Comments on the Competitive Preferential Solvation Theory

Description:

Article commenting on the competitive preferential solvation theory.

Creator(s):
Creation Date: 1990  
Partner(s):
UNT College of Arts and Sciences
Collection(s):
UNT Scholarly Works
Usage:
Total Uses: 56
Past 30 days: 4
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Creator (Author):
Acree, William E. (William Eugene)

University of North Texas

Creator (Author):
Zvalgzne, Anita I.

University of North Texas

Creator (Author):
Tucker, Sheryl A. (Sheryl Ann)

University of North Texas

Publisher Info:
Place of Publication: [Cambridge, England]
Date(s):
  • Creation: 1990
Description:

Article commenting on the competitive preferential solvation theory.

Degree:
Department: Chemistry
Note:

Journal of the Chemical Society, Faraday Transactions, 1990, 86:2, pp. 307-309, http://pubs.rsc.org/en/content/articlehtml/1990/ft/ft9908600307

Note:

Abstract: Simple additive relationships for the physico-chemical properties of a solute dissolved in binary solvent mixtures are developed from the competitive preferential solvation model. Additive expressions for solute mole fraction solubility and logarithm of solute solubility are mathematically identical to equations derived previously from the microscopic partition and basic nearly ideal binary solvent models. Calculated values based on the various additive relationships are compared to carbazole solubilities in ten binary solvent mixtures containing dibutyl ether with n-hexane, n-heptane, n-octane, cyclohexane, cyclo-octane, methylcyclohexane, iso-octane, n-hexadecane, squalane and t-butylcyclohexane.

Physical Description:

3 p.

Language(s):
Subject(s):
Keyword(s): preferential solvation theory | binary solvent mixtures
Source: Journal of the Chemical Society, Faraday Transactions, 1990, Cambridge: Royal Society of Chemistry (Great Britain), pp. 307-309
Partner:
UNT College of Arts and Sciences
Collection:
UNT Scholarly Works
Identifier:
  • DOI: 10.1039/FT9908600307
  • ARK: ark:/67531/metadc157300
Resource Type: Article
Format: Text
Rights:
Access: Public
Citation:
Publication Title: Journal of the Chemical Society, Faraday Transactions
Volume: 86
Issue: 2
Page Start: 307
Page End: 309
Peer Reviewed: Yes