Correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase

Description:

Article discussing research on the correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase.

Creator(s):
Creation Date: July 25, 2009
Partner(s):
UNT College of Arts and Sciences
Collection(s):
UNT Scholarly Works
Usage:
Total Uses: 138
Past 30 days: 6
Yesterday: 0
Creator (Author):
Sprunger, Laura M.

University of North Texas

Creator (Author):
Achi, Sai S.

University of North Texas

Creator (Author):
Acree, William E. (William Eugene)

University of North Texas

Creator (Author):
Abraham, M. H. (Michael H.)

University College London

Creator (Author):
Hoekman, David

David Hoekman Consulting, Inc.

Creator (Author):
Leo, Albert J.

BioByte Corp.

Publisher Info:
Publisher Name: Elsevier Science Ltd.
Place of Publication: [Amsterdam, Netherlands]
Date(s):
  • Creation: July 25, 2009
Description:

Article discussing research on the correlation and prediction of solute transfer to chloroalkanes from both water and the gas phase.

Degree:
Department: Chemistry
Note:

This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2009.04.012

Note:

Abstract: Data have been compiled from the published literature on the partition coefficients of solutes and vapors into chloroform, carbon tetrachloride, dichloromethane and 1-chlorobutane from both water and from the gas phase. The logarithms of the water-to-chloroalkane (log P) and gas-to-chloroalkane partition coefficients (log K) are correlated with the Abraham solvation parameter model. The derived correlations describe the observed log P and log K values within standard deviations of about 0.13-0.20 log units. For chloroform and carbon tetrachloride, the derived correlations were validated using training set and test set analyses.

Physical Description:

71 p.

Language(s):
Subject(s):
Keyword(s): carbon tetrachloride | chloroform | dichloromethane | 1-chlorobutane | partition coefficients | molecular solute descriptors
Source: Fluid Phase Equilibria, 2009, Amsterdam: Elsevier Science Ltd., pp. 144-162
Partner:
UNT College of Arts and Sciences
Collection:
UNT Scholarly Works
Identifier:
  • DOI: 10.1016/j.fluid.2009.04.012 |
  • ARK: ark:/67531/metadc155630
Resource Type: Article
Format: Text
Rights:
Access: Public
Citation:
Publication Title: Fluid Phase Equilibria
Volume: 281
Issue: 2
Page Start: 144
Page End: 162
Peer Reviewed: Yes