Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Chloroform and 1,2-dichloroethane Based on the Abraham Model

Description:

This article discusses enthalpy of solvation correlations for gaseous solutes dissolved in chloroform and 1,2-dichloroethane based on the Abraham model.

Creator(s):
Creation Date: September 15, 2007
Partner(s):
UNT College of Arts and Sciences
Collection(s):
UNT Scholarly Works
Usage:
Total Uses: 75
Past 30 days: 4
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Creator (Author):
Mintz, Christina

University of North Texas

Creator (Author):
Burton, Katherine

University of North Texas

Creator (Author):
Acree, William E. (William Eugene)

University of North Texas

Creator (Author):
Abraham, M. H. (Michael H.)

University College London

Publisher Info:
Publisher Name: Elsevier Science Ltd.
Place of Publication: [Amsterdam, Netherlands]
Date(s):
  • Creation: September 15, 2007
Description:

This article discusses enthalpy of solvation correlations for gaseous solutes dissolved in chloroform and 1,2-dichloroethane based on the Abraham model.

Degree:
Department: Chemistry
Note:

This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://dx.doi.org/10.1016/j.fluid.2007.06.016

Note:

Abstract: Enthalpy of solvation data have been compiled from the published literature for more than 80 solutes dissolved in chloroform and 1,2-dichloromethane. Mathematical correlations based on the Abraham general solvation parameter model are developed for describing the experimental solvation enthalpies to within standard deviations of 2.10 kJ/mol (chloroform) and 1.72 kJ/mol (1,2-dichloroethane). Division of the measured values into a training set and a test set shows that there is no bias in predictions, and that the estimative capability of the correlations is better than 2.5 kJ/mol.

Physical Description:

25 p.

Language(s):
Subject(s):
Keyword(s): enthalpy of solvation | enthalpy of transfers | mathematical correlations | partition coefficients | solvation parameter model
Source: Fluid Phase Equilibria, 2007, Amsterdam: Elsevier Science Ltd., pp. 191-198
Partner:
UNT College of Arts and Sciences
Collection:
UNT Scholarly Works
Identifier:
  • DOI: 10.1016/j.fluid.2007.06.016
  • ARK: ark:/67531/metadc155628
Resource Type: Article
Format: Text
Rights:
Access: Public
Citation:
Publication Title: Fluid Phase Equilibria
Volume: 258
Issue: 2
Page Start: 191
Page End: 198
Peer Reviewed: Yes