Abraham Model Correlations for Transfer of Neutral Molecules and Ions to Sulfolane

Description:

Article on Abraham model correlations for the transfer of neutral molecules and ions to sulfolane.

Creator(s):
Creation Date: October 15, 2011
Partner(s):
UNT College of Arts and Sciences
Collection(s):
UNT Scholarly Works
Usage:
Total Uses: 105
Past 30 days: 4
Yesterday: 1
Creator (Author):
Stephens, Timothy W.

University of North Texas

Creator (Author):
De la Rosa, Nohelli E.

University of North Texas

Creator (Author):
Saifullah, Mariam

University of North Texas

Creator (Author):
Ye, Shulin

University of North Texas

Creator (Author):
Chou, Vicky

University of North Texas

Creator (Author):
Quay, Amanda N.

University of North Texas

Creator (Author):
Acree, William E. (William Eugene)

University of North Texas

Creator (Author):
Abraham, M. H. (Michael H.)

University College London

Publisher Info:
Publisher Name: Elsevier Science Ltd.
Place of Publication: [Amsterdam, Netherlands]
Date(s):
  • Creation: October 15, 2011
Description:

Article on Abraham model correlations for the transfer of neutral molecules and ions to sulfolane.

Degree:
Department: Chemistry
Note:

This is the authors' manuscript version of the article. Reprinted from the Fluid Phase Equilibria, 2011, 523:1-2, pp. 214-220. Reprinted with permission from Elsevier Science Ltd. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2011.06.037

Note:

Abstract: Data have been compiled from the published literature on the partition coefficients of solutes and vapors into anhydrous sulfolane. The logarithms of the water-to-sulfolane partition coefficients, log P, and gas-to-sulfolane partition coefficients, log K, were correlated with the Abraham solvation parameter model. The derived correlations described the observed log P and log K values for solutes dissolved in sulfolane to within average standard deviations of 0.14 log units or less. The log P correlation was extended to include the partition of ions by inclusion of a cation-solvent and an anion-solvent term.

Physical Description:

20 p.

Language(s):
Subject(s):
Keyword(s): partition coefficients | sulfolane | nonelectrolyte solutes | ionic solutes | Abraham model correlations
Source: Fluid Phase Equilibria, 2011, Amsterdam: Elsevier Science Ltd., pp. 30-35
Partner:
UNT College of Arts and Sciences
Collection:
UNT Scholarly Works
Identifier:
  • ARK: ark:/67531/metadc157293
Resource Type: Article
Format: Text
Rights:
Access: Public
Citation:
Publication Title: Fluid Phase Equilibria
Volume: 309
Issue: 1
Page Start: 30
Page End: 35
Peer Reviewed: Yes