Effects of Layer Double Hydroxide Nanoclays on the Toxicity of Copper to Daphnia Magna

Description:

Nanoparticles may affect secondary pollutants such as copper. Layer Double Hydroxides (LDH) are synthetically produced nanoparticles that adsorb copper via cation exchange. Pretreatment of copper test solutions with LDH nanoparticles followed by filtration removal of LDH nanoparticles demonstrated the smallest LDH aggregates removed the most copper toxicity. This was due to increased surface area for cation exchange relative to larger particle aggregates. Co-exposure tests of copper chloride and clay were run to determine if smaller clay particles increased copper uptake by D. magna. Coexposure treatments had lower LC50 values compared to the filtration tests, likely as a result of additive toxicity. LDH nanoclays do reduce copper toxicity in Daphnia magna and may serve as a remediation tool.

Creator(s): Blake, Deanne Renee
Creation Date: May 2012
Partner(s):
UNT Libraries
Collection(s):
UNT Theses and Dissertations
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Publisher Info:
Publisher Name: University of North Texas
Publisher Info: www.unt.edu
Place of Publication: Denton, Texas
Date(s):
  • Creation: May 2012
Description:

Nanoparticles may affect secondary pollutants such as copper. Layer Double Hydroxides (LDH) are synthetically produced nanoparticles that adsorb copper via cation exchange. Pretreatment of copper test solutions with LDH nanoparticles followed by filtration removal of LDH nanoparticles demonstrated the smallest LDH aggregates removed the most copper toxicity. This was due to increased surface area for cation exchange relative to larger particle aggregates. Co-exposure tests of copper chloride and clay were run to determine if smaller clay particles increased copper uptake by D. magna. Coexposure treatments had lower LC50 values compared to the filtration tests, likely as a result of additive toxicity. LDH nanoclays do reduce copper toxicity in Daphnia magna and may serve as a remediation tool.

Degree:
Level: Master's
PublicationType: Thesi
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Subject(s):
Keyword(s): Nanoclays | nanoparticle | daphnia
Contributor(s):
Partner:
UNT Libraries
Collection:
UNT Theses and Dissertations
Identifier:
  • ARK: ark:/67531/metadc115048
Resource Type: Thesis or Dissertation
Format: Text
Rights:
Access: Public
Holder: Blake, Deanne Renee
License: Copyright
Statement: Copyright is held by the author, unless otherwise noted. All rights Reserved.