023, 11:43 a.m.

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Thumbnail image of item number 1 in: 'Determination of the Solubilizing Character of 1-Methoxyethyl-1-Methylpiperidinium Tris(Pentafluoroethyl)Trifluorophosphate Based on the Abraham Solvation Parameter Model'.
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Twu, Pamela; Anderson, Jared L.; Stephens, Timothy W.; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.). Determination of the Solubilizing Character of 1-Methoxyethyl-1-Methylpiperidinium Tris(Pentafluoroethyl)Trifluorophosphate Based on the Abraham Solvation Parameter Model, article, January 2012; [Hungary]. (https://digital.library.unt.edu/ark:/67531/metadc172359/: accessed April 25, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT College of Arts and Sciences.

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