Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Dimethyl Sulfoxide and Propylene Carbonate Based on the Abraham Model Page: 29
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TABLE 2. Values of the gas to propylene carbonate solvation enthalpy in kJ/mole at 298
K for 106 solutes, together with the solute descriptors
Solute E S A B L V Exp Ref
Ethane 0.000 0.000 0.000 0.000 0.492 0.3904 -5.73 62
Propane 0.000 0.000 0.000 0.000 1.050 0.5313 -6.44 62
2-Methylpropane 0.000 0.000 0.000 0.000 1.409 0.6722 -9.71 62
Butane 0.000 0.000 0.000 0.000 1.615 0.6722 -10.83 62
Pentane 0.000 0.000 0.000 0.000 2.162 0.8131 -17.57 62
Hexane 0.000 0.000 0.000 0.000 2.668 0.9540 -21.00 62
Heptane 0.000 0.000 0.000 0.000 3.173 1.0949 -24.66 62
Octane 0.000 0.000 0.000 0.000 3.677 1.2358 -31.41 27
Decane 0.000 0.000 0.000 0.000 4.686 1.5176 -37.97 27
Cyclohexane 0.305 0.100 0.000 0.000 2.964 0.8454 -24.18 43
Methylcyclopentane 0.225 0.100 0.000 0.000 2.816 0.8454 -23.14 27
Methylcyclohexane 0.244 0.060 0.000 0.000 3.319 0.9863 -26.22 27
1-Butene 0.100 0.080 0.000 0.070 1.491 0.6292 -17.60 23
1-Hexene 0.078 0.080 0.000 0.070 2.572 0.9110 -24.81 27
1-Octene 0.094 0.080 0.000 0.070 3.568 1.1928 -30.56 27
Cyclohexene 0.395 0.200 0.000 0.100 3.021 0.8025 -27.01 27
1,3-Butadiene 0.320 0.230 0.000 0.100 1.543 0.5862 -19.30 23
Methyl acetate 0.142 0.640 0.000 0.450 1.911 0.6057 -32.50 63
Ethyl acetate 0.106 0.620 0.000 0.450 2.314 0.7466 -34.51 63
Propyl acetate 0.092 0.600 0.000 0.450 2.819 0.8875 -38.46 63
Vinyl acetate 0.223 0.640 0.000 0.430 2.152 0.7040 -34.28 63
Butyl acetate 0.071 0.600 0.000 0.450 3.353 1.0284 -41.22 63
tert-butyl acetate 0.025 0.540 0.000 0.470 2.802 1.0284 -35.42 63
Isobutyl acetate 0.052 0.570 0.000 0.470 3.161 1.0284 -36.13 63
Pentyl acetate 0.067 0.600 0.000 0.450 3.844 1.1693 -45.45 63
Hexyl acetate 0.056 0.600 0.000 0.450 4.351 1.3102 -47.36 63
Methyl propanoate 0.128 0.600 0.000 0.450 2.431 0.7466 -35.21 63
Ethyl propanoate 0.087 0.580 0.000 0.450 2.807 0.8875 -37.79 63
Propyl propanoate 0.070 0.560 0.000 0.450 3.338 1.0284 -40.40 63
Butyl propanoate 0.058 0.560 0.000 0.470 3.833 1.1693 -46.95 63
Methyl butanoate 0.106 0.600 0.000 0.450 2.893 0.8875 -38.08 63
Ethyl butanoate 0.068 0.580 0.000 0.450 3.271 1.0284 -39.85 63
Propyl butanoate 0.050 0.560 0.000 0.450 3.783 1.1693 -44.43 63
Methyl pentanoate 0.108 0.600 0.000 0.450 3.392 1.0284 -40.89 63
Ethyl pentanoate 0.049 0.580 0.000 0.450 3.769 1.1693 -43.63 63
Ethyl hexanoate 0.043 0.580 0.000 0.450 4.251 1.3102 -48.30 63
Ethyl heptanoate 0.027 0.580 0.000 0.450 4.733 1.4511 -47.61 63
Ethyl isobutyrate 0.034 0.550 0.000 0.470 3.072 1.0284 -37.63 63
Dimethyl carbonate 0.142 0.540 0.000 0.570 2.328 0.6644 -37.49 65
Diethyl carbonate 0.060 0.580 0.000 0.530 3.412 0.9462 -42.47 65
Acetone 0.179 0.700 0.040 0.490 1.696 0.5470 -30.79 64
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Mintz, Christina; Acree, William E. (William Eugene); Burton, Katherine & Abraham, M. H. (Michael H.). Enthalpy of Solvation Correlations for Gaseous Solutes Dissolved in Dimethyl Sulfoxide and Propylene Carbonate Based on the Abraham Model, article, July 2007; [New York, New York]. (https://digital.library.unt.edu/ark:/67531/metadc155626/m1/29/: accessed April 25, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT College of Arts and Sciences.