Mathematical correlations for describing enthalpies of solvation of organic vapors and gaseous solutes into ionic liquid solvents Page: 13
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TABLE 1. Cation-Specific and Anion-Specific Equation Coefficients for the Abraham
Model Enthalpy of Solvation Correlation (Eqn.6)Ion
CATIONSa
[MEIm]+
(N=257)b
[BMIm]+
(N= 179)
[MHIm]
(N=101)
[MOIm]
(N= 86)
[M3BAm]+
(N=51)
[M2EIm]+
(N=37)Cion
Sion
-6.007
(0.829)
-6.223
(0.648)
-5.543
(0.691)
-7.758
(0.915)
-7.255
(0.978)
-0.592
(1.584)3.914
(1.578)
-1.307
(1.420)
0.111
(1.591)
1.088
(2.174)
1.352
(2.060)
4.122
(2.117)-15.247
(1.765)
-8.699
(1.944)
-6.842
(2.032)
-4.778
(2.656)
-9.405
(2.750)
-15.849
(2.242)-20.601
(2.167)
-20.815
(2.189)
-19.484
(2.3 84)
-21.886
(2.711)
-22.715
(3.096)
-23.339
(2.654)-7.607
(1.720)
-9.869
(2.350)
-10.780
(2.379)
-6.993
(2.612)
-7.191
(3.180)
-7.193
(2.034)lion
-7.153
(0.251)
-7.072
(0.175)
-7.795
(0.188)
-7.448
(0.277)
-6.761
(0.240)
-8.667
(0.446)13
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Grubbs, Laura M.; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.). Mathematical correlations for describing enthalpies of solvation of organic vapors and gaseous solutes into ionic liquid solvents, article, September 20, 2010; [New York, New York]. (https://digital.library.unt.edu/ark:/67531/metadc155634/m1/13/: accessed April 24, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT College of Arts and Sciences.